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Circular birefringence means different refractive indices for opposite circular polarizations. In a transparent isotropic medium, their relative wave phase changes rotate the direction of transmitted linear polarization; optical activity gives the solution measurement and convention.

For fixed circular eigenvectors ${\mathbf{u}}_{\pm }=(1,\mp i{)}^{\mathsf{T}}/\sqrt{2}$, let $P_{\pm }={\mathbf{u}}_{\pm }{\mathbf{u}}_{\pm }^{†}$. A uniform optical medium with amplitude propagation coefficients ${\gamma }^{\pm }$ has the displayed Jones matrix. Put $\gamma =({\gamma }^{+}+{\gamma }^{-})/2$ and $\delta =({\gamma }^{+}-{\gamma }^{-})/2$. ThenThe sum of the two modal exponentials supplies a hyperbolic cosine, not its reciprocal. The determinant is $e^{-2\gamma z}$, and $\mathcal{J}(z_1+z_2)=\mathcal{J}(z_1)\mathcal{J}(z_2)$. Real modal coefficients give circular dichroism; purely imaginary coefficients give lossless circular birefringence. Complex modal labels do not have an intrinsic numerical ordering.

The Faraday effect is magnetic field-induced circular birefringence: opposite circular polarizations acquire different wave phases, rotating transmitted linear polarization. For a transparent medium with isotropy before applying the magnetic field, in the linear magnetic-response regime at fixed vacuum wavelength ${\lambda }_0$ and temperature $T$,Here $V$ is the Verdet constant, $L$ is the material path length, and $B_{\parallel }$ is the applied magnetic flux density component along the ray. This $\mathbf{B}$ is the external bias, distinct from the oscillating magnetic field of the light itself. Michael Faraday discovered the effect in 1845.^[ref]

Fix the sign before using the formula. On the forward path choose a right-handed Cartesian coordinate system, propagation along $+z$, and measure $\theta$ from $+x$ toward $+y$ for the electric field's oscillation line. Positive $\theta$ is counterclockwise in the $x$-right, $y$-up end view seen from $z>0$, looking toward the source. Then $B_{\parallel }=B_z$ and positive $V$ means positive rotation for positive $B_z$. This convention differs from the clockwise-positive convention in optical rotation. A linear polarization line is unchanged by $180^{\circ }$; a measured orientation determines accumulated rotation only modulo $\pi$, unless continuity selects a branch.

For uniform $B_{\parallel }$, the formula reduces to $\theta =VBL$. Its appeal is that a weak change of refractive index becomes a visible change of orientation. Magnetic reversal measurement of Faraday rotation turns this into an inference of $V$ or of the magnetic field path integral. Faraday rotation on a round trip explains the directional behavior used by an optical isolator. In an astronomical cold plasma, the high-frequency limit instead leads to the rotation measure law $\theta =\mathrm{RM}{\lambda }_0^2$; that wavelength dependence is not a universal law for transparent solids.

The factor of one half follows from superposition, without assigning ambiguous right/left names to the circular polarizations. Use the complex amplitude convention $\mathrm{Re}[\mathbf{E}(z)e^{-i\omega t}]$ and fixed transverse unit vectorsFor equal transmitted wave amplitudes, let the accumulated wave phases be ${\varphi }_{+}$ and ${\varphi }_{-}$. Their sum isThe common wave phase $\bar{\varphi }$ sets the timing of the electric field oscillation; the real direction in parentheses sets its linear polarization. Opposite circular polarizations have changed their relative wave phase, yet their sum still oscillates along a line. Unequal transmitted wave amplitudes would generally give elliptical polarization instead.

In a uniform sample, with refractive indices $n_{+},n_{-}$ and vacuum wavenumber $k_0=2\pi /{\lambda }_0$, the phase difference is $(k_{+}-k_{-})L=k_0(n_{+}-n_{-})L$. ThusThe second relation identifies the small signed circular birefringence responsible for the rotation in this basis. Unlike a waveplate, whose separated modes have orthogonal linear polarizations, this ideal rotator has modes with opposite circular polarizations.

Linear birefringence means that two orthogonal linear polarizations have different refractive indices. Their different propagation phases produce phase retardation. In a lossless waveplate, with fast-axis angle $\theta$ and slow-minus-fast retardation $\delta$, the Jones matrix, up to a common phase, isusing time dependence $e^{-i\omega t}$. Circular birefringence instead has circular eigenpolarizations.

Optical activity is the ability to rotate the direction of linear polarization of transmitted light. In an achiral solvent, the two members of an enantiomer pair have equal and opposite optical rotations at the same wavelength, temperature and concentration. The measured angle concerns a bulk sample; it is not a geometric rotation of the molecules.^[ref]

The rotating object in this description is the direction along which the electric field oscillates. At each position the transmitted light can still have linear polarization: its electric field moves back and forth along a line, while the orientation of that line changes along the sample. Nothing requires the molecules to turn bodily through the observed angle. This makes polarimetry a bridge from molecular chirality to a visible bulk measurement, and, with a suitable calibration, a way to follow concentration or the balance of enantiomers.

In a transparent, isotropic chemical solution, natural optical rotation can be understood as circular birefringence: the two opposite circular polarizations accumulate different wave phases, and their equal-amplitude sum remains linearly polarized along a rotated direction. Circular dichroism instead means unequal absorption of those components and can produce elliptical polarization. These are related responses, not interchangeable measurements. General birefringence need not produce this simple rotation of linear polarization.^[ref]

General pure state. Use time dependence $e^{i(kz-\omega t)}$. The most general nonzero Jones vector can be writtenThere are four real parameters in the full complex field. Removing overall intensity $A^2$ and the unobservable common phase $\chi$ leaves two real degrees of freedom for pure polarization, $\alpha$ and $\delta$. Their endpoint degeneracies simply reflect the fact that the phase of a vanishing component is irrelevant. A single Jones vector cannot represent partially polarized light.

Three linear polarizers. Define the transmission axis ${\mathbf{a}}_{\theta }=(\cos \theta ,\sin \theta {)}^T$. An ideal linear polarizer has Jones matrix $P_{\theta }={\mathbf{a}}_{\theta }{\mathbf{a}}_{\theta }^T$. For definiteness label $(1,-i{)}^T/\sqrt{2}$ as right-circular in the chosen convention; reversing the handedness convention changes no intensity below. The first polarizer produces $(1,0{)}^T/\sqrt{2}$. The intermediate polarizer and final $y$ analyzer then giveso Malus's law givesThe maximum is $1/8$ at $\theta =\pi /4+m\pi /2$, and the transmission vanishes at $\theta =m\pi /2$. The first polarizer accounts for an initial factor $1/2$; retaining that factor is essential when quoting transmission relative to the incident circularly polarized beam.

Waveplate and quarter-wave matrix. A lossless waveplate has linear birefringence: its orthogonal fast and slow axes have indices $n_f<n_s$. A thickness $L$ produces slow-minus-fast phase retardationResolving the incident Jones vector into the plate axes, advancing the two phases and transforming back gives, up to a common phase,A quarter-wave plate has $\delta =\pi /2$ modulo $2\pi$. With $c_{\theta }=\cos \theta$ and $s_{\theta }=\sin \theta$, its Jones matrix is thereforeIn particular $Q(0)=\mathrm{diag}(1,i)$. Equal incident components along the two axes acquire a relative quarter-cycle phase, converting $45^{\circ }$ linear polarization to circular polarization; an incident component along either principal axis stays linearly polarized.

Half-wave replacement. A half-wave plate has $\delta =\pi$ and henceIt converts the $x$-polarized output of the first polarizer to a linear state at angle $2\theta$. The final $y$ analyzer givesThe maximum is $1/2$, because the ideal half-wave plate loses no light after the first polarizer.

Quarter-wave replacement. The transmitted $y$ amplitude is $(1-i)c_{\theta }{s}_{\theta }/\sqrt{2}$, givingMore generally, the retarder gives $I_{\mathrm{out}}/I_{\mathrm{in}}=\frac{1}{2}{\sin }^2(\delta /2){\sin }^2(2\theta )$. All three requested curves have the same zeros and angular period, but different heights:

Preparing an arbitrary ellipse. Yes: two rotatable quarter-wave plates already suffice. Let the input left-circular state be ${\mathbf{J}}_L=(1,i{)}^T/\sqrt{2}$. Up to an overall phase, any target pure polarization can be parameterized by its polarization ellipse:Here $\beta$ is the major-axis orientation, and $\eta$ sets the signed minor-to-major semiaxis ratio $\tan \eta$. First note directly from $Q(\theta )$ thatChoose the two fast-axis angles asThe first quarter-wave plate produces linear light at $\beta +\eta$. In the axes of the second, its components are $(\cos \eta ,\sin \eta )$; the second gives precisely ${\mathbf{J}}_{\mathrm{target}}$. This proves pure-polarization preparation with two quarter-wave plates, including the linear and circular limiting cases. A half-wave plate can also rotate the axes, but is not required. The phrase about left-handed input is understood as left-circular light in this construction; the explicit vector fixes the convention.

Switchable retardation. The electro-optic Kerr effect induces linear birefringence quadratic in a static transverse electric field. Defining the coefficient $K$ by $\Delta n={\lambda }_{0}K{E}_{\mathrm{dc}}^2$, its phase retardation isThe two eigenpolarizations are linear, parallel and perpendicular to the applied field. Thus an appropriate field produces a switchable quarter-wave plate:The sign of $K$ determines which axis is fast. Switching the field off removes the induced retardation, assuming no residual birefringence.

The Faraday effect instead gives circular birefringence for a longitudinal magnetic field. The two circular eigenmodes acquire different phases, rotating a linear polarization throughwith sign set by the handedness convention and the Verdet constant $V$. Its Jones matrix in the linear basis is a real rotation, up to a common phase. It preserves the ellipticity of a pure state, so a linear input remains linear. A $\pi /2$ phase difference between circular eigenmodes rotates a linear state by $\pi /4$; it does not make it circular. The Kerr device supplies the switchable quarter-wave plate; a Faraday rotator alone does not.

Write ${\gamma }^{\pm }=-i{\beta }^{\pm }$, $\overline{\beta }=({\beta }^{+}+{\beta }^{-})/2$ and $\chi =({\beta }^{+}-{\beta }^{-})z/2$. Then $\gamma z=-i\overline{\beta }z$ and $\delta z=-i\chi$. With $\cosh (-i\chi )=\cos \chi$ and $\sinh (-i\chi )=-i\sin \chi$, the corrected matrix becomesThe scalar is a common propagation wave phase and the real rotation matrix rotates the input linear polarization through $\chi$. There is no attenuation and no generated ellipticity: the field map is a unitary matrix. The two circular eigenmodes accumulate different wave phases, giving circular birefringence and optical activity.

The correct unfactored matrix remains finite where $\cos \chi =0$. In contrast, the printed $\mathrm{sech}$ form would give $e^{i\overline{\beta }z}{\sec }^2\chi$ times the rotation matrix, including unphysical divergent gain in this stipulated lossless case. This provides a direct physical check on the correction in part (d).

Birefringence means that two independent polarization eigenmodes have different refractive indices at the same frequency and propagation direction. The rotatory-power formula relevant here requires circular birefringence: the eigenmodes are opposite circular polarizations. General linear birefringence instead introduces phase retardation between linearly polarized components and need not rotate every incident linear polarization through one common angle.

Use the complex amplitude convention $\mathrm{Re}[\mathbf{E}{e}^{-i\omega t}]$ and transverse unit vectors ${\mathbf{e}}_1,{\mathbf{e}}_2$. DefinePropagation through thickness $d$ adds phases ${\varphi }_{\pm }=(2\pi /{\lambda }_0)n_{\pm }d$, where ${\lambda }_0$ is the vacuum wavelength. Recombining the two components givesThus the rotation and the specific rotatory power per unit length areThe units of $\rho$ are $\mathrm{rad}{\mathrm{m}}^{-1}$. The sign follows the specified circular basis and viewing convention. Equal attenuation of the two eigenmodes has been assumed; unequal attenuation also produces elliptical polarization.

Flint glass is approximately optically isotropic without an applied magnetic field. A longitudinal magnetic field changes the motion of its bound Electrons: the magnetic part of the Lorentz force acts with opposite sense on the two circularly rotating components of a driven electronic oscillation. Their optical response, and hence their refractive indices, split. Equivalently, the transverse permittivity tensor acquires a field-odd antisymmetric contribution whose eigenvectors are opposite circular polarizations.

The resulting circular birefringence gives Faraday rotation. For a weak longitudinal bias it is linear in the field:Here ${\rm Y}$ is the Verdet constant and $L$ the path length. The magnetic field breaks time-reversal symmetry, which is why this rotation is nonreciprocal. Reversing the bias reverses the rotation; reversing propagation while keeping the bias fixed does not undo it when physical polarization directions are compared in fixed laboratory axes. A transverse magnetic bias can have different, higher-order effects; the setup here is the longitudinal Faraday effect.

The rotatory power is the rotation of transmitted linear polarization per unit path length, in $\mathrm{rad}{\mathrm{m}}^{-1}$. With equally transmitted circular eigenmodes $({\mathbf{e}}_1\mp i{\mathbf{e}}_2)/\sqrt{2}$ and time convention $e^{-i\omega t}$, their accumulated phase difference gives $\theta =({\varphi }_{+}-{\varphi }_{-})/2$. For uniform circular birefringence, $\rho =\pi (n_{+}-n_{-})/{\lambda }_0$. Generic linear birefringence need not admit one rotation angle common to all incident polarization directions. In a weak longitudinal Faraday effect, $\rho =V{B}_{\parallel }$, with signed Verdet constant $V$.