The adapted process is bounded by , so every is an integrable random variable, indeed a square-integrable random variable. Independence of from and its continuous uniform distribution give
This calculation with a random threshold is justified by conditioning on the -measurable value of : for a fixed , the Lebesgue integral equals . More formally, independence integrates the bounded Borel measurable function over its second coordinate. Therefore
which verifies the martingale property for this filtration.
Since , the conditional expectation of the squared martingale difference is
The law of total expectation yields . In particular, for every .
For each ,
since is adapted. This verifies directly that is a stopping time.
Set . On , the random walk is at some integer strictly between and . If its next steps are all , it must hit within that block. These future steps are independent of and have probability of being all . Hence
The law of total expectation and mathematical induction give the geometric tail bound from a uniform escape probability:
Therefore . In fact this also proves by grouping the tail-sum formula into blocks of length . No assertion of independence between successive survival events is needed.
The function is a concave function, and is integrable since . The concave form of the conditional Jensen inequality gives
The random variables and have the same probability distribution, so . Using the law of total expectation, the nonnegative difference between the right and left sides of the inequality has zero expectation. It must vanish almost surely. Therefore
The equality comes from the distributional assumption as well as the conditional Jensen inequality.
Put . Given , its conditional expected value is and its conditional variance is , since is then fixed. The law of total expectation and law of total variance give
The two scores are dependent: the law of total covariance gives . Adding their two variances without that covariance term would give an incorrect total.
The law of total expectation gives . The law of total variance separates the two sources of randomness:
Substitution gives
The binomial thinning of a geometric random variable identity supplies a further check: itself has a zero-based geometric distribution with success probability .
For an integrable random variable and a partition of a sample space , the law of total expectation states
It follows by writing and using . Integrability justifies the countable sum. The same equality is valid with nonnegative, possibly infinite expectations when .
Let be the absorption time. Its expectation is finite: from every interior state, a string of at most successive left moves reaches , and the probability of such a string is at least . Hence the Markov property gives , a geometric tail bound, and .
For , one step is always spent before absorption or the remaining walk. Apply first-step analysis and the law of total expectation to the three possible first moves. The conditional expectations of the remaining absorption time are , respectively; independence of future moves gives the same law as a fresh random walk from the new position. Thus
which rearranges to
The term also appears when the walk stays at , because staying still consumes a step.
For , condition on . Its independence from the preserves their independent common distribution, so part (ii) gives
For , this is , agreeing with . By the law of total expectation,
This proves the probability generating function of an independent random sum. For nonnegative outside , the same argument is valid whenever the right side is finite, by Tonelli's theorem for nonnegative sums. For signed or complex , a sufficient absolute-convergence condition is ; it holds automatically on . Outside this domain, mere evaluation of an analytically extended expression is not a substitute for existence of the probability generating function.
Given , there are exactly independent opportunities to stay awake, each with probability . Hence
The standard binomial distribution formulas are and . The Poisson distribution formulas are , , and therefore . By the law of total expectation,
Using the definition of covariance,
Thus and are not independent, even though the separate awake and asleep counts produced by Poisson thinning are independent.
For an integrable random variable , the law of total expectation on the finite or countable measurable partition is
Here for positive-probability cells; null cells contribute zero and need no conditional value. The series is absolutely convergent since its absolute terms sum to at most . For a nonnegative , the same identity is valid with possible value .
Use the measurable partition for , omitting any null cells. For , the random variable is bounded, so the law of total expectation applies without moment assumptions. Conditional on , the sum contains exactly terms. Independence of from the whole sequence preserves their joint law under this conditioning; independence of the then gives
For the empty sum is zero and the empty product is one, in agreement with the formula. Therefore the probability generating function of an independent random sum is
The conditional expectation given an event of positive probability is
Apply the law of total probability to each event :
This is the law of total expectation. Interchanging the sums is justified by nonnegative terms, for example by Tonelli theorem, so it remains valid when the expectation is infinite.
Let count successful journeys before the first breakdown. The probability of surviving the first journeys is the tail probability . For , independence gives
where again . For a nonnegative integer-valued random variable, the tail-sum formula follows by writing and interchanging nonnegative sums. Therefore
As a separate first-day check using the law of total expectation, if , then . Solving gives the same finite value. This counts only successful journeys, excluding the failed journey.
Condition first on . A Poisson distribution with parameter has conditional probability generating function , including the degenerate zero case when . The law of total expectation gives
For the inner argument is in , so this use of the generating function is justified directly. The result is a compound Poisson distribution with a Poisson distribution of unit parameter for each jump, also called a Neyman Type A distribution in this case. It is generally not an ordinary Poisson distribution.
The finite-partition form of the law of total expectation states
Because the events form a partition of a sample space of the sample space, pointwise. Multiply by and use linearity of expectation to obtain
An event of zero probability contributes zero to the middle expression and is omitted from the final expression, so no undefined conditional expectation is multiplied by zero.
Complete the square in the joint probability density function:
The density therefore factors as the standard normal distribution density for times a normal distribution density in with mean and variance . It follows that , , and . Symmetry gives . By the law of total expectation,
Consequently the covariance of this bivariate normal distribution is . This calculation derives the result from the given density.
A partition of a sample space is a finite or countable family of pairwise disjoint events whose union is the whole sample space. For an integrable random variable, the partition form of the law of total expectation is
Zero-probability cells contribute zero and are omitted because elementary event-conditioning on them is undefined. The formula also holds with extended nonnegative values when . Integrability makes the signed series legitimate in the finite-expectation case.
Photoelectron peak overlap and resolution Created 2026-10-18 Updated 2026-10-20
Choose two hypothetical environments A and B of one chemical element, with line centers and . Model each line by a normalized Gaussian function with common standard deviation , and stipulate integrated count weights , . On the binding energy axis , the normalized count density is
All energies in this expression use electronvolts. Each component's integrated area equals its count weight, and . There is no background, statistical counting fluctuation, or additional emission feature in this stipulated model. These choices deliberately isolate photoelectron peak overlap and resolution.
Figure 1.
Two chemical components can blend into one maximum
. Original arbitrary normalized data, not a measured spectrum. The chosen Gaussian mixture distribution has centers and and integrated count weights and . Changing the common standard deviation from to changes the number of maxima from two to one, while leaving the centroid at . These count weights are not mole fractions; a chemical abundance inference requires cross section and analyzer-response calibration. Details.
Direct integration, or the law of total expectation applied to the component label, gives the centroid
The centroid lies between the chemical environments and is not either component's binding energy. Expanding within each component, the odd cross term integrates to zero. The resulting variance is
For the variance is and the two maxima are separated. For it is and there is one maximum. Each Gaussian's full width at half maximum is , approximately and respectively. The chemical separation remains in both cases. The number of visible maxima therefore does not equal the number of chemical components.
One interpretation of this change is additional independent Gaussian instrument blur. The convolution of probability densities adds the variances, so broadening to requires response standard deviation . A normalized response with zero mean preserves the centroid and integrated counts. Real line shapes and backgrounds can depart from this model, and separating hidden components is an inverse problem; a plausible fit does not alone establish uniqueness.
Finally, count weights describe detection. In a simple response model, let denote the number of emitting sites sampled in environment , its effective photoionization cross section, and the probability that its emitted electron contributes to the selected measured line. Then
The common factor includes exposure. Here includes escape from the sample, analyzer transmission and detection. Count weights equal site fractions only if the relevant response factors are equal or corrected. They are not automatically molecular mole fractions; different molecules can supply different numbers of the selected emitting sites. In an original example, equal site numbers with give the plotted count ratio despite a site ratio.