Conservation of quantum probability Created 2026-09-24 Updated 2026-09-24
If the probability current of a normalizable wavefunction vanishes at spatial infinity, integrating the probability continuity equation over all space shows that the total probability is constant in time.
For a bound state, : the Hamiltonian operator is nonnegative, and an energy at or above the exterior potential does not give a nonzero normalizable wavefunction. The Time-independent Schrodinger equation and the hard wall at zero therefore give
Continuity of the wavefunction and its derivative at the finite step gives . Put and . The matching equation becomes
It requires , so solutions lie in the intervals for . Squaring, with that sign restriction retained, gives . On each such interval this function increases strictly from to infinity: its derivative is , because the second term in the numerator is positive there. Each interval therefore contributes exactly one bound state if and only if . These are the bound-state thresholds for a square well with one hard wall.
Exactly one normalizable bound state exists if and only if
The printed strict upper inequality misses the threshold case. At the upper endpoint, the prospective second state has and . Its exterior solution is constant or linear, hence is not square-integrable unless zero; the zero exterior solution and matching would force the entire solution to vanish. Thus there is still exactly one bound state at that endpoint. The strict upper inequality is valid if threshold values are additionally excluded, but that exclusion is not part of the stated assumptions.
For a wavefunction , the probability density and probability current are
Multiply the Schrodinger equation by , multiply its complex conjugate by , and subtract. The real potential energy terms cancel, leaving
which is the probability continuity equation .
For a stationary state, , so and is constant in space. A normalizable wavefunction has vanishing current at spatial infinity, forcing this constant to be zero. By contrast the nonnormalizable plane wave
has stationary density and nonzero current
when .
For a one-dimensional wavefunction,
The probability continuity equation is
For a stationary state , the probability density is independent of time, so and the probability current is constant in space.
For the plane wave
one obtains
This is a momentum eigenstate with momentum and, when it satisfies the free Schrodinger equation, energy . Its constant density and current describe a spatially uniform beam carrying probability in the sign of . It is not a normalizable wavefunction, so it represents an idealized state rather than a localized particle.
The one-dimensional Time-dependent Schrodinger equation for a wavefunction in a real potential is
Multiplying this equation by , multiplying its complex conjugate by , and subtracting gives the probability continuity equation
If and its first derivative decay sufficiently rapidly as , then the probability current vanishes at both ends. Integrating the continuity equation and using the fundamental theorem of calculus yields
This conservation of quantum probability is required by the Born rule: once a normalizable wavefunction has total probability one, its time evolution must preserve that normalization.
For the stated Gaussian wave packet, put . Since
its squared modulus is
The Gaussian integral then gives
which is independent of time, as required.