Latent-to-sensible heat ratio 2026-10-05
The latent-to-sensible heat ratio is the reciprocal of the Stefan number defined by . Large means that phase change uses much more energy than changing temperature by .
Past exam of the mathematics course of the University of Cambridge 2002 iii Paper 55 1 Solution Created 2026-10-03 Updated 2026-10-14
Write , and . The requested model neglects density differences and uses the same thermal transport coefficients in the interfacial balances. Let and . With no imposed heat gradient in the fresh liquid, its temperature remains . The prescribed linear temperature in the ice isThe salt and temperature fields in the lower liquid satisfy diffusion equations, and . For constant interfacial values and the proposed similarity solution, their decaying solutions areThese follow by substituting a variable into the diffusion equation, which gives ; integrating gives the complementary error function. Their values at and at infinity give the required boundary data.
For the upward-moving fresh-water/ice boundary, the Stefan condition is : negative means fresh water freezes. At the lower boundary the signed heat balance isSalt cannot enter the pure ice. With no bulk liquid motion its interfacial conservation law isThe derivatives and interface velocities areDefine . Substitution into all three balances givesTogether with , these determine the interfacial constants. In particular .
The physical branch has . Since is negative at negative arguments, the salt relation gives : lower-surface melting dilutes the brine. Combining the two heat balances eliminates the ice gradient and givesThus . The interface is at local liquidus equilibrium with diluted brine, while the undiluted far-field brine remains above its own liquidus. The similarity model describes a layer starting with zero thickness, or the long-time limit when an initial finite thickness no longer sets the dominant scale.
For the small-diffusivity-ratio limit, put and , keeping and the imposed concentrations fixed. Seek and . Then and . The upper heat balance givesIn the lower balance the two terms of order must cancel, givingConsequentlyand . Adding the two temperature differences yields . The negative root isThe resulting lies strictly between zero and . The salt relation therefore determines a finite negative , confirming its scaling. The top interface travels on the thermal scale , whereas the lower melting interface travels on the shorter solutal scale . This is the brine-ice sandwich with disparate diffusion scales; is the latent-to-sensible heat ratio, the reciprocal of the usual sensible-to-latent Stefan number convention.
The sketches show constant fresh-water temperature, a declining linear ice temperature, and a much broader thermal than solutal boundary layer in the brine. Concentration is zero in freshwater and pure ice, jumps to across the lower interface, and rises to . Accordingly the local liquidus is on the salt-free side, jumps to and falls rapidly to . In the phase diagram, the brine starts on the liquidus at and ends above it at ; the pure ice has concentration zero, and the interface tie-line joins it to the diluted brine.
Physically, the cold saline liquid permits freshwater to freeze above, but salt lowers the liquidus and allows the existing ice to melt into brine below even though that brine is colder than . Dilution raises the lower interfacial freezing temperature. Heat released by upper freezing supplies the lower melting and the conductive loss to the colder deep brine. With , upper freezing exceeds lower melting and the ice layer thickens as .
Past exam of the mathematics course of the University of Cambridge 2009 iii Paper 80 4 Solution Created 2026-10-03 Updated 2026-10-14
Let be the particle radius and the supercooling. Use spherical symmetry, constant thermal properties, equal phase densities , and negligible fluid advection. Let be latent heat per unit mass, the liquid specific heat, its thermal conductivity and its thermal diffusivity. The exterior temperature satisfies the radial heat equationwith for , and as .
The Gibbs-Thomson effect gives curvature-induced melting-temperature depression. For a spherical interface writewhere is solid-liquid interfacial energy per area and the factor two is the sphere's curvature . Here in the thermodynamic formula is an absolute temperature. The notation also permits a given measured capillary coefficient without requiring its microscopic derivation.
In the one-phase Stefan problem, the solid has no internal heat flux and the Stefan condition isThe sign follows from heat balance: positive outward liquid heat flux releases latent heat as the solid grows. If the solid's thermal storage is retained, its temperature instead satisfies its own radial heat equation, , and . The two-phase condition is . It reduces to the one-phase condition in the quasistatic limit because a regular harmonic temperature inside a sphere is spatially constant. An initial solid temperature profile is additional data for a fully time-dependent two-phase problem.
Two reciprocal Stefan number conventions are common. The large parameter appropriate to the requested slow-interface limit is the latent-to-sensible heat ratioIt measures the energy required for phase change relative to cooling or heating by the supercooling. The often-used sensible-to-latent definition is . Thus “large Stefan number” here means large , not large in that other convention.
The thermal diffusion time for scale is , whereas the interface time is . More explicitly, with , and slow time , the liquid equation isFor , temperature therefore equilibrates before the radius changes appreciably. The quasistatic spherical Stefan problem with capillarity has a harmonic exterior temperature, fixed by its interface and far-field values:The small initial diffusion adjustment is omitted at this order. Inserting into the Stefan condition givesThis is the critical radius for a supercooled spherical seed. For , the interface is warmer than the liquid and loses heat, driving growth. For , its curvature-depressed interface temperature is colder than the liquid, so heat enters and the solid melts. At , the uniform temperature supplies an equilibrium radius. It is unstable, since the radius-velocity derivative there is . For a growing particle with , increases asymptotically as .
For a subcritical particle the radius decreases monotonically and remains below . HenceIt cannot remain positive beyond , proving finite-time extinction of a subcritical spherical seed. The exact extinction time in the reduced model is obtained by separating variables:With , this isNear disappearance, the capillary term dominates and , so . For , the lifetime is ; it diverges logarithmically as , consistently with the unstable equilibrium. The threshold and lifetime above are conclusions of the specified large- quasistatic continuum model, rather than an assertion that its approximation is uniform through every finite- shrinking-interface transient.
Past exam of the mathematics course of the University of Cambridge 2010 iii Paper 72 2 Solution Created 2026-10-03 Updated 2026-10-14
Use the one-sided thermal conduction model encoded by the requested dispersion relation: neglect solid-side perturbation heat flux, take equal phase densities, and let the normal point from solid into liquid. Write the isotropic linear kinetic undercooling law using the solidification attachment mobility :Here is solid-liquid surface energy, is the sum of principal curvatures, and is absolute temperature. Positive curvature convex into liquid lowers the equilibrium freezing temperature through the Gibbs--Thomson relation. The planar base state has .
Set and defineThe paper's is the latent-to-sensible heat ratio, the reciprocal of the common Stefan number convention. Below, velocities, lengths and growth rates are dimensionless in these scales. In the travelling coordinate , the liquid heat equation gives , while the bounded solid steady field is constant. Matching a decaying liquid profile to the Stefan condition givesThe kinetic undercooling condition is . ThusThe speed is constant for , determined by and the attachment coefficient in the specified scales. Thermal diffusivity sets the exponential decay length , not the selected speed. Including solid-side perturbation conduction would change the stability equation below.
For linear stability analysis, corrugate the interface to and write the liquid perturbation as . The liquid heat equation requiresFor this graph the linearized curvature is . Evaluate the temperature on the displaced interface: its perturbation is . The kinetic undercooling law therefore givesLikewise the derivative evaluated at the displaced surface is , with . The Stefan condition at perturbation order readsElimination proves the one-sided kinetic solidification dispersion:The destabilizing term comes from a protrusion encountering colder liquid; capillarity and kinetic relaxation oppose it.
At , and the base liquid has no thermal contrast generated by latent heat. The interface obeys : positive surface energy damps all nonzero modes, while is neutral at this order. Here the thermal perturbation amplitude vanishes, so the auxiliary decay exponent is immaterial to that pure kinetic relaxation. At , and the formal limit givesFor it has a negative real branch and no growing branch; at the interface branch is neutral. Strictly, is a singular endpoint of the travelling profile: no finite-width stationary exponential connects to the far-field value zero. These stability statements describe the limit of the travelling-front model.
For , assume at small wavenumber. ExpandSubstituting into the dispersion relation cancels on both sides and givesAt the capillary stability threshold for a kinetic freezing front , continuing the same expansion gives : the nonzero long waves are damped even at threshold.
For large wavenumber, multiply the dispersion relation by and eliminate using the thermal equation. The exact algebraic form isIt prevents the uncontrolled replacement when itself is of order . In the usual small-capillarity range the leading results areFor the second result, set in the cubic; its quadratic-order balance gives . Thus positive capillarity stabilizes sufficiently short waves. If also and , the useful reduced approximation isits finite terms should not be treated as a uniform expansion for arbitrary fixed .
For completeness, large dimensionless capillarity has different balances. At , and . For , , so . At , the real branch reaches : for its growth rate is , and for that endpoint is exact. For at this boundary, or for , the selected real- normal mode ceases to exist at sufficiently large wavenumber; the full diffusion problem includes a thermal continuous spectrum and cannot be assigned a real isolated interface growth rate by this ansatz there. Indeed, writing the bulk thermal perturbation as reduces its heat equation to , whose half-line diffusion modes have decay rates for . The thermal branch endpoint is . Loss of a damped isolated interface mode is not a morphological instability.
The approximate instability condition is already clear from the long-wave coefficient: , equivalently . In fact it is exact for growing modes of the present one-sided model. At , let , so . The right side of the dispersion relation becomesFor real , the residual is strictly increasing, sinceTherefore a unique positive root exists precisely when . For , the unstable band isThere are no unstable oscillatory roots hidden by this real-root test. Indeed, if and , the thermal equation implies . For , the imaginary parts of the two equations would require , contradicting . Thus growing modes have real and real .
The sketch shows zero capillarity approaching the positive plateau , weak capillarity giving a positive band followed by short-wave damping, and threshold/stronger capillarity giving damping at every nonzero wavenumber. The zero-wavenumber mode is a translation. As with fixed positive , both the unstable bandwidth and the positive growth rates shrink to zero; the small-wavenumber expansion is not uniform in that limit.
Past exam of the mathematics course of the University of Cambridge 2013 iii Paper 71 1 Solution Created 2026-10-03 Updated 2026-10-14
Use a planar saline Stefan problem with upward coordinate , the initial contact at , and phase boundaries and enclosing pure ice, where . Fresh liquid occupies and brine occupies . We assume negligible bulk flow, equal constant mass density , specific heat capacity and thermal diffusivity in all regions, and zero salt content and salt transport in the ice. Equal densities remove phase-change volume flow; suppressing convection isolates the molecular-transport mechanism. Different material properties would change the numerical coefficients. Set for the common thermal conductivity and . Denote the brine salt diffusion coefficient by .
Use a linear ice liquidus, , with and the salt mass fraction. Assume the initial brine is a stable liquid, , and all concentrations considered are below the eutectic composition. Thus . These assumptions exclude independent nucleation in a supercooled brine or an eutectic system event, neither of which is specified by the initial data alone. Start with a negligible seed of ice and use local phase equilibrium without interfacial kinetics or curvature. Temperature differences may be in Celsius, since only differences enter this calculation.
WriteThe paper calls a Stefan number; it is the latent-to-sensible heat ratio, reciprocal to another common Stefan number convention. At the lower phase boundary, define and letThe liquidus relation is .
A similarity solution gives an explicit calculation of the two positions. Putand use , . The temperatures and salinities areThese error function and complementary error function profiles satisfy the heat equation and the salt diffusion equation, their far-field conditions, and the interfacial temperature conditions. The fresh-water temperature is constant because the interface and the far field are both at .
Salt conservation at the moving lower phase boundary requiresFor upward motion this is dilution by melting salt-free ice, rather than salt rejection by freezing brine. Substitution gives the dilution function for a melting saline Stefan front:For , , so the interfacial brine is fresher than the remote liquid.
The Stefan condition at the upper boundary is , since the fresh liquid has no temperature gradient. At the lower boundary it isThese signs follow from the jump in enthalpy: the upper front freezes liquid while a positive melts solid. With , they reduce toTogether with , these equations determine , and hence both positions, without discarding the salt-diffusion correction.
For the stated large latent-to-sensible heat ratio, the layer is thin relative to the thermal diffusion length. Expanding the thermal equations for givesConsequently a useful leading calculation iswhere the positive is obtained fromThe left side decreases with while the right side increases, and their values at zero and infinity guarantee a unique positive root for large . Thus this leading calculation includes the translation of the lower boundary as well as the increasing thickness.
If the scale separation also obeys , the familiar simpler result iswithThis last simplification needs the logarithmic refinement . The algebraic ordering alone should not be used to discard an arbitrarily large logarithmic correction; the preceding coupled equations remain the appropriate calculation when that refinement is unavailable. This distinction is captured by large latent heat in a freezing and melting ice layer.
Fresh-water freezing and basal ice melting with the temperature and salinity profiles on their distinct diffusion scales
. Details. The illustration uses , and . Solving the full equations gives , and . It shows the ice layer between freshwater and cold brine, with both fronts advancing upward and a strongly diluted lower liquid boundary.
Temperature-salinity trajectory from cold bulk brine to the ice liquidus and through salt-free ice to fresh water
. Details. The phase diagram shows the spatial path from remote brine to the lower interface: temperature first changes over at almost unchanged salinity, then salinity changes over its much smaller diffusion scale at nearly constant temperature. The liquid path ends on the liquidus at ; the solid has and its temperature rises from to . The eutectic position is schematic, with in the illustration, and is not used in the calculation. A point initially in the fresh layer freezes when reaches it, cools in the ice, and later melts when reaches it. The inset indicates this temporal path in the opposite direction through the solid branch and into the liquid.
The mechanism is simultaneous upper freezing and lower melting, with net growth of the ice thickness. Cold brine accepts most of the latent heat released by upper freezing. Salt reaching the lower contact lowers its equilibrium melting temperature, and melting freshens that liquid until its liquidus is close to . The heat delivered through the ice supplies the much smaller melting demand there. The remote brine remains liquid even though it is below the pure-water melting temperature, because it lies above its own saline liquidus. Thus “cold” does not by itself decide which phase is stable. These conclusions apply while the layers remain effectively deep and the stated no-convection, pure-ice and phase-equilibrium assumptions hold.
Past exam of the mathematics course of the University of Cambridge 2015 iii Paper 78 3 Solution Created 2026-10-03 Updated 2026-10-06
Let measure distance inward from the surface. While , curvature is negligible and this is a planar two-phase Stefan problem. Use a common reference mass density , specific heat capacity , thermal conductivity and thermal diffusivity ; retain the mass density differences only in the subsequent buoyancy estimates. Define , , and . The paper's parameter is the latent-to-sensible heat ratio, reciprocal to the more usual Stefan number.
For superheated two-phase Stefan similarity, solving with , and gives the Neumann solution of the Stefan problem. With ,The solid expression holds for and the liquid expression for . The interface gradients inserted in the Stefan condition determine the positive constant :The right-hand bracket decreases from infinity and crosses zero, while the equivalent left-hand side increases, proving uniqueness. The liquid-side flux subtracts from the roof cooling: it is heat brought to the interface by the superheated interior.
For large , . Keeping the superheat term while using and yields . Hence the small-interface-parameter growth with liquid superheat approximation isThe solid temperature is approximately linear across its thin crust, while the liquid thermal boundary layer has thickness of order . For fixed superheat and , ; for , . This retains the strong suppression of growth by a very hot interior.
To estimate overturn, take local gravitational acceleration at the roof. The liquid's mass density contrast is , while the solid contrast is . A liquid thermal layer of thickness has Rayleigh number . As , it reaches its critical value after a time scaling asIn viscous overturn of a dense crust, an unstably stratified viscous crust has a Rayleigh-Taylor instability growth time of order . Setting this equal to its age, with , givesThese are formation-to-overturn times. A specified critical liquid Rayleigh number multiplies by ; logarithmic amplification and geometrical constants also affect the crust estimate. They are omitted for the requested order-of-magnitude scaling.
The given numbers yield , and . ThusLiquid thermal overturn is enormously faster than crustal overturn throughout the stated range. Even a critical-Rayleigh prefactor of order does not change that ordering. Since is not asymptotically large, low-superheat coefficients from the permitted approximation are only approximate. At the upper end , so the linear thermal-density approximation also ceases to be quantitatively credible; that endpoint is a formal scaling estimate under the supplied constant-property model. At a common age the instantaneous viscous instability-time ratio instead scales as ; it should not be confused with the above formation-time ratio.
For a boundary-layer renewal model, the liquid layer reaches . Its cycle-averaged thermal flux is consequentlyIf a critical Rayleigh number is retained, insert a factor . Averaging the diffusive flux over a cycle only changes an order-one coefficient. The crust reachesso its average solid-volume flux per roof area is the crust-removal fluxThe corresponding mass flux is and latent-heat flux is . This independent-cycle estimate is a scale for a crust that reaches overturn thickness and is then renewed. Because the liquid renews much more rapidly, in a hot interior its average heat flux can limit actual crust growth: the consistent interfacial budget is . A stalled crust would not realize repeated solid cycles. In a superheated interior, detached solid may also remelt; permanent core deposition is most directly justified in the late regime requested next.
At late times , liquid thermal buoyancy vanishes and . ThusAssuming thin renewed crust, efficient sinking and constant asteroid radius, conservation of mass gives under the permitted equal-density approximation. Therefore the asteroidal core growth by crustal sinking law isFor a self-gravitating approximately uniform sphere, , so and a zero-seed core scales as . This law applies while the thin-crust renewal model remains valid and liquid remains available; it cannot continue beyond complete solidification. The specific numerical lifetime cannot be inferred without the absolute solid viscosity and conductivity.
Past exam of the mathematics course of the University of Cambridge 2017 iii Paper 332 3 Solution Created 2026-10-03 Updated 2026-10-14
Introduce specific heat capacity , latent heat per unit mass , and . Write the prescribed convective heat flux as , whereThere is a dimensional convention to specify: with measured in and dimensionless , this printed expression makes a heat transfer coefficient only if is kinematic viscosity. If denotes dynamic viscosity, the numerator needs instead. The question says only “viscosity”; use the consistent kinematic interpretation, or equivalently the corrected dynamic formula. The following balances apply to either convention once has units .
For a thin lava lake crust with a linear temperature profile, Fourier's law gives the outward conductive flux . The Stefan condition balances it against upward thermal convection and freezing, while the well-mixed liquid loses the convective flux and gains radiogenic heating. To leading order in the radiogenically heated lava-lake crust model isThe fixed surface temperature already incorporates radiative cooling, so no extra radiative loss is added to the interior balance. The linear conductive profile is interpreted as a quasi-steady approximation, so sensible-heat storage within the crust is not evolved. Thinness alone does not establish this approximation: rapid thermal adjustment in the crust is also needed, for example a small Stefan number during the initial conduction-driven growth. Replacing the liquid depth by and retaining the moving liquid-volume enthalpy would introduce thin-crust corrections: the requested constant-temperature branch refers to the leading model above. A transient thermal profile in a thick or newly nucleating crust would require the full Stefan problem, rather than this linear-profile closure.
Using the thermal diffusion time , defineThe three independent dimensionless parameters are the convective-conductive coefficient , the heating parameter , and the Stefan number . For positive the evolution equations becomewhere prime denotes . Temperature has the exact solutionConsequently the unique constant-temperature initial condition isAt this temperature, the convective flux equals the column's radiogenic heat production. Starting with no crust, the constant-temperature lava-crust growth law is obtained by separating :The crust grows towards , or , where conduction carries all the radiogenic input. The logarithm makes reaching this equilibrium take infinite time. For an initial thickness , subtract on the same side of the equilibrium; the corresponding antiderivative uses on either branch. The thin-crust description through equilibrium requires .
For general initial temperature, the full early and intermediate history is specified by the exact temperature above and one scalar ordinary differential equation. A particularly convenient integral formulation for an initially bare surface isThis removes the infinite initial derivative of . The right-hand side points into at zero, and is decreasing in when ; two nonnegative solutions therefore cannot separate, which gives uniqueness. Its solution, together with the temperature formula, determines the entire model evolution and can be computed without a phase-boundary search. The early expansion follows by substitution:The dimensional leading crust thickness is . Thus hotter liquid reduces the first correction to conductive crust growth, whereas colder liquid permits more rapid thickening.
If , the temperature decreases and the instantaneous stationary lava-crust thickness increases towards . Starting from zero, the crust always remains below this rising curve: at a first contact but , so it cannot cross from below. Hence hot-start crust grows monotonically. It also stays thinner than the constant-temperature solution: the early expansion puts it below, and at a proposed first crossing their derivative difference is , preventing crossing from below. If , the temperature increases and the instantaneous stationary lava-crust thickness decreases. The crust stays thicker than the constant-temperature solution by scalar comparison, but it may cross the decreasing , reach a maximum and subsequently melt back towards . Such overshoot is possible, not inevitable; the two relevant relaxation rates are and . The numerical plot uses , , , so crust adjustment is faster than temperature relaxation and the cool-start example does overshoot:
Lava temperature and crust thickness
. Details. The curves use and initially . They solve the complete reduced time-dependent equations, rather than replacing the moving stationary thickness by the actual crust. At late times, set , ; linearization gives . For ,At equal rates the forced term is . In particular, slow warming with approaches equilibrium from a thicker crust, explaining the plotted remelting. These long-time expressions describe the linearized response; nonlinear corrections can have their own faster exponential rates. All predictions are restricted to , nonnegative liquid superheat, and the assumed vigorous-convection flux law. If crust growth violates those conditions, the reduced model must be replaced rather than extrapolated to total freezing.
For a one-phase spherical Stefan problem with melting-temperature boundary value and supercooling , use the latent-to-sensible heat ratio . Large separates heat diffusion from slow interface motion. The exterior harmonic temperature is . The Stefan condition gives the displayed radius equation with . This is the large inverse-Stefan number convention; the common sensible-to-latent Stefan number is .
Radiogenically heated lava-lake crust model 2026-10-06
For a well-mixed lava lake of depth and a thin conductive crust of thickness , put , and use the convective flux with constant heat transfer coefficient . The Stefan condition and liquid heat balance give, to leading order in ,Here latent heat is per unit mass and . Crust heating and changes of liquid depth are neglected. The linear conductive profile uses a quasi-steady approximation; thinness alone does not justify neglecting crust thermal storage. During initial growth, a small Stefan number supplies a sufficient rapid-adjustment regime. Define , , and . Scaling by the thermal diffusion time and gives and , where , , and is the Stefan number. Thus exactly. The reduction applies while , the conductive profile is approximately linear, and the thermal convection closure remains valid; it does not model complete freezing of a deep lake.




