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A wavenumber measures how rapidly a wave phase changes with distance. Two conventions coexist: angular wavenumber counts radians per unit length, while ordinary spatial frequency counts cycles per unit length. For a monochromatic wave with wavelength $\lambda >0$,Here $K\ge 0$ is the magnitude of the angular wavenumber. The symbol $k$ can instead denote a signed one-dimensional angular wavenumber: a factor $e^{ikx}$ has wavelength $2\pi /|k|$ for real $k\ne 0$. Both conventions have dimensions of inverse length; writing $\mathrm{rad}{\mathrm{m}}^{-1}$ or “cycles per metre” exposes the convention. A quoted value in ${\mathrm{m}}^{-1}$ alone does not resolve the factor of $2\pi$. Spectroscopic wavenumber usually uses the cycles-per-length convention.^[ref]

For a real monochromatic plane wave, fix the conventionThe wavevector $\mathbf{k}$ supplies both the spatial wave phase slope and the normal to the wavefronts; its dot product with position makes the wave phase constant on parallel planes. The angular frequency is $\omega =2\pi f$, with $f>0$ the ordinary frequency. Moving a distance $\lambda$ along $\mathbf{k}$ changes the wave phase by $2\pi$. Holding a wave crest's wave phase fixed gives its phase velocity $\omega \mathbf{k}/K^2$ and phase speedIn one dimension the signed phase velocity is $\omega /k$. This identifies a moving pattern; it does not identify the motion of the medium's particles or a wave packet's group velocity.

For the synthetic plane wave below, choose $\lambda =0.40\mathrm{m}$ and $f=5\mathrm{Hz}$. Then $K=5\pi \mathrm{rad}{\mathrm{m}}^{-1}$, ${\nu }_x=2.5$ cycles per metre, $\omega =10\pi \mathrm{rad}{\mathrm{s}}^{-1}$, and $v_p=2\mathrm{m}{\mathrm{s}}^{-1}$. The wave crests are $0.40\mathrm{m}$ apart at one instant; after a quarter oscillation period, each has advanced $0.10\mathrm{m}$. The lower panel retains whole turns of wave phase, making its slope visible instead of reducing it modulo $2\pi$.

A waveplate uses birefringence to change polarization of an electromagnetic wave through phase retardation. Its fast axis has the smaller refractive index, hence the larger phase velocity; its slow axis has the larger index. Consider normal incidence with the optic axis in the plate face, so both components follow the same straight path. A linear polarization at $45^{\circ }$ to these axes excites equal wave amplitudes.

A complementary experiment uses two sheet polarizers with a cellophane sheet between them. First cross the polarizers and remove the sheet: the field is dark. Insert and rotate the sheet about the beam: light returns at intermediate orientations, but extinction recurs at two perpendicular orientations. The sheet has changed the polarization of an electromagnetic wave, without requiring a resolved double image. With white light, different wavelengths can produce different transmitted colors.^[ref]. Brightness alone does not establish circular polarization: an ideal rotating linear polarizer also gives orientation-independent light intensity for unpolarized light.

In a clear terrestrial atmosphere, Rayleigh scattering by air molecules redirects some sunlight toward an observer looking away from the Sun. Shorter wavelengths are preferentially scattered, enriching the scattered light in blue compared with the incoming sunlight. Along the longer atmospheric path to the low Sun, more short-wavelength light is removed from the direct beam, helping produce red sunsets. ^[ref].

Violet light has an even shorter wavelength than blue light, so the Rayleigh scattering wavelength dependence alone cannot predict the perceived sky color. The incoming solar optical spectrum and the eye's differing response to wavelengths both matter; human vision is less sensitive to violet than to blue. ^[ref]. Multiple scattering and other atmospheric particles also affect the observed sky. Cloud droplets are generally too large for this simple Rayleigh scattering model: Mie scattering describes spherical droplets, with much weaker visible wavelength selectivity, while repeated scattering helps make clouds appear white. ^[ref].

Wien's displacement law says that the wavelength maximizing the Planck function per unit wavelength, $B_{\lambda }(T)$, moves inversely with absolute temperature:Here $b$ is the Wien displacement constant. Heating an ideal blackbody therefore shifts this peak toward shorter wavelengths, while also increasing its emission at every fixed wavelength. The peak identifies where equal narrow wavelength intervals carry the most power; it is not a single emitted wavelength. Planck's law supplies the full curve, and the Stefan–Boltzmann law supplies its integral.

Specify the spectral coordinate before finding a peak. The frequency form of Wien's displacement law maximizes $B_{\nu }$, which is spectral radiance per unit frequency. Its maximum is not $c/{\lambda }_{\max }$. The frequency and wavelength spectral radiance conversion changes the density as well as the horizontal coordinate; the existing frequency and wavelength peaks of Planck's law give a complementary numerical comparison.

In his 11 December 1911 Nobel lecture, Wilhelm Wien explained the displacement principle through a thought experiment: compress black-body radiation between reflecting moving walls. Work against radiation pressure raises the energy density, while reflection changes each frequency by the Doppler effect. The Second law of thermodynamics connects the resulting spectrum to one at a higher temperature. This determines how the spectrum scales between temperatures, without determining its complete shape. The Wien approximation is a separate, restricted spectral formula.^[ref]

A physicist.^[ref]

Wien's displacement law connects a thermal spectrum's peak position to temperature. Specifying whether the spectrum is expressed per unit wavelength or per unit frequency is essential to stating which peak is meant.

X-rays are high-frequency electromagnetic radiation, conventionally with wavelengths of roughly $0.01$ to $10\mathrm{nm}$. The precise wavelength convention varies with context. Hot accreting gas and energetic electronic processes can emit X-rays, whose short wavelengths make them useful probes of compact objects and electron shells.

For a photon, $E=h\nu =hc/\lambda$, where $h$ is the Planck constant and $c$ is the speed of light. As a calculated example, $\lambda =0.10\mathrm{nm}$ gives $E\simeq 12.4\mathrm{keV}$, using $hc\simeq 1.23984\mathrm{keV}\mathrm{nm}$. The same wavelength can describe different production mechanisms: bremsstrahlung produces a continuous frequency spectrum, whereas Characteristic X-rays arise from discrete electronic changes in chemical atoms. Measuring transmitted X-rays gives radiography; measuring their frequency spectrum gives spectroscopy.