Theory that describes electrons and photons really well, and as Feynman puts it "accounts very precisely for all physical phenomena we have ever observed, except for gravity and nuclear physics" ("including the laughter of the crowd" ;-)).
Learning it is one of Ciro Santilli's main intellectual fetishes.
While Ciro acknowledges that QED is intrinsically challenging due to the wide range or requirements (quantum mechanics, special relativity and electromagnetism), Ciro feels that there is a glaring gap in this moneyless market for a learning material that follows the Middle Way as mentioned at: the missing link between basic and advanced. Richard Feynman Quantum Electrodynamics Lecture at University of Auckland (1979) is one of the best attempts so far, but it falls a bit too close to the superficial side of things, if only Feynman hadn't assumed that the audience doesn't know any mathematics...
The funny thing is that when Ciro Santilli's mother retired, learning it (or as she put it: "how photons and electrons interact") was also one of her retirement plans. She is a pharmacist by training, and doesn't know much mathematics, and her English was somewhat limited. Oh, she also wanted to learn how photosynthesis works (possibly not fully understood by science as that time, 2020). Ambitious old lady!!!
Experiments: quantum electrodynamics experiments.
Combines special relativity with more classical quantum mechanics, but further generalizing the Dirac equation, which also does that: Dirac equation vs quantum electrodynamics. The name "relativistic" likely doesn't need to appear on the title of QED because Maxwell's equations require special relativity, so just having "electro-" in the title is enough.
Before QED, the most advanced theory was that of the Dirac equation, which was already relativistic but TODO what was missing there exactly?
As summarized at: youtube.com/watch?v=_AZdvtf6hPU?t=305 Quantum Field Theory lecture at the African Summer Theory Institute 1 of 4 by Anthony Zee (2004):
- classical mechanics describes large and slow objects
- special relativity describes large and fast objects (they are getting close to the speed of light, so we have to consider relativity)
- classical quantum mechanics describes small and slow objects.
- QED describes objects that are both small and fast
That video also mentions the interesting idea that:Therefore, for small timescales, energy can vary a lot. But mass is equivalent to energy. Therefore, for small time scale, particles can appear and disappear wildly.
- in special relativity, we have the mass-energy equivalence
- in quantum mechanics, thinking along the time-energy uncertainty principle,
QED is the first quantum field theory fully developed. That framework was later extended to also include the weak interaction and strong interaction. As a result, it is perhaps easier to just Google for "Quantum Field Theory" if you want to learn QED, since QFT is more general and has more resources available generally.
Like in more general quantum field theory, there is on field for each particle type. In quantum field theory, there are only two fields to worry about:
- photon field
- electromagnetism field
Theoretical framework on which quantum field theories are based, theories based on framework include:so basically the entire Standard Model
The basic idea is that there is a field for each particle particle type.
E.g. in QED, one for the electron and one for the photon: physics.stackexchange.com/questions/166709/are-electron-fields-and-photon-fields-part-of-the-same-field-in-qed.
And then those fields interact with some Lagrangian.
One way to look at QFT is to split it into two parts:Then interwined with those two is the part "OK, how to solve the equations, if they are solvable at all", which is an open problem: Yang-Mills existence and mass gap.
- deriving the Lagrangians of the Standard Model: why do symmetries such as SU(3), SU(2) and U(1) matter in particle physics?s. This is the easier part, since the lagrangians themselves can be understood with not very advanced mathematics, and derived beautifully from symmetry constraints
- the qantization of fields. This is the hard part Ciro Santilli is unable to understand, TODO mathematical formulation of quantum field theory.
There appear to be two main equivalent formulations of quantum field theory:
The first really good quantum mechanics theory made compatible with special relativity was the Dirac equation.
And then came quantum electrodynamics to improve it: Dirac equation vs quantum electrodynamics.
TODO: does it use full blown QED, or just something intermediate?
www.youtube.com/watch?v=NtnsHtYYKf0 "Mercury and Relativity - Periodic Table of Videos" by Periodic Videos (2013). Doesn't give the key juicy details/intuition. Also mentioned on Wikipedia: en.wikipedia.org/wiki/Relativistic_quantum_chemistry#Mercury
Experiments explained:
- via the Schrödinger equation solution for the hydrogen atom it predicts:
- spectral line basic lines, plus Zeeman effect
- Schrödinger equation solution for the helium atom: perturbative solutions give good approximations to the energy levels
- double-slit experiment: I think we have a closed solution for the max and min probabilities on the measurement wall, and they match experiments
Experiments not explained: those that the Dirac equation explains like:
- fine structure
- spontaneous emission coefficients
To get some intuition on the equation on the consequences of the equation, have a look at:
The easiest to understand case of the equation which you must have in mind initially that of the Schrödinger equation for a free one dimensional particle.
Then, with that in mind, the general form of the Schrödinger equation is:where:
- is the reduced Planck constant
- is the wave function
- is the time
- is a linear operator called the Hamiltonian. It takes as input a function , and returns another function. This plays a role analogous to the Hamiltonian in classical mechanics: determining it determines what the physical system looks like, and how the system evolves in time, because we can just plug it into the equation and solve it. It basically encodes the total energy and forces of the system.
The argument of could be anything, e.g.:Note however that there is always a single magical time variable. This is needed in particular because there is a time partial derivative in the equation, so there must be a corresponding time variable in the function. This makes the equation explicitly non-relativistic.
- we could have preferred polar coordinates instead of linear ones if the potential were symmetric around a point
- we could have more than one particle, e.g. solutions of the Schrodinger equation for two electrons, which would have e.g. and for different particles. No matter how many particles there are, we have just a single , we just add more arguments to it.
- we could have even more generalized coordinates. This is much in the spirit of Hamiltonian mechanics or generalized coordinates
The general Schrödinger equation can be broken up into a trivial time-dependent and a time-independent Schrödinger equation by separation of variables. So in practice, all we need to solve is the slightly simpler time-independent Schrödinger equation, and the full equation comes out as a result.
To better understand the discussion below, the best thing to do is to read it in parallel with the simplest possible example: Schrödinger picture example: quantum harmonic oscillator.
The state of a quantum system is a unit vector in a Hilbert space.
"Making a measurement" for an observable means applying a self-adjoint operator to the state, and after a measurement is done:Those last two rules are also known as the Born rule.
- the state collapses to an eigenvector of the self adjoint operator
- the result of the measurement is the eigenvalue of the self adjoint operator
- the probability of a given result happening when the spectrum is discrete is proportional to the modulus of the projection on that eigenvector.For continuous spectra such as that of the position operator in most systems, e.g. Schrödinger equation for a free one dimensional particle, the projection on each individual eigenvalue is zero, i.e. the probability of one absolutely exact position is zero. To get a non-zero result, measurement has to be done on a continuous range of eigenvectors (e.g. for position: "is the particle present between x=0 and x=1?"), and you have to integrate the probability over the projection on a continuous range of eigenvalues.In such continuous cases, the probability collapses to an uniform distribution on the range after measurement.The continuous position operator case is well illustrated at: Video "Visualization of Quantum Physics (Quantum Mechanics) by udiprod (2017)"
Self adjoint operators are chosen because they have the following key properties:
- their eigenvalues form an orthonormal basis
- they are diagonalizable
Perhaps the easiest case to understand this for is that of spin, which has only a finite number of eigenvalues. Although it is a shame that fully understanding that requires a relativistic quantum theory such as the Dirac equation.
The next steps are to look at simple 1D bound states such as particle in a box and quantum harmonic oscillator.
This naturally generalizes to Schrödinger equation solution for the hydrogen atom.
The solution to the Schrödinger equation for a free one dimensional particle is a bit harder since the possible energies do not make up a countable set.
This formulation was apparently called more precisely Dirac-von Neumann axioms, but it because so dominant we just call it "the" formulation.
Quantum Field Theory lecture notes by David Tong (2007) mentions that:
if you were to write the wavefunction in quantum field theory, it would be a functional, that is a function of every possible configuration of the field .
TODO. Can't find it easily. Anyone?
This is closely linked to the Pauli exclusion principle.
What does a particle even mean, right? Especially in quantum field theory, where two electrons are just vibrations of a single electron field.
Another issue is that if we consider magnetism, things only make sense if we add special relativity, since Maxwell's equations require special relativity, so a non approximate solution for this will necessarily require full quantum electrodynamics.
As mentioned at lecture 1 youtube.com/watch?video=H3AFzbrqH68&t=555, relativistic quantum mechanical theories like the Dirac equation and Klein-Gordon equation make no sense for a "single particle": they must imply that particles can pop in out of existence.
Bibliography:
- www.youtube.com/watch?v=Og13-bSF9kA&list=PLDfPUNusx1Eo60qx3Od2KLUL4b7VDPo9F "Advanced quantum theory" by Tobias J. Osborne says that the course will essentially cover multi-particle quantum mechanics!
- physics.stackexchange.com/questions/54854/equivalence-between-qft-and-many-particle-qm "Equivalence between QFT and many-particle QM"
- Course: Quantum Many-Body Physics in Condensed Matter by Luis Gregorio Dias (2020) from course: Quantum Many-Body Physics in Condensed Matter by Luis Gregorio Dias (2020) give a good introduction to non-interacting particles
In the Galilean transformation, there are two separate invariants that two inertial frame of reference always agree on between two separate events:
- time
- length, given by the Pythagorean theorem
However, in special relativity, neither of those are invariant separately, since space and time are mixed up together.
Instead, there is a new unified invariant: the spacetime-interval, given by:
Note that this distance can be zero for two events separated.
Spin is one of the defining properties of elementary particles, i.e. number that describes how an elementary particle behaves, much like electric charge and mass.
Possible values are half integer numbers: 0, 1/2, 1, 3/2, and so on.
The approach shown in this section: Section "Spin comes naturally when adding relativity to quantum mechanics" shows what the spin number actually means in general. As shown there, the spin number it is a direct consequence of having the laws of nature be Lorentz invariant. Different spin numbers are just different ways in which this can be achieved as per different Representation of the Lorentz group.
Video 1. "Quantum Mechanics 9a - Photon Spin and Schrodinger's Cat I by ViaScience (2013)" explains nicely how:
- incorporated into the Dirac equation as a natural consequence of special relativity corrections, but not naturally present in the Schrödinger equation, see also: the Dirac equation predicts spin
- photon spin can be either linear or circular
- the linear one can be made from a superposition of circular ones
- straight antennas produce linearly polarized photos, and Helical antennas circularly polarized ones
- a jump between 2s and 2p in an atom changes angular momentum. Therefore, the photon must carry angular momentum as well as energy.
- cannot be classically explained, because even for a very large estimate of the electron size, its surface would have to spin faster than light to achieve that magnetic momentum with the known electron charge
- as shown at Video "Quantum Mechanics 12b - Dirac Equation II by ViaScience (2015)", observers in different frames of reference see different spin states
Light watch transverse to direction of motion. This case is interesting because it separates length contraction from time dilation completely.
Of course, as usual in special relativity, calling something "time dilation" leads us to mind boggling ideas of "symmetry breaking": if both frames have a light watch, how can both possibly observe the other to be time dilated?
And the answer to this, is the usual: in special relativity time and space are interwoven in a fucked up way, everything is just a spacetime event.
In this case, there are three spacetime events of interest: both clocks start at same position, your beam hits up at x=0, moving frame hits up at x>0.
Those two mentioned events are spacelike-separated events, and therefore even though they seem simultaneous to you, they are not going to be simultaneous to the moving observer!
If little clock one meter away from you tells you that at the time of some event (your light beam hit up) the moving light watch was only 50% up, this is just a number given by your one meter away watch!
- www.youtube.com/watch?v=-_qNKbwM_eE Unsolved: Yang-Mills existence and mass gap by J Knudsen (2019). Gives 10 key points, but the truly hard ones are too quick. He knows the thing though.