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For $H=p^2/(2m)+V(x)$ and a time-independent operator $O$, differentiate its expectation value and use the Schrödinger equation and its adjoint. Moving $H$ across the inner product by integration by parts givesWork with wavefunctions in the displayed operators' domains; the vanishing at infinity removes the associated boundary terms. This is the Ehrenfest theorem derived from time evolution.

The canonical commutation relation follows directly from differentiating $x\psi$: $[p,x]\psi =-i\hslash \psi$. Thus $[p^2,x]=p[p,x]+[p,x]p=-2i\hslash p$, while $[V(x),x]=0$. It follows thatFor the momentum equation, apply both products to a test wavefunction:The kinetic term commutes with $p$, so $[H,p]=i\hslash V^{\prime }$. ThereforeThese are the classical equations from Ehrenfest theorem for position and momentum expectations; the force expectation need not equal the force evaluated at the expected position.

A Hermitian operator satisfies $⟨u,Av⟩=⟨Au,v⟩$ for all admissible states in its domain; in finite dimension this is $A^{\ast }=A$. For an unbounded physical observable one specifies a self-adjoint realization, rather than only a formal differential expression.

Here $p=-i\hslash d/dx$ and $H=-{\hslash }^2{d}^2/(2md{x}^2)+V(x)$. For states with sufficient regularity and decay, integration by parts givesThe multiplication term cancels because $V$ is real. Thus the Quantum Hamiltonian is Hermitian on the stated admissible domain. Equivalent boundary conditions must remove this boundary term if the system is on a bounded interval.

The Schrödinger equation $i\hslash \dot{\psi }=H\psi$ and its conjugate imply, for a time-independent observable $A$ and normalized state,This follows by differentiating both factors in $⟨\psi ,A\psi ⟩$ and moving $H$ using Hermiticity. The canonical commutator $[x,p]=i\hslash$ givesConsequently the two Ehrenfest theorem identities areThey require the displayed expectations and domain operations to exist; real-valuedness of a potential alone is not a proof about every possible singular operator domain.

A Hermitian operator $A$ satisfies $⟨\phi ,A\psi ⟩=⟨A\phi ,\psi ⟩$ on its operator domain. HereTwo integration by parts operations, together with the boundary conditions in the Hamiltonian domain, show that the kinetic term is Hermitian; multiplication by the real function $V$ is Hermitian as well. Thus $H$ is Hermitian.

For a time-independent operator $A$, the Schrödinger equation and its adjoint give the Ehrenfest theoremUsing the canonical commutation relation $[x,p]=i\hslash$,Consequently

The Time-dependent Schrödinger equation is $i\hslash {\partial }_t\psi =\hat{H}\psi$. Differentiate $⟨\hat{A}⟩=⟨\psi |\hat{A}|\psi ⟩$, use the equation and its adjoint, and include explicit time dependence of the operator. This gives Ehrenfest theorem

For a particle in the scalar potential energy $U(x)$,The canonical commutation relation $[x,p]=i\hslash$ givesThe Ehrenfest theorem with $O=x$ therefore givesSince $[p^2,p]=0$ and direct action on a wavefunction gives $[U(x),p]=i\hslash U^{\prime }(x)$,Finally $H$ has no explicit time dependence and $[H,H]=0$, so

The first two equations are the expectation-value counterparts of momentum equals mass times velocity and Newton's second law; the last is conservation of energy. They become the classical equations directly when the force varies negligibly across the wave packet, so that $⟨U^{\prime }(x)⟩\simeq U^{\prime }(⟨x⟩)$. These conclusions are summarized by the classical equations from Ehrenfest theorem.

Differentiating $⟨O⟩=⟨\psi |O|\psi ⟩$ and using the Schrödinger equation and its adjoint gives the Ehrenfest theorem

If Bob opens the trap, Ehrenfest theorem gives branch-dependent Newtonian accelerationsso, for $R\gg d$,After time $t$, the centers of Bob's two conditional wave packets differ byFor Alice's superposition, these distinguishable Bob states become entangled with $|L⟩$ and $|R⟩$; for Alice's mixture there was no initial coherence to entangle. Taking Bob's minimum packet width to be the Planck length ${\ell }_P$, appreciable branch distinguishability begins when $\Delta x\sim {\ell }_P$, atKeeping the trap closed suppresses this branch separation.

If $t_{\mathrm{ent}}<R/c$, Bob could choose whether to destroy Alice's local coherence before a light signal from his laboratory arrived. Any procedure by which Alice distinguished the coherent superposition from the mixture in less than $R/c$ would then enable superluminal signalling. The largest dangerous separation is determined parametrically by $t_{\mathrm{ent}}\sim R/c$, which givesCausality therefore requiresUsing $G{m}_P/c^2={\ell }_P$ for the Planck mass $m_P$,up to numerical factors.

Differentiating the expectation value and using ${\partial }_t|\psi ⟩=-i\hat{H}|\psi ⟩/\hslash$ and ${\partial }_t⟨\psi |=i⟨\psi |\hat{H}/\hslash$ givesThe second term means explicit operator time dependence, distinct from the state's evolution.

The commutator product rule follows by adding and subtracting $\hat{B}\hat{A}\hat{C}$:For the mathematical induction step, let $\hat{D}=[\hat{A},\hat{B}]$ and use $[\hat{A},\hat{D}]=0$. The case $n=1$ is immediate. If $[{\hat{A}}^m,\hat{B}]=m\hat{D}{\hat{A}}^{m-1}$, thenThus the claimed identity holds for every positive integer. Commutation of $\hat{B}$ with $\hat{D}$ is not needed for this particular step. This is the central-commutator differentiation rule. Termwise application to a convergent power series, on a common domain where the operations are justified, gives

For position and momentum, $[\hat{x},\hat{p}]=i\hslash \hat{I}$. Hence $[{\hat{p}}^2,\hat{x}]=-2i\hslash \hat{p}$, $[V(\hat{x}),\hat{x}]=0$ and $[V(\hat{x}),\hat{p}]=i\hslash V^{\prime }(\hat{x})$. Substitution gives Ehrenfest theorem:The mean momentum changes by the mean force. It does not follow for a general nonlinear Potential energy that $⟨V^{\prime }(\hat{x})⟩=V^{\prime }(⟨\hat{x}⟩)$: a closed classical trajectory for the mean position requires an additional condition, such as a quadratic Potential energy or a sufficiently localized wave packet.

Ehrenfest theorem relates the dynamics of quantum expectation values to operator commutators. For a normalized state obeying $i\hslash |\dot{\psi }⟩=\hat{H}|\psi ⟩$ and a possibly time-dependent observable $\hat{A}$, differentiate $⟨A⟩=⟨\psi |\hat{A}|\psi ⟩$. Using the adjoint Schrödinger equation for the bra givesThusThe identity assumes a common domain on which the required products and derivatives are defined.

For $H=p^2/(2m)+V(x)$, the canonical commutation relation gives $[x,H]=i\hslash p/m$ and $[p,H]=-i\hslash V^{\prime }(x)$. ThereforeThese resemble Hamilton's equations and Newton's second law, but generally $⟨V^{\prime }(x)⟩\ne V^{\prime }(⟨x⟩)$. If the state is localized about $\overline{x}=⟨x⟩$, a local expansion givesThe classical trajectory equation for the mean is accurate when the force changes little across the wave packet. For a quadratic harmonic potential, $V^{\prime }$ is linear and this closure is exact for every state with the relevant finite moments: $m{d}^2⟨x⟩/d{t}^2=-m{\omega }^2⟨x⟩$. This exact classical evolution of the centroid does not eliminate its quantum position uncertainty or make every state a point particle.

The correspondence principle is broader: quantum predictions recover classical ones in an appropriate limit, such as large action compared with $\hslash$ and observations that cannot resolve individual quantum levels. It is not the assertion that every large quantum number automatically makes every possible state classical. Delocalized superpositions and interference can remain significant unless the physical preparation and measurement justify a classical description.

A spectral example is useful. For a quantum harmonic oscillator, neighboring levels differ by $\hslash \omega$, giving transition frequency $\omega /(2\pi )$, equal to its classical oscillation frequency. A coherent state makes the connection more concrete: its mean position and momentum oscillate classically while the finite-width Gaussian profile retains its quantum uncertainty. For hydrogenic Bohr levels $E_n=-A/n^2$, transitions between nearby large $n$ have $\Delta E/\hslash \simeq 2A/(\hslash n^3)$, which equals the classical circular orbital angular frequency in that model. Ehrenfest's theorem supplies an exact expectation-value bridge; a classical trajectory follows only when the force can also be evaluated at the mean position.

The Hamiltonian operator isSince multiplication by $x$ commutes with multiplication by $V(x)$, part (b) gives $[x,H]=i\hslash p_x/m$. Similarly $[p_x,H]=-i\hslash V^{\prime }(x)$. Substituting into part (c) gives Ehrenfest theorem:Thus the mean momentum changes according to the mean force, and the derivative of mean position is mean velocity. These exact quantum equations resemble Hamilton's classical equations, but $⟨V^{\prime }(x)⟩$ generally differs from $V^{\prime }(⟨x⟩)$. The classical point-particle equation for the center is exact for potentials at most quadratic and is an approximation for a localized packet when the force varies little across it. A spatially broad packet in a nonlinear potential need not follow a classical trajectory. Even where its center follows classical motion, its width and measurement uncertainties remain quantum properties.

A localized quantum particle is described by a wave packet: a coherent quantum superposition of momentum components, rather than a single delocalized plane wave. The Born rule assigns the position probability density $|\psi (x,t){|}^2$. A useful normalized initial Gaussian wave packet isIts mean position and momentum are $x_0$ and $p_0$, and its standard deviations satisfy ${\sigma }_x(0)={\sigma }_0$, ${\sigma }_p=\hslash /(2{\sigma }_0)$. This unchirped initial state saturates the Heisenberg uncertainty relation.

For a free particle, the momentum-space Schrödinger equation multiplies each amplitude by $e^{-i{p}^{2}t/(2m\hslash )}$. The inverse Fourier transform is a Gaussian integral, giving the free Gaussian wave packet evolutionOne way to obtain this expression explicitly is to write the initial momentum amplitude as proportional to $\exp [-{\sigma }_0^2(p-p_0{)}^2/{\hslash }^2-ip{x}_0/\hslash ]$, multiply by the free evolution phase and complete the square in $p$. Taking the modulus squared removes the position-dependent phase and leavesThe expectation value follows uniform classical motion while the density spreads. A narrower initial packet needs a wider momentum distribution and therefore spreads more rapidly. At long times its width grows linearly with $|t|$; its variance grows quadratically, unlike the linear variance growth of ordinary diffusion. The probability continuity equation preserves total probability despite the decreasing peak height. The mean momentum and the mean energy $(p_0^2+{\sigma }_p^2)/(2m)$ remain constant, since the momentum populations do not change.

The same result has a wave interpretation. For a free nonrelativistic particle $\omega (k)=\hslash k^2/(2m)$, so the group velocity is $d\omega /dk=\hslash k/m$, equal to $p_0/m$ at the packet center. The curvature $d^2\omega /d{k}^2=\hslash /m$ makes different momentum components travel with different group velocities, producing dispersion. The phase velocity is $\omega /k=\hslash k/(2m)$ for this energy convention and does not describe the motion of the envelope. The evolving quadratic spatial phase is essential to the spreading; a density snapshot alone does not specify the full quantum state.

A freely spreading Gaussian wave packet remains a pure Gaussian state but develops position-momentum correlations. Its symmetrized covariance is $C_{xp}=⟨\{x-⟨x⟩,p-⟨p⟩\}⟩/2=t{\sigma }_p^2/m$. ConsequentlyEquality in the Robertson-Schrödinger uncertainty relation survives at every time, whereas the simpler product ${\sigma }_x{\sigma }_p$ equals $\hslash /2$ only initially. A chirped Gaussian wave packet can already have $C_{xp}(0)\ne 0$. More generally, $x(t)=x(0)+p(0)t/m$ gives ${\sigma }_x(t{)}^2={\sigma }_x(0{)}^2+2t{C}_{xp}(0)/m+t^2{\sigma }_p(0{)}^2/m^2$. A sufficiently negative initial covariance permits initial contraction before subsequent spreading.

A potential energy changes this behavior. A quadratic potential preserves the Gaussian form because the evolution of position and momentum is linear. For a quantum harmonic oscillator, the Gaussian covariance in a harmonic potential isA coherent state has ${\sigma }_x^2=\hslash /(2m\omega )$, ${\sigma }_p^2=m\hslash \omega /2$ and zero centered covariance. Its width is constant, and its center follows $x_c(t)=x_0\cos \omega t+p_0\sin \omega t/(m\omega )$. In oscillator notation its coherent state label rotates as $\alpha (t)=\alpha (0)e^{-i\omega t}$, apart from the common ground-energy phase of the state vector. A squeezed coherent state generally has a width that breathes at $2\omega$. Thus being Gaussian does not imply either free spreading or constant width; the Hamiltonian operator and initial covariance determine the result.

For a general nonquadratic potential, different parts of the packet experience different nonlinear forces, and an initially Gaussian profile need not remain Gaussian. Ehrenfest theorem gives the exact relations $d⟨x⟩/dt=⟨p⟩/m$ and $d⟨p⟩/dt=-⟨V^{\prime }(x)⟩$. Replacing the last mean by $-V^{\prime }(⟨x⟩)$ is exact for a quadratic potential and approximate for a packet narrow compared with the scale on which the force varies. This connects packet motion to the correspondence principle without treating a quantum state as a definite classical path. Scattering can split a packet into reflected and transmitted components, while confinement can produce oscillations and interference between discrete energy eigenstates. Their relative phases evolve even when their populations remain constant. Localization, spreading and coherent motion all follow from the same linear unitary time evolution.

In the Schrödinger picture, a time-independent Hamiltonian gives $|{\psi }_S(t)⟩=U(t)|\psi (0)⟩$, where $U=e^{-iHt/\hslash }$. The Heisenberg picture transfers this evolution to each observable:Both pictures give the same probabilities and expectation values. Differentiating yields the Heisenberg equation of motionThe last term is an explicit change of the measured operator. If it is absent and $[H,A]=0$, the observable is conserved.

The corresponding classical equation is $dA/dt=\{A,H{\}}_{\mathrm{PB}}+\partial A/\partial t$. The correspondence principle relates the Poisson bracket to $[A,H]/(i\hslash )$, with suitable operator ordering and a classical limit. For $H=p^2/(2m)+V(x)$, the canonical commutation relation givesTaking means gives Ehrenfest theorem. Its second equation contains $-⟨V^{\prime }(x)⟩$, which need not equal $-V^{\prime }(⟨x⟩)$. A narrow wave packet in a slowly varying force field can follow the classical equations approximately; a quadratic potential makes the equality exact for the means.

For a quantum harmonic oscillator, direct solution gives $x_H(t)=x_H(0)\cos \omega t+p_H(0)\sin \omega t/(m\omega )$ and $p_H(t)=p_H(0)\cos \omega t-m\omega x_H(0)\sin \omega t$. These have the classical form as operator identities. A coherent state supplies a localized center moving on the classical orbit, whereas an energy eigenstate has stationary density and $⟨x⟩=0$, even at large excitation. Thus large quantum numbers alone do not create a localized classical trajectory. Classical behavior also concerns state preparation, relative fluctuations and the resolution of the measurements.

Time dependence in quantum mechanics describes how a prepared quantum state changes and thereby changes the probabilities of later measurements. For an isolated system, the Schrödinger picture assigns this evolution to a state vector $|\psi (t)⟩$, governed by the Time-dependent Schrödinger equationThe Hamiltonian is a self-adjoint operator; it has units of energy, while $\hslash$ has units of action, so $\hat{H}/\hslash$ has units of inverse time. For a particle with potential energy $V(\mathbf{r},t)$, this becomesGiven a suitable initial wavefunction and the physical boundary conditions, this first-order equation determines its subsequent propagation. Its linearity means that the evolution of a quantum superposition is the corresponding quantum superposition of evolved states.

For a real potential energy, this equation and its complex conjugate imply the local continuity equationHere $\rho$ is the probability density and $\mathbf{j}$ the probability current. Vanishing net boundary flux preserves wavefunction normalization, as required by the Born rule.

The time-evolution operator packages the solution for every initial state:Because ${\hat{H}}^{†}=\hat{H}$, differentiation givesTherefore $U^{†}U=I$: this is unitary time evolution, preserving inner products and all state norms. It is reversible, with $U(t,t_0{)}^{-1}=U(t_0,t)=U(t,t_0{)}^{†}$, and obeys the composition law $U(t_2,t_0)=U(t_2,t_1)U(t_1,t_0)$.

For a time-independent Hamiltonian, the solution is the operator exponentialIf the Hamiltonian varies with time, the analogous simple exponential of its integral is valid when $[\hat{H}(t),\hat{H}(t^{\prime })]=0$ for all relevant times. Otherwise time ordering is essential:The meaning is explicit in the first terms of the ordered series,the later-time operator stands on the left. In the position representation, the same propagation is expressed by the quantum-mechanical propagatorIts initial value is the Dirac delta function ${\delta }^3(\mathbf{r}-{\mathbf{r}}^{\prime })$.

A time-independent Hamiltonian has energy eigenstates satisfying $\hat{H}|n⟩=E_n|n⟩$. A single such initial state evolves asIt is a stationary state: its global phase changes, but its probability density and the distributions of time-independent observables do not. Its energy is sharp. Any quantum superposition entirely within one degenerate energy eigenspace also acquires one common global phase and is stationary. Stationarity does not require zero probability current; for instance, $u_n(\varphi )=e^{in\varphi }/\sqrt{2\pi }$ on the ring has a constant density and persistent circulation when $n\ne 0$.

An arbitrary normalized state can instead contain different energy eigenvalues:A continuous spectrum requires corresponding integrals. For the discrete case, an energy measurement gives $E_n$ with fixed probability $|c_n{|}^2$ (summed over degeneracies), but relative quantum phases change with time. ConsequentlyThe interference terms can oscillate at angular frequencies $(E_m-E_n)/\hslash$. For two populated energy levels, this supplies a characteristic period $2\pi \hslash /|E_m-E_n|$ when the interference term is nonzero. Thus fixed energy populations do not imply a stationary spatial distribution.

For a normalized state and an observable $\hat{A}(t)$, its expectation value isThis is the statistical mean over repeated preparations and measurements. In an eigenbasis of energy eigenstates for a time-independent Hamiltonian and a time-independent $\hat{A}$,Only matrix elements connecting different energies can generate these oscillations. If $[\hat{A},\hat{H}]=0$, its expectation value is constant for every initial state, provided it has no explicit time dependence.

Differentiating the expectation value and substituting the Schrödinger equation for both the bra and ket proves the general Ehrenfest theorem:Equivalently,These manipulations require the state to lie in the relevant operator domains. Taking $\hat{A}=\hat{H}$ gives $d⟨H⟩/dt=⟨{\partial }_t\hat{H}⟩$, so energy is conserved under a time-independent Hamiltonian.

For $\hat{H}={\hat{p}}^2/(2m)+V(\hat{x})$, the canonical commutation relation givesHence the particularly useful position-and-momentum form of Ehrenfest theorem isIt resembles Newton's second law, but the mean force generally differs from the force at the mean position. If a narrow wave packet samples a region where the force varies little, $⟨V^{\prime }(x)⟩\simeq V^{\prime }(⟨x⟩)$ gives approximate classical motion. For a quadratic potential energy this replacement is exact. In particular the quantum harmonic oscillator obeysThe centroid follows the classical harmonic oscillator, although this does not specify the full evolving wavefunction or its width.

The Heisenberg picture expresses the same physics by assigning evolution to observables instead:The expectation value is unchanged, and differentiation yields $d{\hat{A}}_H/dt=(i/\hslash )[{\hat{H}}_H,{\hat{A}}_H]+U^{†}({\partial }_t{\hat{A}}_S)U$. Thus state propagation, evolving expectation values, and the classical correspondence in Ehrenfest theorem are mutually consistent descriptions of the same unitary time evolution.

Write $k=\pi /a$, $A=\sqrt{2/a}$ and ${\Psi }_0=A{e}^{ikx}\sin kx$. Its derivative isIntegration by parts with the Dirichlet boundary conditions gives the energy expectationIt is constant in time, since the time-independent Hamiltonian operator has fixed energy measurement probabilities: $⟨H{⟩}_t={\sum }_n{E}_n|c_n{|}^2$.

For the midpoint parity operator, $R{\Psi }_0=-A{e}^{-ikx}\sin kx$. Hence, again putting $u=kx$,Indeed the imaginary part integrates to zero by reflection and ${\int }_0^{\pi }\cos 2u{\sin }^{2}udu=-\pi /4$. This expectation value is also constant in time, because the bounded self-adjoint operator $R$ commutes with $H$ and hence with its time-evolution operator. Equivalently, $⟨R{⟩}_t={\sum }_n(-1{)}^{n+1}|c_n{|}^2$.

For the momentum operator, direct evaluation givesThe real sine-cosine integral vanishes. This expectation value is not constant in time: the infinite square well walls reverse motion. One can prove the change exactly without approximating the wavefunction. Atthe energy eigenstate expansion and $R{\psi }_n=(-1{)}^{n+1}{\psi }_n$ give $\Psi (t_{\ast })=-R{\Psi }_0$. Differentiation shows $PR=-RP$, soThis half revival in an infinite square well is a concrete counterexample to momentum conservation. The sign from $-R$ is only a global phase.

The apparent interior identity $[H,P]=0$ cannot justify conservation here: the momentum operator does not preserve the Dirichlet boundary conditions of the Hamiltonian operator's operator domain. For sufficiently regular states, retaining the boundary terms in Ehrenfest theorem instead gives the boundary force in an infinite square well,In the strictly confined interval, $-i\hslash {\partial }_x$ with both endpoint values zero is symmetric but not itself a self-adjoint operator. The requested integral is the conventional mean momentum; it also equals the full-line momentum mean of the zero-extended state, as measured upon releasing the walls. This domain distinction explains why the formal interior commutator misses the wall force.

A physicist associated with the Ehrenfest theorem and, with Tatyana Afanasyeva-Ehrenfest, the Ehrenfest model.