For a ferromagnetic Ising model with coordination number of a lattice , its mean-field self-consistency equation is . Put . For , the only solution is zero. For , strict concavity of on gives one positive solution and its spin-reversed partner. Expanding gives , proving a continuous onset with order-parameter critical exponent . The Bragg-Williams free energy of the Ising model has a positive quartic coefficient at , so these are the stable ordered minima rather than a first-order jump.
For a scalar quartic Landau free energy with , rescaling gives this minimized scaling form, with and . The two functions minimize . In particular and . Below the transition the equilibrium field dependence has a cusp at zero; pure-phase derivatives are one-sided. The form gives order-parameter critical exponent and magnetic-susceptibility critical exponent .
The uniform mode of a pure Gaussian field theory with negative squared mass has an unbounded quadratic energy. Its partition function diverges even with a finite-volume ultraviolet regulator, so it supplies no stable ordered branch. At positive squared mass the zero-source average is zero. Thus the scaling dimension of the field can yield a formal order-parameter critical exponent without establishing a negative-reduced-temperature magnetization law. A stabilizing quartic interaction is relevant below four dimensions and ordinarily changes the critical theory to the Wilson-Fisher fixed point; above four its coefficient is a dangerously irrelevant coupling for the ordered phase.
With the dimensionless magnetic field conjugate to the magnetization, . Set and differentiate the homogeneous free-energy density:
On the ordered branch, the one-sided value is nonzero, so the order-parameter critical exponent is
To reach the critical isotherm, take at fixed nonzero . Suppose at large . Cancellation of the residual thermal factor requires . Hence and
The singular scaling function determines the nonanalytic critical-isotherm contribution; any analytic response background is subleading for the usual .
Critical exponents describe leading singular powers near a continuous phase transition. Using the reduced temperature , the standard definitions include
These are the order-parameter critical exponent, magnetic-susceptibility critical exponent, heat-capacity critical exponent and correlation-length critical exponent. The critical-isotherm exponent is defined by . The anomalous dimension gives the critical long-distance connected correlation function, , when an ordinary scale-invariant critical point exists.
In the Landau approximation, minimize the Landau free energy to obtain the equation of state, differentiate it with respect to the field conjugate to an order parameter to obtain magnetic susceptibility, and differentiate the minimized free energy with respect to temperature to obtain heat capacity. These operations determine , respectively. Expanding the Landau-Ginzburg theory about its uniform minimum gives the quadratic fluctuation kernel , whose Fourier transform determines the correlation length and the anomalous dimension. At the ordinary quartic critical point this gives and .
For , gives and hence ; the equilibrium free energy gives a finite heat capacity discontinuity, conventionally . Together with the explicit calculation below, the ordinary mean-field critical exponents are
These describe neglect of fluctuation corrections, rather than the exact exponents of every low-dimensional Landau-Ginzburg theory.
A tricritical point is the meeting of a line of continuous phase transitions and a line of first-order phase transitions. In the symmetric scalar Landau free energy, it occurs at with . Two independent controls are needed to tune both coefficients. The continuous transition lies at , and the tricritical three-phase line found above has ; both approach the tricritical point. At zero conjugate field the three coexisting states on this first-order line are the disordered state and the two opposite ordered states.
Setting makes the leading stabilizing interaction sextic. The nonzero minimum obeys , so the order-parameter critical exponent along this tuned direction is . Substitution gives
and two temperature derivatives give the heat-capacity critical exponent . At , the equation of state is , giving the critical-isotherm exponent .
For magnetic susceptibility, differentiating gives . This is above the transition and below, hence . The quadratic fluctuation kernel still has a mass proportional to , giving and . Thus the mean-field tricritical exponent calculation yields
Detuning gives tricritical crossover scaling; one must specify the approach to the tricritical point when quoting these critical exponents. The sextic interaction has upper critical dimension three, so sufficiently strong long-distance fluctuations change these mean-field predictions below three dimensions.
Take the symmetric scalar Landau free energy with , for a positive constant , and leading equation of state
At zero conjugate field, minimization gives for and for . Selecting the positive pure thermodynamic phase,
Consequently the order-parameter critical exponent is .
Differentiate the equation of state at fixed temperature, within the selected phase:
Both sides diverge as , so the magnetic-susceptibility critical exponent is . The leading above-to-below magnetic susceptibility amplitude ratio is two. These are the ordinary mean-field critical exponents, valid under the fluctuation qualification explained above.
Write for inverse temperature to distinguish it from the order-parameter critical exponent. A normalized blocking kernel is a nonnegative conditional distribution of coarse spins given the fine spins, normalized by
For deterministic blocking it can impose a majority rule or block average, with a Dirac delta replacing the sum constraint for continuous coarse variables. Each block occupies original cells, so the new lattice spacing and number of sites are
The physical volume is unchanged. After blockings, and .
Define the coarse statistical Hamiltonian by the exact Boltzmann-weight identity
The operator family must include all generated interactions for this renormalization-group transformation to be exact; restricting it to a few couplings is an approximation. The scalar has energy units and is the contribution per original site that is independent of . Restoring the original constant term gives
hence
This convention measures per original site; defining a constant per new site would move a factor into its definition.
The identity-operator contribution to renormalization-group free energy records the configuration-independent normalization generated by the eliminated spins. It includes their contribution to free energy, including entropy and measure factors, and need not be independent of temperature. It has no effect on normalized probabilities of the retained spins, but is indispensable for the total partition function and its temperature derivatives. Iterating its recursion gives
Thus is the original constant plus the accumulated free-energy contributions of the eliminated degrees of freedom.
To obtain the additive free-energy recursion under blocking, use energy-valued free energy per current lattice site,
The blocking kernel normalization implies
Substituting the recursion for cancels , giving
A second step gives , and induction proves
For dimensionless free energy , multiply throughout by .
The singular free-energy density must be distinguished from the exact per-site representative . If is a regular background and , then
Thus the same displayed inhomogeneous recursion holds with after subtraction. When a suitable analytic background solves , it leaves a homogeneous singular recursion. Analytic subtraction of an inhomogeneous renormalization recursion explains this separation. A renormalization-group free-energy resonance can obstruct analytic subtraction and produce a logarithm. The original function originates in the short-distance spins that were summed out, rather than in an extra external interaction.
Near a renormalization-group fixed point , linearize the transformation:
An eigenvector of with eigenvalue defines a scaling coordinate with to leading order. A relevant operator has : its coupling grows towards large distances, so it must be tuned to reach the fixed point. An irrelevant operator has and dies away; a marginal operator has and requires higher-order flow analysis. An operator of scaling dimension has .
The coarse spins also require a multiplicative normalization. In continuum notation, write
where is the retained field and is its anomalous dimension. This restores the normalization of the critical long-distance connected correlation function. Since a uniform field conjugate to an order parameter enters through , it has eigenvalue exponent .
Let be the thermal relevant coordinate with exponent . After regular backgrounds have been removed, the leading singular free-energy density obeys
for a large total scale factor . Choosing gives the scaling hypothesis for critical phenomena
Two temperature derivatives give the heat-capacity critical exponent; one conjugate-field derivative gives the order-parameter critical exponent; two such derivatives give the magnetic-susceptibility critical exponent. Scaling the correlation length gives . Consequently,
At , instead choose ; differentiating gives . These scaling relations for critical exponents assume that irrelevant variables can be set to their fixed-point values without singular consequences. A dangerously irrelevant coupling or logarithmic correction requires keeping the corresponding dependence.
For the Gaussian field theory, integrate out the Fourier modes in and retain . The modes are independent at zero external field, so this Gaussian thinning transformation changes the normalization by a Gaussian determinant and leaves a quadratic statistical Hamiltonian for the retained modes. Restore the cutoff with
In the integrated statistical Hamiltonian, the volume element contributes , each gradient contributes , and each field contributes . Thus the coefficient of the gradient energy is unchanged, while
In particular , and . The Gaussian critical exponents and the Gaussian order-parameter scaling index therefore give the requested indices
The sign convention corresponds to the physical conjugate field and does not affect these powers.
There are physical qualifications to these Gaussian indices. The strictly quadratic Gaussian field theory is stable for positive and has no stable ordered phase for negative ; its purported spontaneous is therefore the formal Gaussian order-parameter scaling index. A stabilizing quartic term gives an actual ordered phase. Below four dimensions that term is relevant and changes the exponents; above four dimensions it is a dangerously irrelevant coupling and gives the actual mean-field , rather than the Gaussian hyperscaling value.
The heat capacity power can also be checked directly. Apart from constants, the zero-field Gaussian free-energy density is
If , its singular second temperature derivative is controlled by . For , rescaling gives a power , as above. At there is a logarithm, and for an analytic background dominates the heat capacity. The negative formal Gaussian then describes the subleading singular piece, with logarithmic resonances at appropriate even dimensions. This is the Gaussian specific-heat infrared threshold, and it prevents confusing singular indices with the entire observable.
Write to distinguish inverse temperature from an order-parameter critical exponent. For the Ising model, define the full two-point correlation function and its connected correlation function in a translation-invariant phase. Away from a thermodynamic critical point, the large-distance envelope decays exponentially, possibly multiplied by a power of distance:
This defines the correlation length in physical distance units when the limit exists. At a continuous phase transition, and the critical connected correlation function typically has algebraic decay , where is the anomalous dimension. Below the transition the full tends to , so the decay definition must use .
Let and be the extensive Helmholtz free energy. Holding the field-independent constant and other physical couplings fixed,
Because the Hamiltonian contains , and . Translation invariance then proves the correlation-function susceptibility sum rule:
In the ordered zero-field phase these statements refer to a selected pure thermodynamic phase; averaging equally over opposite magnetizations introduces the separate spin-mixture contribution to zero-field susceptibility.
A normalized blocking kernel satisfies . For example, assign one block spin to each block of microscopic spins using majority sign, with equal probabilities for a tie. Define the blocked Hamiltonian, retaining the entire generated operator space, by
The field-independent contribution belongs to the identity operator. With and
summing over proves exactly. Iterating gives and the same partition function with . Observables at large scales are reproduced by appropriately blocked observables and sources. Truncating the generated interactions makes this an approximation; dropping the additive constant already destroys the equality of free energies even when normalized spin expectations remain correct.
The extensive Helmholtz free energy is unchanged: . In contrast, its value per site changes because the number of sites changes. Define the reduced zero-constant free-energy density in the thermodynamic limit. The preceding equality yields
and iteration proves the additive free-energy recursion under blocking:
Equivalently . Thus the inhomogeneous source records the identity-operator contribution to renormalization-group free energy from eliminated short-distance degrees of freedom.
To express this recursion for the singular part, write , where is the regular analytic background. Then the same displayed recursion holds with and
This is the analytic subtraction of an inhomogeneous renormalization recursion. A purely analytic source can often be absorbed into , after which it does not control the leading singular powers. It is not legitimate simply to discard an analytic source in the full free energy, where it can dominate the regular background. Moreover an analytic monomial contributes
If , the sum is and hence generates a logarithm when : a renormalization-group free-energy resonance. Such a term cannot be discarded when describing that logarithmic singularity. Neglect of the inhomogeneous term in the leading power-law scaling therefore assumes that its regular part has been subtracted, that any remaining source only changes finite scaling amplitudes, and that there are no relevant resonances or marginal logarithms. Omitting an irrelevant operator further requires absence of a dangerously irrelevant coupling, whose vanishing limit can make a scaling function singular.
A renormalization-group fixed point obeys . Linearization gives ; in eigenvector coordinates . Positive label relevant operators, negative label irrelevant operators, and zero labels a marginal operator requiring nonlinear analysis. The critical surface is the stable manifold obtained by tuning all relevant scaling fields to zero. A repulsive renormalization-group trajectory leaves the fixed point along a relevant direction as the observation length increases. Locally a typical zero-field section has , , , so the critical surface attracts along , while trajectories with either sign of depart from it. A magnetic scaling field adds another relevant direction.
Figure 1.
Renormalization-group saddle flow in a zero-field section and two relevant directions transverse to the critical surface
. Details.
Under the stated homogeneous-scaling assumptions and after fixing irrelevant fields at their limiting values, two relevant scaling fields obey , . These fields are analytic coordinates near the renormalization-group fixed point, proportional to the physical reduced temperature and conjugate field to leading order. The singular free-energy density consequently obeys
Here denotes the singular free energy per original site or unit volume, with regular dimensional factors absorbed; the extensive singular part is . Iterate and choose to obtain the scaling hypothesis for critical phenomena:
The sign labels the two sides of the transition: describes , the disordered side, while describes , the ordered side. The two functions need not coincide; has the zero-field one-sided derivative appropriate to spontaneous magnetization. The numbers are scaling eigenvalues in logarithmic form: the corresponding discrete RG multipliers are .
The correlation length obeys . The same scale choice gives . Differentiating once and twice with respect to the conjugate field, and twice with respect to temperature, gives
At , instead choose the scale . Then and , so . Thus differentiation and scale matching establish
The first is the Widom scaling relation and the second the hyperscaling relation. The hyperscaling relation requires precisely the regular homogeneous scaling used here. Above the ordinary upper critical dimension, the quartic coupling is dangerously irrelevant in the ordered phase and this derivation cannot discard it: the mean-field critical exponents , do not obey for . At marginal dimensions logarithmic factors likewise require care beyond the displayed pure powers.
Critical exponents describe leading singular powers as the reduced temperature or conjugate field approaches zero. With used for the order-parameter critical exponent to avoid confusion with inverse temperature, the definitions include
At criticality the connected correlation function behaves as . These definitions refer to the singular part and allow additional logarithms at marginal dimensions.
For an ordinary scalar Landau free energy, the equation of state is . Below the transition , giving . Differentiating the equation of state gives : it equals above and below the transition, so . The quadratic fluctuation kernel is in the symmetric phase, giving correlation length and . At zero mass the momentum-space correlation function is proportional to , so . The minimized free energy and critical equation of state give and , as calculated in the root solution.
At the tricritical point, and . Then , and is above and below the transition. The gradient kernel still gives and . Therefore
These are mean-field critical exponents. A systematic derivation incorporating fluctuations uses the renormalization group, extracts the relevant scaling eigenvalues, and differentiates the singular free-energy density, as in Question 3.
Write , with the Boltzmann constant. For independent Ising spins, the one-site partition functions on the two sublattices are and . Differentiating each logarithm with respect to its local field gives
At , the two sublattices experience opposite fields, so spin reversal combined with sublattice exchange leaves the Hamiltonian invariant and gives .
For the antiferromagnetic Ising model, take sites, equal sublattice sizes and neighbors per site. There are bonds counted once. The two-sublattice Ising mean-field approximation expands each bond as
and drops only the product of fluctuations. Summing the remaining terms gives
The printed constant omits ; for a total Hamiltonian with unnormalized spin sums, this factor is necessary. Applying the independent-spin calculation now gives
The mean-field approximation is favored by large coordination number: averaging many neighbors reduces local relative fluctuations. The size of critical fluctuations still has to satisfy the Ginzburg criterion; high dimension is a reason for validity, not permission to discard every correlation in every regime.
Antisymmetric solutions and the transition. At , putting makes both equations reduce to . A zero-field continuous transition concerns as well: nonzero explicitly selects the staggered sign and rounds this critical bifurcation. Put . The graphical intersections of and give only for . For there are additionally two nonzero intersections : on , is strictly concave, initially increases, and is negative at , so there is exactly one positive root. Spin reversal supplies the negative root. The origin becomes unstable in the staggered direction, whereas the nonzero roots have and are stable. Expanding about the bifurcation gives
Thus turns on continuously, with and order-parameter critical exponent .
Figure 1.
Antiferromagnetic mean-field graphical solutions and continuous onset of staggered magnetization
. Details.
Uniform solutions. At , imposing instead gives . The function has derivative , is negative at and positive at , and consequently has exactly one zero for every positive temperature. At this zero is . Antiferromagnetic exchange opposes uniform polarization, so the uniform branch has no ferromagnetic ordering bifurcation. This does not remove the antisymmetric solutions below , or exclude transitions of staggered order in the full problem at nonzero uniform field. In particular, uniqueness on the diagonal is not uniqueness of all solutions.
Free energy and stability. The appropriate off-shell two-sublattice Ising variational free energy is the energy minus temperature times the independent-spin entropy. Define
There are bonds and spins of each kind, so the free-energy density per site is
Since , stationarity gives
and the analogous equation for ; these are exactly the two mean-field self-consistency equations. On a stationary solution, the identity gives the equivalent on-shell expression
The entropy form must be used to compare off-shell variations; treating this latter auxiliary expression as the variational potential would give spurious stability conclusions.
Using and , gives
This includes the requested quadratic expansion and first-order field terms. The positive quartic coefficient verifies a continuous phase transition in when the staggered quadratic coefficient changes sign at . The uniform quadratic coefficient remains positive.
Susceptibilities and a printed error. On a stable zero-field ordered branch let and . Since the derivative of is , differentiating the two equations with respect to the uniform field gives
Their sum and difference yield
The difference equation is ; stability implies for . Symmetry also explains the zero result: a uniform perturbation changes the two sublattice magnetizations equally to first order, and hence does not linearly change the staggered magnetization. This is a cross response to , not the magnetic susceptibility to the staggered field .
The displayed in the source instead contains . It cannot follow from differentiating the stated equations. A decisive limiting check is : vanishes exponentially and the actual uniform response tends to zero, whereas the printed expression tends to . Above , and the same linear system gives
For comparison, the actual staggered susceptibility is , becoming above . Its divergence, rather than a divergence of the uniform response, detects antiferromagnetic criticality.
Let be the thermal and magnetic scaling fields, with eigenvalues and . After discarding irrelevant variables whose vanishing is nonsingular, the homogeneous singular free-energy density satisfies
Choose . Then
Two thermal derivatives give the heat-capacity critical exponent; one and two field derivatives give the order-parameter critical exponent and magnetic-susceptibility critical exponent. The correlation-length critical exponent follows directly from the length rescaling. Thus
At , choose . Differentiating gives , so . The order parameter has scaling dimension ; therefore its critical connected correlation function has power . Comparing with yields
These formulas express the requested critical exponents in terms of the relevant scaling exponents. Their hyperscaling assumptions must be respected: above an upper critical dimension, a dangerously irrelevant coupling can invalidate the free-energy homogeneity used here. Applying the formulas to the Gaussian thinning transformation in the root solution gives the requested Gaussian indices and their physical qualifications.
The mean-field approximation replaces each site's fluctuating surroundings by a self-consistent average. On a cubic lattice each spin has coordination number of a lattice , even though summing only over positive basis directions counts each bond once. Write and drop products of deviations. Each Ising bond becomes , so the approximate statistical Hamiltonian is
The constant corrects counting each bond twice. The resulting independent-spin partition function is , where . The one-spin probabilities give
Equating this average with the assumed gives
Here is assumed; a ferromagnetic order parameter is not the appropriate choice for an antiferromagnetic coupling. Put . For , at any , so only is possible. For , the function has positive slope at zero, is strictly concave on and is negative at . It therefore has exactly one positive zero and a spin-reversed negative zero. Expanding at the bifurcation gives
The transition is continuous, with order-parameter critical exponent . Stability can also be checked from the Bragg-Williams free energy of the Ising model per Ising spin:
Its derivative is , giving the same self-consistency equation. Near zero,
The quartic coefficient is positive at , the stable minima approach zero continuously, and the minimized free energy has no first-derivative jump. Thus mean-field approximation predicts a second-order transition at . This is the mean-field Ising critical bifurcation.
For short-range interactions, large dimension gives many neighbours and suppresses the relative fluctuations of their average. More quantitatively, Gaussian field theory fluctuations averaged over a correlation volume have variance of order , while the squared ordinary mean-field order parameter is of order . Their ratio is proportional to . The Ginzburg criterion therefore makes neglect of critical fluctuations asymptotically consistent above four dimensions, inconsistent below four, and marginal at four, where logarithms occur. Large dimension is a route to validity; sufficiently long-range or infinite-range interactions can also produce mean-field behaviour. In low-dimensional short-range systems even the existence and location of a transition can differ from this approximation.
Use for inverse temperature, to distinguish it from the order-parameter critical exponent . In a translation-invariant pure thermodynamic phase, the connected two-point correlation function is
For finite correlation length, at it decays exponentially, possibly with an algebraic prefactor; is the asymptotic exponential decay rate. Below an ordered transition the pure phase is selected by taking the thermodynamic limit before or . A zero-field symmetric mixture of the two ordered phases has a nondecaying connected term and does not describe the usual pure-phase magnetic susceptibility.
Let denote extensive physical free energy and . Since the field contributes to the statistical Hamiltonian, differentiation gives
Expanding the variance and using translation invariance proves the correlation-function susceptibility sum rule:
The sum includes . If the source is instead defined as the dimensionless quantity , the corresponding derivative omits the displayed inverse-temperature factor.
A real-space renormalization group step of length factor uses a local blocking kernel satisfying . For example, a deterministic majority-spin rule assigns one coarse Ising spin to each block; tied blocks can be resolved with equal probabilities. Define the blocked statistical Hamiltonian by
The spacing becomes . All generated interactions, including multispin terms and the field-independent constant, must be retained for an exact transformation. Summing over uses normalization to prove . Iteration gives and .
The coarse probability law is the exact marginal law of these block variables. Indeed, for any coarse observable , its expected value is the microscopic expected value of . A blocking rule that retains the long-wavelength order-parameter mode, with source and observable transformations tracked, therefore retains long-distance response and correlation functions. Their field normalization may change, while their physical length scales and critical singularities do not. Partition-function equality alone would not justify this assertion for an arbitrary kernel that discards all slow variables. Truncating the generated operator family is likewise an approximation.
For the free-energy recursion use dimensionless free energy per site,
in the thermodynamic limit. Exact partition-function invariance gives . If one step sends to , the coefficient records the identity-operator contribution from eliminated fluctuations and normalization. Consequently
Repeated substitution derives the additive free-energy recursion under blocking:
In physical energy units, divide this convention by . The additive term is essential for absolute free energies even when it does not affect the leading critical powers.
A renormalization-group fixed point satisfies . Linearize in scaling coordinates so that . A relevant operator has , an irrelevant operator has , and a marginal operator has with behaviour decided by nonlinear terms. Thus the eigenvalues of the discrete linear map are ; the sign criterion applies to the generator exponents , not to the discrete multipliers. The critical surface is the stable manifold on which every relevant scaling field has been tuned away. Irrelevant coordinates flow to the renormalization-group fixed point along it. A repulsive renormalization-group trajectory leaves the renormalization-group fixed point along an unstable relevant direction, ultimately entering a noncritical phase or another scaling regime.
Figure 1.
Local renormalization-group flow in the zero-field slice: attraction along the critical surface and repulsion in the thermal direction
. Details.
To separate the singular free-energy density from its regular background, suppose the eliminated-mode contribution is analytic near the renormalization-group fixed point. Look for an analytic background satisfying . Then satisfies . In linear thermal and field coordinates, an analytic monomial has background coefficient
provided the denominator is nonzero. This explicitly explains when analytic subtraction of an inhomogeneous renormalization recursion works. The printed inhomogeneous equation may describe the free-energy function before this subtraction, or a singular part defined only up to analytic terms. The inhomogeneous sum need not be small compared with the full free energy: an analytic constant can dominate a vanishing singular contribution. It can be omitted in deriving leading singular powers after regular subtraction, provided no renormalization-group free-energy resonance, marginal logarithm or dangerously irrelevant coupling obstructs the homogeneous critical asymptotics. At a renormalization-group free-energy resonance , additive logarithms can remain, so simply dropping the term would miss them.
Suppose there are exactly two relevant scaling fields, thermal and magnetic , with positive exponents , and the remaining fields approach a regular limit. Physical reduced temperature and magnetic field agree with these coordinates to leading order, up to nonuniversal metric factors. The homogeneous scaling hypothesis for critical phenomena is
as an asymptotic scaling equation. Choose to make the thermal argument or . Defining gives
The two functions describe respectively and : approaching the transition from disordered and ordered sides need not give the same function. In particular the ordered zero-field function has one-sided derivatives associated with spontaneous magnetization. Metric factors multiply this formula in different microscopic normalizations.
The correlation length in Bravais lattice units obeys . At , the same choice of gives . Two thermal derivatives of give . One and two field derivatives give, respectively, and , assuming the relevant branch amplitudes are nonzero. At , choose ; then , so . Hence
Simple algebra now gives the Rushbrooke scaling relation and the hyperscaling relation . Also , giving the Widom scaling relation. These statements refer to leading singular contributions with the homogeneous two-field scaling assumptions. Above the upper critical dimension, the quartic coupling is dangerously irrelevant because it is still needed to stabilize the ordered phase; ordinary mean-field critical exponents then satisfy Rushbrooke and Widom but generally not hyperscaling. Marginal logarithms also require qualifications at the upper critical dimension.
For the connected-correlation scaling form , the function tends to a finite nonzero value as and decays exponentially at large , up to powers of , in a massive short-range phase. The scaling ansatz alone does not fix that prefactor. If the usual massive Gaussian field correlation tail applies, matching the powers gives , with a correlation-length-dependent amplitude in fixed by matching the critical scaling form.
In physical coordinates the lattice sum has site-density factor . Its long-distance singular part therefore gives
where is the area of the unit sphere in dimensions. For , finite , an integrable exponential tail and a nonzero integral, the last factor tends to a finite nonzero constant as . Microscopic distances contribute a regular background. Thus , proving the Fisher scaling relation
Equivalently the field has scaling dimension , so its conjugate field has , which gives the same identity from the exponent formulas above.
A critical exponent describes the leading singular power of an observable in a specified scaling limit. The order-parameter critical exponent describes the zero-field ordered branch; the magnetic-susceptibility critical exponent describes response to its conjugate field; and the critical-isotherm exponent describes response at the critical temperature. They are found in the Landau approximation by minimizing the potential and differentiating the resulting equation of state, as calculated in the question's root solution. For a leading stabilizer the same calculation gives , and . Thus , and . Beyond the Landau approximation, the renormalization-group relevance exponents and anomalous dimension determine the singular powers; Question 2 derives their relations. The critical exponents refer to specified paths, and tuning to a higher multicritical point requires eliminating its lower relevant perturbations.
A phase diagram locates stable pure thermodynamic phases and their phase coexistence boundaries in a space of control parameters. For a concrete three-dimensional example, take the temperature, crystal-field parameter, and magnetic field of the Blume–Capel model. Its spins take values ; changing the cost of the zero-spin state can turn a continuous ordering transition into a discontinuous one. A local scalar description near the resulting tricritical point is the Landau-Ginzburg theory
The three local control coordinates are , with varying linearly with the thermal scaling field. For , , the transition at is continuous. For , zero-field coexistence is at , and the magnetization jumps between zero and . The two loci meet at , the tricritical point.
The full three-dimensional phase diagram has an ordered coexistence sheet at , where the two opposite magnetizations exchange stability when changes sign. On its three-phase line it meets two nonzero-field tricritical wings. These wings are first-order phase transition surfaces between minima of the same sign but different magnitude, terminating at ordinary thermodynamic critical points. Their tricritical wing critical edges are found by :
Indeed fixes , and substituting into and gives ; ensures a stable critical quartic minimum. The two signs give the two wings. All transition surfaces and critical edges end together at the tricritical point. The following plot uses ; its wing surfaces come from the exact tricritical wing coexistence factorization, rather than schematic unconstrained surfaces.
Figure 1.
Tricritical coexistence surfaces, the zero-field phase diagram, and ordinary, first-order and tricritical Landau potentials
. Details.
The unheaded requests for critical exponents follow from the uniform equation of state
For an ordinary thermodynamic critical point, is fixed and , . At , , the small ordered minimum obeys , so the order-parameter critical exponent is . Above the transition , giving the magnetic-susceptibility critical exponent . At , , so the critical-isotherm exponent is . At the tuned tricritical point, , instead below the transition and on its critical isotherm, while the disordered susceptibility remains . Therefore
Below the transition the inverse susceptibility is , giving in the ordinary limit and in the tricritical limit. Thus both sides give the same susceptibility power, with different amplitudes.
To derive the general Ginzburg criterion, tune away all lower even nonlinearities and let the leading stabilizer be , . The equation of state gives , and its curvature at the ordered saddle is , so . The fluctuations of the order parameter averaged over a correlation volume are estimated by its long-wavelength quadratic covariance:
The integral has a fixed dimensionless upper limit after ; this is a coarse-volume fluctuation estimate, not the ultraviolet-dominated point variance. Consequently the multicritical Ginzburg ratio is
The Landau approximation is asymptotically controlled by this test only when the ratio tends to zero. This gives the upper critical dimension
The same threshold follows by giving its Gaussian engineering dimension : the coupling to has scaling exponent , which becomes relevant below .
For , the fluctuation ratio diverges and the saddle calculation cannot predict the generic interacting critical exponents. At the test is marginal, not a proof of changed power exponents: the ratio has zero thermal power and marginal interactions can produce logarithmic corrections. Thus the PDF's inclusion of equality in a blanket claim about wrong power exponents needs this qualification. The Landau-Ginzburg theory as a fluctuating field theory remains useful; what loses validity is its fluctuation-free Landau approximation.
A phase diagram partitions a space of control parameters into regions with distinct equilibrium phases. Its boundaries mark nonanalyticities of the thermodynamic-limit free energy; a first-order phase transition has a jump in a first derivative, whereas a continuous phase transition has a continuously vanishing order parameter and singular fluctuations.
An explicit three-parameter example is the scalar Landau free energy
with parameter axes . These can be realized locally by the temperature, single-ion anisotropy and magnetic field of the Blume–Capel model. The three dimensions here refer to control-parameter space, not necessarily to three spatial dimensions. At , minimizing this potential gives a continuous phase transition at for . For , coexistence occurs at , where
There are three global minima, and . Their order parameter jump decreases to zero as . Thus is a tricritical point. The two transition curves in the plane meet there.
In the three-dimensional phase diagram, crossing inside the ordered region switches between opposite signs of , so that region is itself a first-order phase transition sheet. For , two tricritical wings at opposite nonzero fields separate weakly and strongly magnetized phases. Their wing critical edges can be obtained rather than merely sketched: require . Since , the nonzero solutions satisfy
The fourth derivative there is , giving ordinary continuous critical endpoints. The wings meet the zero-field coexistence sheet along the tricritical three-phase line and terminate at these edges. Their exact tricritical wing coexistence factorization supplies the surfaces in the figure: for two nonnegative minima , set , and
Direct expansion gives , proving that these surfaces describe coexistence of global, not merely local, minima.
Figure 1.
Tricritical phase diagram of the sextic scalar free energy: first-order sheets, critical edges and the zero-field slice
. Details.
For the unheaded Ising model calculation, assume ferromagnetic exchange and let denote the mean Ising spin. On the hypercubic lattice the coordination number of a lattice is , even though the original positive-direction bond sum counts each bond only once. The mean-field approximation neglects products of deviations from :
There are bonds, so the approximate energy is . Each independent Ising spin therefore sees the effective field . With , averaging its two Boltzmann weights gives the self-consistency equation
The slope of its right side at zero is , where
Above , for excludes a nonzero solution. Below the initial slope exceeds one, and concavity of the hyperbolic tangent on the positive axis gives one positive solution and its negative partner. The Ising auxiliary mean-field free energy has positive quartic coefficient near , while its quadratic coefficient changes sign there. Its stable minima therefore move continuously away from zero; this is a continuous phase transition in the mean-field theory of the Ising model.
Put and . The Taylor expansion gives, on the nonzero branch,
Consequently and the mean-field order-parameter exponent is . The inverse-temperature symbol used above is distinct from this order-parameter critical exponent.
A critical exponent specifies a leading singular power in a response or order parameter as the thermodynamic critical point is approached. Analytic backgrounds and the selected thermodynamic branch must be distinguished from that singular part. Write , , and first take . The equation of state is .
At zero field on the ordered branch, , giving the order-parameter critical exponent . Differentiating the equation of state gives : above the transition , below it , so the magnetic-susceptibility critical exponent is . At , , giving the critical-isotherm exponent .
The minimized singular free-energy density is above and below. Two temperature derivatives produce a finite specific-heat jump, corresponding to the heat-capacity critical exponent . The inverse quadratic fluctuation kernel is , so gives ; the critical propagator proportional to gives . Thus
These mean-field critical exponents follow from minimization and linear response. More generally, linearize the renormalization group and differentiate its singular free-energy scaling form to obtain the actual fluctuation-controlled exponents.
Critical exponents describe leading power-law singularities as the reduced temperature and the conjugate field tend to zero. Their amplitudes depend on microscopic details, while the exponents are characteristic of a universality class. Define on a selected ordered branch, at zero field, for the singular heat capacity, and . Also define and . In these statements is the order-parameter critical exponent, not inverse temperature.
Assume with and a nonzero positive quartic coefficient . Minimizing the quartic potential gives , hence . Differentiating its equation of state gives
so with different amplitudes. At , , giving . The minimized potential is zero above the transition and below, so its second temperature derivative has a finite jump: .
The quadratic fluctuation kernel around the stable uniform minimum is , so . Since is above and below, . Its critical momentum dependence is , giving . Thus the ordinary mean-field critical exponents are
These are predictions of the Landau approximation, whose validity is constrained by the Ginzburg criterion; they need not be the exponents of the fluctuating theory below its upper critical dimension.