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At normal incidence, continuity of tangential wave phase makes both internal wavevectors normal to the parallel faces. For the ordinary wave in a uniaxial optical medium, the electric field is an eigenpolarization of the permittivity tensor, so $\mathbf{D}\parallel \mathbf{E}$. ThusIts energy path is also normal to the faces. The extraordinary wave differs because $\mathbf{D}\perp \mathbf{k}$ but $\mathbf{E}$ need not be perpendicular to $\mathbf{k}$. In a nonmagnetic crystal, $\mathbf{H}\parallel \mathbf{B}$ and $\mathbf{S}=\mathbf{E}\times \mathbf{H}$ is perpendicular to $\mathbf{E}$. The vectors $\mathbf{D},\mathbf{E},\mathbf{k},\mathbf{S}$ lie in the same meridional plane, with $\mathbf{D}\perp \mathbf{k}$ and $\mathbf{E}\perp \mathbf{S}$. Therefore the electric-displacement angle from birefringent walk-off equals the angular separation between $\mathbf{S}$ and $\mathbf{k}$.

The observed lateral separation is accumulated over thickness $L$, so $\Delta =L\tan {\alpha }_e$. With $L=10\mathrm{mm}$ and $\Delta =0.1\mathrm{mm}$,The two emergent rays are parallel because their outgoing wavevectors are both normal to the faces in air; their internal energy paths can nevertheless be displaced by birefringent walk-off. The angle quoted is the positive angle between the field vectors, so the unspecified lateral direction does not affect its value. The unpolarized light excites both eigenpolarizations; it does not require their energy paths to coincide.

Flint glass is approximately optically isotropic without an applied magnetic field. A longitudinal magnetic field changes the motion of its bound Electrons: the magnetic part of the Lorentz force acts with opposite sense on the two circularly rotating components of a driven electronic oscillation. Their optical response, and hence their refractive indices, split. Equivalently, the transverse permittivity tensor acquires a field-odd antisymmetric contribution whose eigenvectors are opposite circular polarizations.

The resulting circular birefringence gives Faraday rotation. For a weak longitudinal bias it is linear in the field:Here ${\rm Y}$ is the Verdet constant and $L$ the path length. The magnetic field breaks time-reversal symmetry, which is why this rotation is nonreciprocal. Reversing the bias reverses the rotation; reversing propagation while keeping the bias fixed does not undo it when physical polarization directions are compared in fixed laboratory axes. A transverse magnetic bias can have different, higher-order effects; the setup here is the longitudinal Faraday effect.

From molecular dipoles to macroscopic fields. A dielectric contains charges which remain bound to its atoms or molecules. An applied electric field displaces positive and negative charge centres and can orient permanent electric dipoles. The electric polarization $\mathbf{P}$ is electric dipole moment per unit volume, in $\mathrm{C}{\mathrm{m}}^{-2}$. Its associated bound charge isat the boundary of the polarized material, where $\hat{\mathbf{n}}$ points outward. A uniform electric polarization has no volume bound charge, but generally has surface bound charge. The electric field remains the force per unit test charge; it includes the fields of both free and bound charges.

Introducing the electric displacement field $\mathbf{D}={ϵ}_0\mathbf{E}+\mathbf{P}$ packages the free-charge source separately:For a homogeneous linear isotropic dielectric,The electric susceptibility ${\chi }_e$ is dimensionless; the permittivity $ϵ$ has units $\mathrm{F}{\mathrm{m}}^{-1}$. This is a constitutive approximation. An anisotropic dielectric requires a permittivity tensor, while a nonlinear dielectric need not have electric polarization proportional to electric field. The field in these equations is the macroscopic field, not necessarily the local field at an individual molecule.

Interfaces. Let $\hat{\mathbf{n}}$ point from medium 1 into medium 2. Integrating Gauss's law over a thin pillbox, and the electrostatic curl equation around a thin loop, gives the electrostatic interface boundary conditionsThus normal electric displacement is continuous when there is no free surface charge, whereas tangential electric field is continuous even if the permittivity changes. Normal electric field generally jumps because the interface carries bound charge. The electric potential is continuous for an ordinary interface without an ideal dipole sheet. These conditions, together with Laplace's equation in each homogeneous charge-free region, determine the field.

Energy and electrical sources. Reversibly assembling free charge requires incremental work $\delta W=\int \mathbf{E}\cdot \delta \mathbf{D}dV$. For a linear dielectric whose response can be reversibly integrated from zero field, the electrostatic energy isThis includes the material polarization response, rather than simply using ${ϵ}_0{E}^2/2$ everywhere. In a capacitor, $W=Q^2/(2C)=C{V}^2/2$. Inserting a dielectric increases capacitance. At fixed charge the stored energy decreases. At fixed voltage the stored field energy increases, but the voltage source supplies $VdQ$; the appropriate mechanical energy including that source changes by $-V^{2}dC/2$. Both cases predict attraction of dielectric into the capacitor. A force calculation must state which electrical quantity is fixed. A lossy or hysteretic dielectric also dissipates energy, so the reversible quadratic expression does not describe its full history.

Shape and depolarization. Suppose the dielectric is surrounded by vacuum and the distant imposed electric field is ${\mathbf{E}}_0$. Bound surface charge produces a depolarization field. For a uniformly polarized ellipsoid, along a principal axis,Here $N_d$ is the depolarization factor of a dielectric ellipsoid. This self-consistent field explains why the same material responds differently in different shapes.

An infinite slab with electric field normal to its faces has $N_d=1$, giving $E_{\mathrm{in}}=E_0/{ϵ}_r$; its opposite surface bound charges reduce the internal field. For electric field parallel to the faces, $N_d=0$, giving $E_{\mathrm{in}}=E_0$. End effects are neglected.

A very long circular rod in an axial electric field has negligible depolarization away from its ends, so $E_{\mathrm{in}}\simeq E_0$. In a transverse electric field the infinite-cylinder solution has $N_d=1/2$, giving $E_{\mathrm{in}}=2E_0/({ϵ}_r+1)$. To see the latter directly, take the applied field along $x$. The interior and exterior electric potentials can be written ${\varphi }_{\mathrm{in}}=-Br\cos \theta$ and ${\varphi }_{\mathrm{out}}=-E_{0}r\cos \theta +A\cos \theta /r$. Continuity of potential and normal electric displacement at $r=a$ gives $B=2E_0/({ϵ}_r+1)$.

For a sphere of radius $a$, $N_d=1/3$ andFor example, write ${\varphi }_{\mathrm{in}}=-Br\cos \theta$ and ${\varphi }_{\mathrm{out}}=-E_{0}r\cos \theta +C\cos \theta /r^2$. Continuity of potential gives $B=E_0-C/a^3$, and continuity of normal electric displacement gives $ϵB={ϵ}_0(E_0+2C/a^3)$. Solving yields $B=3E_0/({ϵ}_r+2)$ and $C=a^3{E}_0({ϵ}_r-1)/({ϵ}_r+2)$. The $1/r^2$ potential is that of the electric dipole moment above. For ${ϵ}_r=1$ all these induced effects vanish; as ${ϵ}_r$ becomes very large the normal-field sphere and slab approach the corresponding conductor field exclusion. The ideal infinitely long rod in an exactly axial imposed field has a different, singular end-free limit.

The permittivity tensor is the linear material-response matrix relating electric displacement field to electric field at a specified frequency. An isotropic local medium has ${ϵ}_{ij}=ϵ{\delta }_{ij}$. A magnetically biased transparent medium can have an imaginary antisymmetric transverse contribution; its eigenmodes can have opposite circular polarizations and different refractive indices.