Photon decoupling is a dynamical loss of frequent scattering, distinct from the chemical conversion of charged particles into neutral atoms. Before recombination, Thomson scattering on free Electrons keeps photons coupled to the baryon plasma. The physical scattering rate is
in units with . Define the approximate decoupling temperature by
Equivalently the photon mean scattering time becomes comparable to an expansion time. A refined last-scattering definition uses the optical depth and the maximum of the visibility function; it need not coincide exactly with the local rate criterion. As falls, scattering becomes inefficient, ordinarily after the half-ionized recombination stage, so .
Residual electron freeze-out concerns the remaining ionized fraction. The Saha equation presumes sufficiently rapid forward and reverse reactions to maintain chemical equilibrium. Real recombination is slowed by radiative bottlenecks and expansion; the free-electron fraction can therefore exceed its equilibrium value. Eventually the effective recombination rate per free Electron, roughly , falls below . The remaining Electrons cannot all find and recombine with protons within an expansion time. A small nonzero residual fraction survives while the Saha prediction decreases exponentially toward zero.
The sketch shows this lag and residual floor. Its kinetic curve and the position of the decoupling marker are schematic: the data supplied determine the equilibrium curve, but not a quantitative recombination history or an exact . Determining those needs the expansion history and atomic transition rates. The horizontal axis decreases toward the right to follow cosmological cooling.
Figure 1.
Saha equilibrium and a schematic delayed recombination curve, with recombination and photon-decoupling temperatures marked during cooling
. Details.
For fully ionized hydrogen, the outward radiation force on a coupled proton-electron pair at radius is , while its inward gravitational force is approximately . Equating them yields the Eddington luminosity,
This uses isotropic radiation, Thomson scattering and efficient momentum coupling between electrons and ions. Composition or other opacity sources alter the corresponding limit.
With radiative efficiency , a rest-mass supply rate gives . In the approximation that supplied mass is added to the hole, continuous accretion at the Eddington luminosity gives
Here is the elapsed time since seed formation. If the radiated rest mass is counted exactly, and the Salpeter time becomes . The displayed approximation in the question neglects this correction; retaining it lengthens the growth time.
The required growth factor is , corresponding to e-folds. With the supplied efficiency,
At , the expansion is overwhelmingly matter-dominated. Using total and gives
The baryon density is part of the total matter density, so it is not added to in this age calculation. Dark-energy and radiation corrections are small for this estimate. Even starting at the earliest possible time, the approximate growth time exceeds the age, and a real stellar seed forms later. A seed cannot reach the stated mass through uninterrupted Eddington-limited growth with the stated efficiency. Exactly retaining the radiated mass gives about and strengthens this conclusion. A heavier seed, lower radiative efficiency or super-Eddington episodes can relieve the time constraint; interruptions make it harder.
All dots in this solution denote differentiation with respect to conformal time . This is required by comoving , the streaming term , and . The PDF's reference to proper-time derivatives is inconsistent with these coefficients. Proper-time equations follow by dividing the conformal-time equations by , replacing streaming by and the collision rate by .
The monopole equation of the photon Boltzmann hierarchy is ; its collision term vanishes. Consequently the photon continuity equation is
For the dipole the hierarchy gives
Using the relations from the preceding part, the photon Euler equation becomes
Because , the collision term drives the photon velocity towards the baryon velocity, as Thomson scattering should.
For pressureless baryons, stress-energy conservation without energy exchange gives . At this order Thomson scattering changes momentum but not the local photon energy: energy transfer by the relative bulk motion is second order, and recoil/thermal energy exchange is neglected. Total momentum conservation fixes the baryon force to be the negative of the photon force. The momentum densities are proportional to their enthalpy densities, and . Thus
Including the pressureless expansion and gravitational terms yields the baryon Euler equation with Thomson drag
The expansion coefficient for photons cancels against the changing background pressure, while pressureless baryons retain the Hubble drag term. The opposite drag signs and the enthalpy ratio ensure that the combined photon-baryon fluid conserves momentum.
Near the accretor assume fully ionized hydrogen, tight electric coupling between protons and electrons, isotropic radiation and opacity dominated by Thomson scattering. The gravitational force on an electron–proton pair is approximately ; the outward radiation pressure force is . Balancing them gives the Eddington luminosity
Writing defines the radiative efficiency of black-hole accretion. In the approximation that the radiated rest-mass fraction is ignored in the mass bookkeeping, , so at the Eddington accretion rate
This is the printed approximate Salpeter time; for the adopted efficiency. More exactly , giving with . The difference is a ten-percent-level convention here, not a change from exponential growth. Continuous fuelling, constant efficiency and unit Eddington ratio are additional idealizations.
Next normalize the ionizing spectrum rather than replacing every photon by a threshold photon. For above ,
Here is Planck's constant, distinct from the cosmological . The mean ionizing photon energy of a power-law spectrum is therefore . With ionizing luminosity fraction , the hydrogen-ionizing photon production rate is .
Assume a sharp spherical ionization front, homogeneous initially neutral hydrogen at the cosmic mean baryon density, escape fraction one, one primary ionization per photon, and no recombinations or secondary ionizations. The ionization-front growth from an exponentially brightening source is then fixed by photon conservation. In the printed approximate mass convention,
Take the stated separation to be a proper separation at the seed-formation epoch, and take the distant halo to follow the expansion on this large scale. Its initial separation defines a fixed comoving radius . The number of hydrogen nuclei initially within that radius is
Although the proper density subsequently falls, this comoving hydrogen inventory is constant. Thus the photon count does not require freezing the expansion for the entire growth interval.
The supplied critical density gives , so for the initial proper-distance interpretation. Equating requires
and therefore
Light propagation adds a retarded-time correction of order a few million years, small compared with this growth time; it should not be replaced by instantaneous propagation when modelling the very early front. Expansion increases the proper distance to the comoving halo during the wait, but not the required comoving photon inventory. If the unspecified distance is instead a comoving distance, the inventory is smaller by and the corresponding answer is . A distance held at a fixed proper radius until arrival would need a different evolving-volume treatment.
Using exact rest-mass bookkeeping changes to and to . The proper-at-formation case then gives about , and the comoving-distance case about . These modest changes are smaller than the uncertainties of the sharp-front, no-recombination model. In particular real absorption of the high-energy tail, secondary electrons and a nonunit escape fraction would require radiative-transfer corrections.
The small halo initially holds cool gas in hydrostatic equilibrium. Photoionization deposits energy far above its virial binding scale. With the emitted mean energy, the excess per primary ionization is ; if all were converted to thermal energy of one electron and one proton with no cooling, would give about . Allowing atomic cooling, use a representative ionized temperature for an order-of-magnitude escape estimate. Even this is much greater than the initial , so the pressure support that balanced gravity becomes excessive and an outflow develops. The baryons are photoheated and undergo photoevaporation of a dark-matter minihalo; the shallow halo loses much of its gas and its future star formation is suppressed.
For the size estimate assume mean collapsed density times the mean matter density at collapse. Its virial radius of a dark-matter halo is
This is an order-of-magnitude virial convention, not an exact conversion of the approximate quoted temperature: different factors in the virial temperature definition give comparable radii near . Keep the radius of the bound halo fixed after its stated collapse, rather than rescaling it with the later cosmic mean density. Fully ionized pure hydrogen has mean molecular weight . With monatomic , its adiabatic sound speed is
This exceeds the virial escape-speed scale . A sound-crossing outflow estimate gives
measured after the ionization front arrives. Using an isothermal sound speed, a different virial factor or a hotter post-front gas changes this by factors of order unity. It is not a second hundreds-of-millions-of-years black-hole growth interval.
The crossing-time estimate assumes the relevant gas can be ionized without a long trapped-front delay. A simple photon-supply check is useful: initially retained gas mass is , while at front arrival . A halo intercepts roughly the fraction of that isotropic supply. For around one to two proper megaparsecs, its hydrogen inventory divided by the intercepted photon rate is also of order ; continued exponential brightening shortens the constant-flux estimate. Thus a gas-loss estimate of one to a few is justified in the idealized model. A detailed evaporation time is not uniquely determined without the gas profile, post-ionization temperature and shielding; retained recombinations would further delay a front in dense gas.
Throughout this question dots denote conformal time derivatives, and is the conformal Hubble parameter. The monopole of the photon Boltzmann hierarchy gives . With the specified velocity convention, the photon continuity equation is therefore
The dipole equation is . Thus the photon Euler equation is
In particular, makes the scattering term damp the photon-baryon velocity slip; it does not amplify it.
The linear momentum density of the photon-baryon fluid is weighted by enthalpy, not merely energy density:
Elastic Thomson scattering exchanges momentum internally. Its photon force density is , so the baryon force density is its negative. Dividing by gives the baryon Euler equation with Thomson drag
This is the baryon loading parameter, the baryon-to-photon inertia ratio. The two collision terms cancel exactly when the equations are weighted by their enthalpies. Background conservation gives and , so .
In the local orthonormal tetrad, the components of the photon number current are
They are respectively the photon number density and the photon number flux. Thus is the photon number four-current, not an energy current or an electric charge current. Photons carry no electric charge. For the isotropic background,
Integrating the covariant Boltzmann equation over the invariant mass-shell measure, with vanishing momentum-boundary flux, gives
where is the collision operator in the covariant streaming equation. Therefore
Collisionless photon propagation satisfies this condition, as do Thomson scattering and ordinary Compton scattering when all participating photons are counted: each collision has one incoming and one outgoing photon. Photon emission, photon absorption, bremsstrahlung, double Compton scattering and electron-positron annihilation in cosmology or its inverse generally give a nonzero number source. A cancellation of net creation and destruction can nevertheless make the integrated source vanish even when individual number-changing reactions occur. Cosmological redshift itself changes photon energy, not photon number; in an expanding homogeneous universe a conserved photon number current gives .
For a nonzero Fourier mode , the divergence-free condition implies . The complex vectors form a Hermitian orthonormal basis of this transverse plane. Their opposite rotation phases give the helicity decomposition of a transverse Fourier mode; the factor in the amplitudes is a convention. The baryon velocity in this vector sector has the analogous decomposition.
For helicity , the angular source is
The same formula holds for . Thus these sources have only angular order . Streaming multiplies by and the stated Thomson scattering operator is diagonal in , so neither mixes this sector with other angular orders. Assuming the initial anisotropy is in the same vector-helicity sector, or considering the anisotropy generated from zero initial data, the solution therefore contains only with . Arbitrary independently imposed anisotropies of other would instead evolve in their own homogeneous sectors.
There is a genuine normalization inconsistency in the PDF. To retain its printed temperature expansion, write
where denotes exactly the multipoles called in that expansion. The spherical-harmonic streaming recurrence gives the coefficient of in , divided by , as
Here and . Both streaming denominators are therefore , rather than the PDF's and . The dipole source also changes: , so is . The quadrupole collision correction is still .
Thus the vector photon Boltzmann hierarchy consistent with the literal printed expansion is
A concrete counterexample to the printed hierarchy with this expansion is a collisionless instant with and every other multipole zero. Direct streaming gives , whereas the printed hierarchy would give .
Alternatively, preserve the PDF's desired hierarchy by making the photon multipole normalization change
This is the reciprocal angular normalization, not the printed expansion. Multiplying the corrected hierarchy by gives precisely
This supplies both consistent conventions explicitly. The lower coupling vanishes at , so no vector monopole is introduced. Cosmological optical depth to the observer has , giving damping of the dipole and the factor quadrupole damping in this temperature-only collision model; no polarization collision term has been added to the supplied equation.
Let and let differentiate along the unperturbed photon trajectory. Use to decompose the Thomson scattering gain term:
The Orthogonality of Legendre polynomials identifies as a pure photon quadrupole. Dropping is an approximation, justified when tight coupling makes the scattering quadrupole small; the supplied unpolarized equation already neglects polarization corrections. The Cosmic microwave background line-of-sight solution requested here omits that quadrupole source.
Set . Adding to the Photon Boltzmann equation with Thomson scattering yields
Along , the integrating factor is because . Consequently
An early optically thick boundary makes vanish for finite initial perturbations, and . Therefore
Here and are partial time derivatives, not total derivatives along the ray. We work at first order in scalar cosmological perturbations, evaluate sources along the background radial null geodesic in FLRW spacetime, and ignore observer peculiar velocity. Perturbed paths and lensing affect this first-order source solution only at higher perturbative order. A moving observer adds its local Doppler dipole.
The original PDF, unlike the transcribed TeX, also asks for the instantaneous-last-scattering limit and its interpretation. For with no later scattering, and a matter-era growing mode with constant and , the Integrated Sachs-Wolfe effect vanishes. Hence
The four terms are the intrinsic emission temperature, the gravitational potential at emission, the observer's potential, and the Doppler CMB anisotropy. The two potentials describe the gravitational redshift; the observer term is independent of direction and is absorbed into the measured temperature monopole. The intrinsic temperature and emission potential form the Sachs-Wolfe combination. On superhorizon scales for adiabatic initial conditions in matter domination, , giving the ordinary Sachs-Wolfe effect . The Doppler sign is positive with the paper's propagation direction ; the viewing direction is .
Put , the Thomson scattering rate per unit conformal time. The cosmological optical depth is the integrated scattering rate from emission time to observation, so a Poisson scattering process has survival probability
Since , the cosmological visibility function is
A photon scatters in an interval with rate factor and then reaches us without another scattering with probability , so is its probability of last scattering in that interval. For an optically thick initial epoch,
If the initial optical depth is finite, the missing weight represents photons that have already stopped scattering before .
Before cosmological recombination, the optical depth to the present is enormous: , and is also small because almost every scattering is followed by another. Through photon decoupling, rises rapidly and has its dominant positive peak. After decoupling, without reionization, is close to one and reaches exactly one at , while is small because the remaining electron density and scattering rate are small. Residual ionization can give a weak tail; there is no second reionization peak. The peak marks the Cosmic microwave background last-scattering surface.
Figure 1.
The photon visibility function during recombination
. Normalized schematic without reionization. The right curve is the derivative of the left curve and has unit area; the horizontal scale and width are illustrative, not a numerical recombination calculation. Details.
Write . The tight-coupling approximation requires : frequent Thomson scattering makes the photon-baryon velocity slip small and suppresses higher multipoles. Work with constant on the short scales of the question.
Set and . The dipole and baryon equations imply
To leading order, . Differentiating this and keeping the first correction in yields
Terms involving derivatives of contribute at the next order here.
The leading polarization balance is
The temperature equation then becomes
so the photon quadrupole in tight coupling with polarization is
Finally substitute into the corrected dipole equation. This gives the photon-baryon diffusion damping equation
The oscillation frequency agrees with the photon-baryon sound speed. The positive damping coefficient comes from velocity slip and shear viscosity. Its growth as suppresses small-scale oscillations, producing the Silk damping tail and reducing the high-multipole Cosmic microwave background acoustic peaks.
Dropping gravity and expansion from the photon Boltzmann hierarchy gives
The first equation is photon energy continuity: the photon dipole transports the photon monopole. The second is the photon Euler equation: a pressure gradient accelerates the radiation, its quadrupole contributes shear stress, and Thomson scattering drags the velocity toward the baryon velocity.
With , the scattering contribution to is . Radiation momentum density is , whereas baryon momentum density is . Conservation of total momentum therefore requires
or
Since the cosmological optical depth is measured to the observation time, ; the two drag terms reduce their relative velocity.
A scalar Fourier mode selects one spatial direction, , and has no transverse vector or tensor polarization. Rotations about therefore leave its temperature and polarization patterns unchanged. Only azimuthal number occurs in the corresponding spherical harmonic expansion.
Let and use the paper's convention
which omits the factor used in some other definitions of the photon temperature multipole. In Fourier space the transport term is . The Legendre polynomial recurrence relation makes its coefficient at multipole equal to
The gravitational time derivative is purely monopolar, and the potential gradient and baryon velocity are dipolar. Thomson scattering removes the monopole from its relaxation term and adds the quadrupole polarization correction. Thus the photon Boltzmann hierarchy is
The term containing is understood as zero.
At distance , isotropic luminosity produces radiative acceleration in material of opacity . In fully ionized hydrogen, one Electron supplies a Thomson scattering cross-section for approximately one proton mass of material, so . Balancing radiation against the Newtonian gravitational field of the black hole gives the Eddington luminosity
Below this luminosity gravity can confine optically thin ionized hydrogen; above it, electron scattering alone accelerates the gas outward.
An electron--positron pair has mass and total scattering cross-section , so its opacity is . Therefore
The limit is lower because the radiative force per unit inertial mass is larger in a pair plasma.
For a cloud with arbitrary constant opacity per unit mass,
Suppose the luminosity jumps to a constant while the cloud is at rest at . With , its radial acceleration is
Multiplication by and integration from to infinity gives conservation of energy
This result assumes that and remain constant and that the cloud stays optically thin.
Insert the photon temperature multipole expansion into the Fourier-space transport equation. The Legendre polynomial recurrence relation turns multiplication by into nearest-neighbour multipole couplings, while Orthogonality of Legendre polynomials projects onto a fixed . The monopole projection has no collision term because Thomson scattering conserves photon number:
The dipole projection receives the electron-velocity source,
For every , the collision term damps the anisotropic multipole and the photon Boltzmann hierarchy is
Thus the Free-streaming photon Boltzmann equation moves angular structure between neighbouring multipoles, whereas Thomson scattering suppresses all multipoles above the dipole in the tight-coupling approximation.
A distinct classical Thomson scattering window requires two separated scales:
To remove that window, the binding frequency must be comparable with or greater than the Compton scattering recoil scale. Thus the formal condition for bound-electron scattering without a Thomson frequency window is
Using the stipulated approximate electron mass , and gives
The dimensions are . The inequality denotes a scale comparison, not a uniquely specified spring constant or a sharp transition.
There is also a physical limitation to the question's premise. Compton scattering does not begin discontinuously at ; recoil corrections grow as photon energy approaches the rest energy. If , the assumed nonrelativistic binding model is itself no longer reliable. The calculation therefore locates where no well-separated classical Thomson scattering range exists; it cannot establish a literal direct transition of a real strongly bound system using this oscillator equation alone.
Put , where is the binding spring constant rather than an optical wavenumber. The steady complex amplitude solution of the forced Lorentz oscillator model is
The acceleration complex amplitude is . Hence
This is the scattering cross-section of a harmonically bound charge. The displacement and induced electric dipole moment are parallel to the incident linear polarization, and integrating their dipole radiation over all directions gives the total cross section above.
For , binding dominates and
recovering Rayleigh scattering with static electric polarizability . For , inertia dominates: , so its second time derivative becomes frequency independent and
This is a classical Thomson scattering regime only while . Exactly at , an undamped driven oscillator has no finite steady-state amplitude; the divergent formula must not be used. Finite damping and radiation reaction regulate the physical resonant response. Coherent contributions from many charges in an extended medium can also require a structure calculation rather than multiplying this single-charge result by a particle count.
Thomson scattering describes the low-recoil scattering of electromagnetic radiation by a free charge. For charge and mass , the weak incident field gives peak acceleration . The mean Larmor formula power is therefore
There is no binding force to introduce a characteristic frequency. Dividing by the same incident light intensity gives the Thomson cross-section:
For an Electron, the length inside parentheses is the classical electron radius. The cross section has units and is independent of wavelength in this classical limit. The driven velocity must remain small compared with , and must make Compton recoil kinematics negligible.
P. J. E. Peebles made the connection between microscopic processes and cosmological observables quantitative. His 1968 paper treated cosmological recombination as a kinetic problem. Capturing an Electron directly into the hydrogen ground state releases a photon that can ionize another atom. Net neutralization depends on escape of resonance radiation through cosmological redshift and on two-photon spontaneous emission from the state. An equilibrium Saha equation alone does not give that history.[ref]
This matters for an acoustic prediction because the hydrogen ionization fraction fixes the supply of free Electrons for Thomson scattering. In physical units the scattering rate per photon is . The cosmological visibility function describes the distribution of last-scattering times. Thus atomic physics helps determine when the photon-baryon acoustic oscillator is read out, as well as how rapidly tight coupling fails.
In 1970 P. J. E. Peebles and J. T. Yu followed adiabatic cosmological perturbations by numerically integrating the photon collision equation through cosmological recombination. Their calculation connected acoustic evolution and dissipation to residual matter structure and microwave brightness fluctuations. It did not assume that a perfect photon-baryon fluid remained valid throughout last scattering. Their illustrative cosmological models and normalization were historical choices, rather than the present Lambda-CDM model; their predicted brightness variance versus angular resolution should not be relabelled as a modern measured spectrum.[ref]
The continuing idea is a forward prediction: specify initial conditions, evolve the coupled matter and radiation, project onto the sky, and compare the result with an instrument's readout. Coherent initial phases are needed for acoustic variance peaks explains why a collection of oscillating modes does not automatically produce a peaked power spectrum. The BOOMERANG acoustic-peak measurement provides a later observational test of this physical programme.