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A collection of mobile Electrons treated statistically. A dense electron gas in a metal generally requires Fermi-Dirac statistics.

In three dimensions use the $k$-space density of states $(L/2\pi {)}^3$ per spin species and the spherical shell volume $4\pi k^{2}dk$:Thus the three-dimensional free-electron density of states grows as ${ϵ}^{1/2}$. For physical Electrons, including both spin states givesAll three total density of states functions have units ${\mathrm{J}}^{-1}$ when energy is in joules; they count states per energy interval. The paper explicitly suppresses spin in (a) but does not repeat that convention in (b), so giving both conventions avoids a hidden factor-of-two ambiguity. Parts (c)--(f) below use the physical two-spin-state electron gas.

Keep the Electron number fixed, soand $\mu (0)=E_F$. Heating smooths the Fermi-Dirac distribution across the Fermi energy, creating holes below $\mu$ and particles above it. The sign of the low-temperature adjustment of chemical potential follows from the local slope of the density of states.

In one dimension, $g\propto {ϵ}^{-1/2}$ decreases with energy. At fixed $\mu$, smoothing removes more Electrons below it than it adds above it, so $\mu$ initially rises. In three dimensions, $g\propto {ϵ}^{1/2}$ increases, so $\mu$ falls. In two dimensions the constant density of states makes the leading changes cancel, so $\mu$ stays extremely close to $E_F$ in the degenerate regime.

For quantitative checks, a Sommerfeld expansion gives, for $k_{B}T\ll E_F$,For a constant two-dimensional density of states above an unbounded parabolic band bottom, the number integral can be done exactly:soIt actually decreases, but its low-temperature correction is exponentially small rather than quadratic. “Constant in two dimensions” is therefore a low-temperature approximation, not an exact statement for every $T$.

The one-dimensional rise is also only an initial trend. In the high-temperature Maxwell-Boltzmann distribution limit, the ideal $d$-dimensional electron gas has $\mu \simeq k_{B}T\ln [n_d{\lambda }_T^d/2]$, where $n_d=N_e/L^d$ and ${\lambda }_T=\sqrt{2\pi {\hslash }^2/(m{k}_{B}T)}$ is the thermal de Broglie wavelength. It eventually becomes negative and decreases in every dimension. The one-dimensional chemical potential thus passes through a maximum. This high-temperature statement refers to the stipulated unbounded free-electron dispersion relation, not a claim that a real finite-width crystal band remains parabolic indefinitely.

Use a representative conduction-electron density $n\sim 10^{29}{\mathrm{m}}^{-3}$, roughly one mobile Electron per atom in a dense metal, and the bare Electron mass for this estimate. The plasma frequency is thenThis is an order-of-magnitude answer because no particular metal or carrier density is specified. It corresponds to an ordinary frequency $f_p\simeq 2.8\times 10^{15}\mathrm{Hz}$, excitation energy $\hslash {\omega }_p\simeq 12\mathrm{eV}$, and free-space wavelength near $1.1\times 10^{-7}\mathrm{m}$.

The physical oscillation is collective motion of the electron gas against the positive ionic background. Displacing the Electrons relative to the ions produces a restoring electric field. In the simplest uniform-displacement picture, $\ddot{x}+{\omega }_p^{2}x=0$: the frequency increases with the density of mobile electric charge and decreases with carrier inertia. Quantizing this longitudinal collective oscillation gives a plasmon.

The same scale controls the ideal collisionless Drude model optical response. Its cold collisionless plasma dielectric response is ${ϵ}_r(\omega )=1-{\omega }_p^2/{\omega }^2$. Below ${\omega }_p$, the negative relative permittivity makes a transverse electromagnetic wave evanescent, producing strong reflection; above it, the ideal model admits propagation. Real-metal collisions, interband photon absorption and background polarization modify this simple optical edge. Thus ${\omega }_p$ is a collective charge-response scale, not a single-electron scattering rate or a sharp transparency threshold for every real metal.

Dielectric screening is the rearrangement of a medium's charges in response to an applied charge. In a metal, mobile Electrons accumulate near a positive perturbation and reduce its long-range potential. Thomas-Fermi screening treats the electron gas locally as an equilibrium gas whose density responds to the local electrostatic potential, ignoring gradients of the density on the microscopic wavelength scale.

Take $e>0$, background permittivity ${\epsilon }_b$, and electrostatic potential $\varphi$. An Electron's potential energy is $-e\varphi$, so the local kinetic Fermi energy becomes $\mu +e\varphi$. For a three-dimensional spin-degenerate parabolic band at zero temperature,where $g(E_F)=dn/d\mu$ is the spin-summed density of states per volume per energy. The induced charge is ${\rho }_{\mathrm{ind}}=-e\delta n=-e^{2}g(E_F)\varphi$. Combining it with Poisson equation givesFor a point external charge $Q$, spherical symmetry and decay at infinity selectThus the bare $1/r$ potential is cut off exponentially. Fourier transformation makes the same result transparent: $\varphi (\mathbf{q})={\rho }_{\mathrm{ext}}(\mathbf{q})/[{\epsilon }_b(q^2+k_{\mathrm{TF}}^2)]$, so the static longitudinal dielectric factor is $1+k_{\mathrm{TF}}^2/q^2$ relative to the background. For a free Electron band, $g(E_F)=3n/(2E_F)$ and ${\lambda }_{\mathrm{TF}}^2=2{\epsilon }_b{E}_F/(3n{e}^2)$.

The local linear approximation requires a weak perturbation and slowly varying fields on the relevant microscopic scale. It omits nonlocal Friedel oscillations and atom-scale structure; a nonlinear local-density treatment is needed near a sufficiently strong charge. Finite temperature replaces $g(E_F)$ by the appropriate compressibility derivative $\partial n/\partial \mu$. The nondegenerate limit gives classical screening rather than the degenerate Thomas-Fermi length. A larger density of states means that a smaller potential can move more carriers, hence stronger screening.

Consider a planar surface with outward normal along $z$. For an auxiliary equilibrium electron gas just outside it, let $n_v$ be the total number density, counting both signs of $v_z$. Its Maxwell-Boltzmann velocity distribution has normal-component densityAn Electron with $v_z>0$ crosses more area per unit time when it moves faster. The outgoing number flux therefore uses $v_z{f}_z$, rather than just the probability of $v_z>0$:This integral contributes only $T^{1/2}$. Holding a classical bulk number density fixed and imposing a normal kinetic energy threshold $W$ would instead give $\Gamma =n\sqrt{k_{B}T/(2\pi m_e)}{e}^{-W/(k_{B}T)}$; that argument alone does not produce $T^2$.

For the ideal surface model, measure external Electron energies from the metal's chemical potential $\mu$. A freely propagating external state has $E-\mu =W+p^2/(2m_e)$. When $W\gg k_{B}T$, its Fermi-Dirac distribution reduces to the Maxwell–Boltzmann statistics tail. Counting two spin states per phase space cell of volume $h^3$ givesEach of the three Gaussian integrals supplies $T^{1/2}$. Combining this $T^{3/2}$ state count with the $T^{1/2}$ crossing factor givesThe auxiliary atmosphere supplies an equilibrium state-counting argument; an operating collector removes the outgoing Electrons. It need not maintain a real equilibrium gas throughout the gap. Unit transmission and the ideal free Electron state count are substantive assumptions, so this calculation does not determine an arbitrary real surface's measured $A$.

In particular, Electrons inside a metal generally form a degenerate Fermi gas. A classical distribution for the escaping tail does not imply a classical distribution for the whole interior. Richardson himself emphasized this distinction in his lecture.^[ref]

An electron gas confined in one spatial direction, with motion available in the other two. Its Electron number per unit area is $n_s=N/A$. The ideal Fermi gas approximation neglects interactions between Electrons; an actual two-dimensional electron gas can have important interactions. Confinement alone does not require a magnetic field or Landau levels.