For transverse coupling with equal mode amplitudes , Fermi's golden rule and the oscillator creation operator and annihilation operator give
where the first index is the final spin and is the density of states per unit angular frequency. Decay creates a quantum and carries the factor ; excitation annihilates one and carries . For nonuniform resonant occupations, is their density-weighted mean.
With a thermal Bose-Einstein distribution, . The two-state master equation therefore has the Boltzmann distribution as its unique stationary populations when . The population deviation relaxes at rate . If there is no resonant coupling, both rates vanish and stationarity does not determine the populations.
The Pauli matrix flips the spin with unit matrix element. A nonzero oscillator matrix element changes exactly one occupation number, through a creation operator or an annihilation operator:
For a spin flip, the spin energy change divided by is . Thus creation and annihilation in mode have total frequency changes and , respectively. Distinct modes or different occupation changes lead to orthogonal final quantum states, so their probabilities add. Fermi's golden rule consequently gives
The Dirac delta function is even, accounting for the sign in the annihilation term. Since all , an initially up spin can only emit an oscillator quantum, while an initially down spin can only absorb one. Writing the oscillator density of states per unit angular frequency as , the continuum limit gives
The permits emission even from the oscillator vacuum; absorption requires a quantum already present. The notation assumes a common or smoothly specified occupation at the resonant frequency. If several resonant modes have different occupations, it denotes their density of states weighted mean, so that after continuum smoothing. This is the golden-rule relaxation of a spin coupled to an oscillator bath.
In first-order time-dependent perturbation theory, the resonant time factor before taking the Fermi's golden rule limit is
Its central frequency width is of order , and its total area is . To replace it by , the oscillator density of states and relevant occupations must be approximately constant over that width. Thus . At the same time, the perturbative flip probability must remain much smaller than one.
Define , so the two flip rates are and . A sufficient common time window for both initial spins is
For a specified initial spin, the upper condition is simply its own flip rate times . Such a window requires weak enough coupling. The continuum approximation also presumes times shorter than recurrences from a resolved finite oscillator spectrum, and long enough to resolve the positive-frequency resonance from its nonresonant counterpart.
In the simple box-state counting used here, the final three-momentum lies in a spherical shell: , where the common constant contains the normalization volume and angular factor. Momentum conservation fixes the other final particle's momentum. Hence the density of states is
Combining parts (a) and (b) gives
With the paper's rounded masses,
By Fermi's golden rule, equal squared matrix elements make the rate ratio equal to this density ratio. Thus the naive constant-matrix-element estimate is , which favours the electronic decay by about to one.
This is the particular noncovariant state-counting convention in the question. A calculation with the Lorentz-invariant phase-space measure places factors in the measure and correspondingly normalizes its decay amplitude differently. Only the complete product of phase space and squared matrix element is convention-independent; mixing the two conventions would give a wrong rate.