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A generalized eigenfunction solves the eigenvalue equation for a linear operator in an enlarged space, often a space of distributions, although it may fail to belong to the underlying Hilbert space. A plane wave $e^{ikx}$ on the whole real line is a generalized momentum eigenstate, with momentum $\hslash k$, and is not square-integrable. This usage differs from a generalized eigenvector in a Jordan chain, where a higher power of $L-\lambda$ vanishes rather than $L-\lambda$ itself.

For a temporal photon wave packet $|f,0⟩=\int d^{3}pf(\mathbf{p})a_{\mathbf{p}}^{0†}|0⟩/(2\pi {)}^3$, the oscillator commutator gives $⟨f,0|f,0⟩=-\int d^{3}p|f(\mathbf{p}){|}^2/(2\pi {)}^3<0$ when $f\ne 0$. This is the negative direction of the indefinite Hermitian form, not the divergent normalization of an unsmeared momentum eigenstate. It is excluded by the physical condition in Gupta-Bleuler quantization.

The wavefunction is a plane wave and a simultaneous formal eigenfunction of the momentum operator and the time-translation energy operator:Its momentum and energy are therefore definite, while its probability density is spatially uniform:For a particle of mass $m$, the probability current is $j=(\hslash /m)\mathrm{Im}(\overline{\varphi }{\partial }_x\varphi )=\hslash k{A}^2/m$, directed according to the sign of $k$.

On the whole real line, a nonzero constant-amplitude plane wave is not square-integrable and cannot be normalised to total probability one. It represents an idealised momentum eigenstate, interpreted through generalized eigenfunctions or as a limit of wave packets. Also, arbitrary $k,E$ do not automatically solve the Schrodinger equation for a specified potential energy: for a free particle, $E={\hslash }^2{k}^2/(2m)$, or this value plus the constant potential energy for a constant-potential region. If $A=0$, the zero function is not a physical quantum state.

The oscillator-generated covariant photon Fock space has an indefinite Hermitian form, not a positive Hilbert space inner product. For a normalizable one-photon wave packet of polarization $\lambda$, its squared norm is proportional to $-{\eta }^{\lambda \lambda }\int d^{3}p|f(\mathbf{p}){|}^2$. Thus $\lambda =0$ gives a negative-norm photon state. The divergent ${\delta }^3(0)$ of an unsmeared momentum eigenstate is a separate normalization issue, avoided by the wave packet.

Choose contravariant polarization vectors ${ϵ}^{0\mu }=(1,0)$, ${ϵ}^{3\mu }=(0,\hat{\mathbf{p}})$, and two ${ϵ}^{r\mu }=(0,{\mathbf{e}}_r)$ with ${\mathbf{e}}_r\cdot \mathbf{p}=0$ for $r=1,2$. The third spatial polarization is longitudinal polarization; the first two are transverse polarization. The timelike photon polarization is distinct from the longitudinal one.

The Gupta-Bleuler quantization condition sets the divergence of the positive-frequency part of a quantum field to zero on physical states:Restore the factors $e^{-i|\mathbf{p}|t}$ to the annihilation terms. Since $p_{\mu }{ϵ}^{0\mu }=|\mathbf{p}|$ and $p_{\mu }{ϵ}^{3\mu }=-|\mathbf{p}|$, Fourier transform gives the equivalent conditionIts sign depends on the chosen sign of the longitudinal polarization vector; the covariant condition does not.

To see its content for a general Fock state, temporarily discretize momentum and decompose one unphysical oscillator sector as $|\Psi ⟩={\sum }_{n,m\ge 0}|n,m{⟩}_{0,3}\otimes |{\chi }_{nm}{⟩}_{\perp }$, where $|n,m⟩=(a^{0†}{)}^n(a^{3†}{)}^m|0⟩/\sqrt{n!m!}$. The temporal oscillator obeys $a^0|n,m⟩=-\sqrt{n}|n-1,m⟩$, while $a^3|n,m⟩=\sqrt{m}|n,m-1⟩$. The condition therefore becomesEquivalently, the allowed finite-particle states use the transverse creation operators and only $b^{†}=a^{0†}-a^{3†}$ in the unphysical sector. Indeed the constraint acts on a polynomial of the two unphysical creation operators as $-{\partial }_{a^{0†}}-{\partial }_{a^{3†}}$, whose kernel consists of polynomials in their difference. Also $[b,b^{†}]=-1+1=0$, and a state containing $b^{†}$ is orthogonal to every constrained state because $b$ annihilates every such state. This argument applies mode by mode and extends by smearing to continuum momentum.

For one photon, $c_0{a}^{0†}|0⟩+c_3{a}^{3†}|0⟩$ is constrained only when $c_3=-c_0$, producing a null state. The Gupta-Bleuler null-state quotient removes these null directions. The condition excludes negative-norm physical states; quotienting its null states leaves the two positive-norm transverse photon polarizations. The condition alone gives a positive semidefinite Hermitian form, not yet a positive definite Hilbert space.

Assume a complete relativistically normalized basis of scalar momentum eigenstates transforms asThis states both reversal of spatial momentum and preservation of the normalization of basis quantum states. Antilinearity alone would not suffice: multiplying a conjugation operator by two gives an antilinear operator that multiplies squared norms by four.

Expand $|\varphi ⟩=\int d{\Pi }_p\varphi (\mathbf{p})|\mathbf{p}⟩$ and similarly for $|\psi ⟩$, with $d{\Pi }_p=d^{3}p/((2\pi {)}^{3}2E_p)$. This Lorentz-invariant phase-space measure is unchanged under $\mathbf{p}\mapsto -\mathbf{p}$. The antilinearity of the quantum time-reversal operator gives conjugated expansion coefficients. Orthogonality of the momentum eigenstates and cancellation of their unit-modulus phases yieldSince momentum reversal is a bijection of the complete basis, $\hat{T}$ is also onto. ThusThis proves antiunitarity, with the normalization hypothesis explicitly included. For scalar multiparticle quantum states the same argument uses the complete occupation-state basis and reverses all momenta; it is not restricted to a single-particle wave packet.

The vacuum has zero momentum and is invariant under translations. HenceThus a one-particle momentum eigenstate remains the same ray and acquires the translation phase appropriate to its momentum.

For a one-dimensional wavefunction,The probability continuity equation isFor a stationary state $\psi (x,t)=\varphi (x)e^{-iEt/\hslash }$, the probability density is independent of time, so ${\partial }_{x}j=0$ and the probability current is constant in space.

For the plane waveone obtainsThis is a momentum eigenstate with momentum $p=\hslash k$ and, when it satisfies the free Schrodinger equation, energy $E={\hslash }^2{k}^2/(2m)$. Its constant density and current describe a spatially uniform beam carrying probability in the sign of $k$. It is not a normalizable wavefunction, so it represents an idealized state rather than a localized particle.

Insert a complete set of momentum eigenstates into the quantum-mechanical propagator:Completing the square and evaluating the resulting Gaussian integral, with the usual i-epsilon prescription, gives the free-particle propagatorThe square-root branch is fixed by requiring $K(x_f,T;x_i,0)\to \delta (x_f-x_i)$ as $T\downarrow 0$.

A plane wave has constant amplitude and a phase linear in space and time. It is a momentum eigenstate and is not spatially normalizable.

A quantum time-reversal operator is an antiunitary operator reversing spatial momentum and angular momentum. For a time-reversal-invariant Hamiltonian operator, its conjugation of $i$ makes it intertwine forward and backward unitary time evolution without reversing the energy spectrum. A scalar momentum eigenstate may transform as $\hat{T}|\mathbf{p}⟩=e^{i\chi (\mathbf{p})}|-\mathbf{p}⟩$. With unit-modulus phases and a complete normalized basis, expansion of arbitrary states proves antiunitarity.