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A characteristic wave impedance relates an effort-like quantity to its conjugate flow-like quantity in a single travelling wave: for a mechanical wave these are force and velocity, and their product is power. The sign depends on the propagation and force conventions. Use the transverse force transmitted towards increasing $x$, $F=-T{\Psi }_x$. A rightgoing travelling wave $\Psi =f(x-vt)$ has transverse velocity $u={\Psi }_t=-v{\Psi }_x$, soThis is the positive characteristic impedance of a stretched string. A leftgoing component has $F/u=-Z$ with the same force orientation. Its units differ from pressure-based acoustic impedance because it uses force, rather than force per area.

In a homogeneous linear medium, write $\mathbf{D}=ϵ\mathbf{E}$ and $\mathbf{B}=\mu \mathbf{H}$. Without free charge or current, Maxwell's equations becomeTaking the curl of Faraday's law, using $\nabla \times (\nabla \times \mathbf{E})=\nabla (\nabla \cdot \mathbf{E})-{\nabla }^2\mathbf{E}$, givesTheir plane-wave solutions have ${\omega }^2=k^2/(\mu ϵ)$ and speed $v=1/\sqrt{\mu ϵ}$; in vacuum this is $c=1/\sqrt{{\mu }_0{ϵ}_0}$. For a wave $\mathrm{Re}[{\mathbf{E}}_0{e}^{i(\mathbf{k}\cdot \mathbf{r}-\omega t)}]$, the divergence equations give $\mathbf{k}\cdot {\mathbf{E}}_0=\mathbf{k}\cdot {\mathbf{B}}_0=0$, while Faraday's law gives ${\mathbf{B}}_0=\mathbf{k}\times {\mathbf{E}}_0/\omega$. Thus the fields and propagation direction form an orthogonal triad, with $B_0=E_0/v$.

The two independent transverse electric components allow linear, circular and elliptical polarization of an electromagnetic wave. Their relative amplitudes and phase determine the polarization state. In a lossless nondispersive medium the energy density and energy flux areA travelling plane wave has equal electric and magnetic energy contributions and time-averaged intensity $⟨S⟩=E_0^2/(2Z)$, where $Z=\sqrt{\mu /ϵ}$ is its wave impedance and $E_0$ denotes peak electric-field amplitude. Reflection and refraction follow by imposing the electromagnetic boundary conditions. Frequency-dependent constitutive response introduces dispersion; conductivity introduces attenuation, so the simple real constant-speed result has a specified domain of validity.

Electromagnetic waves drive mobile charges in a conducting medium. Their current changes both the phase and attenuation of the wave. A description in terms of a real, frequency-independent refractive index is therefore generally insufficient: the material response and the propagation constant are complex and frequency dependent.

Use phasors proportional to $e^{i(kz-\omega t)}$, with $k=k^{\prime }+i{k}^{\prime \prime }$ and $k^{\prime \prime }\ge 0$ for a passive medium. In a homogeneous, isotropic, linear material, let ${ϵ}_b$ represent the permittivity associated with bound-charge electric polarization, $\mu$ the magnetic permeability and $\sigma (\omega )$ the mobile-charge conductivity. The macroscopic Maxwell equations giveFor a transverse plane wave, taking another curl yieldsThis division of the response avoids counting mobile Electrons both in ${ϵ}_b$ and in $\sigma$. Define the complex refractive index $\tilde{n}=ck/\omega =n+i\kappa$. For a nonmagnetic medium, ${\tilde{n}}^2={ϵ}_{\mathrm{eff}}/{ϵ}_0$. Its real part determines the phase variation, while the positive optical extinction coefficient $\kappa$ gives amplitude attenuation $e^{-\omega \kappa z/c}$ and intensity attenuation $e^{-2\omega \kappa z/c}$. The amplitude penetration length is

A simple microscopic explanation comes from the Drude model. Let Electrons of charge $-e$, mass $m$ and number density $n_e$ move against an effectively stationary positive background. Collisions relax their mean velocity at rate $\nu$:ConsequentlyWith a vacuum-like bound-charge background, this givesIts imaginary part is positive for positive $\omega ,\nu$, consistent with dissipation under the chosen phasor convention. Real materials can require an effective Electron mass, a nontrivial bound-charge response, or additional absorption associated with the electronic band structure.

A plasma is a conducting ionized medium with mobile Electrons and ions, approximately neutral on large scales because of plasma screening. For the electron-frequency transverse waves considered here, the heavy ions can often be treated as stationary. In a dilute weakly collisional plasma, $\nu \ll \omega$, soFor $\omega >{\omega }_p$, $k$ is real in this collisionless model and the wave propagates. Its phase velocity is $v_{\mathrm{ph}}=c/n>c$, while its group velocity is $v_g=cn<c$; their product is $c^2$. A phase crest exceeding $c$ does not imply superluminal information transport. For $\omega <{\omega }_p$, the refractive-index square is negative andThe transmitted field is evanescent rather than a traveling bulk wave. A sufficiently thick collisionless plasma reflects such radiation without Ohmic absorption. Collisions make the response complex and permit absorption. This accounts for a plasma cutoff and, qualitatively, the reflection of some radio frequencies by ionized atmospheric layers. The simple model describes transverse waves; plasmas also support longitudinal collective modes.

In a metal, positive ions usually form a crystal lattice. Mobile conduction Electrons occupy states described by the electronic band structure and normally form a degenerate Fermi gas. The conduction-electron density is usually much higher than in a dilute gas plasma. Thus its plasma frequency is commonly in the optical or ultraviolet range, rather than the lower radio-frequency values possible in dilute plasmas. Electron scattering from the lattice, defects and other excitations gives a finite relaxation rate. The distinction is not that every plasma is collisionless and every metal collisional: the controlling ratio for either material is $\omega /\nu$, together with its carrier density and bound-charge response.

At sufficiently low frequency, $\omega \ll \nu$, the metal's conductivity is approximately real, ${\sigma }_0=n_e{e}^2/(m\nu )$. In a good conductor the conduction current dominates the displacement current, ${\sigma }_0\gg \omega {ϵ}_b$. The wave equation then givesFor example, a tangential electric field varies asThe current $\mathbf{J}={\sigma }_0\mathbf{E}$ is therefore concentrated within a few skin depths of the surface: this is the skin effect. As frequency increases within this regime, $\delta \propto {\omega }^{-1/2}$. In a wire whose radius greatly exceeds $\delta$, only a thin outer region carries appreciable alternating current, increasing the effective resistance. In a conducting shield, the same penetration suppresses the field transmitted through a sufficiently thick wall.

The Poynting theorem identifies the loss as Joule heating. The cycle-averaged heating density for a complex conductivity isThe wave impedance is $Z=\mu \omega /k$. For incidence from vacuum at normal incidence, the electric reflection amplitude is $r=(Z-Z_0)/(Z+Z_0)$, where $Z_0=\sqrt{{\mu }_0/{ϵ}_0}$. A good conductor has small $|Z|$ and therefore strong reflection, while the part of the incident power entering it is dissipated over the skin depth.

At high enough frequency that $\omega \gg \nu$, a metal's free-electron response also approaches the collisionless plasma form. The low-frequency formula $\delta \propto {\omega }^{-1/2}$ must not simply be extrapolated into that regime. Real optical behavior additionally depends on the electronic band structure and transitions between bands. Both plasmas and metals are therefore described by the same electromagnetic response framework, but their relevant densities, scattering rates and frequency regimes differ.

An incident electromagnetic wave generally produces reflected and transmitted waves because the two media have different electromagnetic response. Consider a flat interface between homogeneous, linear, lossless media with permittivities ${ϵ}_j$ and magnetic permeabilities ${\mu }_j$. Their wave speeds and wave impedances areFor each plane electromagnetic wave, $\mathbf{H}=\hat{\mathbf{k}}\times \mathbf{E}/Z_j$. With no free surface charge or current, the interface conditions for electromagnetic fields require continuous tangential $\mathbf{E},\mathbf{H}$ and normal $\mathbf{D},\mathbf{B}$. Equality of the phase at every point on the boundary gives equal angular frequencies and tangential wavevectors. Hence the reflection angle equals the incidence angle and Snell's law iswhere $n_j=c/v_j$ and each angle is measured from the normal.

At normal incidence use the same tangential axis for all electric amplitudes. The two independent boundary equations areSolving gives the amplitude Fresnel equationsFor nonmagnetic media, these become $r=(n_1-n_2)/(n_1+n_2)$ and $t=2n_1/(n_1+n_2)$. Reflection into a medium of larger refractive index therefore reverses the electric amplitude's sign at normal incidence.

The normal Poynting vector determines the reflected and transmitted fractions of incident power. At normal incidence,It is the power fractions, rather than the squared electric amplitudes alone, that add to unity.

At oblique incidence separate transverse electric polarization ($s$, electric field perpendicular to the incidence plane) from transverse magnetic polarization ($p$, electric field in that plane). For nonmagnetic media, writing $c_i=\cos {\theta }_i$ and $c_t=\cos {\theta }_t$, the Fresnel equations areHere choose a common $s$ direction and, for each ray, the $p$ direction as $\hat{\mathbf{s}}\times \hat{\mathbf{k}}$. This makes the reflected $p$ basis reverse its tangential direction at normal incidence, explaining why the displayed $r_p$ then has the opposite sign to $r_s$. Physical reflectance is independent of this sign convention. For either polarization with propagating transmission,For $p$ polarization, zero reflection occurs at the Brewster angle $\tan {\theta }_B=n_2/n_1$. If $n_1>n_2$, incidence above the critical angle for total internal reflection $\sin {\theta }_c=n_2/n_1$ produces an evanescent field in total internal reflection and $\mathcal{R}=1$ for an isolated lossless interface. A lossy second medium requires complex response coefficients and an absorption term in the energy balance.