A resistance thermometer using platinum as its sensing material. It provides the temperature readout in the saturation-pressure equilibrium measurement.
Transduction turns electrical resistance into a temperature indication. A uniform wire has , with electrical resistivity , length , and cross-sectional area . Stronger atomic vibrations at higher temperature scatter Electrons more, increasing platinum's electrical resistivity; impurities and crystallographic defects also contribute.[ref]
A small known electric current and measured electric potential difference give through Ohm's law; a resistance bridge can instead compare the element with a reference resistor. Inverting the calibrated response then gives the sensing element's temperature. This makes electrical readout convenient, but the platinum resistance thermometer lead resistance error, resistance thermometer self-heating, and resistance thermometer immersion test explain why a stable display alone is insufficient. The gas thermometer supplies a contrasting route through an equation of state; the saturation-pressure equilibrium measurement shows why a trustworthy independent temperature readout matters.
With two shared leads of electrical resistances , Ohm's law gives
Using the Pt100 local linear model, positive lead electrical resistance appears as a warmer temperature. At true , stipulated leads of each change into , producing : a calculated bias of about . Subtracting a measured loop correction works only while that loop electrical resistance remains appropriate; cable temperature changes can invalidate it.
Figure 1.
Two shared leads include cable voltage drops; four leads sense at the platinum element
. Red paths carry electric current; blue paths connect an ideal high-input-electrical resistance voltmeter. In the two-wire circuit the sensing terminals span both leads and the element. In four-terminal sensing they span the element alone. The stated lead values and temperature bias are illustrative calculations. Source. Details.
Four-terminal sensing separates the electric current and electric potential difference leads. Negligible sensing electric current suppresses sensing-lead drops; force-lead drops lie outside the interval. Real voltmeter loading, connections, and leakage still need checking.[ref]
For a stable offset from the thermoelectric effect, two signed electric potential differences obey and . The current-reversal calculation in four-terminal sensing yields
At stipulated , and , and recover exactly in this model. If the offset or sample temperature changes between readings, cancellation is incomplete. Reversal also leaves Joule heating unchanged because it depends on .
Measuring electric current creates Joule heating, raising the sensing temperature. At fixed bath temperature, compare settled readings at and and extrapolate the approximately linear dependence toward zero current.[ref]
Under the local model ,
For synthetic readings at and at , the extrapolated value is . The lower-current excess corresponds to in the Pt100 local linear model. At , dissipates ; power alone does not specify a temperature rise without a thermal coupling model. These stipulated values are not measurements.
Repeat the comparison after settling and test the approximation if necessary. Changing from liquid to air changes heat transfer; a self-heating correction need not transfer unchanged. The saturation-pressure equilibrium measurement provides an existing example of controlling this disturbance in resistance thermometry.
A standard platinum resistance thermometer uses very pure, annealed platinum with strain-limiting construction. An industrial platinum resistance thermometer commonly uses supported wire or a film. Their response curves differ.[ref]
The word standard describes the instrument's metrological role. Calibrated SPRTs realize specified interpolation intervals of the International Temperature Scale of 1990 and transfer reference temperatures to other thermometers.[ref] They are primary standards for realizing that practical scale, but their electrical resistance alone does not determine absolute thermodynamic temperature without calibration. Primary thermometry such as the corrected gas thermometer obtains thermodynamic temperature from a physical law. A reference in a comparison bath may be an SPRT; an individually calibrated industrial platinum resistance thermometer can also serve as a working reference with an appropriate uncertainty.