Past exam of the mathematics course of the University of Cambridge 2020 ii Paper 2 35C b i Solution 2026-09-29
The potential has period , so the first Brillouin zone is . At its boundary the free-particle statesare degenerate, with energyThe relevant Fourier coefficient is supplied by :The term changes wavevector by two and has no matrix element within this degenerate pair. Thus degenerate perturbation theory gives the matrixand the two band-edge energiesThe nearly-free electron model therefore predicts the lowest band gap
Past exam of the mathematics course of the University of Cambridge 2022 ii Paper 2 36D Solution Created 2026-09-23 Updated 2026-10-05
Let . The free states and are degenerate at the Bragg point . Sincedegenerate perturbation theory restricts the Hamiltonian near this crossing toWriting and diagonalizing gives the nearly-free electron dispersion near a one-dimensional band gapThus the two continuous bands avoid crossing, and at their separation isThis is the nearly-free electron model. The dispersion relation is the relation between energy and Bloch wavevector.
For the specified potential,Henceand all other nonconstant Fourier coefficients vanish. The gaps are thereforeTheir centre energies are respectivelyThe extended-zone sketch consists of the free-particle parabolas shifted upward by , with avoided crossings of these two widths at the listed Bragg points; elsewhere they meet to this order because the corresponding Fourier coefficients vanish.
