Past exam of the quantum mechanics and electromagnetism course of the University of Oxford / 2011 / A

Use International System of Units, with $c^{-2}={\mu }_0{\epsilon }_0$. The Maxwell equations with charge density $\rho$ and current density $\mathbf{J}$ areLocally, or in a suitable contractible region, the zero divergence of $\mathbf{B}$ allows a magnetic vector potential $\mathbf{B}=\nabla \times \mathbf{A}$. Faraday's law then makes $\mathbf{E}+{\partial }_t\mathbf{A}$ curl-free, so a electric potential can be chosen withThese formulas automatically satisfy the two homogeneous Maxwell equations. The local topology assumption rules out obstructions to expressing a closed field as a gradient or curl.

For any sufficiently smooth scalar $\chi$, the gauge transformationleaves both physical fields unchanged, because curl of a gradient is zero and spatial and time derivatives commute. In such a region this accounts for the freedom between potentials for the same fields.

The Lorenz gauge is $\nabla \cdot \mathbf{A}+c^{-2}{\partial }_t\Phi =0$. Substitution into the sourced Maxwell equations, using $\nabla \times (\nabla \times \mathbf{A})=\nabla (\nabla \cdot \mathbf{A})-{\nabla }^2\mathbf{A}$, gives the decoupled wave equationsFor example, Gauss's law gives $-{\nabla }^2\Phi -{\partial }_t\nabla \cdot \mathbf{A}=\rho /{\epsilon }_0$; the gauge condition turns this into the scalar equation. The remaining gauge freedom preserving the condition has $({\nabla }^2-c^{-2}{\partial }_t^2)\chi =0$.

Put $\theta =\omega t-Kz$ for the given wave. Direct differentiation gives $\nabla \cdot \mathbf{E}=0$ and $\nabla \times \mathbf{E}=K\mathbf{E}$. Integrating Faraday's law in time yields the wave's magnetic fieldOne could superpose a time-independent divergence-free and curl-free magnetic field; the expression displayed chooses no such extra background. It has zero divergence and ${\partial }_t\mathbf{B}=-K\mathbf{E}$, so the magnetic Gauss and Faraday equations hold. MoreoverSince the time derivative is nonzero, the vacuum Ampere-Maxwell law holds precisely whenThis verifies all four source-free equations, including both divergence constraints. The sign of $\omega /K$ selects the direction of propagation.

A wave has circular polarization when, at a fixed spatial point, its transverse electric vector has constant nonzero magnitude and rotates uniformly through a circle. Here $E_x^2+E_y^2=E^2$ and the angle changes at rate $\omega$, so the wave is circularly polarized. Its magnetic vector is perpendicular to the electric vector, has magnitude $|E|/c$ under the dispersion relation, and rotates with it. A handedness label additionally requires a convention for the observer's viewing direction.

The Lorenz-gauge potentials for a circularly polarized plane wave give a convenient choice. Take $\Phi =0$ and $\mathbf{A}={\omega }^{-2}{\partial }_t\mathbf{E}$. Because ${\partial }_t^2\mathbf{E}=-{\omega }^2\mathbf{E}$,Also $\nabla \cdot \mathbf{A}={\omega }^{-2}{\partial }_t\nabla \cdot \mathbf{E}=0$. Together with ${\partial }_t\Phi =0$, this proves these potentials satisfy the Lorenz gauge. They satisfy the source-free potential wave equations because every component has the same dispersion relation just obtained.

Take $m,\omega >0$ and use the usual common invariant domain for the position operator, momentum operator and their products. Since $X$ and $P$ are self-adjoint,Expanding the commutator and using $[P,X]=-i\hslash I$ givesThe two products areConsequently the quantum harmonic oscillator Hamiltonian operator isThe identity $[AB,C]=A[B,C]+[A,C]B$ now givesThus $H(a_{\pm }\psi )=(E\pm \hslash \omega )a_{\pm }\psi$. Each ladder image is an eigenstate if it is nonzero; a zero vector is not an eigenstate. The distinction is needed for lowering the ground state. Their squared norms areThese follow by moving the operator to the other side of the inner product with its adjoint operator. The first inequality implies $E\ge \hslash \omega /2$ for every eigenstate.

For a lowest-energy quantum state, $a_{-}{\psi }_0$ must vanish, since otherwise it would be an eigenstate with lower energy. The norm formula then forces $E_0=\hslash \omega /2$. Raising never vanishes and producesTo see that there are no other eigenvalues, repeatedly lower any eigenstate. If $E/(\hslash \omega )-1/2$ were not a nonnegative integer, there would be a final nonzero lowered quantum state with energy strictly between $\hslash \omega /2$ and $3\hslash \omega /2$. Its lower image would have positive norm but energy below the lower bound, a contradiction. Thus every eigenstate reaches the ground eigenspace after an integer number of lowerings. On a positive level, lowering is injective by its strictly positive norm factor. The assumed one-dimensional ground eigenspace therefore makes every eigenspace one-dimensional, so the displayed raised quantum states give all eigenstates up to nonzero multiples. If ${\psi }_0$ is normalized, their norms are $\Vert {\psi }_n{\Vert }^2=n!$.

For $k\ge 1$, $(a_{+}{)}^k\psi$ has eigenvalue $E+k\hslash \omega$, distinct from $E$. eigenstates of a self-adjoint operator with distinct eigenvalues are orthogonal: applying self-adjointness to their inner product gives $(E^{\prime }-E)⟨\psi ,\varphi ⟩=0$. ThereforeThe expectation of $(a_{-}{)}^k$ also vanishes, either by lowering and orthogonality or by conjugating the adjoint relation.

Solving the ladder definitions for $X$ and $P$ givesso $T-V=\frac{1}{2}\hslash \omega ((a_{+}{)}^2+(a_{-}{)}^2)$. Both terms have zero expectation by the preceding orthogonality. Since $T+V=H$, the oscillator form of the quantum virial theorem isExpectations here are divided by $\Vert \psi {\Vert }^2$ if the eigenstate is not normalized; no normalization assumption was used in the ladder argument.

For a nonzero quantum state $\psi$ and a self-adjoint operator $A$, the expectation value and standard deviation of its measurement areThe squared deviation is also called the variance of the observable. All displayed products are understood on quantum states for which the relevant moments exist. Self-adjointness gives $\overline{⟨\psi ,A\psi ⟩}=⟨A\psi ,\psi ⟩=⟨\psi ,A\psi ⟩$, so $a$ is real. Expanding the squared norm gives the variance expression. A norm is nonnegative and is zero exactly for the zero vector, hence ${\Delta }_{\psi }(A)=0$ precisely when $A\psi =a\psi$. Thus zero dispersion is equivalent to being an eigenstate.

For bounded $H$, the operator exponential is the norm-convergent power seriesFor a general unbounded self-adjoint Hamiltonian operator, the spectral theorem defines the same notation byThis definition does not require the power series to converge on every quantum state. complex conjugation of the spectral multiplier gives $U_t^{\ast }=U_{-t}$, and multiplication of the phases gives $U_{-t}{U}_t=I$. Thus $U_t$ is unitary, preserves the quantum state norm, and has $U_0=I$.

For initial data in the domain of $H$, differentiating the spectral expression yields ${\partial }_t{U}_t{\psi }_0=-(i/\hslash )H{U}_t{\psi }_0$. Consequentlysolves the Schrödinger equation with the prescribed initial quantum state. Uniqueness follows by differentiating $U_{-t}{\psi }_t$: the two terms cancel, leaving the constant ${\psi }_0$.

In the two-dimensional energy basis, expand the initial quantum state as ${\psi }_0=c_1{\Psi }_1+c_2{\Psi }_2$. Each energy eigenvector receives its own phase under the operator exponential, givingThis is the general solution because every initial vector has a unique basis expansion.

In that orthonormal basis the other observable has the real symmetric matrixIts conjugate transpose equals itself, so it is self-adjoint. Also $A^2=I$ and $\mathrm{tr}A=0$, giving eigenvalues $+1$ and $-1$. Direct substitution gives the normalized orthogonal eigenvectorsAn irrelevant global phase may multiply either vector. With the chosen lower eigenstate initially,The Born rule says that the probability for the higher eigenstate is $|⟨v_{+},{\psi }_t⟩{|}^2$. Its amplitude is $\sin \alpha \cos \alpha (e^{-it{E}_2/\hslash }-e^{-it{E}_1/\hslash })$. Using $|e^{-iu}-e^{-iv}{|}^2=4{\sin }^2((u-v)/2)$ givesThis is the transition probability for a rotated two-level observable. Its time dependence comes from the relative phase between two energy eigenstates. If their energies coincide, or if the measured observable has the energy eigenvectors as its eigenvectors, this transition probability is zero at all times.