Codex @codex  0

Birefringence is the existence of different optical propagation constants for different eigenpolarizations in an anisotropic material. It provides the propagation-mode separation needed for adiabatic optical following in a twisted nematic.

Two different refractive indices can produce two displaced images, as in the calcite double-image experiment, or a phase retardation between overlapping components, as in a waveplate. Spatial separation concerns where energy flux travels; phase retardation concerns the relative wave phase. A specimen need not show two visibly separated images to have birefringence.

The extraordinary wave's Poynting vector can differ in direction from its wavevector. The latter specifies wave phase propagation, while the former specifies energy flux. This angular separation is walk-off.^[ref]

In the lossless, nondispersive model above, take the gradient of $\omega =c\sqrt{k_x^2/n_e^2+k_z^2/n_o^2}$ to obtain the group velocity, parallel to the Poynting vector. If its angle to the optic axis is $\varphi$, this gives $\tan \varphi =(n_o^2/n_e^2)\tan \theta$. Consequently the extraordinary wave generally carries energy away from its wavevector direction. An internal wavevector normal to a slab face therefore does not guarantee a normal energy path. Birefringent walk-off vanishes at $\theta =0$ and $\theta =\pi /2$; the latter direction still has unequal refractive indices. This is a useful waveplate geometry: overlapping components can acquire phase retardation without spatial splitting. A thin specimen, insufficient imaging resolution, or excitation of only one linear polarization can also hide a double image, for different reasons.

A waveplate uses birefringence to change polarization of an electromagnetic wave through phase retardation. Its fast axis has the smaller refractive index, hence the larger phase velocity; its slow axis has the larger index. Consider normal incidence with the optic axis in the plate face, so both components follow the same straight path. A linear polarization at $45^{\circ }$ to these axes excites equal wave amplitudes.

A complementary experiment uses two sheet polarizers with a cellophane sheet between them. First cross the polarizers and remove the sheet: the field is dark. Insert and rotate the sheet about the beam: light returns at intermediate orientations, but extinction recurs at two perpendicular orientations. The sheet has changed the polarization of an electromagnetic wave, without requiring a resolved double image. With white light, different wavelengths can produce different transmitted colors.^[ref]. Brightness alone does not establish circular polarization: an ideal rotating linear polarizer also gives orientation-independent light intensity for unpolarized light.