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Use flavor hypercharge $Y=B+S$, where $B$ is baryon number and $S$ is strangeness. The isospin coordinate is $I_3$. The baryon octet has coordinatesHere the nucleons have $S=0$, the Sigma baryons and Lambda baryon have $S=-1$, and the Xi baryons have $S=-2$. The central Sigma baryon belongs to an isospin triplet while the central Lambda baryon is an isospin singlet; equal coordinates do not identify the states.

The pseudoscalar meson octet isThe pions have $S=0$, the upper kaons have $S=+1$, and their lower antiparticles have $S=-1$. The two central states are the neutral pion and the Eta octet state. This is the octet basis of flavor symmetry; the physical eta can also mix with the flavor-singlet state.

For the flavor SU(3) Cartan generators, choose the Hermitian physics convention and the inner product $⟨A,B⟩=\mathrm{tr}(AB)$. Then an orthonormal diagonal basis isStrictly, $i{h}_1,i{h}_2$ are elements of the anti-Hermitian SU(3) Lie algebra; $h_1,h_2$ are the corresponding Hermitian observables. In the quark basis $(u,d,s)$, the up and down quarks form an isospin doublet and the strange quark is a singlet. Their $I_3$ values are $(1/2,-1/2,0)$. Each quark has baryon number $1/3$, and their strangeness values are $(0,0,-1)$. It follows thatThese flavor hypercharge conventions differ from the electroweak hypercharge convention. If instead the inner product is $2\mathrm{tr}(AB)$, the orthonormal basis is $t_3=h_1/\sqrt{2}$, $t_8=h_2/\sqrt{2}$, and the same operators are $I_3=t_3$, $Y=2t_8/\sqrt{3}$.

In the ordinary quark model, the proton has valence content $uud$ and charge $+1$, while the neutron has content $udd$ and charge zero. Additivity of electric charge gives $2q_u+q_d=1$ and $q_u+2q_d=0$, hence $q_u=2/3$, $q_d=-1/3$. The Sigma baryon ${\Sigma }^{-}$ has content $dds$ and charge $-1$, giving $2q_d+q_s=-1$. Thus the quark triplet's electric charges, in units of the positive elementary charge, areThe Gell-Mann--Nishijima formula is consequentlyIt also reproduces every baryon octet charge from the first diagram. On antiquarks the additive quantum numbers reverse sign, and combining a quark with an antiquark reproduces the meson octet charges.

Because the down and strange quarks have identical electric charge, $Q$ commutes with the U-spin generatorsThey satisfy $[U_a,U_b]=i{ϵ}_{abc}{U}_c$; equivalently the anti-Hermitian matrices $i{U}_a$ span an $\mathfrak{su}(2)$ subalgebra. The entries on the $d,s$ block of $Q$ are equal, so $[Q,U_a]=0$ for all three U-spin generators. The electric charge is therefore constant within each irreducible U-spin multiplet. For example, U-spin relates ${\pi }^{+}$ and $K^{+}$, and relates $p$ and ${\Sigma }^{+}$, without changing their charge. It does not imply exact mass degeneracy: unequal down- and strange-quark masses break U-spin.

For pion-nucleon octet channels, assume the collision is governed by the strong interaction. The initial baryon number is one and strangeness is zero, so an outgoing meson-baryon pair must preserve $B=1$, $S=0$, and electric charge. Thus its total flavor hypercharge is $Y=1$. The allowed types areA kaon of $S=+1$ can accompany a Lambda baryon or Sigma baryon of $S=-1$. An antikaon cannot balance the nonpositive strangeness of an octet baryon. A Xi baryon would require a meson of $S=+2$, which the meson octet does not contain.

Resolving these types by electric charge gives all possible pairs:In the isospin-symmetric approximation, total isospin is conserved as well: the incoming $1\otimes \frac{1}{2}$ contains $I=\frac{1}{2},\frac{3}{2}$. The $\pi N$ and $K\Sigma$ channels contain both values, while ${\eta }_{8}N$ and $K\Lambda$ contain only $I=\frac{1}{2}$. The extreme-charge initial states are pure $I=\frac{3}{2}$, consistently excluding ${\eta }_{8}N$ and $K\Lambda$. Clebsch-Gordan coefficients relate amplitudes in different charge channels; the table establishes permission, not equal probabilities. Electromagnetism and unequal up- and down-quark masses introduce small violations of isospin symmetry.

Finally, energy and momentum conservation require $\sqrt{s}\ge m_M+m_B$ for a particular pair, where $s$ is the squared total four-momentum. Only channels above their own threshold can occur. Total angular momentum and parity symmetry in quantum field theory constrain the partial waves of the meson-baryon scattering: a pseudoscalar meson and a positive-parity spin-one-half baryon have pair parity $-(-1{)}^L$ and total angular momentum $J=L\pm \frac{1}{2}$ (only $J=\frac{1}{2}$ for $L=0$). Initial and final partial waves must have matching $J$ and parity. Sufficient energy can open a channel, but cannot remove the electric charge conservation, baryon number, or strangeness constraints.

Use the Gaussian units convention implicit in the $4\pi$ coefficient. For a uniform dielectric and a counterion-only electrolyte, the Boltzmann distribution and Poisson-Boltzmann equation areThe reference electric potential is $\varphi (a)=0$, so $n_0=n(a)$; it is not a prescribed nonzero bulk concentration at infinity. A salt reservoir with additional ion species would require their charge densities as well. With $u=\log (r/a)$, the cylindrical Laplacian is $r^{-2}{d}^2/d{u}^2$. Since $\beta q\varphi =\Phi +2u$ and $r^2=a^2{e}^{2u}$, the factors of $e^{2u}$ cancel:Here primes mean differentiation with respect to $u$, and the surface condition is $\Phi (0)=0$ in this coordinate.

Multiply by ${\Phi }^{\prime }$ to obtain a first integral:The two specified far-field limits set $K=0$. For a solution tending upwards to infinity, take the positive square root. Writing $b=\sqrt{C/2}$ gives $(e^{\Phi /2}{)}^{\prime }=b$, hence the cylindrical counterion-only Poisson-Boltzmann profileFor $b>0$, $\Phi \to \infty$ and ${\Phi }^{\prime }=2b/(1+bu)\to 0$. The corresponding number density is

Apply Gauss's law to a coaxial surface per unit cylinder length. Define the positive accumulated cylindrical screening charge byThe signed outward electric field is $E_r=2[-\lambda +Q(r)]/(ϵr)$, so its magnitude is $2|\lambda -Q(r)|/(ϵr)$. In the branch here, $Q(r)<\lambda$, the field is inward andIn this display, ${\varphi }^{\prime }$ is a radial derivative. The quantities $Q$ are electric charges per unit axial length, not total charges of an infinite cylinder.

At the surface, $a{\varphi }^{\prime }(a)=2\lambda /ϵ$. Define the charge-$q$ Bjerrum length ${\ell }_B=\beta q^2/ϵ$ and the Manning parameter $\eta =\lambda {\ell }_B/q$. Matching the derivative of the solution givesThus the condensed branch exists only for $\eta >1$, and its normalization isThe sign condition $b>0$ is essential: simply squaring $\eta -1$ would produce a spurious subcritical density. Direct integration using $rn(r)dr=n_0{a}^{2}du/(1+bu{)}^2$ yieldsEquivalently, $E(r)=2{\lambda }_c[1+b/(1+b\log (r/a))]/(ϵr)$: the remaining far-field line-charge magnitude is ${\lambda }_c$. The Manning condensed fraction is $1-1/\eta$.

Below threshold, no positive-density profile can satisfy those same far-field conditions. Indeed ${\Phi }^{\prime \prime }\le 0$, so a negative initial slope $2(\eta -1)$ cannot increase to zero. The physical interpretation is the infinite-dilution limit of cylindrical counterions: start with a neutral finite cylindrical cell and send its outer radius to infinity. For $\eta \le 1$, counterions escape to arbitrarily large radii, leaving $n_0\to 0$ and no finite condensed charge. The bare-cylinder Boltzmann distribution $n\propto r^{-2\eta }$ also shows why its radial normalization $\int r^{1-2\eta }dr$ diverges in this regime. In the local zero-density limit, $\Phi =2(\eta -1)u$; this does not obey the condensed branch's imposed limits. At $\eta =1$ the branch has zero amplitude and $\Phi =0$, rather than $\Phi \to \infty$.

Consequently the intended counterion condensation result, interpreted as a local infinite-dilution density, isEvery finite neutral cell still contains enough counterions to neutralize the cylinder; the missing residual charge in the local limiting profile is carried to infinity. Taking the infinite-cell limit before the charge integral differs from integrating the entire finite cell first. In SI units, the same reference-charge Bjerrum length is $q^2/(4\pi {ϵ}_{\mathrm{abs}}{k}_{B}T)$; the electrostatic prefactors must be changed consistently.

Use Coulomb's law in vacuum, $F=q_1{q}_2/(4\pi {ϵ}_0{r}^2)$. The constant $4\pi$ is dimensionless, so the vacuum-permittivity dimension isThus the physical dimension of vacuum permittivity follows directly from the dimensions of electric charge, force, and separation.

An electric field is defined through the electric force on a stationary electric charge: $\mathbf{F}=q\mathbf{E}$. Therefore the electric-field dimension is

In electrostatics, the relevant Maxwell equations reduce to $\nabla \cdot \mathbf{E}=\rho /{\epsilon }_0$ and $\nabla \times \mathbf{E}=0$. For a volume $V$ with outward unit normal $\mathbf{n}$, integrate the first equation and apply the divergence theorem:This is the integral form of Gauss's law, with $Q_V$ the enclosed electric charge. The zero curl is the accompanying condition allowing an electrostatic potential locally, and globally when the domain permits one.

Use a local first-derivative Lagrangian density $\mathcal{L}(\varphi ,{\partial }_{\mu }\varphi ,x)$ with sufficient differentiability, and let variations have compact support or vanish at the spacetime boundary. If the phrase “a function of the field” were read literally as forbidding derivatives, the equation below would reduce to $\partial \mathcal{L}/\partial \varphi =0$; a propagating field requires derivative dependence. Varying the action givesIntegration by parts and arbitrary interior variations yield the Euler-Lagrange field equation,The boundary condition is part of this derivation; if boundary variations are allowed, their separate boundary equations must also be imposed.

A variational symmetry of a Lagrangian density is an infinitesimal field change $\delta \varphi =\epsilon X$ for which $\delta \mathcal{L}=\epsilon {\partial }_{\mu }{K}^{\mu }$ off shell. Equality to zero is sufficient but is not necessary: a divergence changes only the boundary contribution to the action. For fixed-coordinate field variations,Equating the two expressions proves the scalar-field form of the Noether theorem:Thus every differentiable one-parameter variational symmetry gives a conserved current, and its Noether charge $Q=\int d^{3}x{j}^0$ is constant when the spatial boundary flux vanishes. This is the Noether current for a first-derivative scalar field; the same identity applies to several real components by summing over them. Identically conserved improvement terms can change its local expression without changing the charge under the same boundary assumptions.

For an active spacetime translation, ${\varphi }^{\prime }(x)=\varphi (x-a)$ and $\delta \varphi =-a^{\nu }{\partial }_{\nu }\varphi$. If the Lagrangian density has no explicit coordinate dependence, $\delta \mathcal{L}=-a^{\nu }{\partial }_{\nu }\mathcal{L}$, so $K^{\mu }=-a^{\mu }\mathcal{L}$. The Noether current is $j^{\mu }=-a^{\nu }{T}^{\mu }{}_{\nu }$, whereThese four translation currents are the canonical stress-energy tensor, also called the energy-momentum tensor. The sign in $j=-aT$ follows from the chosen active translation; the translation charges themselves can be labelled by $P_{\nu }=\int T^0{}_{\nu }{d}^{3}x$.

For the free real scalar field, take the standard kinetic term and mass term. Its Lagrangian density and Klein-Gordon equation areHere ${\Pi }^{\mu }={\partial }^{\mu }\varphi$, so $T^{\mu \nu }={\partial }^{\mu }\varphi {\partial }^{\nu }\varphi -{\eta }^{\mu \nu }\mathcal{L}$. Raising the charge index gives the four-momentum of a free real scalar field,The first is total energy, and the three components of the second are physical spatial momentum. With signature $(+,-,-,-)$, $P_i=-P^i$; this explains the opposite sign if the conserved quantities are instead written with lower spatial indices. For example, a plane wave proportional to $\cos (Et-\mathbf{k}\cdot \mathbf{x})$ has momentum density along $\mathbf{k}$, confirming the sign. All charges require convergence of the integrals and vanishing boundary flux, or periodic boundary conditions in a finite box.

For the complex scalar field, treat $\psi$ and ${\psi }^{\ast }$ as independent variables when varying, equivalently use their two real components. The global phase symmetry of a complex scalar field is $\psi \mapsto e^{-i\alpha }\psi$, ${\psi }^{\ast }\mapsto e^{i\alpha }{\psi }^{\ast }$ for constant $\alpha$. Both the kinetic term and $V(|\psi {|}^2)$ are invariant. This is a global internal symmetry of a classical field theory with circle group $U(1)$; a spacetime-dependent phase would require a gauge connection.

Choosing this orientation for the phase parameter gives the Noether charge of a complex scalar field:To check conservation directly, the Euler-Lagrange field equations are $\square \psi +V^{\prime }(|\psi {|}^2)\psi =0$ and their complex conjugates, assuming a real differentiable potential. Hence ${\partial }_{\mu }{j}^{\mu }=i({\psi }^{\ast }\square \psi -\psi \square {\psi }^{\ast })=0$. Reversing the phase-parameter orientation reverses the current and charge, which is merely a convention. For a scalar carrying electric charge $q$, the physical electric charge is $qQ$ after electromagnetic coupling. In a neutral theory the same global charge can instead label an internal conserved quantum number; the density alone does not identify it automatically with electricity.

Forbidden by electric-charge conservation. The initial bottom quark has electric charge $-1/3$, while the displayed final electric charges sum to $2/3+1+0=5/3$. Therefore no Standard Model Feynman diagram, at tree level or any loop order, can realize this channel.

This is an intentionally disallowed process, not a transcription correction. The charge-conserving semileptonic bottom decay instead has an Electron and an antineutrino of Electron flavour, while a Positron accompanies the conjugate antiquark decay. Replacing the displayed particles silently would change the requested classification.

Allowed through a t-channel W boson. Along one fermion line the up quark becomes a down quark by emitting a virtual $W^{+}$; along the other the charm antiquark absorbs it and becomes a strange antiquark. The middle panel shows this weak charged current exchange. Both electric charge and baryon number are conserved at each vertex, and the relevant CKM matrix entries are nonzero.

This is the unique physical-particle tree-level Feynman diagram. A neutral exchange would require a flavor-changing neutral current on each line, absent at tree level in the Standard Model. An annihilation into a neutral boson would likewise require an off-diagonal up-type neutral current. The different generations do not forbid the charged-current graph.

Allowed through a virtual W boson. The charm quark emits a $W^{+}$ and becomes a down quark through the nonzero CKM matrix element $V_{cd}$. The virtual W boson produces a positive muon and a muon neutrino through the leptonic weak charged current. The right panel is the unique physical-particle tree-level Feynman diagram.

Its total electric charge is $-1/3+1=2/3$, equal to the initial charge, and its final lepton number is $-1+1=0$. The decay is Cabibbo suppressed, rather than forbidden. These diagram counts use unitary gauge: in covariant gauges charged unphysical Goldstone bosons can supply gauge-dependent pieces of the same physical amplitudes, not additional physical channels.

In the local orthonormal tetrad, the components of the photon number current areThey are respectively the photon number density and the photon number flux. Thus $J^{\mu }$ is the photon number four-current, not an energy current or an electric charge current. Photons carry no electric charge. For the isotropic background,Integrating the covariant Boltzmann equation over the invariant mass-shell measure, with vanishing momentum-boundary flux, giveswhere $C[f]$ is the collision operator in the covariant streaming equation. ThereforeCollisionless photon propagation satisfies this condition, as do Thomson scattering and ordinary Compton scattering when all participating photons are counted: each collision has one incoming and one outgoing photon. Photon emission, photon absorption, bremsstrahlung, double Compton scattering and electron-positron annihilation in cosmology or its inverse generally give a nonzero number source. A cancellation of net creation and destruction can nevertheless make the integrated source vanish even when individual number-changing reactions occur. Cosmological redshift itself changes photon energy, not photon number; in an expanding homogeneous universe a conserved photon number current gives ${\bar{n}}_{\gamma }\propto a^{-3}$.

The electric field is force per unit electric charge, so

The free-space Green function of the Laplacian for the Poisson equation gives the electric potentialFor $r=|\mathbf{x}|\gg R$, its electric multipole expansion begins withDefine the total electric charge and electric dipole moment byThen

The analogous solution for the magnetic vector potential isIts apparent $r^{-1}$ coefficient is ${\mu }_0(4\pi {)}^{-1}\int \mathbf{J}{d}^3{x}^{\prime }$. For each component, the supplied identity and the divergence-free vector field condition giveThe divergence theorem turns this into a surface integral outside the compact support of the current density, where $\mathbf{J}=0$. Hence $\int \mathbf{J}{d}^3{x}^{\prime }=0$, so the $1/r$ term vanishes.

In the absence of free electric charge and electric current, the source-free Maxwell equations in a linear medium aretogether with the constitutive relations $\mathbf{D}=\epsilon \mathbf{E}$ and $\mathbf{B}=\mu \mathbf{H}$.