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A semiconductor whose mobile charge carrier population requires Fermi-Dirac statistics rather than a dilute Maxwell-Boltzmann distribution. In a strongly degenerate n-type semiconductor, the Fermi level lies inside the conduction band; in a strongly degenerate p-type semiconductor, it lies inside the valence band. The occupied and empty quantum states on opposite sides of a tunnel diode can then overlap in energy. Heavy semiconductor doping both changes these occupations and narrows the depletion region; a narrow barrier and accessible final quantum states serve different roles.

The region around a p-n junction with reduced mobile charge carrier density.

An illustrative abrupt-junction depletion approximation assumes uniform, fully ionized donor impurities and acceptor impurities, negligible mobile space charge in the depleted layer, and permittivity ${\epsilon }_s$. For area $A$, doping number densities $N_A,N_D$ and built-in electric potential difference $V_{\mathrm{bi}}$, it givesHere $q>0$ is the elementary charge and $V$ is positive for forward bias. Increasing both doping densities reduces $W$ in this estimate. That explains the preparation strategy for a tunnel diode; it does not make this sharp-depletion approximation a precise microscopic model of a degenerate semiconductor.

Quantum tunnelling between different energy bands, including transfer between the valence band and conduction band in a tunnel diode.

A Josephson junction couples two regions with superconductivity through a weak link. A tunnel barrier is one implementation.

The remarkable possibility is a steady electric current across an insulating barrier at zero electric potential difference. This is the DC Josephson effect, carried by coherent transfer of Cooper pairs. It differs from single-electron superconducting tunneling, which probes the quasiparticle excitation spectrum and produces a dissipative current-voltage characteristic. Both contributions can occur in the same superconducting tunnel device. Brian D. Josephson predicted the pair contribution in 1962; his paper treats transfer that leaves the quasiparticle distribution unchanged. ^[ref]

The Josephson effect turns a difference of quantum phases into a measurable electric current, and an applied electric potential difference into a rate of phase advance. The Giaever gap experiment instead turns an electric potential difference into an excitation energy scale. These complementary measurements expose two aspects of superconductivity: its coherent order parameter and its gapped quasiparticle spectrum. The microscopic pairing calculation belongs to BCS theory and the BCS gap equation. A tunnel diode uses a different device, a semiconductor p-n junction.

Adding capacitance and an external bias makes the Gauge-invariant Josephson phase dynamical. Current-biased Josephson phase dynamics explains how its trapped energy levels and escape can be measured electrically.

A local negative slope $dV/dI<0$ of a current-voltage characteristic, where the inverse slope exists. This differs from negative $V/I$: a tunnel diode can have positive electric potential difference and positive electric current while $dV/dI<0$.

A p-n junction joins regions of a semiconductor with opposite majority charge carriers: Electrons on one side and electron holes on the other. It provides the junction modeled by the Shockley diode equation.

Near an unbiased p-n junction, diffusion leaves exposed ionized donor impurities and acceptor impurities. Their electric field opposes further majority-carrier transfer. At thermal equilibrium, drift and diffusion balance; there is no net electric current. Forward bias reduces the barrier to carrier injection; reverse bias enlarges it. A heavily doped tunnel diode adds a different transport route, quantum tunnelling, that the ordinary Shockley diode equation omits.

A tunnel diode is a p-n junction with sufficiently heavy semiconductor doping on both sides to make a thin depletion region and permit substantial interband tunnelling. The neutral regions are degenerate semiconductors. Its distinctive forward current-voltage characteristic contains a peak followed by a valley: over part of the curve, increasing the applied electric potential difference decreases the electric current. The Esaki tunnel-diode experiment made this behavior experimentally concrete.

The useful quantity is the local slope, not the ratio of total voltage to total electric current. With conventional electric current $I$ entering the positive-voltage terminal, defineNegative differential resistance means $g_d<0$, hence $r_d<0$ where defined. A forward operating point can still have $V>0$, $I>0$ and absorbed power $VI>0$. A small voltage increase then gives a negative current increment; this does not make the total electric current negative or turn the device into an unlimited source of energy. The external supply sets the operating point and supplies the energy available for an electronic amplifier.

An original idealized construction explains the shape. Put the n-type semiconductor on the left and the p-type semiconductor on the right. Take $q>0$ as the elementary charge and $V=V_p-V_n$. Increasing forward bias lowers the right-hand Electron energy levels relative to the left. Denote the two reservoir electrochemical potentials by ${\mu }_n,{\mu }_p$, so that ${\mu }_n-{\mu }_p=qV$. At zero temperature, occupied left-hand conduction band states extend up to ${\mu }_n$; empty right-hand valence band states start at ${\mu }_p$. For transfer conserving Electron energy, the available interval isIt is nonempty only when its upper endpoint exceeds its lower endpoint. Both an occupied initial quantum state and an empty final quantum state must exist at the same energy. The Pauli exclusion principle prevents transfer into an already occupied final quantum state.

For the original diagram, choose arbitrary energy units with $E_{c,n}=-0.5$, ${\mu }_n=0$, ${\mu }_p=-u$ and $E_{v,p}=0.5-u$, where $u$ is $qV$ in those units. The available interval has widthThus $L(0.25)=0.25$, $L(0.50)=0.50$, $L(0.70)=0.30$, and $L(1.15)=0$. Initially forward bias opens a transfer window; further forward bias closes it by moving the right-hand valence band edge below the left-hand conduction band edge. This is a state-counting illustration, not a formula for a measured electric current.

For reverse bias, the transfer direction changes: occupied right-hand valence band states can feed empty left-hand conduction band states. In the same construction, $u=-0.70$ opens the interval $0<E<0.70$ for this reverse transfer. A narrow depletion region allows a large reverse quantum tunnelling electric current at small electric potential difference, whereas the ordinary Shockley diode equation predicts only a small reverse saturation electric current before diode reverse breakdown. At zero biasing, equal reservoir occupations give zero net electric current; quantum tunnelling does not require a net equilibrium flow.

A finite-temperature refinement replaces sharp occupation cutoffs with the Fermi-Dirac distribution. An illustrative weak-transfer expression isHere $\mathcal{W}\ge 0$ describes allowed initial/final quantum states and their coupling, and $f_n,f_p$ are Fermi-Dirac distributions with the respective electrochemical potentials. The occupation difference follows by subtracting the reverse transfer factor from the forward one: $f_n(1-f_p)-f_p(1-f_n)=f_n-f_p$. An overlap interval alone does not determine $\mathcal{W}$: transmission probability, density of states, crystal momentum selection and phonons can matter. A complete germanium calculation is more demanding than multiplying two constant density of states factors. At larger forward bias, ordinary carrier injection and diffusion supply a rising current branch even after direct band overlap is lost.

A current-voltage characteristic determines possible steady operating points; it does not alone determine their linear stability. Consider an ideal voltage source $V_s$ feeding a tunnel diode through a resistor $R>0$, with a positive constant capacitance $C$ across the junction. Assume a quasistatic device relation $I(V)$ and neglect inductance, transit delays, noise and heating. Kirchhoff's current law gives the original one-state modelA steady operating point $V_{\ast }$ satisfies $I(V_{\ast })=(V_s-V_{\ast })/R$: the device curve intersects the descending supply line. This is the source-side counterpart of a resistive load line. A small perturbation $V=V_{\ast }+\delta V$ obeysThus the equilibrium point is locally attracting if $1/R+I^{\prime }(V_{\ast })>0$ and unstable if the inequality reverses. Equality requires higher-order analysis. Even on a negative differential resistance segment, a sufficiently small supply electrical resistance can stabilize this model. The assumption about the electrical circuit matters: an inductive or delayed circuit has additional state variables and may behave differently.

Choose an original toy forward characteristic, with no fitted device parameters:where $V_0=0.10\mathrm{V}$, $I_0=1.0\mathrm{mA}$ and $0\le x\le 3.6$. For every $x>0$, $i(x)>0$, so this entire forward curve absorbs positive total power. NeverthelessThe model therefore separates negative differential resistance from negative total $V/I$. The corresponding peak and valley are at approximately $0.1184\mathrm{V}$ and $0.2816\mathrm{V}$; these voltages deliberately differ from the historical peak.

With $R=100\Omega$ and $V_s=0.60\mathrm{V}$, the supply line is $I/I_0=6-x$. The intersection equation factors exactly:The three operating points are $(0.10\mathrm{V},5\mathrm{mA})$, $(0.20\mathrm{V},4\mathrm{mA})$ and $(0.30\mathrm{V},3\mathrm{mA})$. Their values of $1/R+I^{\prime }(V_{\ast })$ are respectively $20$, $-10$ and $20\mathrm{mS}$. The outer two attract nearby trajectories; the middle one repels them. This is bistability in the specified one-state electrical circuit.

For the second panel, choose $R=25\Omega$ and $V_s=0.30\mathrm{V}$. Now $I/I_0=12-4x$ andThere is exactly one real operating point, again $(0.20\mathrm{V},4\mathrm{mA})$. Here $1/R+I^{\prime }(V_{\ast })=20\mathrm{mS}>0$, despite the device's own slope $I^{\prime }(V_{\ast })=-20\mathrm{mS}$. With $C=10\mathrm{nF}$, the perturbation decays with time constant $C/(20\mathrm{mS})=0.50\mu \mathrm{s}$; the unstable middle point of the first panel has growth time $1.0\mu \mathrm{s}$.

The one-state autonomous model supports switching between attracting operating points after a perturbation or parameter change; it cannot produce a nonconstant periodic orbit. A proposed oscillator needs additional dynamics. This limitation is useful: a load-line intersection establishes a possible steady reading, the slope test establishes local attraction in a specified model, and neither calculation alone predicts an oscillation frequency for a real tunnel diode.