Write the surface tension as , where . The thermocapillary thin-film equation has flux . Balancing both terms at thickness scale gives aspect ratio and time scale . The fractional surface-tension variation is , so using constant tension in the leading capillary pressure term is consistent with the balanced long-wave limit.
Capillary diffusion 2026-10-07
Eliminating phase pressures with gives . For decreasing capillary pressure, . This nonlinear diffusion broadens a saturation shock; it can degenerate where a phase mobility vanishes. Endpoint conservation retains the limiting Rankine-Hugoniot condition.
Capillary length Created 2026-09-24 Updated 2026-10-14
The capillary length measures when gravity and surface tension are comparably important in shaping a liquid interface. For a liquid of uniform mass density , beneath a gas whose mass density is negligible, with uniform gravitational acceleration and constant surface tension ,
A deformation of height and horizontal length scale has hydrostatic pressure variation of order and small-slope capillary pressure of order . Equating these gives : surface tension smooths small features, whereas gravity matters for broad ones. For two resting fluids, replace by their positive mass density difference in this static balance. This change alone does not give the two-fluid wave dynamics, because both fluids can have inertia. [ref]
With the stipulated illustrative parameters , , and , the capillary length is . These parameters define the ideal calculations below; they are not a measurement of a particular sample.
Figure 1.
The gravity-capillary wave crossover occurs at wavelength , where phase speed is smallest
. Calculated phase velocity and group velocity magnitudes, and the ratio of the surface tension and gravity terms in the deep-water dispersion relation, for the stipulated , and . The capillary length is , while the equality wavelength is . Both panels show ideal theory, without experimental data. Details.
For a sinusoid with wavenumber , the relevant horizontal scale is , while its wavelength is . Thus the Bond number for this scale and the reciprocal restoring-term ratio are
Equality is at , hence for these parameters. Using instead produces a different numerical Bond number; state the length convention. The capillary length itself is not the equality wavelength. This distinction helps choose whether a measured ripple should be modeled as a surface gravity wave, a nearly pure capillary wave, or a gravity-capillary wave. [ref]
Gravity-capillary wave 2026-10-14
A gravity-capillary wave has restoring contributions from both gravity and surface tension. Consider an initially resting, horizontally unbounded liquid layer of constant depth , with uniform mass density , incompressible flow, inviscid flow and irrotational flow. The upper gas exerts constant pressure and has negligible inertia. Assume a clean interface with constant surface tension : no surfactant stresses, imposed current or wind. The wave amplitude must satisfy and , so linearized boundary conditions apply. Deep water means , rather than a particular depth in metres. [ref]
Let be the undisturbed free surface, with liquid below it. Potential flow gives a velocity potential with , and incompressible flow gives the Laplace equation. The linearized kinematic boundary condition for a free-surface graph and the Unsteady Bernoulli equation, including gravity and the Young–Laplace equation, give
Here is the interface displacement; the signed small-slope pressure jump is . A wave crest has , so its capillary pressure is positive. Choose a right-travelling Fourier mode of positive wavenumber and angular frequency :
The factor decays into the deep liquid, satisfies the Laplace equation, and makes at . Substituting in the dynamic boundary condition leaves
This derivation displays the two restoring contributions with the same sign. Dimensional analysis also checks the result: has units , so both and have units . [ref]
At finite depth, a flat impermeable bottom at requires . Replacing by the normalized vertical factor makes the surface ratio . Eliminating the mode amplitudes then gives
Thus the same model supplies its own depth check: use the deep-water formula only when is sufficiently close to one for the required accuracy. For example, reduces by about relative to deep water, while reduces it by about . These percentages are calculations from this factor. [ref]
In deep water the phase velocity magnitude follows a wave crest, while the group velocity magnitude follows the wave envelope of a narrow wave packet. Differentiating the positive-frequency dispersion relation gives
For , the surface gravity wave limit has . For , the deep-water capillary-wave dispersion relation has : a wave crest slips backward relative to the faster wave envelope, even while both advance. Neither speed is the oscillating fluid element's own velocity. [ref]
There is a particularly neat coincidence at the crossover. Differentiate : its unique minimum is at , exactly where the restoring terms are equal. Therefore
For the stipulated parameters in capillary length, the minimum is . At , direct substitution gives , and . This short wavelength is capillary dominated, but its group velocity is still slightly below the pure-capillary ratio because gravity has not vanished.
Without surfactant, capillary pressure drives a surface flow towards a growing bulge. Advection compresses the insoluble surfactant in converging parts of that motion, increasing concentration and lowering surface tension. The resulting gradient supplies a tangential Marangoni stress that opposes the surface motion. This additional resistance slows capillary-driven redistribution of liquid even after the base-tension decrease has already been accounted for.
In the strong-elasticity limit, concentration gradients suppress tangential interface motion. The surface behaves as effectively immobile at leading order. Setting in the velocity formula gives , hence
one-quarter of the clean shear-free mobility . This mobility reduction explains the quarter-rate limit; it slows the unstable capillary mode without removing the long-wave unstable band.
Choose transverse along the cusp from the line of cylinder contact, and across its narrow gap. Expanding the two circular boundaries for gives , so the local full gap is . At the meniscus, , a semicircle fits across this gap with radius . Thus the leading area and transverse curvature in the cusp flow between touching cylinders are
The meniscus area correction is and is small relative to . The curvature is stated as a positive suction magnitude; the liquid pressure relative to air is . Axial curvature is negligible compared with this transverse curvature under the slow-variation approximation.
At fixed , axial lubrication theory gives a local slit Poiseuille flow between rigid walls :
Integrating across the cusp gives
The local meniscus edge correction occupies a transverse width small compared with and does not change this leading flux. Since , the axial volume flux is . Area conservation now gives
Writing also puts this in porous medium equation form , explaining the finite-support spreading profile.
Set . Fixed volume means . If and axial extent is proportional to , this conservation gives . The evolution equation gives , hence , .
For the symmetric source-type similarity solution, write , . The differential equation becomes
Integrate from the centre using zero flux and symmetry. This gives , so on the positive support . With ,
Therefore the fixed-volume capillary spreading in a cylindrical cusp profile is
Let . Its volume is
With , the last integral is , equal to the supplied sine integral by symmetry. Consequently , yielding
The other tip is at . The maximum width decays as . This is the leading slender outer solution: the ideal point injection and the steep microscopic nose require local descriptions outside its uniform lubrication range.
Finally, for vertical cylinders let denote the liquid density, and take the bath pressure at as the air-pressure reference. At rest the liquid pressure is . Equating hydrostatic suction with the wetting-meniscus capillary pressure gives the hydrostatic rise in a cylindrical cusp:
The cusp can therefore support an indefinitely high, increasingly narrow ideal wetting tail rather than a fixed terminal rise height. Large makes and strengthens the transverse cusp approximation, until microscopic physics limits the continuum description.
For the motionless uniform layer, the heat equation reduces to . The lower temperature and upper heat-transfer condition determine the quasistatic temperature of a conductively cooled film:
When , . For a varying film let its vertical velocity scale as , as required by incompressible flow. Relative to vertical thermal diffusion, horizontal thermal diffusion is smaller by , and either horizontal or vertical thermal advection is smaller by . Time variation on the film's transport timescale has the same small factor. Thus the leading heat equation is again at each when both specified dimensionless parameters are small. This argument retains the small assumption. If thickness were externally varied on a faster timescale , one would additionally need ; the spatial conditions alone do not control arbitrary rapid time dependence.
Define . The surface tension at the surface is , so the Marangoni stress is . With capillary pressure to leading order, horizontal Stokes flow in the film solves , , . Hence
The continuity equation gives the thermocapillary thin-film equation
To justify using constant surface tension in the capillary pressure, compare the two volume fluxes on horizontal scale : their magnitudes are and . When both mechanisms are retained at leading order, their balance gives . Thus replacing by in the curvature term incurs only a relative small correction. Equivalently, small ensures this if is bounded; if it were parametrically large, the extra small surface-tension-variation condition would have to be imposed separately.
The capillary pressure is higher beneath a crest than beneath a trough, so pressure-driven volume flux drains the crest and smooths thickness. The Marangoni effect acts oppositely: a thicker region has a colder surface and therefore larger surface tension. Surface velocity is pulled towards that region, supplying more liquid and amplifying the thickness variation. The arrows below represent these two mechanisms separately.
Figure 1.
Capillary pressure drains film crests whereas cooling-induced Marangoni stress draws liquid towards them
. Details.
Put and . Substitution of , , gives coefficients and . Making both equal to one yields
In these scales the fractional surface tension change is , making the previous approximation explicit.
The linear stability analysis about gives . For a normal mode ,
Long waves with grow, decay, and are neutral. The neutral mode changes the mean film thickness. The dispersion relation is even in , with its two maxima at .
For a steady positive film with zero volume flux, divide by and integrate to obtain . Choosing as specified fixes . Multiplication by and another integration then give the zero-flux thermocapillary film profiles first integral
For , and : the unique minimum is , while and . This potential energy interpretation classifies the profiles without assuming a sinusoidal shape at finite amplitude.
For , the only profile is the uniform film . For , there are two positive turning heights and a smooth periodic film oscillates between them. Its period is
For , the maximum is and the lower endpoint is zero. A drop reaches zero thickness in finite distance, with zero limiting slope but unbounded curvature since . Its half-width is
Thus the formal limiting profile consists of drops of peak height and footprint width , with zero limiting contact angle. Identical drops can touch, or a zero-thickness region can separate them in the degenerate zero-flux model. These are limiting wet-region solutions, not everywhere positive twice differentiable films; the singular contact region is not resolved by lubrication theory. A useful parametric drop profile is
Finally let with small positive . Writing gives and . The small-amplitude steady profile is , with period tending to . Its wavenumber tends to the neutral boundary of the unstable band, not to the fastest-growing wavenumber.
Figure 2.
Thermocapillary-film dispersion relation, energy potential and periodic or dry-contact steady profiles
. Details.
Effective permeability of a porous medium. Work to leading order in the slender-layer ratio . Take the growing lower wedge to have porous permeability , with interface , and the upper wedge to have porous permeability . The leading pressure is independent of ; vertical flow is smaller than horizontal flow by . Define
Darcy's law and the fixed two-dimensional volume flux give
Here is Darcy velocity; the parcel speed is . Integrating the pressure gradient over the length and defining yields
The equal-porous permeability limit is . This logarithmic mean comes from parallel layers at each cross-section followed by series addition of their local hydraulic resistances. It is a slender-layer result; a full two-dimensional transmission problem has small end and interface corrections.
Parcel paths and travel times. Pressure equalization does not mean that parcels stay at fixed : mass conservation requires a small vertical flow. Define a streamfunction by and . Its leading expression is
Let label a parcel released at the inlet. There . At the inclined interface , so the parcel crosses from the upper wedge into the lower one at
Before crossing, ; afterwards, . These expressions show why integrating the speed along a horizontal line would give the wrong parcel time.
Put and , the pore-volume throughput time. Integrating on the two portions of the path gives
Its derivative with respect to is , so it is monotone. The limiting streamline times at the lower and upper boundaries are and respectively. Hence
The printed expression assumes . The absolute value is needed for a nonnegative maximum difference without that ordering. For equal porous permeabilities every parcel has time .
Figure 1.
Streamlines crossing an inclined permeability interface in a slender layer with lower-wedge permeability ten times the upper-wedge permeability
. Details.
Oil recovery. In the ideal passive-displacement model with , the earliest and latest travel times are and , a spread of . Preferential paths through the high-porous permeability wedge therefore give early water breakthrough while oil on slower paths remains unswept. Continued injection sends much water through paths already swept; complete displacement requires several pore volumes. The flux-weighted residence time in a porous layer remains . Real waterflooding also depends on phase mobilities, relative permeabilities, capillary pressure and mixing, so these numbers illustrate heterogeneity rather than a quantitative two-phase recovery prediction.
Saturation equation. Introduce intrinsic permeability of a porous medium and porosity . The relative porous permeabilities depend on the wetting fluid saturation. Define the phase mobilities and fractional flow
Use the conventional capillary pressure , generally decreasing as wetting saturation increases. Neglect gravity in this horizontal model. The two Darcy fluxes are and . Eliminate the common pressure gradient using to obtain
The wetting-phase mass conservation law is consequently
For , and the capillary pressure provides nonlinear diffusion. The initially uniform saturation is . Pure wetting-fluid injection prescribes and ; in the zero-capillarity, zero-residual-nonwetting idealization this corresponds to inlet saturation one. With residual nonwetting fluid, replace one by the appropriate maximum accessible saturation.
Shock formation and its speed. Neglect capillarity first. Smooth saturation values travel along characteristic curves at speed . When the trailing values have larger characteristic speeds than the values ahead, the curves intersect, and the Buckley-Leverett equation requires a shock selected as an entropy solution. This is typical for the increasing-convex part of a physical fractional-flow curve; shocks are not inevitable for every possible .
Integrating mass conservation across a shock from upstream to downstream gives the Rankine-Hugoniot condition
If an upstream rarefaction wave joins the shock smoothly in similarity coordinates, its terminal characteristic speed equals . Therefore the saturation at that join obeys the fractional-flow tangent construction
This is the printed equality. It is a tangent-selection condition, not the dimensional speed by itself; the speed includes . An arbitrary shock between prescribed constant states satisfies the jump condition but need not satisfy this additional tangency relation.
Positive capillary diffusion spreads a jump into a transition layer. For a travelling profile , integration gives
The endpoint states still satisfy the same Rankine-Hugoniot condition. Thus small capillarity primarily gives the front a finite thickness rather than changing the selected limiting speed; vanishing phase mobility at an endpoint can make the regularization degenerate.
The specified reciprocal fractional flow. On its stated branch, and . If extends continuously to the initial saturation and the inlet is at one, the decreasing saturation from behind to ahead makes characteristic speeds increase forwards: there is a rarefaction wave, not a compressive shock. Write and . The self-similar solution is
The fan connects continuously to the initial state and broadens linearly in time. This interpretation requires . A nonnegative physical fractional flow on the entire interval also requires .
The PDF specifies the formula only for and earlier calls residual. If that means an immobile wetting phase with , the endpoint is an extra constraint and the continuous-branch answer applies without conflict only at . For , the printed branch would give negative fractional flow for , so it cannot be the complete physical constitutive law. With an additional admissible extension, for example up to and the given positive branch above it, a compound fan–shock is possible. The tangent condition then gives
The fan ends at , followed by a jump to . This is a conditional physical extension, not data supplied by the question. For an immobile residual endpoint is likewise incompatible with a continuous version of the stated branch. These distinctions identify what is, and is not, determined by the printed constitutive assumption.
Take positive downwards. The leading axial velocity of a slender viscous thread is independent of radius. Incompressible flow then gives , while steady mass conservation gives . The Newtonian fluid stress tensor has and . The Young–Laplace equation, neglecting axial curvature at slender order, gives and hence .
The axial cut transmits both the integrated Newtonian fluid stress tensor and the circumferential surface tension. After subtracting the ambient pressure, its tensile force is
The coefficient three is the Trouton ratio for axial extension. The last term is essential: the capillary tensile force of a slender thread is , not , because the capillary pressure subtracts half the interfacial line contribution. Axial force balance is . Together the governing equations are
Define the dimensionless variables
Then and the axial equation becomes
For the increasing power-law branch, all three terms have the same dependence when . Substitution leaves . Thus
This remains valid at , when . The other root is negative and describes a decreasing local branch up to its singular endpoint, not a thread accelerating downwards indefinitely. Positive surface tension decreases , so it slows the fall at a given height on this branch. Thinning reduces the capillary tensile force . Its negative axial derivative supplies an upward capillary force on a thread segment, balancing part of the weight. The viscous tensile force therefore supplies a smaller remaining balance; on the quadratic family this reduces the stretching rate.
The condition alone does not select a unique solution of this second-order ordinary differential equation. The boxed power law is the requested verified branch, with tensile force tending to zero at large height; an additional nozzle tension or downstream condition is required to select it physically. The slender, negligible-inertia approximation must remain valid over the height range considered.
Take upwards and write , so that the unperturbed interface is , with carbon dioxide above and water below. Use the sharp-interface, incompressible flow version of Darcy's law, with constant porosity and permeability of a porous medium, no capillary pressure, and effectively unbounded layers. The distinction between Darcy flux and interface speed matters: the base flux is , since the printed is the speed of the interface. Thus the base pressure gradients satisfy
The mass density ordering is stabilizing, whereas injection of the less viscous fluid into the more viscous fluid produces the Saffman–Taylor instability.
For linear stability analysis, displace the interface by . Taking the divergence of Darcy's law shows that the perturbation pressure satisfies the Laplace equation. Decay away from the interface gives, for ,
The kinematic boundary condition and continuity of normal Darcy flux give
Meanwhile pressure continuity, evaluated on the displaced interface, gives
Eliminating yields the buoyancy-modified Darcy fingering dispersion relation:
Every nonzero wavenumber decays when , grows when , and is neutral at equality, where
The zero wavenumber is a uniform displacement and is neutral. Without a short-scale regularization such as surface tension, this model has no fastest-growing finite wavenumber: on the unstable side its growth rate increases without bound as increases. Finite layer depths would change the dispersion relation; none are specified here.
Taking and a year of days, the data give
The numerical paragraph supplies no porosity, so it cannot determine a unique numerical interface speed. If were instead intended to mean Darcy velocity, the numerical critical value would be , and the interface would move at . These two velocity conventions must not be conflated.
Take in the injection direction and along the flat interface. The specified must be a Darcy velocity, so the pore-fluid velocity and unperturbed interface speed are . Write the perturbed interface as , with , and choose the normal from fluid 1 into fluid 2. The background pressure gradients from Darcy law are .
By incompressibility and uniform permeability of a porous medium, pressure perturbations are harmonic functions. A transverse Fourier mode with positive wavenumber has the decaying forms
The kinematic boundary condition and equal normal Darcy flux imply
Without capillarity the pressure is continuous at the displaced interface. Its linear perturbation is therefore
Consequently the planar viscous-fingering dispersion relation reduces to
This is the Saffman–Taylor instability: less viscous fluid advances preferentially through protrusions. Without a short-wave regularizing mechanism the idealized rate has no finite maximum.
For the prescribed apparent capillary pressure, the chosen normal is , so . Subtract the flat-front pressure jump . Linearization of the jump at gives
There is no first-order product of the surface-tension perturbation and the perturbed macroscopic curvature. Thus
Using the capillary number convention and , this is
If is measured from the unperturbed front and denotes its local apparent tension, set to obtain the usual fixed-coefficient expression. For a physically fixed spatial gradient, and the displayed rate is an instantaneous, generally time-dependent growth rate; the amplitude solves , rather than one constant exponential law for the entire displacement. The parameter has dimensions of inverse length; the absolute tension gradient is .
Assume , as required for positive apparent surface tension, and define . If , unstable modes satisfy . Differentiating the cubic dispersion relation gives the fastest-growing mode
When , every nonzero mode decays, with a neutral zero-wavenumber translation in the infinite-domain limit. For , surface-tension-gradient stabilization of viscous fingering suppresses the instability entirely at positive injection speeds satisfying
If , no positive injection speed eliminates every long-wave unstable mode in an unbounded interface. The prescribed wetting variation is treated as an effective normal pressure law for porous-media flow.
Let be downward Darcy flux, measured per unit total horizontal area. Neglect the resistance of the displaced phase, capillary pressure, and horizontal subsurface flow. Taking atmospheric pressure as zero, the upper end of the saturated column has pressure and its advancing lower end has pressure zero. Across a column of depth , Darcy law therefore gives
The pressure head from the overlying layer supplies , and gravity supplies one. Because the new liquid fills a pore volume per unit area, the vertical imbibition under a draining liquid layer obeys . Volume conservation gives , so, until the surface layer is exhausted,
The initial condition is understood as a limiting solution of this singular equation. For , separation of variables gives
At small penetration, expansion of the logarithm yields , hence
A sufficient dimensional early-time condition is , for which . The printed needs a chosen time unit or nondimensionalization. In the limiting case , holds exactly until . The divergent initial Darcy flux is an idealization of sudden contact with a dry continuum; it cannot describe penetration below the pore scale.
For the spreading surface layer, measure upwards from the substrate. A thin, slow gravity current has hydrostatic pressure and a leading horizontal viscous balance . A no-slip boundary condition at and a stress-free boundary condition at give
This lubrication gravity-current flux drives horizontal spreading down the surface-pressure gradient. Surface volume conservation is , while conservation in the pores is . Combining these balances gives the deep-substrate drainage of a gravity current model
Drainage transfers liquid from the surface layer into the substrate. Indeed .
For definiteness take a one-sided current on , supplied at . The imposed volume is per unit span, so has dimensions of area. The boundary conditions and volume conservation constraint are
The source starts from zero injected volume. Initially dry points acquire only when the advancing current reaches them; the formula is not applied outside that region. At the advancing nose these are limiting conditions for a singular drainage equation. For a source feeding two identical sides, each side has half the volume and inlet flux; only the corresponding numerical prefactors change. The integral and inlet-flux conditions are equivalent once the local balance and nose conditions hold.
The physical approximations are lubrication theory, negligible inertia, slowly varying surface height, small pore-scale Reynolds number, and negligible capillary entry pressure. Treating the substrate as vertically draining columns also requires its lateral flow to be negligible and its depth to exceed the penetration depth. The model is valid while surface liquid remains available above each draining column.
For a similarity solution, let and scale as , and let the current length scale as . Since then has no time dependence, drainage requires . Balancing with the horizontal spreading term gives , so and . These exponents also give injected volume , explaining the particular supply law.
Define scales
which satisfy and . The cubic-input similarity for a draining gravity current is
Substitution into the two conservation equations gives
where
Thus only and remain in the dimensionless problem. Its constraints are
Integrating the sum of the two ordinary differential equations verifies that the inlet flux and integral normalization agree. The dimensionless endpoint is the undetermined multiplicative constant in the length law; solving for it is not required.
The material derivative follows the interfacial surfactant. The term describes dilution by tangential expansion and concentration by compression. The term accounts for changing surface area due to normal motion of a curved interface. Finally, describes surface diffusion. Together these give conservation of insoluble surfactant on a moving interface.
The relevant surface Péclet number is
Write and . Since has zero trace and , the surface divergence is
There is no normal motion. To first order in , the steady surfactant balance becomes . The traceless quadratic is a degree-two spherical harmonic, so . The mean of is zero by total surfactant conservation; consequently
The discarded advective term is smaller by . This is the quadrupolar surfactant distribution on a spherical interface.
With the unit normal directed from the bubble into the exterior, the interfacial stress balance with variable surface tension is
Using the specified first-order curvature and , together with , gives
The first term is the spherical capillary pressure; the last contains the normal tension correction and the tangential Marangoni stress.
The ambient Stokes flow has the symmetry of the symmetric traceless tensor . In the Unscaled Papkovich–Neuber representation, is harmonic and yields . The decaying vector potential must have the form , and the scalar disturbance must have the degree-two form . They are harmonic outside the bubble and have precisely the required rotational covariance. Dimensionless amplitudes may therefore be written
For a steady bubble, the no-penetration boundary condition gives . Its tangential velocity gives . The tangential stress boundary condition then yields
Hence , and . The inviscid interior supplies only the constant pressure balancing . Matching the remaining normal stress gives
Eliminating gives
As , : the Marangoni stress suppresses tangential motion and effectively immobilizes the interface. This limit must retain the small surface Péclet number and small-deformation assumptions; can grow through increasing without invalidating the linear concentration approximation.
In a cross-section normal to the cylinder axes, measure from the line of contact. The two circular boundaries have the parabolic approximation
for their separation. The contact point of the meniscus is at , so the leading cross-sectional area is
The area of the small meniscus cap is and is lower order. At its upper end the gap has width . A tangent semicircle therefore has radius and curvature
The Young–Laplace equation makes the liquid pressure, relative to the nearly uniform gas pressure,
At a fixed , lubrication theory gives a planar Poiseuille flow through a gap of width , with axial flux per unit
Integrating across the cusp,
The continuity equation now gives
Set . Since , this is the porous medium equation
Conservation of the fixed volume
and dimensional analysis give the self-similar solution . One integration of the resulting ordinary differential equation yields the compactly supported Barenblatt solution
Equivalently,
Its tip is . Using
in the volume constraint gives . Therefore
For vertical cylinders at equilibrium, hydrostatic pressure gives . Balancing this with the capillary pressure gives the large-height profile
Write the perturbation as and use the same factor for all velocity and pressure amplitudes. At the upper interface, the linearized kinematic boundary condition, zero tangential traction, and normal-stress balance are
The first term in the normal stress is the linearization of the attractive disjoining pressure , while the second is the stabilizing capillary pressure. Symmetry about makes even and odd, and supplies the lower-interface conditions.
For a two-dimensional Fourier mode, the Papkovich–Neuber representation is equivalently expressed by the odd biharmonic stream function for planar Stokes flow
The tangential-stress condition at , with , gives
whereas the kinematic condition gives . The associated normal traction is
Equating this with the linearized interfacial traction yields the dispersion relation
This is the Van der Waals rupture instability of a viscous sheet.
For , the growth rate is positive, starts from as , and decreases to zero like as . For , it has the same long-wave limit, vanishes at , and is negative for : surface tension damps wavelengths shorter than the cutoff. Long waves feel the attractive interaction but require coherent flow over a large distance; at short wavelengths viscous resistance suppresses the clean-film instability, while capillarity adds direct decay. A finite film size, fluid inertia, surrounding-fluid stresses, gravity, surface viscosity, and failure of the continuum disjoining pressure law can shift the observable most unstable wavelength.
During a growing thin spot, interfacial flow stretches the surface and dilutes its surfactant, thereby increasing the local surface tension above . Adjacent less-stretched regions retain more surfactant and lower tension. The resulting surface-tension gradient pulls toward the thin spot and opposes the outward flow that drives thinning. This is surfactant stabilization of film rupture; in the strong limit the surfaces behave almost as immobile boundaries.
For strong surfactant and , instability requires . The Taylor expansion
reduces the supplied relation to
It is maximal at
Thus the characteristic rupture time is . Surfactant greatly extends the life of a soap bubble while its film is moderately thick, but the growth-rate dependence predicts rapid final rupture after drainage has made the film sufficiently thin.
The gas pressure exceeds the distant liquid pressure by the capillary pressure associated with each cylindrical bubble. In the flat film the interface curvature is nearly zero, so its liquid pressure is close to the gas pressure and therefore exceeds the external liquid pressure by approximately . This pressure excess drives liquid out through the two transition regions.
Inside the flat region , so . The extensional-force equation gives , hence is independent of . Symmetry gives and define , so
The mass-conservation equation becomes
It contains no dependence, so an initially uniform film remains uniform within the flat region.