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A narrow fringe makes the center easier to resolve statistically; it does not certify an unbiased frequency. For example, with ideal $\pi /2$ pulses and a second-pulse oscillation phase offset ${\phi }_c$, the finite-pulse Ramsey transition probability approachesThis sign uses exactly the Rabi detuning convention and pulse Hamiltonian operator above, with the second pulse replacing ${\sigma }_x$ by $\cos {\phi }_c{\sigma }_x+\sin {\phi }_c{\sigma }_y$. The factor $2\pi$ converts angular frequency to ordinary frequency. For the original example, ${\phi }_c=0.010$ rad and $T=5\mathrm{ms}$ give a shift of about $-0.318\mathrm{Hz}$. For finite pulses or distributed flight times, use the full signal and its atomic clock frequency lock rather than inserting an unweighted mean $T$.

NIST-7 used optical pumping and fluorescence. Controls included field-sensitive transitions, independent beam-speed measurements, microwave power stabilization, and beam reversal for cavity quantum phase errors.^[ref]

The connection to special relativity is quantitative. A freely moving emitter's proper time advances more slowly than laboratory time by $\sqrt{1-v^2/c^2}$. With first-order propagation effects removed in the ideal comparison, its internal laboratory frequency is thereforeCorrecting an ensemble signal requires the effective velocity weights of preparation, interrogation and detection, not simply the oven's mean speed. Additional shifts from Zeeman splitting, unwanted light, collisions and cavity fields likewise require separate evaluation; feedback control locks to the observed line, including any uncorrected bias. Comparing clocks at different gravitational potentials additionally requires gravitational time dilation. The moving-clock experiments in twin paradox clock experiments compare calibrated clock readings along different world lines; the beam atoms' internal motion is part of the clock mechanism's own correction.

Choose an isolated pair of energy levels, with ground state $|g⟩=(0,1{)}^T$ and excited state $|e⟩=(1,0{)}^T$. Use the Pauli matrices in the ordered basis $(|e⟩,|g⟩)$, so ${\sigma }_z=\mathrm{diag}(1,-1)$. After subtracting the mean energy, prescribe the laboratory Hamiltonian operatorThe unperturbed energy gap is $\hslash {\omega }_0$, the drive has angular frequency $\omega$, and $\varphi$ fixes its oscillation phase at the chosen time origin. All of ${\omega }_0$, $\omega$, the Rabi angular frequency $\Omega$ and the Rabi detuning $\delta$ are in radians per second; ordinary frequency is angular frequency divided by $2\pi$. In particular, $\Omega$ here is the coefficient multiplying the cosine in $H_{\mathrm{lab}}/\hslash$, not twice that coefficient.

Write $|{\psi }_{\mathrm{lab}}⟩=R(t)|{\psi }_{\mathrm{rot}}⟩$ with $R(t)=\exp (-i\omega t{\sigma }_z/2)$. Transforming the Schrödinger equation gives $H_{\mathrm{rot}}=R^{†}{H}_{\mathrm{lab}}R-i\hslash R^{†}\dot{R}$. The rotating-wave approximation drops terms at angular frequency $2\omega$, leavingThis approximation requires $\Omega ,|\delta |\ll {\omega }_0,\omega$, and an interaction duration over which omitted corrections remain small. It also assumes that other energy levels can be neglected. Resonance alone does not justify either assumption. An exactly co-rotating drive has no discarded counter-rotating component; the linearly oscillating laboratory drive above does.

The Pauli matrix multiplication law gives $K^2={\Omega }_{\mathrm{eff}}^{2}I$. Separating even and odd terms of the matrix exponential therefore proveswith the continuous limit $U=I$ when $\Omega =\delta =0$. Starting from $|g⟩$, the upper probability amplitude is $-i{e}^{-i\varphi }(\Omega /{\Omega }_{\mathrm{eff}})\sin ({\Omega }_{\mathrm{eff}}t/2)$. The Born rule givesThe rotating transformation only changes the quantum phases of these basis states, so their laboratory populations are the same. Rabi detuning tilts the rotation axis of the Bloch vector: it increases the oscillation rate to ${\Omega }_{\mathrm{eff}}$ but caps the transferred population at ${\Omega }^2/({\Omega }^2+{\delta }^2)$. A fixed drive oscillation phase cancels from this single-pulse population when the initial state is $|g⟩$. It still fixes the relative quantum phase of a resulting quantum superposition and matters when another pulse supplies a phase reference.

Use the Driven two-level Rabi model in the ordered basis $(|e⟩,|g⟩)$, with Pauli matrices satisfying ${\sigma }_z=\mathrm{diag}(1,-1)$. Let the Rabi detuning be $\delta ={\omega }_0-\omega =2\pi ({\nu }_0-\nu )$, in angular frequency, while ${\nu }_0$ and $\nu$ are ordinary frequencies in hertz. Assume two identical square pulses, equal drive oscillation phases, constant positive Rabi angular frequency $\Omega$, constant $\delta$ during pulses and flight, and no quantum decoherence or loss. The rotating-wave approximation and isolation of the chosen two-level system are required, just as for the Driven two-level Rabi model. Free flight means no transverse drive; the reference oscillator continues running.

The pulse and free-flight Hamiltonian operators in the rotating frame areThe Pauli matrix multiplication law gives $(\delta {\sigma }_z+\Omega {\sigma }_x{)}^2=q^{2}I$. Thus the exact special unitary group $\mathrm{SU}(2)$ pulse matrix for this effective Hamiltonian operator, and the flight matrix, areThe sequence is $U_p{U}_f{U}_p$. Starting in $|g⟩$, matrix multiplication and the Born rule giveThis retains the tilted rotation axis and quantum phase accumulated during each finite pulse. At resonance it gives $P_{g\to e}(0)={\sin }^2(\Omega \tau )$; with no flight it reduces to the single square-pulse response for duration $2\tau$. Both checks would fail if arbitrary ideal $\pi /2$ rotations were silently substituted at nonzero Rabi detuning.

For resonant pulse area $\Omega \tau =\pi /2$, $|\delta |/\Omega \ll 1$ and $\tau \ll T$, the central fringe approachesIts half-height points are $|\nu -{\nu }_0|=1/(4T)$, so the central peak's full width at half maximum is $1/(2T)$ in hertz, or $\pi /T$ in angular frequency. This width assumes an effectively flat pulse envelope across that central peak, one flight time and unit contrast; it is neither a universal finite-pulse width nor a frequency uncertainty. Longer flight lets a smaller frequency difference accumulate the same observable quantum phase.

The two pulses here have the same sign and the plotted outcome is transfer to $|e⟩$. The earlier Ramsey interferometry example uses an inverse analysis pulse and reports return to its initial label. Specifying the measured outcome and pulse oscillation phases reconciles the two conventions. In a beam the lengths and speed determine $\tau$ and $T$; in the Quantronium Ramsey interference experiment electronics set the pulse times for a stationary circuit.

Write ${\omega }_z=\gamma B_z$ and use the ordered spin basis $(|\uparrow ⟩,|\downarrow ⟩)$. The free Hamiltonian operator is $H_0=-\hslash {\omega }_z{\sigma }_z/2$, soResolving the cosine into its two complex exponentials gives the exact upper off-diagonal factorwith the complex conjugate in the lower entry. Choose the field orientation with ${\omega }_z>0$, as implicit in the printed near-resonance condition, and put $\delta =\omega -{\omega }_z$. The rotating-wave approximation discards the terms at $\omega +{\omega }_z$, retaining the slow terms at $\delta$. The resulting interaction picture equations areThe factor $1/4$ contains $1/2$ from $S_x=\hslash {\sigma }_x/2$ and $1/2$ from the cosine decomposition. This is a Driven two-level Rabi model, with signed on-resonance coupling $\Omega =\gamma B_x/2$ and generalized Rabi angular frequency ${\omega }_R=\sqrt{{\delta }^2+{\Omega }^2}$. Here the Rabi detuning uses the paper's convention, drive minus free frequency.

Small detuning alone is insufficient to derive the printed equations. One also requires $|\gamma B_x|,|\delta |\ll \omega +{\omega }_z$, and an evolution time over which neglected terms stay small. At resonance this is the weak transverse-field regime $|B_x|\ll |B_z|$. The supplied solution is thus an approximate solution for the linearly oscillating field, not an exact one at arbitrary drive strength. If $\gamma B_z<0$, the other exponential is resonant and the physical positive resonance frequency is $|\gamma B_z|$.

The first-order excitation amplitude is the Fourier transform of the temporal pulse envelope evaluated at the Rabi detuning. Two rectangular time windows therefore give exactly the mathematical structure of double-slit interference: each window gives a sinc function amplitude, and their separation gives a relative quantum phase $\delta T$. The transition probability is a sinc function squared envelope multiplied by ${\cos }^2(\delta T/2)$.

Pulse duration corresponds to slit width, pulse-start separation to slit-center separation, and Rabi detuning to the transverse wavevector sampled on the screen. The narrow fringes measure the long separation, while the broad envelope measures the short interaction duration. As in spatial interference, adding probabilities instead of coherent probability amplitudes would lose the fringes. Randomizing the relative pulse phase averages the cosine squared to $1/2$.

Differentiating the specified rotating-frame amplitudes gives the time-independent Schrödinger equationThe characteristic polynomial is ${\lambda }^2-({\delta }^2+{\Omega }^2)/4=0$, henceFor $\Omega \ne 0$, corresponding normalized eigenvectors are proportional to $(\Omega ,2{\lambda }_{\pm }-\delta {)}^T$. Their arbitrary complex coefficients evolve as $e^{-i{\lambda }_{\pm }t}$; this solves the amplitude equations for any initial quantum state.

Restoring the common energy origin $\overline{E}=(E_1+\hslash \omega +E_2)/2$, the two dressed state energy eigenvalues areThus their positive energy separation increases byEquivalently, the branches connected to $E_1^{\prime }=E_1+\hslash \omega$ and $E_2$ shift by $+\hslash {\Omega }^2/(4\delta )$ and $-\hslash {\Omega }^2/(4\delta )$ respectively. Their signed difference $E_1^{\prime }-E_2$ changes by $\hslash {\Omega }^2/(2\delta )$, which is the printed expression with a signed convention. For negative Rabi detuning, an actual positive separation still increases; for example at $\delta =-10\Omega$ it cannot have the negative change implied by reading the printed expression as an unsigned gap. These opposite AC Stark shifts describe level repulsion.

Choose the relative phases of the two energy eigenstates so that $d=⟨{\psi }_2|{\hat{D}}_0|{\psi }_1⟩$ is real and nonnegative. Define the resonant Rabi angular frequency $\Omega =d/\hslash$, the Rabi detuning $\delta ={\omega }_0-\omega$, and $\Sigma ={\omega }_0+\omega$. Substitution into the Schrödinger equation, followed by projection onto the two eigenstates, gives the exact interaction picture equationsKeep both probability amplitudes dynamical: replacing $c_1$ by one would incorrectly impose weak excitation and miss complete population transfer.

For $|\delta |,\Omega \ll {\omega }_0$, apply the rotating-wave approximation to discard the rapidly oscillating terms at $\Sigma$. Differentiating the second remaining equation and using the first givesThe initial conditions are $c_2(0)=0$ and ${\dot{c}}_2(0)=-i\Omega /2$. With ${\Omega }_R=\sqrt{{\Omega }^2+{\delta }^2}$, their solution isConsequently,This result permits order-one excitation, including full population transfer on resonance, even though the drive is small compared with the optical angular frequency.

For an average from switch-on to time $\tau$, integrate the squared sine:On resonance this limiting average is $1/2$, although the instantaneous probability repeatedly reaches one. The zero-coupling, zero-Rabi detuning case is understood separately as $P_2=0$.

Near resonance alone does not make this an exact result for arbitrarily strong driving. The stated sinusoidal Hamiltonian also needs the rotating-wave approximation. A concrete counterexample is $\omega ={\omega }_0$ and $\Omega ={\omega }_0$: the exact equations give $P_2(t)={\Omega }^2{t}^2+O(t^4)$ at switch-on, while the claimed rotating-wave sinusoid gives ${\Omega }^2{t}^2/4+O(t^4)$. Thus “without assuming weak radiation” can mean without assuming small excitation, but cannot remove the drive-to-carrier scale separation. The infinite-time average above belongs to the rotating-wave model; omitted corrections can accumulate over sufficiently long times.

Rabi oscillations require a coherent drive with a stable phase over several population cycles and an isolated, appreciably coupled pair of quantum states. For large-amplitude oscillations, the Rabi detuning must be comparable to or smaller than the Rabi angular frequency. The population lifetime, optical coherence time, transit time and drive coherence time should all exceed $2\pi /{\Omega }_R$ by enough to resolve the cycles. An ensemble also needs sufficiently uniform Rabi frequencies and Rabi detunings that phase averaging does not wash the oscillations out. The usual sinusoidal formula additionally assumes the rotating-wave approximation.

The Einstein coefficients describe incoherent transition rates, rather than the evolving optical probability amplitudes. Their simplest use is appropriate for broadband, randomly phased radiation, with field correlation time short relative to population evolution, or for rapidly dephased chemical atoms whose optical coherences can be eliminated. The radiation energy density per unit frequency must be smooth over the relevant spectral line. Stimulated upward and downward transitions and spontaneous emission then enter rate equations, without predicting coherent population return. A short observation time can give a small excitation probability even for a coherent field; that condition alone does not justify an Einstein coefficients rate description. Coherent laser irradiation can also admit steady rate equations after optical coherence has relaxed, with the appropriate saturation response.

Treat $|a⟩=|0⟩$ and $|b⟩=|1⟩$ as an isolated ground-state hyperfine qubit. Their transition angular frequency is ${\omega }_0=2\pi \times 320.7\mathrm{MHz}$. The radiofrequency magnetic field couples them through an allowed magnetic dipole transition. After choosing its phase reference, take the two-level laboratory Hamiltonian operator to bewhere $X,Z$ are Pauli operators. Here $\Omega$ is defined by the on-resonance rotating-frame off-diagonal matrix element $\hslash \Omega /2$.

Use a quantum rotating frame and the rotating-wave approximation, valid for $\Omega ,|\delta |\ll {\omega }_0$, with Rabi detuning $\delta ={\omega }_0-\omega$. Ignoring off-resonant coupling to other levels givesAt resonance $\delta =0$, the unitary time evolution isThus the Born rule gives coherent Rabi oscillations,The stated amplitudes are in the rotating frame; the laboratory carrier phases are tracked by the drive reference.

These logical states are orthogonal, individually resolvable hyperfine levels in the same electronic ground state. They avoid fast optical decay, can be coherently coupled by radiofrequency control, and have a state-selective optical readout through $|c⟩$. The excited level $|c⟩$ is useful for fluorescence detection rather than for the storage superposition in this model. Long lifetimes alone do not guarantee a useful qubit: control isolation and adequate quantum coherence are also required.

A good atomic qubit needs two reproducible, orthogonal internal states whose populations and relative quantum phase survive for many gate times. Both should be long lived, with weak spontaneous emission and little decoherence from fluctuating fields or atomic motion. Their transition must nevertheless permit fast, selective, coherent control with little leakage to other states. Reliable initialization and state-selective quantum measurement are also required; optical pumping and fluorescence readout can supply these functions.

For rubidium-87, use the two ground state hyperfine levels in the $5{}^2{S}_{1/2}$ electronic configuration. The electronic angular momentum is $J=1/2$, and addition of angular momentum to the given nuclear spin $I=3/2$ gives $F=|I-J|,\dots ,I+J=1,2$. A suitable Rubidium-87 clock qubit isThese are coupled electron-nucleus angular momentum eigenstates, rather than two bare nuclear-spin projections. Their hyperfine structure supplies a resolvable splitting ${\nu }_{01}\simeq 6.835\mathrm{GHz}$. Both belong to the electronic ground state, avoiding a short optical excited-state lifetime. Since the weak-field Zeeman shift is proportional to $g_F{m}_{F}B$, both have zero linear shift at $B=0$: their rubidium-87 clock transition suppresses first-order magnetic-field dephasing near zero field. A quadratic Zeeman shift of a clock transition and differential optical shifts remain. A small stable bias field can define the quantization axis and help resolve unwanted transitions, at the cost of some residual magnetic sensitivity.^[ref]

Drive the magnetic dipole transition with a resonant microwave field of suitable polarization, here $\Delta m_F=0$, or use two phase-coherent optical fields for a far-detuned stimulated Raman transition with their frequency difference resonant with ${\nu }_{01}$. The optical excited state is then only virtually populated, reducing spontaneous emission. In the rotating frame and rotating-wave approximation, define the drive phase $\varphi$ by the effective HamiltonianHere $X,Y,Z$ are the Pauli matrices on the chosen qubit, and $\Omega$ is the Rabi angular frequency. Pulse duration controls the rotation gate angle, while phase selects the axis in the equatorial plane of the Bloch sphere. A $\pi$ pulse exchanges the populations; a $\pi /2$ pulse makes an equal quantum superposition from either basis state. Controlled Rabi detuning, a differential energy shift, or compositions of these pulses give $z$ rotations. For example, $R_z(\alpha )R_y(\beta )R_z(\gamma )$ realizes any one-qubit unitary operator up to a global phase. Thus the atomic encoding admits arbitrary single-qubit quantum gates.

The two $D$ states are metastable, so a quantum superposition can retain its relative phase much longer than one involving a rapidly decaying $P$ state. In the stipulated transition diagram they have no allowed downward electric-dipole transition; real weaker decay channels limit, rather than eliminate, this lifetime advantage. Their distinct energies permit resolved state-selective optical control.

Both $D$ levels couple to $P_{3/2}$. Apply coherent beams near 850 nm and 854 nm, detuned from that common intermediate level by a large Rabi detuning ${\Delta }_R$. Absorption from one beam and stimulated emission into the other transfer population between the two $D$ states without appreciably populating the short-lived intermediate level. Tune the frequency difference to their splitting, including differential AC Stark shifts. In the far-detuned limit,for an initially pure $D_{3/2}$ state on two-photon resonance. The controllable relative optical phase sets the rotation axis; the large Rabi detuning suppresses spontaneous-scattering errors. Suitable polarizations and a chosen pair of magnetic sublevels are required in an actual experiment.

The total excitation operator $\mathcal{N}=a^{†}a+({\sigma }_z+1)/2$ commutes with the Hamiltonian. Each sector with $\mathcal{N}=n+1\ge 1$ is therefore spanned by $|e,n⟩,|g,n+1⟩$, and no term connects it to a sector of different excitation number.

In that ordered basis, with the source's Rabi detuning $\Delta =\omega -{\omega }_0$,The first term is the common sector energy; the remaining diagonal entries record the bare Rabi detuning and the off-diagonal terms exchange the excitation.

The isolated ground sector of the Jaynes-Cummings model is an important exception to a statement that the entire Hilbert space consists of such pairs: $|g,0⟩$ has no partner and is annihilated by both interaction terms. It is a one-dimensional invariant sector with energy $-\hslash {\omega }_0/2$. The full decomposition is this one-dimensional sector plus all the two-dimensional sectors above.

For the stated Hamiltonian operator, put $\mathbf{\Omega }=(V,0,-\delta )$ and $\Omega =\sqrt{V^2+{\delta }^2}$. The Bloch vector obeysThus it rotates right-handedly about the fixed axis $\mathbf{\Omega }$, preserving its length and its projection on that axis. For example, on resonance $\delta =0$, a north-pole Bloch vector follows $(0,-\sin Vt,\cos Vt)$ and reaches the south pole at $t=\pi /V$.

Take $V>0$, with the field phase chosen accordingly. The Hadamard gate is $H=({\sigma }_x+{\sigma }_z)/\sqrt{2}$. Align the axis with $(1,0,1)$ and rotate through $\pi$:The factor $-i$ is an irrelevant common global phase. This realizes the whole quantum gate, rather than merely its action on one input quantum state.

There is a basis-ordering convention to make explicit: this $H$ is the Hadamard gate matrix in the ordered basis $(|1⟩,|0⟩)$ chosen in part (a). If instead its definition is the usual ket rules $H_{01}|0⟩=(|0⟩+|1⟩)/\sqrt{2}$ and $H_{01}|1⟩=(|0⟩-|1⟩)/\sqrt{2}$, its matrix in our order is $({\sigma }_x-{\sigma }_z)/\sqrt{2}$. For that definition choose $\boxed{\delta =+V,\tau =\pi /(\sqrt{2}V)}$. Both conventions use the same pulse duration; the sign of the Rabi detuning selects the desired axis.

Keep the Pauli matrix and north-pole conventions of part (a), and neglect Rabi detuning during each short pulse. Write $P=R_x(\pi /2)$ and $\varphi =\delta T$. During the first pulse the Bloch vector is $(0,-\sin \theta ,\cos \theta )$ for $0\le \theta \le \pi /2$. During free evolution,because the Hamiltonian operator generates $R_z(-\delta t)$. During the final pulse it isThese formulas specify every arc in the two Bloch sphere sketches. For $T=\pi /(2\delta )$ the path is north $\to -y\to -x$, and the last pulse leaves $-x$ fixed. For $T=\pi /\delta$ the path is north $\to -y\to +y\to$ north.

To test the complete quantum gate, multiply its unitary operators:It is proportional to the Hadamard gate when $\cos (\varphi /2)=-\sin (\varphi /2)$, hence the shortest positive waiting time isMore generally $\delta T=-\pi /2(\mathrm{mod}2\pi )$. With the alternative conventional ket definition $H_{01}$ specified in part (b)(i), the required matrix is $({\sigma }_x-{\sigma }_z)/\sqrt{2}$, so $\boxed{T_{H_{01}}=\pi /(2\delta )}$ and $U_R=-i{H}_{01}$. The distinction concerns which basis order defines the named Hadamard gate; the evolution and the return population do not depend on that naming choice. Finally $r_z=-\cos \varphi$, so the actual return population isThe printed plus sign is inconsistent with the two identical pulses. At $T=0$, $U_R=P^2=-i{\sigma }_x$, so $|1⟩$ becomes $|0⟩$ and ${\rho }_{11}(0)=0$; the printed expression gives one. This counterexample is independent of Bloch sphere labeling. A plus sign would describe the complementary population ${\rho }_{00}$, or the return population with an opposite-sign final pulse. That changed sequence also changes the gate question and must not be silently substituted.

An ideal instantaneous NOT about $x$ reverses each atom's accumulated phase relative to its subsequent free precession. Algebraically, $X{\sigma }_{z}X=-{\sigma }_z$, so for a static Rabi detuning and $F=e^{i\delta T{\sigma }_z/4}$,The entire Ramsey interferometry sequence is consequently $PXP=-iI$, up to the additional common global phase if NOT is implemented as $-iX$. ThusThis spin echo restores the initial population even for the distribution of static Rabi detunings in part (d). It removes reversible inhomogeneous dephasing; fluctuating Rabi detuning, finite pulse errors and irreversible loss of quantum coherence need not refocus. With an opposite final pulse, the return population would instead be zero; this distinguishes that alternative from the sequence actually specified.

Resolve the weak broadband radiation into narrow frequency intervals whose relative phases are uncorrelated. The transition probabilities, rather than the coherent amplitudes, can then be added after ensemble or time averaging. For the x-polarized field, the energy density in one interval is $\rho (\omega )d\omega ={ϵ}_0{\mathcal{E}}_{\omega }^2/2$, so its squared coupling is $|d_{21}{|}^2{\mathcal{E}}_{\omega }^2/{\hslash }^2$. Inserting this into the weak rotating-wave result givesFor times long compared with the optical coherence time of the field, the narrow resonant kernel samples a nearly constant $\rho ({\omega }_0)$. Provided the resonance is well away from the zero-frequency boundary, extend the Rabi detuning integral to the full real line. Its value is $2\pi t$, yieldingThis is the stimulated absorption rate for the specified polarization and spectral radiation energy density per angular-frequency interval. The averaging window should also satisfy $Wt\ll 1$ while the lower state is treated as undepleted. A deterministic phase-locked broadband pulse would not in general permit adding these probabilities without its interference terms.

For isotropic unpolarized radiation with total spectral radiation energy density ${\rho }_{\mathrm{tot}}$, orientational averaging instead gives $W=\pi |{\mathbf{d}}_{21}{|}^2{\rho }_{\mathrm{tot}}({\omega }_0)/(3{ϵ}_0{\hslash }^2)$. The factor one third is not inserted into the original x-polarized formula. If ordinary frequency is used, ${\rho }_{\nu }=2\pi {\rho }_{\omega }$ and the isotropic coefficient becomes $|{\mathbf{d}}_{21}{|}^2/(6{ϵ}_0{\hslash }^2)$ multiplying ${\rho }_{\nu }({\nu }_0)$. The spectral convention and polarization must be stated together to avoid spurious factors of three or $2\pi$.

For nonzero Rabi detuning,The sketch starts at zero and oscillates between zero and ${\gamma }^2/({\gamma }^2+{\Omega }^2)<1$, with period $\pi /\sqrt{{\gamma }^2+{\Omega }^2}$ when the coupling is nonzero. Relative to resonance, the oscillations have a smaller maximum and a shorter period at fixed coupling. The sign of the Rabi detuning changes the amplitudes' phases but leaves this transition probability unchanged. For $|\Omega |\gg |\gamma |$, its maximum is approximately ${\gamma }^2/{\Omega }^2$, so population transfer is strongly suppressed. The plotted detuned example has $|\Omega |=|\gamma |$, giving maximum $1/2$.

The Rabi detuning is the unperturbed transition angular frequency minus the drive angular frequency in this convention. Its sign controls the longitudinal rotation of the Bloch vector; the single-pulse population formula is even in $\delta$. Reversing the definition of Rabi detuning requires reversing its sign in the rotating-frame Hamiltonian operator as well.

For a constant-amplitude square pulse on resonance, a Rabi pi pulse lasts ${\tau }_{\pi }=\pi /\Omega$ and gives $|g⟩\mapsto -i{e}^{-i\varphi }|e⟩$ in the rotating frame. A half-duration pulse prepares $(|g⟩-i{e}^{-i\varphi }|e⟩)/\sqrt{2}$. The quantum pulse area $\Omega t$ determines these rotations only under the stated resonant, constant-axis assumptions; a detuned drive rotates about a different axis.

As an original numerical illustration, choose $\Omega =2\pi \times 1000\mathrm{rad}{\mathrm{s}}^{-1}$ and hence ${\tau }_{\pi }=0.500\mathrm{ms}$. These are chosen model parameters, not historical apparatus settings. Holding that duration fixed givesThus $P_{\pi }(0)=1$, $P_{\pi }(1)=\frac{1}{2}{\sin }^2(\pi /\sqrt{2})\simeq 0.3166$, and $P_{\pi }(\sqrt{3})=0$. The last zero comes from completing a full rotation about the tilted axis, rather than switching the drive off. At zero Rabi detuning, doubling the pulse duration restores the ground-state population; continuous driving does not keep transferring population irreversibly.

For an ideal single transit, let the oscillatory magnetic field occupy a region of length $L$, take the longitudinal speed $v$ constant, and neglect edge fields. Each molecule then experiences one square pulse of duration $\tau =L/v$. This is one contiguous interaction region, distinct from the two separated pulses of Ramsey interferometry. The static magnetic field sets the selected transition gap; the transverse drive sets Rabi angular frequency. A change of RF frequency or static magnetic field changes Rabi detuning.

For an original ideal detector model, suppose every successful transition removes an otherwise accepted molecule and the incident beam occupies the lower state of the selected pair. With accepted no-transition signal $S_0$, constant background $S_{\mathrm{bg}}$, and effective loss contrast $0\le \eta \le 1$, writeFor identical trajectories $\overline{P}=P_{g\to e}(L/v)$, giving an intensity dip where transfer is largest. For real trajectory variation, a normalized joint probability density $w(v,ϵ,{\Omega }^{\prime })$ gives the static-offset modelHere $ϵ$ is the trajectory's transition-frequency offset and ${\Omega }^{\prime }$ its drive strength, each in angular-frequency units. The weighting is for molecules accepted by the apparatus, rather than an assumed unfiltered oven distribution. In particular, designing $\Omega L/v_0=\pi$ does not produce a Rabi pi pulse for every speed: at $0.8v_0$ and $1.2v_0$ the resonant transfer probabilities are respectively ${\sin }^2(5\pi /8)\simeq 0.8536$ and ${\sin }^2(5\pi /12)\simeq 0.9330$.

Spread in transit times, static magnetic fields and drive amplitudes can reduce or smear oscillations without quantum decoherence on any individual trajectory. Even the single-transit square pulse has finite spectral width of order $1/\tau$ in angular frequency. If the magnetic field varies substantially along one path, its Hamiltonian operator changes during the passage and the constant-offset average above must be replaced by a time-ordered exponential. Actual molecules may also have several coupled energy levels; the isolated pair and perfect loss discriminator are explicit idealizations of this model.