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One becquerel is a radioactive activity of one nuclear transformation per second.

Let $\overline{N}$ be the expected value of the number of radioactive product atomic nuclei, initially zero, produced at constant rate $R$. Let their nuclear decay constant be $\lambda >0$. Assume one product species, negligible target depletion and negligible capture by the product. During irradiation, production adds $Rdt$ while radioactive decay removes $\lambda \overline{N}dt$ in expectation. Multiplying the resulting ordinary differential equation by $e^{\lambda t}$ givesThe expected radioactive activity $\overline{A}=\lambda \overline{N}$ tends to the production rate $R$. This saturation is a balance of continuing production and radioactive decay, not exhaustion of target atomic nuclei.

If irradiation ends at $t_i$, let $s$ denote elapsed time afterward. Setting the production term to zero givesFor detection efficiency $\epsilon$, constant background count rate $b$, delay $d$ and counting-window duration $\Delta$, integrating the expected count rate givesThis assumes at most one recorded pulse per product transformation and negligible counter losses. Detector response, branching fractions and background must be calibrated independently. Subtracting an estimated background does not remove its counting uncertainty. Several products give a sum of these terms with distinct nuclear decay constants; a single exponential decay fit can then mislead.

For a wholly stipulated example, choose $R=120{\min }^{-1}$, half-life $2\min$ and $t_i=4\min$. Then $\lambda =\log 2/(2\min )$, $\overline{A}(t_i)=90{\min }^{-1}$ and $\overline{N}(t_i)\simeq 259.69$. Choose $\epsilon =0.25$, $b=2{\min }^{-1}$ and $d=\Delta =2\min$. The result isThe background contributes four expected counts. Multiplying the initial net count rate in that window by its duration would give $22.5$ net counts, overestimating the integrated $16.23$ because the product decays appreciably during counting. All these values and the following curves are original examples, not measured historical data or parameters assigned to a particular silver isotope.

Dating principle. Atmospheric cosmic rays produce secondary neutrons, which can generate carbon-14 through ${}^{14}\mathrm{N}(n,p){}^{14}\mathrm{C}$. Carbon then enters atmospheric carbon dioxide and living organisms. While an organism exchanges carbon with its environment, its carbon-14 to carbon-12 ratio approximately tracks that reservoir. After exchange stops, surviving carbon-14 undergoes beta-minus decay, whereas the stable carbon remains. On the closed-sample, constant-initial-ratio model, radioactive decay givesThus radiocarbon dating infers elapsed time from the loss of an isotope ratio or of radioactive activity per fixed carbon mass. It dates cessation of carbon exchange, which need not equal the date an object was manufactured or buried. Actual calendar dating also requires radiocarbon calibration and control of contamination and reservoir differences.

Mean lifetime. For exponential decay, the half-life obeys $e^{-\lambda T_{1/2}}=1/2$, while the mean lifetime is $\tau =1/\lambda$. HenceUsing $1\mathrm{yr}=365.25\times 86400\mathrm{s}$ gives $\lambda =3.83325\times 10^{-12}{\mathrm{s}}^{-1}$ and $\tau =2.60875\times 10^{11}\mathrm{s}$.

The mass minimum and beta stability. Treat the supplied masses as nuclear rest energies in $\mathrm{MeV}$, and omit nuclear pairing as instructed. At fixed mass number $A$, the volume and surface terms of the semi-empirical mass formula are constant. Expanding the remaining terms gives a convex nuclear mass parabola,The continuous minimum in atomic number is thereforeAt $A=14$, the quadratic coefficient is $7.01302\mathrm{MeV}$ and $Z_{\ast }=6.79450$. The nearest integer is $Z=7$; the nuclear isobar of minimum mass is nitrogen-14. Maximizing nuclear binding energy alone would omit the neutron-proton rest-mass difference; its continuous optimum is slightly different, but also selects integer $Z=7$ here.

The values most useful for checking neighboring decay thresholds areConsequently carbon-14 can lower its nuclear mass by changing a neutron into a proton:For bare nuclear masses, the Q value must include the emitted electron mass. Taking $m_e{c}^2=0.511\mathrm{MeV}$,The opposite proton-to-neutron conversion would lead to $Z=5$, whose nuclear mass is $18.1567\mathrm{MeV}$ higher than that of carbon-14. Neither beta-plus decay nor electron capture can bridge that gap by supplying an electron-mass correction. For the nitrogen-14 daughter, both neighboring nuclear masses are higher: $Z=6$ by $4.13070\mathrm{MeV}$ and $Z=8$ by $9.89535\mathrm{MeV}$. Even electron capture to $Z=6$ has $Q=0.511-4.13070<0$. Thus the daughter has no further energetically allowed single beta decay in this model; physical nitrogen-14 is stable.

These threshold numbers belong to the supplied smooth semi-empirical mass formula, not to an accurate prediction of the carbon-14 electron spectrum or its long half-life. Semi-empirical mass errors can change beta-decay thresholds. Also, the instruction to omit nuclear pairing is a model simplification: even $A=14$ does not make physical pairing vanish, and even-even carbon and odd-odd nitrogen need not have the same pairing correction. No omitted pairing coefficient is guessed here.

Activity of modern carbon. Neglect the small contribution of other stable carbon isotopes when counting atoms in a gram. The Avogadro constant givesThe expected radioactive activity of that one gram isor approximately $15.0$ decays per minute per gram of carbon. A becquerel is one decay per second; the normalization is per gram of carbon, rather than per gram of the entire organic sample.

Artefact age. Its remaining activity fraction is $0.13/0.25008=0.51983$. Inverting the exponential decay law,This is the radiocarbon age on the supplied constant-initial-activity, $5730$-year half-life model. It is not a calibrated calendar date; the sample's historical initial ratio and any later carbon exchange are not supplied.

The number of radioactive atoms is determined by the supplied isotope mass, rather than by the total body mass:The radioactive activity is $\mathcal{A}=\lambda N$, with nuclear decay constant $\lambda =\ln 2/T_{1/2}$. Using $1\mathrm{yr}=365.25\times 86400\mathrm{s}$,ThereforeA becquerel is one decay per second; this is total activity over all decay branches. Multiplying by the argon-producing branching fraction would give that branch's activity, not the total asked for. Activity alone is also distinct from an absorbed radiation dose.

Radiocarbon dating measures how long carbon-bearing material has been isolated from a carbon reservoir. Atmospheric cosmic rays produce secondary neutrons, which create carbon-14 chiefly throughThe carbon-14 enters atmospheric carbon dioxide and then living organisms through carbon exchange, including photosynthesis and food consumption. While exchange continues, the organism's ${}^{14}\mathrm{C}/{}^{12}\mathrm{C}$ ratio tracks the relevant environmental ratio approximately.

After exchange ceases, the remaining carbon-14 undergoes beta-minus decay,while stable carbon-12 remains. With half-life $T_{1/2}\simeq 5730\mathrm{yr}$, the radioactive decay law givesThus measuring the isotope ratio $R$, or the radioactive activity per fixed amount of carbon, givesHere $a=\lambda N_{14}$ is compared at equal carbon content; $R_0,a_0$ describe the appropriate initial reservoir. Accelerator mass spectrometry counts the rare carbon-14 relative to stable carbon directly; a decay-counting method instead measures its radioactive activity.

The initial ratio is not perfectly constant. Atmospheric production changes and reservoir differences therefore require radiocarbon calibration, often using independently dated tree rings. Contamination and subsequent carbon exchange must also be controlled. The date measures closure of the carbon system, not automatically the date of every later event involving the object. The physical half-life is about $5730$ years; conventional radiocarbon ages historically use $5568$ years and must be calibrated before interpretation as calendar dates.^[ref]

With $n$ parent atomic nuclei present, the conditional expected number of transformations in a short interval is approximately $\lambda n\Delta t$. The corresponding radioactive activity is $A=\lambda n$. Averaging over the finite-population radioactive decay model gives $\overline{A}(t)=\lambda \overline{N}(t)$. Its unit is the becquerel.^[ref]

For a finite counting interval, depletion matters. Suppose each transformation is recorded independently with detection efficiency $\epsilon$, with at most one count per transformation and no background. The expected value of the count between $t$ and $t+\Delta t$ isOnly when $\lambda \Delta t\ll 1$ does this become approximately $\epsilon \overline{A}(t)\Delta t$. A count rate therefore needs a detector model before it can be interpreted as the source's radioactive activity.

Radioactive decay is the spontaneous transformation of an unstable atomic nucleus or nuclear state. Its timing can be unpredictable for an individual atomic nucleus while a large population has a reproducible average behavior. A constant nuclear decay constant $\lambda >0$ gives the familiar exponential decay law. The half-life describes how quickly the parent population falls, while radioactive activity describes its rate of transformations.^[ref]

This connection between randomness and a regular population law makes radioactive decay useful for measuring elapsed time and for understanding sources of radiogenic heating. It also distinguishes two questions in an experiment: what the source emits, and what an instrument records. Becquerel's uranium-radiation experiment used a photographic plate; the Curie ionization-current measurement measured an electrical consequence of radiation. Their readouts reveal different aspects of the same investigation.

Radiocarbon dating uses the loss of carbon-14 relative to stable carbon after carbon exchange stops. It can measure either an isotope ratio by accelerator mass spectrometry or radioactive activity per fixed carbon content. Interpreting an age requires radiocarbon calibration and control of contamination and reservoir differences.