Choose the extending direction as and write . The uniaxial extensional flow, satisfying incompressibility, has
Starting from rest, symmetry preserves . The differential pom-pom model tensor equation becomes
Put . For , the solutions are
If , both transients decay, giving
If , the axial component is instead and grows exponentially without bound, while . At the boundary , which lies between the two stated regimes, grows linearly and .
Normalization makes the molecular orientation finite even when the unnormalized conformation tensor diverges. For , direct division by gives
For , the divergent axial component dominates the matrix trace, so
The same normalized limit holds at , agreeing continuously with the limit of the subcritical expression. The limiting orientations have nonnegative eigenvalues and unit matrix trace, as required for the normalized molecular orientation.
Now set . Its limiting value is
The scalar stretch equation is . If , its coefficient is eventually bounded above by a negative constant. The variation of constants formula gives a bounded solution, converging to
If , the coefficient is eventually positive, and the positive stretch grows without bound. At equality a bounded stretch would imply , which contradicts boundedness. Thus equality is not an additional bounded steady regime.
The function is continuous and strictly increasing from zero to infinity. Consequently there is a unique critical extension rate defined by
and the molecular stretch remains bounded precisely for . This is distinct from the tensor threshold . If , for example, the normalized orientation can remain well defined and the stretch remain bounded for some rates above the tensor threshold; divergence of alone does not prove divergence of the physical stress.
In the requested doubly subcritical regime, write . The steady uniaxial extension of the differential pom-pom model has
The isotropic pressure cancels from the tensile normal-stress difference. Hence the extensional viscosity is
or
Its zero-rate limit is , recovering the Trouton ratio of three. The restrictions exclude both loss of a finite tensor steady state and loss of a finite stretch steady state; neither denominator may be continued through its singularity as a physical steady constitutive response.
Let two observers be related by , with Q a proper rotation matrix. A spatial second-rank tensor has material frame indifference if its values at corresponding events satisfy . This defines an objective second-rank tensor, and allows the observer's rotation to depend on time.
For Cauchy stress tensor, consider a material surface element with unit normal n and contact traction . A rigid observer change preserves its area and rotates both its normal and actual contact force: , . Thus for every n, proving . Fictitious body forces of an accelerated observer do not alter this transformation of physical contact traction.
To keep the vorticity convention explicit, write , and , the negative of the usual component-first spin tensor. Equivalently, with the derivative-index-first used in the paper, . Put , which is antisymmetric. The transformed velocity is , and direct differentiation gives
The additional observer spin cancels from the symmetric part, proving that the rate-of-strain tensor is objective.
Along the same material particle, differentiating gives
The two extra terms cancel those from . Moreover . Hence the complete objective time derivative satisfies
This proves covariance for every constant scalar ; changing the spin convention without changing the commutator sign would not. It is a Gordon--Schowalter derivative with the paper's slip-parameter convention.
For the Johnson-Segalman fluid, first use the standard uniaxial extensional flow , with . Here and E is diagonal. The steady conformation equation gives
with vanishing off-diagonal components on the stable steady branch. The tensile normal-stress difference is . Dividing by the extension rate gives the Johnson-Segalman extensional response:
The conformation tensor evolution in each principal direction is . Therefore a positive, attracting steady conformation requires both displayed denominators positive. For the first pole is at ; for it is at in the transverse components. At a pole the corresponding component grows linearly in time, and beyond it generically grows exponentially. The model has a finite-rate extensional catastrophe; the algebraic viscosity cannot be continued as a physical steady response past the first pole. At zero rate, , giving Trouton ratio three. For the polymer contribution to stress disappears and the response is simply Newtonian.
The question does not specify extension geometry. If a planar convention is intended instead, the same diagonal calculation gives , valid on the stable branch . The preceding boxed formula uses the standard uniaxial definition of extensional viscosity.
For simple shear flow , write , , , and . The xx, yy and xy components of the steady constitutive equation give
Substituting the first two relations into the third yields , with . Define the viscometric functions by , and , using x for flow, y for the shear gradient and z for vorticity. The Johnson-Segalman steady viscometric functions are therefore
The solvent creates no normal-stress differences in this flow. For nonzero , the fluid is shear thinning with positive first and negative second normal-stress differences.
To classify the stress curves, set and . The scaled shear stress is , and
The second term has minimum at . Thus the shear stress is monotone for and has a decreasing segment for . At equality it has a horizontal tangent but no decreasing interval. Below the threshold, its maximum and minimum occur at
with the smaller root giving the maximum. Negative-rate curves are obtained by odd reflection.
Figure 1.
Monotone, marginal and nonmonotone Johnson-Segalman shear-stress curves
. Details.
For small b, polymer stress dominates the low-rate response, while the solvent restores a positive high-rate slope. The Johnson-Segalman negative-slope shear threshold signals a constitutive instability of homogeneous shear: different local shear rates can carry the same shear stress, permitting shear banding. A stress plateau or a selected interface position cannot be inferred from the local curve alone; spatial regularization and boundary/history information matter. This limitation is illustrated in a primary diffusive Johnson-Segalman study. If , the scaling by b is inapplicable and the stress is just .
A plain material derivative of the conformation tensor is not an objective time derivative: an observer undergoing a time-dependent rigid rotation would infer a different constitutive response, and even rigid-body rotation could appear to change polymer deformation. The upper-convected derivative subtracts deformation and rotation carried by the velocity gradient and is frame indifferent.
The Oldroyd-B model is often inadequate because its Hookean dumbbells are infinitely extensible. It predicts constant shear viscosity rather than shear thinning, zero second normal-stress difference, and an unbounded extensional viscosity at a finite extension rate. Real polymer chains have finite extensibility and commonly exhibit shear thinning, bounded extensional stress, multiple relaxation times, and nonlinear solvent or concentration effects.
For extension rate and , the steady conformation tensor is . Its normalized orientation has axial component and transverse components . Stretch is finite only if , when and the displayed extensional viscosity follows. Above , the unnormalized axial tensor grows exponentially but ; then stretch remains bounded only if . Orientation normalization and stretch relaxation therefore impose different thresholds.