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An antiferromagnetic Ising model on a closed one-dimensional ring, with Ising spins $S_j=\pm 1$ and the displayed periodic boundary conditions. Every opposite neighboring pair minimizes its bond energy. An even ring admits two completely alternating ground states; an odd ring must contain at least one parallel pair, an example of geometric frustration.

Assume $\sigma >0$. With periodic boundary conditions, the spatial mean of $B$ is a conserved quantity. For zero mean write $B=H_X$ with periodic zero-mean $H$. The functional $V=⟨\mu A^2/2+\alpha A^3/3-A^4/4-A_X^2/2-A^2{H}_X/2-H_X^2/(4\delta )⟩$ generates $A_T=\delta V/\delta A$, $H_T=2\delta \sigma \delta V/\delta H$. Thus $V_T=⟨A_T^2+H_T^2/(2\delta \sigma )⟩\ge 0$. Completing the square in $H_X$ bounds $V$ above by a coercive quartic polynomial when $0<\delta <1$, ruling out nonconstant recurrent motion on regular precompact trajectories.

A representative scaled amplitude model has complex $A$ and real $B$ withPeriodic boundary conditions conserve $\int BdX$, because the right-hand side is a total second derivative. The slow field can change long-wave convection roll stability and permit localized pulses. For zero mean $B$, the uniform convection rolls are $A=R{e}^{iqX}$, $R^2=1-q^2$, $B=0$.

An energy estimate tests a differential equation against the solution or one of its derivatives to control a norm by initial data and forcing. Coercive terms represent dissipation, while Young inequality and the Gronwall inequality control lower-order terms.

For the difference $w$ of two smooth heat equation solutions with $D>0$, identical PDE source term, initial conditions, and either periodic boundary conditions or Dirichlet boundary data, integration by parts givesThe initially zero nonnegative integral stays zero, proving uniqueness. The same computation bounds changes in the L2 norm when the initial conditions differ. Specifying data and a solution class makes this argument meaningful.^[ref]

Fermi momentum is the magnitude of the momentum at the boundary of filled one-particle states in an isotropic zero-temperature Fermi gas. For the uniform three-dimensional two-component electron model, a short state count givesTo see the factors, impose periodic boundary conditions on a cubic box of side $L$, so $V=L^3$ and each momentum component is $p_i=2\pi \hslash j_i/L$ for an integer $j_i$. Each allowed momentum point occupies a cell of volume $(2\pi \hslash /L{)}^3$ in momentum space. Divide the sphere volume $4\pi p_F^3/3$ by this cell volume and multiply by two for the two spin states. Replacing the discrete count with a volume is the large-box approximation; surface and shell effects are neglected.^[ref]

The factor two is not automatic for every Fermi gas. If only one internal state is populated, its number density $n_{\sigma }$ instead satisfies $p_{F,\sigma }=\hslash (6{\pi }^2{n}_{\sigma }{)}^{1/3}$. For two equally populated states, $n_{\sigma }=n/2$ recovers the displayed result. A Fermi surface in a crystal can have a more complicated shape, so a single spherical Fermi momentum is a property of this isotropic model.

Take a cycle graph with four labeled graph vertices and four distinct edges $\{1,2\},\{2,3\},\{3,4\},\{4,1\}$. Set $h=0$, $J>0$, and impose periodic boundary conditions by writing ${\sigma }_5={\sigma }_1$. The square drawing represents a one-dimensional ring: it has no diagonal interactions and is not a two-dimensional lattice.

Call an edge between opposite Ising spins a domain wall. If $d$ is their number, the four bond products sum to $4-2d$, so the energy isEach domain wall costs $2J$ relative to an aligned bond. Returning around the ring must return to the starting Ising spin, so $d$ is even: equivalently, ${\prod }_{i=1}^4({\sigma }_i{\sigma }_{i+1})=1$. Choosing an even set of $d$ wall edges and then choosing ${\sigma }_1$ determines the entire pattern. The state degeneracy is therefore $g_d=2\left(\genfrac{}{}{0ex}{}{4}{d}\right)$, using a binomial coefficient.

The twelve middle microstates consist of eight patterns with one exceptional Ising spin and four patterns with two adjacent $+1$ Ising spins and two adjacent $-1$ Ising spins. The two alternating patterns have four domain walls. All $2+12+2=16$ microstates are shown below.

Writing $K=\beta J$, the partition function and the probability of each energy class areFor an original exact example, choose $K=(\ln 2)/4$. Then $e^{4K}=2$, $Z=17$, and $P(d=0)=4/17$, $P(d=2)=12/17$, $P(d=4)=1/17$. Each aligned microstate has probability $2/17$, each middle microstate $1/17$, and each alternating microstate $1/34$: multiply by state degeneracy before comparing whole classes. As $K\to 0$, all sixteen microstates become equally likely, but the class probabilities approach $1/8,3/4,1/8$. As $K\to \infty$, the two all-aligned microstates each have limiting probability $1/2$.

The free electron model approximates conduction electrons by noninteracting particles with the displayed parabolic dispersion relation, filling one-particle states according to Fermi-Dirac distribution. A uniform positive background supplies charge neutrality. Periodic boundary conditions give one spatial state per $k$-space volume $(2\pi {)}^d/V_d$ in $d$ dimensions; the physical spin degeneracy is two. The model captures basic state counting and degeneracy but omits the periodic lattice potential, interaction corrections and detailed electronic band structure.

For a particle on a circle with arc length $x\sim x+2\pi R$ and periodic boundary conditions, the Hamiltonian operator $P^2/(2m)$ has orthonormal basis ${\varphi }_n=e^{inx/R}/\sqrt{2\pi R}$, $n\in \mathbb{Z}$, and energy eigenvalues $E_n={\hslash }^2{n}^2/(2m{R}^2)$. To see this, periodicity forces the wave number to be $n/R$, and applying the momentum operator $-i\hslash {\partial }_x$ gives $\hslash n/R$. The integral of $|{\varphi }_n{|}^2$ over one turn is one. The zero energy eigenvalue is simple; each positive energy eigenvalue has quantum degeneracy two, from $n$ and $-n$.

A neighboring parallel pair in an antiferromagnetic Ising ring. It costs $2J$ relative to a satisfied antiparallel pair. If there are $m$ such pairs, the energy is $-JN+2Jm$, and the periodic boundary conditions force $N-m$ to be even because ${\prod }_j{S}_j{S}_{j+1}=1$. Thus an odd ring has $2N$ ground states, obtained by locating one such pair and choosing one overall Ising spin orientation. The even ring has two ground states with no such pair. This definition uses the local preferred ordering; a parallel pair is a defect in staggered order rather than a wall between uniformly magnetized domains.

Let $\beta =1/(k_{B}T)$ and use the two spin values $+1,-1$ as row and column labels. Define the spin-chain transfer matrixIt is a real symmetric matrix because $E_0(s,t)=E_0(t,s)$; every entry is strictly positive for finite bond energies at $T>0$. The Boltzmann factor of a spin configuration factorizes into the product $W_{{\sigma }_1{\sigma }_2}\cdots W_{{\sigma }_L{\sigma }_1}$. Summing the intermediate spin labels is exactly matrix multiplication, and the final closure imposes periodic boundary conditions. ThusWriting $W=\left(\begin{array}{cc}a& b\\ b& d\end{array}\right)$, its eigenvalues areA positive-entry matrix need not have two positive eigenvalues; ${\lambda }_{-}$ can be negative. The Perron–Frobenius theorem ensures ${\lambda }_{+}>|{\lambda }_{-}|$ here. Therefore the Helmholtz free energy is $F_L=-k_{B}T\ln Z_L$, and its value per spin in the thermodynamic limit is $-k_{B}T\ln {\lambda }_{+}$.

Let $M=L/2$, so that the total number of Ising spins is $3M$. Write $K=\beta J$ and group each triangle's two base spins and its apex into one cell. The Ising chain with alternating triangular decorations has a triangle bond followed by an undecorated connecting bond. Summing an apex Ising spin first gives a decorated-bond Boltzmann weightThe undecorated bridge has Boltzmann weight $B_{t{s}^{\prime }}=e^{-Kt{s}^{\prime }}$. In the basis $+1,-1$,Each cell contributes $T=AB$, so periodic boundary conditions giveThe two matrices have common normalized eigenvectors $(1,1{)}^{\mathsf{T}}/\sqrt{2}$ and $(1,-1{)}^{\mathsf{T}}/\sqrt{2}$, expressing spin inversion symmetry. Their respective eigenvalues areConsequently the cell transfer matrix has eigenvaluesand the finite-size partition function isFor $K>0$, ${\lambda }_{-}\ge 0$ and ${\lambda }_{+}-{\lambda }_{-}=4+2e^{-2K}+2e^{2K}>0$, so only ${\lambda }_{+}$ survives in the thermodynamic limit. Divide the Helmholtz free energy by $3M$, the number of sites rather than the number of cells or base spins:As a counting check, $K=0$ gives ${\lambda }_{+}=8$, ${\lambda }_{-}=0$, hence $Z_L=8^M=2^{3M}$, exactly the number of independent Ising spin configurations. This model has separated decorated bonds and should not be confused with the corner-sharing sawtooth Ising chain, which has a different site count.

Let $w$ count the unequal neighbouring pairs, or domain walls. The energy is $E=-JL+Jw$. A single domain wall is impossible with periodic boundary conditions: following all the other, equal-state bonds around the ring would force its endpoints to be equal too. Two domain walls are possible, splitting the ring into two nonempty uniform arcs carrying different states. Thus the first excited state hasChoose the two wall bonds in $\left(\genfrac{}{}{0ex}{}{L}{2}\right)$ ways. For that choice, identify one of the resulting arcs by its smallest site label. Its state has $Q$ choices and the other arc has $Q-1$. This counts each configuration exactly once, giving the two-domain-wall degeneracy of a Potts ringFor example, $Q=2,L=4$ gives $d_0=2$ and $d_1=12$; the remaining two configurations are alternating and have four domain walls. The formula also covers $L=2$, where the specified ring energy counts the two directed neighbouring bonds, and an unequal pair breaks both. If $Q=1$ or $L=1$, every allowed configuration is a ground state and there is no first excited state. For $Q\ge 3$, the number of domain walls need not be even: three distinct states on a three-site ring give three, although one remains impossible.

The Boltzmann factor factorizes over bonds. Define the spin-chain transfer matrix byHere ${\delta }_{ab}$ is the Kronecker delta. Summing the product of these matrix elements over all configurations, and closing the final bond by periodic boundary conditions, gives the canonical partition functionHence, writing $I$ for the identity matrix and $P$ for the all-ones matrix,Every element of $P^2$ is a sum of $Q$ ones, while every diagonal element of $P$ is one. ThusMore explicitly, for $u=(1,\dots ,1{)}^T$, $Pu=Qu$. If ${\sum }_a{v}_a=0$, then $Pv=0$. These complementary eigenspaces have dimensions $1$ and $Q-1$. Equivalently, $P/Q$ is the orthogonal projector onto the linear span of $u$. The eigenvalues and their eigenvalue multiplicities are thereforeSince the two matrices share these eigenvectors, the exact finite-ring canonical partition function isBoth terms matter in the finite-ring low-temperature limit: discarding the second would lose the correct ground state degeneracy factor and introduce a spurious single-wall contribution.

Let $V=L^3$ be the box volume. The number operator is the sum of the occupation numbers of all momentum eigenstates, including the zero mode:In the Fourier series for the contact interaction, the two creation operators supply phase $e^{-i({\mathbf{k}}_1+{\mathbf{k}}_2)\cdot \mathbf{r}}$ and the two annihilation operators supply $e^{i({\mathbf{k}}_3+{\mathbf{k}}_4)\cdot \mathbf{r}}$. Fourier orthogonality with periodic boundary conditions givesThe four normalization factors together contribute $V^{-2}$, leaving the momentum-space contact-interaction HamiltonianThe Kronecker delta enforces momentum conservation. An equivalent expression that resolves the momentum transfer isBoth are already in normal ordering; no extra commutator constant is introduced.

Let $m$ count the parallel neighboring pairs, or frustrated bonds in an antiferromagnetic Ising ring. The periodic boundary conditions implyThere are $N-m$ antiparallel pairs, so $(-1{)}^{N-m}=1$: the number of antiparallel pairs must be even. For odd $N$, $m$ must consequently be odd. Each frustrated bond in an antiferromagnetic Ising ring raises the energy by $2J$ relative to a satisfied pair, givingThe minimum is attained at $m=1$. Choose its position among the $N$ labeled bonds, choose either orientation of one Ising spin, then alternate across every other bond. This constructs exactly two spin configurations per position. ThusThis is geometric frustration: every local interaction prefers opposite Ising spins, but the closed odd ring prevents all preferences being satisfied at once. No particular location is preferred for the single frustrated bond in an antiferromagnetic Ising ring.

Each neighboring pair of Ising spins contributes at least $-J$ to the energy, with equality exactly when the two Ising spins are opposite. For even $N$, alternation closes consistently under the periodic boundary conditions. The ground states are thereforeHere $g_0$ is the ground-state degeneracy. Choosing $S_1$ fixes every other Ising spin, so these are all the ground states; translations do not give additional spin configurations. The two ground states are exchanged by spin inversion symmetry.

Write $K=\beta J$, where $\beta =1/(k_{B}T)$ is the inverse temperature, $T$ is temperature and $k_B$ is the Boltzmann constant. In the canonical ensemble, each spin configuration has probability $e^{-\beta H}/Z_N$. The nearest-neighbor Boltzmann factors multiply, so the spin-chain transfer matrix, in the order $+1,-1$, isMultiplying its entries around the ring and summing over every Ising spin yields the partition function:The trace implements the periodic boundary conditions; replacing it by an endpoint sum would describe a different partition function. The normalized eigenvectors and corresponding eigenvalues areThe negative eigenvalue is essential for the antiferromagnetic Ising model. Introduce their ratioThe exact finite-$N$ partition function and Helmholtz free energy areFor finite $K>0$, $|t|<1$, so $Z_N>0$ for both even and odd $N$. The last term retains the finite-ring effect of geometric frustration.

To insert an Ising spin into this trace, use the diagonal matrix $\mathsf{S}=\mathrm{diag}(1,-1)$. In the eigenbasis of $\mathsf{T}$, it exchanges $|+⟩$ and $|-⟩$, and hence has vanishing diagonal entries. The one-point correlation function is thereforeThe same conclusion follows directly from spin inversion symmetry: reversing every Ising spin preserves the energy and the Boltzmann factor while reversing $S_1$.

For the two-point correlation function, the two insertions divide the ring into paths of $n$ and $N-n$ bonds. ThusIn particular, the exact finite-ring antiferromagnetic Ising correlation isBecause the one-point correlation functions vanish, this is also the connected correlation function. It gives $C_0=1$ and $C_n=C_{N-n}$, as required by $S_1^2=1$ and exchanging the two paths around the ring. At $K=0$, distinct Ising spins are independent and $C_n=0$ for $1\le n\le N-1$; $C_0=1$ is understood separately if a power $0^0$ occurs in the displayed expression.

For direct-lattice points $x_n=na$, a lattice-periodic plane wave must have the same phase at every translated lattice point:Thus $Ga=2\pi m$, with integer $m$, and the reciprocal lattice isIts spacing is $2\pi /a$. These plane waves execute an integer number of complete cycles within a direct-lattice period, so their wavelength magnitudes are $a/|m|$ for $m\ne 0$.

A general electronic Bloch wave need not itself be lattice-periodic: wavevectors differing by $G_m$ have the same translation phase. The reciprocal lattice labels that equivalence, while a large finite specimen with periodic boundary conditions has a much finer grid of allowed electronic wavevectors.

The FCC conventional unit cell has four atoms, so the cube containsatoms, neglecting surface corrections. A phonon is one excitation quantum of a vibrational normal mode; there can be many quanta per mode, and zero-point motion does not add half a phonon to the thermal population.

For the low-temperature thermal phonon number, integrate the Bose-Einstein distribution against the Debye model phonon density of states:At $10\mathrm{K}$, ${\Theta }_D/T=21.5$, so extending the upper limit to infinity has negligible effect at the precision required. The supplied integral yieldsThis is the thermally excited phonon number, not the number $3N$ of available modes.

The continuum approximation fails when the thermally occupied wavelengths become comparable with the cube size $L$. From the Debye temperature,A lowest nontrivial acoustic frequency is of order $v/L$; a standing-wave estimate ${\omega }_{\min }\sim \pi v/L$ corresponds to $\hslash {\omega }_{\min }/k_B\sim 0.25\mathrm{K}$. Periodic boundary conditions instead give $2\pi v/L$ and $0.50\mathrm{K}$. The precise spectrum depends on mechanical boundary conditions and branch speeds, neither of which is specified.

This finite-crystal phonon freeze-out requires summing discrete normal modes. For a finite positive lowest frequency, $N_{\mathrm{ph}}\sim g_{\min }{e}^{-\hslash {\omega }_{\min }/(k_{B}T)}$, rather than extrapolating the bulk $T^3$ law indefinitely. Rigid translations and rotations of an isolated crystallite are not internal thermal phonons. Surface acoustic modes can modify the intermediate crossover, but do not justify inventing a unique boundary spectrum.

Let the sample area be $A$, set the band touching energy to zero, and write $m^{\ast }=m_e^{\ast }=m_h^{\ast }$. Assume one electronic valley in each energy band with two spin states. The near-edge parabolic dispersions areUnder periodic boundary conditions, each spin occupies reciprocal-space area $(2\pi {)}^2/A$. Counting the quantum states inside a circle givesIts derivative is the constant two-dimensional free-electron density of states. Defining $D=A{m}^{\ast }/(\pi {\hslash }^2)$, the signed-energy density of states isThe total electronic density of states is therefore $D$ on either side of zero, not $2D$ at every signed energy. If instead one counts positive-energy excitations, the electron and hole species each have density of states $D$, giving $2D$ when summed. A common additional valley degeneracy multiplies all these quantities by that factor. The effective mass approximation assumes thermally sampled energies remain within the near-edge regions of both energy bands.