In a thin rectangular electromagnetic cavity, the window freezes the nonzero thickness indices while retaining many in-plane normal modes. The zero-thickness-index family has one polarization of an electromagnetic wave and density of states . Multiplying by and integrating gives . Thus thermal energy scales as area times . The Riemann zeta function appears through .
This is an intermediate low-temperature regime of an anisotropic finite cavity. When also falls below the first in-plane excitation, thermal energy becomes exponentially small. If a different model excludes every zero thickness index, its first transverse mode has a finite gap and the proposed regime does not occur. In the three-dimensional continuum regime the corresponding density of states is proportional to volume times and thermal energy is proportional to volume times .
Definition and equations. A normal mode is a motion in which every component of a linear system has the same time dependence with fixed amplitude ratios and phases. For a conservative system near equilibrium, the most useful form is
The vector describes the mode shape, while is its angular frequency. Linear combinations of modes describe arbitrary sufficiently small motions when the modes form a complete basis.
Let be displacements of independent generalized coordinates from equilibrium. Expand the Lagrangian to quadratic order:
The mass matrix defines a positive-definite quadratic form on the independent coordinates, while the stiffness matrix is the Hessian of the potential energy. Substituting a mode gives the generalized eigenvalue problem for small oscillations
A practical calculation identifies the equilibrium, chooses independent coordinates, computes the quadratic kinetic and potential energies, solves for the eigenvalues and then obtains their eigenvectors. One can equivalently diagonalize the real symmetric matrix . This guarantees real and a complete orthogonal basis in mass-weighted coordinates.
For distinct eigenvalues, the fact that and are real symmetric matrices implies
Thus distinct modes are orthogonal in the inner product weighted by the mass matrix. Choosing decouples the motion into , with total energy . A positive-definite matrix gives positive eigenvalues and oscillatory stability. Zero modes can describe rigid translations or rotations without restoring force; a negative eigenvalue gives exponential instability rather than an oscillatory mode.
Symmetry. A symmetry preserving both quadratic energies maps modes into modes of the same frequency. Coordinates adapted to symmetry divide the eigenvalue problem into smaller independent blocks. For two identical subsystems, exchanging them gives symmetric and antisymmetric modes. The degeneracy of normal modes means that independent modes share one frequency. Higher-dimensional group representations of a symmetry can enforce such degeneracies; symmetry does not require every pair of modes to be degenerate, and accidental degeneracies can also occur. Within a degenerate eigenspace, orthogonal linear combinations are equally valid mode shapes.
For two equal masses , each attached to a fixed support by a spring of stiffness and coupled to the other by a spring of stiffness ,
The symmetric mode leaves the coupling spring unstretched and has . The antisymmetric mode stretches it and has . Superposing the two gives beats when their frequencies are close.
Continuous systems. The same idea replaces matrices by differential operators and mode vectors by functions satisfying boundary conditions. For a taut string of length , tension and mass per unit length , the wave equation and fixed endpoints give
Orthogonality of the sine functions allows an arbitrary initial displacement to be decomposed into modes. Changing the endpoints changes the spectrum: boundary conditions are part of the physical mode problem.
A uniform chain of equal masses joined by springs , with spacing , has travelling normal modes with
Their quantization gives phonons; the long-wavelength limit is a sound wave. Rectangular electromagnetic cavity modes satisfy Maxwell's equations and conductor boundary conditions, with in vacuum. An elastic beam instead has a fourth-order spatial equation and flexural dispersion . These examples show how restoring forces and geometry determine the frequency spectrum.
Real systems. Small-amplitude motion is often approximately linear even when the full equations are nonlinear. Large amplitudes produce frequency shifts, mode coupling and transfer of energy between modes. Friction broadens resonances and makes free oscillations decay. A damping matrix proportional to or can retain the undamped mode shapes; general damping need not, and the appropriate eigenfrequencies and modes can be complex. External periodic forcing predominantly excites modes near resonance, with amplitude set by coupling to the forcing and dissipation. Imperfections split ideal degeneracies, while radiation or coupling to a surrounding fluid can remove energy from the chosen subsystem. Normal modes remain useful when linearization, the boundary conditions and the treatment of damping accurately describe the motion being measured.
Equilibrium radiation and cavity frequencies. A blackbody absorbs all incident radiation at every frequency and direction. In thermal equilibrium its emission spectrum depends only on its temperature. Radiation inside an isothermal absorbing cavity, sampled through a small aperture that hardly disturbs equilibrium, realizes black-body radiation to a good approximation. Microscopic absorption and emission establish the equilibrium distribution; a perfectly reflecting wall is the convenient idealization used to count the modes once that distribution is specified.
In a rectangular electromagnetic cavity, the wave equation and perfect conductor wall boundary conditions select component wavenumbers , , . Combining the vacuum dispersion relation and gives
For example, electric-field components can have the spatial dependence
For three positive indices, Gauss's law requires , leaving two independent polarizations of an electromagnetic wave.
Index qualification. The original paper describes the indices as positive integers. That describes the three-nonzero-index family but omits valid electromagnetic modes with exactly one zero index, which have one polarization of an electromagnetic wave. For instance, with , , only above remains; it is normal to the top and bottom faces and vanishes at the side walls. Two zero indices give no nontrivial cavity field. The omitted one-zero-index family does not affect the leading three-dimensional mode count, but is essential to the thin-cavity limit below. Retaining the paper's strict positivity restriction for every mode would instead give a thickness gap and would not yield its requested two-dimensional power law.
Three-dimensional mode count. A lattice cell in positive space has volume , where . In a continuum approximation, a shell of radius and thickness contains its positive octant, multiplied by two polarizations:
Using gives
For a finite cavity the exact density of states is discrete; this formula is its bulk continuum limit, appropriate when many modes contribute and wall corrections are small.
Mean photon number. A mode is a quantum harmonic oscillator with thermal excitation energies , . The zero-point energy does not enter its thermal occupation. Put . Its partition function and mean occupation are
This is the Bose-Einstein distribution with zero photon chemical potential: equilibrium absorption and emission do not conserve photon number.
Thermal energy. Multiply the density of states by the mean excitation energy and integrate:
The substitution isolates all the dependence on cavity dimensions and temperature:
Expanding gives an integral . Hence
This is the thermal energy only, excluding the zero-point contribution. The three-dimensional continuum regime requires large compared with the geometric level spacings in all three directions.
Spectral sketch. The spectral energy density per unit ordinary frequency is Planck's law,
At small frequency it rises as , while at large frequency it decays exponentially. Raising temperature increases the spectrum at every fixed positive frequency, moves the peak to larger frequency in proportion to , and increases the integrated area in proportion to . A plot per unit wavelength has a different peak position because the integration variable changes.
Figure 1.
Planck spectral energy density at three temperatures on common frequency and energy-density scales
. Original plots of the frequency spectrum, with temperatures in the ratios 1:1.5:2. The dimensionless horizontal axis is hν/(kBTref), and the vertical scale is common to all curves. The higher-temperature peak moves right and the area grows as T to the fourth power. Details.
Thin-cavity radiation. Let . The relevant low-temperature window is
Nonzero thickness indices are then thermally suppressed, while many in-plane modes are populated. The family has one polarization of an electromagnetic wave. Its allowed in-plane wavenumbers form a lattice of cell area ; a quarter of a circular shell therefore contains
Thus the dimensional crossover of thermal cavity radiation gives
The integral is by the same geometric-series argument. A model with a different number of independent polarizations of an electromagnetic wave changes the prefactor but not the scaling. For a cavity with fixed finite , cooling still further eventually freezes its lowest in-plane mode as well: the strict thermal energy is exponentially suppressed. The requested area law is the intermediate quasi-two-dimensional regime, not an arbitrarily low-temperature continuum limit.