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A laser generates amplified light through stimulated emission. Its name abbreviates “light amplification by stimulated emission of radiation”. Lasers supply the intense beams used in optical tweezers; optical coherence also makes them useful for wave interference measurements. ^[ref].

In the usual material picture, a gain medium stores energy supplied by pumping, for example by incident light or an electric current. Stimulated emission transfers that stored energy to a selected optical normal mode, while competing photon absorption removes light. Producing net optical gain requires a suitable population distribution, such as population inversion in the simple model below.

A familiar laser oscillator uses mirrors to return light through the gain medium. This optical feedback favours resonant normal modes; a partly transmitting mirror lets useful power escape. Feedback and mode selection have different implementations, including ring arrangements: every laser need not resemble the same two-mirror device. The laser threshold example treats just that device. ^{[ref] [ref]}.

The useful combination is concentrated power and controlled optical normal modes. It gives optical tweezers a localized source of force and wave interference measurements a source with useful optical coherence. A laser can nevertheless emit several frequencies; “laser” alone does not guarantee a single frequency. ^[ref].

An original experimental landmark is T. H. Maiman's 1960 report of stimulated optical radiation from optically pumped ruby at about $694.3\mathrm{nm}$. His paper describes both the pumping path and the observed emission, connecting stored material energy with amplified light. ^[ref].

Optical gain is amplification of light by a medium. Here the small-signal intensity gain coefficient $g$ has units ${\mathrm{m}}^{-1}$: for fixed populations, a weak beam obeysin the nondegenerate resonant two-level model, with common transition cross-section $\sigma$. Thus $g$ includes the competition between stimulated emission and photon absorption on that transition. Separate passive intensity loss $\alpha$ gives $I(z)=I(0)e^{(g-\alpha )z}$. Both coefficients describe light intensity, not wave amplitude; the corresponding field-amplitude exponent is half as large. ^[ref].

For $g=0.30{\mathrm{m}}^{-1}$, $\alpha =0.10{\mathrm{m}}^{-1}$ and $z=0.50\mathrm{m}$, the single-pass intensity multiplier is $e^{0.10}\approx 1.10517$. This is amplification during one passage, before mirror losses. Population inversion can therefore yield positive optical gain while the complete oscillator remains below laser threshold.

A population inversion puts more emitters in the upper than in the lower quantum state of a transition in the nondegenerate two-level model. Let $N_2,N_1$ be their number densities. Equal stimulated-transition strengths make the emission rate proportional to $N_2$ and the competing photon absorption rate proportional to $N_1$, so net optical gain is proportional to $N_2-N_1$. For $N_2=6\times 10^{20}{\mathrm{m}}^{-3}$ and $N_1=4\times 10^{20}{\mathrm{m}}^{-3}$, the difference is positive; swapping them makes the medium absorb. Equal populations give zero net stimulated contribution. With degenerate levels, the relevant comparison uses populations per statistical weight of an atomic level, rather than simply $N_2>N_1$.

Why pump through extra levels? Ordinary steady resonant pumping of a nondegenerate two-level system drives both photon absorption and stimulated emission. With equal induced rate $W$ and upper-state decay rate $\Gamma$, its elementary population equation isat a stationary population. Increasing this pump saturates towards $N_2=N_1$; it cannot sustain population inversion in this model. This is a steady rate-equation conclusion, not a universal prohibition on all driven two-level dynamics or all possible laser gain mechanisms. ^[ref].

In a familiar three-level path, pumping excites a higher level which relaxes into the upper lasing level; the lower lasing level is the ground state, so substantial ground-state depletion is needed. A four-level path also provides rapid emptying of the lower lasing level into a separate ground state. Suitable lifetimes then allow accumulation above and depletion below the lasing transition. Pumping still supplies the energy: extra levels provide a route to population inversion, not free energy. ^[ref].

For the spin-free linear rigid rotor in thermal equilibrium at temperature $T>0$, assume all integer $J\ge 0$ are allowed and ignore nuclear-spin restrictions. Each $J$ level has $2J+1$ quantum states sharing one energy eigenvalue, an instance of degenerate energy levels, so the Boltzmann distribution givesHere $Q_{\mathrm{rot}}$ is a rotational partition function, $h$ the Planck constant, $k_{\mathrm{B}}$ the Boltzmann constant, and $B$ a frequency in $\mathrm{Hz}$. Thus $hB/(k_{\mathrm{B}}T)$ is dimensionless. The $2J+1$ factor counts magnetic quantum numbers; it does not mean that a whole level is one quantum state. For the stipulated $B=5\mathrm{GHz}$, the most populated levels are $J=2$ at $3\mathrm{K}$ and $J=7$ at $30\mathrm{K}$.

Population alone is insufficient to predict intensity. In weak, unsaturated absorption, the integrated absorption coefficient includes the transition frequency, the squared electric dipole moment matrix element, and the difference of lower and upper substate populations because stimulated emission returns energy to the field. A pulsed FTMW spectroscopy signal additionally depends on excitation, quantum coherence, cavity tuning, and receiver response.^[ref]

For an isotropic sample with polarization of an electromagnetic wave along $z$, write $d_z=d\cos \theta$. Normalized spherical harmonics giveThe last equality follows from ${\sum }_{M=-J}^J{M}^2=J(J+1)(2J+1)/3$. Combining this sum with the per-substate Boltzmann distribution and subtracting stimulated emission gives relative integrated absorption areasThe common factor includes $d^2/3$ and cancels upon normalization. This formula describes integrated weak absorption in a thermal, spin-free linear rigid rotor, not arbitrary peak heights. The example's strongest integrated lines originate at $J=3$ and $J=13$ for $3$ and $30\mathrm{K}$, respectively: they differ from the most populated levels. A missing line can reflect population, coupling, coverage, or sensitivity; it does not prove that the corresponding quantum state is absent.

Stimulated emission is emission induced by incident light, in contrast with the unprompted decay in spontaneous emission. It supplies the amplification mechanism of a laser. ^[ref].

For an emitter with upper and lower energy values $E_2>E_1$, the resonant photon has frequency $\nu$ satisfyingwhere $h$ is the Planck constant. In the elementary photon picture, an incident photon stimulates an emitter in the upper quantum state to emit an additional photon into the same optical normal mode, with the same frequency, propagation direction and photon polarization. The emitter supplies the extra energy; the stimulating photon is not consumed. This builds the existing field and its optical coherence. An emitter in the lower quantum state can instead undergo photon absorption, so stimulated emission alone does not establish net optical gain.

For example, a $2.0\mathrm{eV}$ gap corresponds to $\nu \approx 4.8360\times 10^{14}\mathrm{Hz}$ and a vacuum wavelength of about $620\mathrm{nm}$. One ideal stimulated emission event converts one incoming photon into two outgoing photons in the selected optical normal mode, adding $2.0\mathrm{eV}$ of light energy while lowering the emitter's energy by that amount.