Take for the repulsive molecular interaction, as the common reference pressure, and let be the ice-film temperature. All ratios involving use its absolute value, approximately , rather than the numerical Celsius value zero. The premelting film permits water to reach and freeze at the bottom of the ice while the upper surface is displaced upward without freezing there.
For equal phase mass densities, equality of the solid and liquid chemical potentials gives the Clapeyron pressure relation for equal-density phases. Indeed, and , so expansion around coexistence at yields
This is a pressure difference between phases, not a same-pressure Clausius-Clapeyron slope. The molecular disjoining pressure supports this difference:
Treat the normal solid load as its effective pressure in this planar model. The gravitational load corresponding to hydrostatic pressure is , so . Refer the bath pressure to the sheet's upper gravitational datum, or neglect the sheet-scale hydrostatic head. The Darcy flow law then gives the upward supply and the ice growth rate
Here is permeability of a porous medium, is dynamic viscosity, and equal densities identify supplied liquid volume with added ice volume to leading order in .
To recover the printed law, use the usual hydraulic control of frost heave idealization: the sheet's top is at , the liquid film and ice have a common thermal conductivity , and the flow is slow enough that latent-heat production is small compared with the conductive heat passing through the layer. In addition to a quasi-steady ice temperature field, this needs
The leading heat flux is consequently continuous through the film and ice. Their thermal resistances give
Let , a pressure scale. The thermomolecular pressure and the molecular law then give
Substitute this pressure into the Darcy flow law:
The first term draws water toward the undercooled ice; the increasing gravitational load eventually cancels it.
Quasi-steady temperature alone is not sufficient to fix this exact prefactor. With film conductivity , ice conductivity , and nonnegligible latent heat, the appropriate additional balance is
Together with the Darcy equation, this is the implicit growth model. Even in the slow-flow limit, a conductivity ratio changes the leading driving pressure by . Taking is a counterexample to obtaining the printed prefactor from quasi-steadiness alone. Thus the boxed equation is the intended equal-conductivity, thin-film, hydraulically limited model, rather than a consequence of only the stated quasi-steady assumption. This distinction is the heat-balance correction to a premelted-film growth model.
For that reduced equation define
The scale balances against ; has units of pressure times length to the power , so is a length and is a time. They yield
Set . The equation becomes linear:
For initial thickness , the explicit solution of gravity-limited frost heave is
The usual zero-initial-thickness sketch uses
Its early and late behaviour are
For , the derivative is positive and , so the curve is increasing and concave downward. It approaches the stable thickness exponentially. Initial thickness above instead relaxes downward; at it is stationary.
Figure 1.
Exact reduced premelting growth from zero thickness with the early power law and late exponential approach to equilibrium
. Details.
The singular slope at zero belongs to the formal reduced solution. Since , the thin-film assumption eventually fails as . The early power law therefore describes an intermediate continuum regime after any microscopic startup, not arbitrarily early physical times. A finite positive supplies a regular initial condition when that regime begins. Gravity limits the ultimate thickness; molecular suction and the Darcy resistance set the growth toward it.
For a stationary, uniformly permeable skeleton, Darcy law gives . Constant-density conservation of mass gives , hence the pressure is harmonic:
With uniform gravitational acceleration, the same argument applies to pressure after subtracting its hydrostatic part. The spherical calculation below neglects body-force variation and uses the excess pressure relative to the far field.
Set and . When a shell freezes, its pore mass decreases at rate ; the difference must leave as liquid. Since Darcy velocity is volume discharge per total area, not pore-fluid speed, the interfacial and radial balances give
The positive sign means outward expulsion by the expansion on freezing. Integrating Darcy law with gives
There is no liquid Darcy velocity in the ice-filled region.
To state a closed Stefan problem, let be the effective thermal conductivities of the frozen and unfrozen composites and their volumetric heat capacities. If the matrix mass density is , the common specific heat gives and . These material coefficients are not numerically specified. With , the thermal equations are
The exterior equation retains advected sensible heat. A more detailed mechanical-energy model adds the Darcy dissipation source ; its smallness at leading order is checked below. At the origin require , and at infinity require , . At the phase boundary impose temperature continuity, phase equilibrium and the Stefan condition:
These equations, the radial liquid-mass balance and Darcy law, together with an initial radius and compatible initial temperature fields, specify the moving-boundary model. No curvature correction is imposed. A vanishing initial seed corresponds to the leading growth law below with .
Write and , the latent-to-sensible heat ratio. A conductive interfacial balance gives . On length scale , the ratio of thermal diffusion time to growth time is consequently bounded by
It is small for with fixed porosity and comparable constituent densities and thermal properties. Very small porosity requires the sharper condition ; the bare heat-capacity ratio alone should not be used uniformly as . The advective-to-conductive ratio is
Even if mechanical heating is retained, its size relative to latent-heat release is . For fixed water properties this is also small as , consistently with the linearized Clausius-Clapeyron relation. Thus unsteadiness, thermal advection and mechanical heating are higher-order effects. The local leading temperature fields satisfy Laplace's equation. The approximation describes radii of order ; the distant transient diffusion tail supplies the far-field matching and need not be globally steady.
Regularity at zero and the interface/far-field values give
The Stefan condition becomes . Introduce the dimensionless pressure-feedback factor
Combining this heat balance with pressure-dependent phase equilibrium yields the growth and interface values:
This is pressure-limited spherical freezing in a porous medium. The interface values are constant during this leading solution, although changes at a fixed exterior radius.
As permeability of a porous medium decreases, increases: the interface pressure rises toward the finite value , while the interface temperature falls toward . Hydraulic resistance suppresses freezing through pressure-induced freezing-point depression. In the limit , ; a zero-seed radius grows as and tends to zero at fixed time. A finite seed instead hardly changes. At exactly zero permeability an incompressible rigid model cannot expel the expansion volume, so sustained growth stops; deformation or compressibility would require a different model.
Let measure distance inward from the surface. While , curvature is negligible and this is a planar two-phase Stefan problem. Use a common reference mass density , specific heat capacity , thermal conductivity and thermal diffusivity ; retain the mass density differences only in the subsequent buoyancy estimates. Define , , and . The paper's parameter is the latent-to-sensible heat ratio, reciprocal to the more usual Stefan number.
For superheated two-phase Stefan similarity, solving with , and gives the Neumann solution of the Stefan problem. With ,
The solid expression holds for and the liquid expression for . The interface gradients inserted in the Stefan condition determine the positive constant :
The right-hand bracket decreases from infinity and crosses zero, while the equivalent left-hand side increases, proving uniqueness. The liquid-side flux subtracts from the roof cooling: it is heat brought to the interface by the superheated interior.
For large , . Keeping the superheat term while using and yields . Hence the small-interface-parameter growth with liquid superheat approximation is
The solid temperature is approximately linear across its thin crust, while the liquid thermal boundary layer has thickness of order . For fixed superheat and , ; for , . This retains the strong suppression of growth by a very hot interior.
To estimate overturn, take local gravitational acceleration at the roof. The liquid's mass density contrast is , while the solid contrast is . A liquid thermal layer of thickness has Rayleigh number . As , it reaches its critical value after a time scaling as
In viscous overturn of a dense crust, an unstably stratified viscous crust has a Rayleigh-Taylor instability growth time of order . Setting this equal to its age, with , gives
These are formation-to-overturn times. A specified critical liquid Rayleigh number multiplies by ; logarithmic amplification and geometrical constants also affect the crust estimate. They are omitted for the requested order-of-magnitude scaling.
The given numbers yield , and . Thus
Liquid thermal overturn is enormously faster than crustal overturn throughout the stated range. Even a critical-Rayleigh prefactor of order does not change that ordering. Since is not asymptotically large, low-superheat coefficients from the permitted approximation are only approximate. At the upper end , so the linear thermal-density approximation also ceases to be quantitatively credible; that endpoint is a formal scaling estimate under the supplied constant-property model. At a common age the instantaneous viscous instability-time ratio instead scales as ; it should not be confused with the above formation-time ratio.
For a boundary-layer renewal model, the liquid layer reaches . Its cycle-averaged thermal flux is consequently
If a critical Rayleigh number is retained, insert a factor . Averaging the diffusive flux over a cycle only changes an order-one coefficient. The crust reaches
so its average solid-volume flux per roof area is the crust-removal flux
The corresponding mass flux is and latent-heat flux is . This independent-cycle estimate is a scale for a crust that reaches overturn thickness and is then renewed. Because the liquid renews much more rapidly, in a hot interior its average heat flux can limit actual crust growth: the consistent interfacial budget is . A stalled crust would not realize repeated solid cycles. In a superheated interior, detached solid may also remelt; permanent core deposition is most directly justified in the late regime requested next.
At late times , liquid thermal buoyancy vanishes and . Thus
Assuming thin renewed crust, efficient sinking and constant asteroid radius, conservation of mass gives under the permitted equal-density approximation. Therefore the asteroidal core growth by crustal sinking law is
For a self-gravitating approximately uniform sphere, , so and a zero-seed core scales as . This law applies while the thin-crust renewal model remains valid and liquid remains available; it cannot continue beyond complete solidification. The specific numerical lifetime cannot be inferred without the absolute solid viscosity and conductivity.
Take positive downwards from the roof. Write , , and . The cooled magma follows the decreasing liquidus from towards ; the initially superheated liquid starts at above that liquidus. The solid has zero solute concentration. At each temperature in the mushy layer, a horizontal tie line joins the pure solid to the residual liquid on the liquidus. The lever rule gives the liquid fraction from the bulk concentration. Since , this path stops before the eutectic temperature and does not cross the eutectic composition.
Figure 1.
Liquid cooling, residual-liquid enrichment and a solid–liquid tie line in the stagnant magma mush
. Details.
The porosity denotes the liquid fraction, so is the solid fraction. Equal phase mass densities remove volume-change flow; the stable density stratification suppresses convection. In the stagnant mushy-layer model, define bulk specific enthalpy and bulk solute concentration by
The arbitrary reference of specific enthalpy has been omitted. The two conservation laws in are
Here is the thermal diffusivity, with the thermal conductivity. The positive term records increased specific enthalpy on melting; during freezing it supplies latent heat. In the liquid , the heat equation and solute diffusion equation are
where is the solutal diffusivity. Neglecting solute diffusion inside the mushy layer does not permit dropping in the liquid at this stage.
Use , liquid and as , and initially , , for . These are the half-space boundary conditions appropriate before cooling reaches the bottom of the chamber. For a closed chamber of finite depth , replace the far-field conditions by the specified bottom conditions, for example at an insulated impermeable floor; the half-space similarity solution then ceases to apply when the thermal penetration depth approaches .
At , let and be the common liquid concentration and temperature, and let be the limiting porosity on the mush side. Continuity of , the Rankine-Hugoniot condition for solute, and the interfacial conservation of energy give
The first condition has the sign of solute rejection into the liquid. For the sharp-edge stagnant mushy-layer model with nonzero liquid solutal diffusivity, close the free-boundary problem by marginal equilibrium at a mush-liquid boundary:
This prevents constitutional supercooling immediately ahead of the mushy layer. A small solid fraction jump at its edge is allowed: imposing as well as these finite- conditions would generally overdetermine the reduced model. At the roof, follows from the liquidus, and no additional solute-flux boundary condition is needed in the diffusion-free mush.
To obtain the large-concentration similarity solution, put
The positive superheat specifies the physically intended liquid initial state. On a similarity solution, are constant, so every newly incorporated level leaves the same constant . Write and . Then throughout the mushy layer
For , , and , the effective heat capacity is constant to relative error . Thus set
Integration of the similarity solution ordinary differential equation gives the leading analytical profiles
The temperature is . In the mushy layer, the concentration and porosity are the displayed ; in the liquid,
These retain the liquid solutal boundary layer. For completeness, finite- values of are determined analytically, to the same large- order, by setting
and solving
The solute jump gives exactly; replacing by on the right of the last equation retains that jump's next-order factor, but does not make the linearized thermal profiles exact at finite . The branch has , . All these profiles are leading asymptotic expressions, not exact solutions of the nonlinear finite- heat equation.
For at fixed positive , the complementary error function asymptotic gives , hence , , , and . The result simplifies to
In particular, and . There is no finite interfacial latent heat jump in this limit: the latent heat is released continuously throughout the mushy layer. Matching the two temperature gradients gives
The printed final equation is missing the square on in the exponential. The corrected exponent follows directly from differentiating and is consistent with . The positive root is unique: the mush-side gradient decreases from infinity to zero with , whereas increases. The zero-superheat limit is singular and is not described by a finite positive in this two-region construction.
Use the usual saline Stefan problem approximation: no bulk flow, salt-free ice with negligible salt transport, constant properties, equal phase densities, and the same thermal conductivity and thermal diffusivity in both phases. Write for specific heat capacity, for latent heat per unit mass, and . These thermal symmetries are needed for the arithmetic-mean interface temperature requested in the paper; unequal phase conductivities would give a weighted balance instead.
Set , , and . The heat equation and salt diffusion equation reduce to . Their similarity solutions, in terms of the complementary error function, are
These have the required interface values and far-field limits. At each fixed they recover the initial data as . The liquidus condition is .
Salt rejection and the Stefan condition give, with gradients evaluated on the appropriate sides of the interface,
For example, salt rejection is obtained by differentiating the total salt on a moving liquid interval: the moving lower endpoint removes , which must be supplied by diffusive transport away from the salt-free solid. Substitution, including the salt-rejection function for a saline Stefan front, gives the complete algebraic system for the diffusion-controlled iceberg growth and ablation:
The sign of distinguishes freezing from melting; neither sign should be excluded in the general similarity solution.
For , , and fixed and far-field temperatures, the thermal equation has leading right-hand side , while its left-hand side is . Hence
This is a leading-order balance, not an exact cancellation of latent heat. The resulting and the first algebraic equation determine the leading . A physical finite- branch requires ; if the mean temperature is positive, this salt-diffusion scaling cannot describe the leading solution. Likewise, a latent-to-sensible heat ratio diverging as changes the leading thermal balance.
Define and . Put and . Then , which will determine the freezing and constitutional supercooling conditions below.
Use a quasistatic surface energy balance with negligible heat storage in the surface or ice, a linear ice temperature profile, and a fixed freezing temperature at the ice-ocean interface. These are the assumptions behind the single-category sea-ice thermodynamic model used below. Write , and
Here and are heat transfer coefficients, is thermal conductivity, is thermal diffusivity, and is the inverse Stefan number. Here is latent heat per unit mass. The thermal denotes conductivity; the previous questions use for permeability.
While there is open water, the upward ocean heat supply balances the loss to air: . Thus
Freezing begins when this surface reaches on the cooling part of the annual cycle, which requires and gives
For the surface never cools strictly below freezing and no positive ice thickness develops in this model. The limit gives .
With ice present and a cold surface, thermal conduction and Newton's law of cooling give . The surface temperature is
During surface melting the temperature is capped at ; the ice is not permitted to follow the above formula to a temperature higher than its melting point. The upward conductive heat flux during the cold phase is
The Stefan condition at the ocean interface gives . Under the permitted approximation of negligible ocean heat during growth,
Starting from , integration yields the implicit growth law
The leading maximum occurs when the air returns to freezing from below:
The equality for is within the ocean-heat-neglected growth model, with the freezing time set by the open-water balance. If , conductive resistance through the ice dominates the atmospheric boundary resistance at maximum thickness. Consequently
This reproduces the displayed large-conductance limit. A sufficient condition for the quasistatic temperature assumption is ; large ensures this in the thick-ice scaling.
The approximation concerning ocean heat needs care. Its ratio to atmospheric heat removal during the cold phase is
It is uniformly small away from the beginnings and ends of winter provided
For the thick-ice limit this requires both and . This also makes the integrated ocean heat small relative to the latent heat of the maximum ice column. It is not possible to neglect pointwise throughout the closed growth interval: at the actual freezing onset it balances the atmospheric removal, and at the true maximum the growth rate is zero because the two fluxes again balance. The ocean-heat correction to seasonal ice growth therefore gives narrow endpoint corrections. In the full model the maximum is slightly earlier than , with
Thus in the stated approximation, rather than an exact maximum time for finite ocean heat.
For , while ice survives, both the warm air and ocean melt it. The surface is at , and the total Stefan condition is
Integrating from the leading maximum gives
until its first zero. The physical thickness is then zero for the rest of this warm interval and the open-water temperature applies. Therefore at the end of the first year,
Positive ice at that time is equivalent, in the specified approximation, to
This establishes the algebraic criterion printed in the paper.
There is, however, an actual qualification to the paper's word “perennial.” This inequality tests peak-temperature sea-ice survival, since is the next atmospheric temperature maximum. Surface melting continues until at least , so positive thickness at the maximum does not guarantee survival throughout the summer. In the same approximation, survival through that full warm half-cycle would require the stronger inequality
In fact, starting ice-free under the specified zero-mean sinusoidal forcing, even the zero-ocean-heat upper bound on winter growth cannot meet it. In that limit and
since . The expression on the right is already the atmospheric melt over the entire subsequent warm half-cycle. Positive ocean heat can only reduce the winter ice and increase summer melt. Thus the printed condition is a first-year peak-temperature survival test, not a sufficient criterion for literal year-round ice in this model. For example, with and very small positive , it gives , while first-year melt is approximately but full warm-season melt is approximately . Ice is present at the year's endpoint and disappears later that same summer. No reinterpretation of the printed inequality as guaranteed perennial cover is justified without an additional seasonal assumption.
Use , , and , the latent-to-sensible heat ratio. Transforming the heat equation to the fixed apparatus frame and substituting Darcy flux gives the exact steady mush equation
For , the solid fraction is . Since , the latent term remains leading order, whereas the correction is small. Define . The large-concentration thermal profile of a pulled mush then obeys
With and in the liquid,
The thermal conductivity agrees on both sides and the solid fraction vanishes at the mush–liquid interface, so there is no jump in latent production there: continuity of heat flux gives . Thus
The boundary value determines , as calculated next. The crystal fraction is obtained from the previous part's formula, with the temperature field understood to this leading asymptotic accuracy.
Figure 1.
Temperature and crystal fraction in a steadily pulled mush
. The leading large-concentration temperature field matches smoothly to the liquid at the top of the mush. The crystal fraction tends to zero there; the remaining liquid freezes at the eutectic front at the bottom. Details.
Set
so . Apart from material constants, the heat flux in part ii is
The derivative of its logarithm vanishes when
which gives the maximizing interface temperature
Substitution into the flux law gives
where
Thus the proportionality coefficient depends on the thermal conductivity, nonlinear thermal-expansion coefficient , kinematic viscosity, thermal diffusivity, gravity, and critical Rayleigh number. This is the maximum-flux law for penetrative convection in an ice-covered lake.
Let be the thickness of the thermal boundary layer immediately below , let be the kinematic viscosity, let be the thermal diffusivity, and let be the critical local Rayleigh number. The density contrast driving the boundary layer follows from the density anomaly of water:
A Local Rayleigh-number closure sets
and therefore
By Fourier's law, the upward heat flux through this layer is
where is the water's thermal conductivity. This expression applies while the quantity inside braces is positive.
The unperturbed temperature is linear in each material. Continuity of the conductive heat flux at gives
On defining
this becomes . Therefore
Let be the ice mass density and its latent heat of fusion per unit mass. The ice is isothermal in this model, so the Stefan condition equates latent-heat production to the heat flux conducted through the water:
Consequently the unperturbed lateral solidification speed is
The material parameters are the thermal conductivities , ice density , and specific latent heat ; the geometric thermal length is .
Radiometer thermal link 2026-10-14
A radiometer thermal link is the intentional path for thermal conduction from receiver to reference block. Near a chosen operating point, write with local conductance in . A weaker link increases the steady temperature rise per added power, , but also increases the uncontrolled relaxation time when the link dominates other heat transfer. These are local linear approximations: actual thermal conductivity depends on temperature, and active feedback control introduces its own response. NIST explicitly describes the tradeoff between weaker links and smaller receiver heat capacity.[ref]
Single-category sea-ice thermodynamic model Created 2026-10-05 Updated 2026-10-07
A single-category model represents local ice by one thickness and one surface temperature . With basal freezing temperature , atmospheric temperature , thermal conductivity and atmospheric heat transfer coefficient , quasistatic thermal conduction gives
while . If is upward ocean heat flux, the Stefan condition gives . During surface melting, and when . Thickness is constrained to be nonnegative, and the open-water energy balance applies after complete melt.
In the absence of heat advection, an insulating sphere of radius in a uniform remote temperature gradient has the displayed exterior harmonic function as its temperature field. The reflected dipole term makes at . The surface temperature is , so the tangential gradient is amplified by . If the sphere has thermal conductivity ratio relative to its surroundings, temperature and heat-flux continuity instead give surface gradient factor .
Thermal conduction Created 2026-09-24 Updated 2026-10-14
Thermal conduction transfers heat through microscopic interactions without bulk transport of matter. To predict the heating load through a bar, combine Fourier's law with conservation of energy and the imposed end temperatures. In the isotropic model with positive thermal conductivity , the conductive heat flux points from high to low temperature, opposite to the temperature gradient. A spoon warming along its handle and heat escaping through a wall are familiar examples.
Consider a bar of length , constant cross-sectional area and constant thermal conductivity . Maintain its ends at and , with increasing toward the colder end. Assume a steady state, one-dimensional thermal conduction, no internal sources and no heat transfer through the sides. The temperature falls by over , giving
The difference between the two readings in degree Celsius units is the same -kelvin difference. The positive heat flux carries heat toward increasing .
Figure 1.
Steady thermal conduction through a bar: declining temperature, constant heat flux
. An isotropic bar with stipulated constant thermal conductivity , length and cross-sectional area . Its ends remain at and , and its sides exchange no heat. The lower panel distinguishes from . Details.
The general solution under these assumptions is
A proof outline is enough to explain the straight line: conservation of energy in any small slice, with no accumulation, sources or side losses, gives . Constant cross-sectional area gives ; constant thermal conductivity and Fourier's law then give . Two integrations and the end boundary conditions determine the displayed affine function. This is why a visually simple temperature profile can encode a continuous flow of energy. [ref]
Doubling the length halves the rate, while doubling the cross-sectional area doubles it, at fixed end temperatures and thermal conductivity. This explains why a long narrow support can limit unwanted heat transfer, while a short broad path can help remove heat. Joining materials leads to thermal resistance in series. During initial warming, internal energy can accumulate and the temperature profile need not be a straight line; the time dependence is described by the heat equation and thermal diffusivity.
Now join two layers, each of length , with constant cross-sectional area and stipulated constant thermal conductivities and . Keep the outer ends at and . Assume a steady state, one-dimensional thermal conduction, no internal sources or side losses, and perfect contact: the temperature is continuous at the interface, with no extra contact drop. For each layer, use the area-specific thermal resistance and . The series calculation gives
Figure 2.
Two layers in series: continuous heat flux, different temperature gradients
. Each layer is long with the same cross-sectional area and perfect contact. Stipulated constant thermal conductivities are and . The temperature drops by and , reaching at the interface, while and throughout. Details.
The heat flux is continuous: otherwise energy would accumulate at the interface. Yet Fourier's law gives different temperature gradients, and . Lower thermal conductivity requires a steeper temperature gradient to carry the same heat flux; equal lengths therefore give drops in the ratio . A kink in the temperature profile records the change of material while perfect contact keeps the temperature itself continuous.