Boltzmann factor Created 2026-09-24 Updated 2026-10-06
At inverse temperature , the Boltzmann factor is the relative canonical ensemble weight of a microstate with energy .
Macrostate Created 2026-09-24 Updated 2026-09-24
Past exam of the mathematics course of the University of Cambridge 2023 ii Paper 2 37A a Solution Created 2026-09-24 Updated 2026-09-25
The extension of the one-dimensional freely jointed chain isAs the integer runs from to , the possible extensions are thereforeFor fixed and , choosing which of the links point in the positive direction determines the microstate. The state degeneracy is consequently the binomial coefficient
Past exam of the mathematics course of the University of Cambridge 2023 ii Paper 2 37A c Solution Created 2026-09-24 Updated 2026-09-25
Several microstates can have the same extension. If denotes their state degeneracy, grouping equal terms in the state sum givesFor the one-dimensional freely jointed chain, a macrostate with positive links and negative links hasHenceThe binomial theorem now gives the fixed-tension partition function of a one-dimensional chain
State degeneracy Created 2026-09-24 Updated 2026-09-24
The degeneracy of a macrostate labelled by is the number of distinct microstates having that value of .