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The Doppler effect changes the observed frequency of a wave when source and observer move relative to one another. For light and a small radial recession speed $v_r\ll c$, $\Delta \lambda /\lambda \simeq v_r/c$, where $\lambda$ is wavelength. This is the basis of Doppler spectroscopy.

Frequency is the number of repetitions of a periodic phenomenon per unit time. For a wave of period $T$, its frequency is $\nu =1/T$, measured in hertz. The angular frequency is $\omega =2\pi \nu$.

With the sign convention of the displayed operator, the Lax equation is $L_t=[L,A]$. Differentiating $L\phi =k^2\phi$ shows that ${\phi }_t+A\phi$ is another solution at the same spectral parameter. The normalization at $-\infty$ fixessince $A{e}^{-ikx}=4i{k}^3{e}^{-ikx}$ there. At $+\infty$, comparison of the two plane-wave coefficients givesThus the transmission denominator $a$ is time independent. This is the Time evolution of KdV scattering data for the stated normalization.

The logarithmic derivative $S={\phi }_x/\phi +ik$ obeys the Riccati equationIts formal large-$k$ expansion givesThere is an important qualification to the integral identity in the question. For real $k$ with nonzero reflection, $e^{ikx}\phi \sim a+b{e}^{2ikx}$ has no limit at $+\infty$, so the literal improper integral of the exact $S$ need not exist. Continue to $\mathrm{Im}k>0$, where the reflected exponential decays relative to $e^{-ikx}$, and take sufficiently large $k$ away from zeros and with a consistent logarithm. Then the normalization givesThe second equality is an asymptotic expansion, not an asserted convergent series. Time independence of $a$ fixes every coefficient, so each $\int S_{n}dx$ is a conserved quantity of the Korteweg-De Vries equation. The first two nontrivial examples are $-\int udx$ and $\int u^{2}dx$.

For the usual real-valued KdV potential and real formal $k$, write $S=X+iY$ with real coefficient functions. Its imaginary part of the Riccati equation is $Y^{\prime }-2kX+2XY=0$, henceIn the formal expansion, $X$ contains precisely the even-indexed $S_n$ and $Y$ the odd-indexed ones. Rapid decay of $u$ and its derivatives makes every coefficient of the logarithm vanish at both spatial ends. Therefore $\boxed{{\int }_{\mathbb{R}}{S}_{2j}dx=0(j\ge 1)}$. This is a coefficientwise formal identity; it does not claim that the exact real-axis reflected solution has a convergent integral of $X$. The analytically continued scattering identity and the formal expansion are the conventions needed to make the requested argument valid.

Physical optics describes light as a wave, including wave interference and diffraction.