Fermi level 2026-10-06
The Fermi level is the chemical potential controlling electron occupations. For an ideal Fermi gas at zero temperature it equals the Fermi energy; at nonzero temperature the chemical potential need not equal that zero-temperature energy.
Fermi momentum Created 2026-10-05 Updated 2026-10-06
Fermi momentum is the momentum at the boundary of occupied one-particle states in a zero-temperature Fermi gas. For spin-one-half particles in three dimensions, counting the two spin states gives , where is number density.
For a two-dimensional Fermi gas of spin-one-half particles with Fermi energy , the constant density of states makes the low-temperature internal energy correction and heat capacity at constant area
Thus its low-temperature heat capacity obeys a power law with exponent one.
Assume zero temperature, complete ionization, constant composition, noninteracting electrons, negligible ion thermal pressure, and Newtonian stellar gravity. Ions supply almost all the mass, while electron degeneracy pressure supplies support. By the Pauli exclusion principle, the two electron spin states fill a momentum sphere up to Fermi momentum . Counting states gives
where is mean molecular weight per electron. The momentum flux of this isotropic Fermi gas is
Writing and performing the integral gives the equation of state of a cold electron gas
In the nonrelativistic limit , , so
In the ultrarelativistic limit , , so
These are polytropic equations of state with indices and , respectively. The relativistic softening underlies the Chandrasekhar mass limit; Coulomb corrections, thermal effects, rotation, and general relativity are excluded from this idealized derivation.
For an ultrarelativistic particle, . Including the two spin states of an electron, counting wavevectors in a sphere gives the density of states
The grand canonical partition function of the ideal Fermi gas is therefore
Since the grand potential satisfies , integration by parts gives
Thus
This is the equation of state of an ideal ultrarelativistic gas.
For density of states proportional to , , and positive temperature, set , , and . Differentiation and integration by parts give
The inequality is strict Cauchy-Schwarz inequality, since is not constant under this positive weight. Thus fixed entropy per particle forces fixed . This is the injectivity step behind the adiabatic scaling of an ideal Fermi gas.