Past exam of the condensed matter physics course of the University of Oxford 2012 4 e Solution 2026-10-25
With spin degeneracy, each energy band contains two electrons per primitive unit cell. Divalency therefore permits a filled first band, but only if its maximum lies below the second band's minimum. With negligible ionic periodic potential, the circular Fermi surface and the rectangular zone have equal enclosed area, not equal shape. Electrons occupy some states outside the first zone while some higher-energy first-zone states remain empty. Folded bands overlap, and the material is a metal.
A periodic potential mixes plane waves differing by a reciprocal lattice vector. At a two-wave Bragg point, the nearly-free electron model gives a direct gap . Increasing appropriate Fourier coefficients can remove the band overlap. With the first band filled, the system is then a band insulator, provided the temperature is small compared with the insulating band gap in energy units.
The rectangular free-electron band-overlap scale follows from two different points in reciprocal space. Put . Before gap opening, the highest first-zone energy is at the corner, while the lowest second-zone energy is at the midpoint of the nearer face:Thus the downward shift of the first-band maximum plus the upward shift of the second-band minimum must overcomeIn a rigid-splitting estimate, an opening lowers the first band by and raises the second by , giving the familiar threshold . Equality is only band touching, not a positive insulating gap. This expression is the overlap that must be removed, under that explicit band-shift approximation.
Positive direct gaps can coexist with band overlap: a local direct splitting and the global indirect band gap are not interchangeable. The shape and Fourier coefficients of the ionic potential are unspecified, so there is no universal exact critical direct-gap width determined by alone. For a concrete demonstration, a separable potential has axial direct gaps and . To first order, the corner's lowest level is , and the two candidate second-band minima are and . Therefore, within this model and neglecting higher-order band shifts, nonoverlap requiresEqual axial gaps would give the first-order estimate , rather than the rigid-splitting estimate. Such a large opening can exceed the quantitative range of weak-potential perturbation theory, but the example identifies the missing model assumption: corner levels feel both couplings. The exact general answer is the positive indirect-gap criterion above; a geometry-only direct-gap threshold would claim more than the supplied potential information supports.
Past exam of the condensed matter physics course of the University of Oxford 2014 2 c Solution 2026-10-25
An electron losing energy to an acoustic phonon has, in a normal process, , with possible addition of a reciprocal-lattice vector for an Umklapp process. The energy transfer is at most of order , much smaller than . Hence the magnitudes change very little even though the momentum direction can change substantially. At , thermal vacancies near the Fermi surface allow emission into some lower-energy states; exactly at zero temperature emission into an occupied Fermi sea would be blocked by the Pauli exclusion principle.
Using and the free-electron dispersion, energy conservation givesSince , the bracket is . Rearranging yieldsEquivalently . For a Debye-cutoff phonon in the preceding model, , confirming the approximation. Near-elastic scattering constrains the radial distance in wave-vector space, not the scattering angle alone.
Past exam of the condensed matter physics course of the University of Oxford 2016 2 a Solution 2026-10-25
In the free electron model, conduction electrons occupy independent plane-wave states with energy in a uniform mean background. Crystal-periodic band structure and explicit electron–electron correlations are omitted. Electrons still obey the Pauli exclusion principle and Fermi–Dirac statistics; free does not mean distinguishable classical particles. A scattering time can be added phenomenologically to describe transport.
The Fermi energy is the highest occupied single-particle energy at zero temperature, measured here from the bottom of the parabolic band. The Fermi temperature is the corresponding scale , not the actual thermal temperature of the sample. Metallic electron densities are large, so filling all distinct states up to the required momentum gives Fermi energies of several electronvolts, equivalent to tens of thousands of kelvin or more. At ordinary temperatures, only a narrow region around the Fermi surface has appreciably changing occupations.
A room-temperature metal and its lattice are nevertheless at room temperature, not at . High occupied kinetic energies are present even in the zero-temperature ground state and cannot all be liberated as heat without violating the allowed occupancy structure. A metal below skin temperature often feels cold because it transfers heat rapidly out of the skin; its thermal conductivity and thermal effusivity matter, not the value of its Fermi temperature. At the same actual temperature, a poorly conducting material can therefore feel warmer while neither material is thermodynamically hotter.
Past exam of the condensed matter physics course of the University of Oxford 2016 2 c i Solution 2026-10-25
A conventional face-centered cubic cell contains four atoms. With three conduction electrons per atom,Using the bare electron mass,The Drude transport relation is , givingFor a degenerate electron gas, transport samples electrons near the Fermi surface, so use m/s:This is a transport relaxation time and associated transport mean free path inferred from the specified resistivity. It need not equal a single-particle quantum lifetime when scattering is strongly angle dependent. The free-electron valence count also neglects the detailed band structure of aluminium, as the stipulated model requires. A classical thermal speed is not the appropriate velocity scale for this strongly degenerate metal.
Past exam of the condensed matter physics course of the University of Oxford 2018 2 d Solution 2026-10-25
The first Brillouin zone is the squareAt half filling, translation of the wavevector by exchanges the two band energies:Thus the same energy-pair argument as in part c givesAt zero temperature, the Fermi surface satisfies . Within the square Brillouin zone this is the diamondwhose vertices are and . The occupied region is the diamond's interior, containing the band minimum at the zone centre. It has half the Brillouin zone area, consistent with one electron per atom and two spin states per wavevector.
Past exam of the condensed matter physics course of the University of Oxford 2018 2 e Solution 2026-10-25
The reciprocal primitive vectors are and , so the first Brillouin zone isIt is wider in the direction because .
The geometry alone does not fix the hopping amplitudes or a unique Fermi surface. One consistent tight-binding model isrepresenting larger hopping between the closer atoms. It remains a nearest-neighbour bipartite band at half filling, so its chemical potential is . Its Fermi surface consists of the two sheetsThese meet the top and bottom zone edges and continue periodically into the neighbouring zones. The right panel of the figure gives an explicit example with and . The central region between the sheets is occupied and has half the zone area. If the hopping amplitudes instead remained equal, a geometrically stretched diamond would also satisfy the stated information. The metric inequality alone does not determine which of these shapes occurs.
A parabolic isotropic band has group velocity and semiclassical force for electrons with charge , where . In the relaxation-time approximation the nonequilibrium drift velocity loses momentum at rate . Combining these givesThe relaxation term represents the average effect of scattering rather than a force on every carrier between collisions. Linear response, an approximately energy-independent and near the Fermi surface, and wavelengths long enough for a local bulk response are implicit. The equilibrium random velocities average to zero and do not themselves contribute a drift current.
In a low-carrier-density semiconductor use a thin, cold sample in a transmission spectrometer. Direct microwave or far-infrared radiation through it, commonly with propagation parallel to and electric field transverse to it. Sweep at fixed frequency and detect transmitted power. The active circular polarization shows an absorption peak, or transmission dip, near . Resolving it requires a long enough scattering time, .
A metal's large plasma frequency usually prevents that radiation from sampling its bulk directly. In surface cyclotron resonance in a metal, put approximately parallel to a clean metal surface and excite an rf electric field in the skin depth, transverse to . Electron orbits extend into the bulk and repeatedly return to that layer. Coherent energy absorption occurs when the rf phase repeats on a return, including harmonics . Measure cavity loss, reflected power, or surface impedance rather than attempting ordinary bulk transmission. The characteristic regime has cyclotron radius larger than the skin depth and sufficiently specular, long-lived orbits.
For the spherical parabolic band the metal harmonic fields areThey are evenly spaced in , with amplitudes and widths determined by surface geometry and scattering. A semiconductor generally gives the simple bulk fundamental, whereas the metal can show this harmonic series in a surface-loss signal. For an anisotropic real Fermi surface the measured mass is the appropriate cyclotron effective mass rather than necessarily every component of a transport effective-mass tensor. These classical resonance harmonics are distinct from the Landau-level quantum oscillations in c.
One orbital per primitive cell supplies two states per wave vector when spin is included. A monovalent metal therefore half-fills this band. Nearest-neighbor hopping on the bipartite rectangular lattice has for , fixing the half-filled Fermi energy atFor , the two Fermi surface obeyThey are corrugated open sheets in an extended-zone description, with ranging from to . They are not a small circular pocket centered at the band bottom. The same maps one Fermi line onto its nested partner. A density-wave or Peierls-like modulation at that wave vector can open additional gaps at the Fermi energy. The unperturbed single-orbital band does not acquire those new gaps without a symmetry-breaking modulation or another coupling; ordinary lattice Bragg effects are already built into its dispersion.
For the three-dimensional tetragonal version set , , . The corresponding half-filled surface isIt is a corrugated periodic surface, not a sphere. At its regular closed contour is electron-like around , with ; at the closed contour is hole-like around , with the sum . The topology switches through the square-lattice separatrix at . Drawing one simple weakly warped cylindrical pocket across every section misses that feature of the half-filled cosine band.
Angle-resolved photoemission can directly map the dispersion and occupied Fermi surface. Angular quantum-oscillation measurements test its closed extremal cross sections and cyclotron masses; momentum-density probes such as positron annihilation or Compton scattering give a complementary bulk test. The different techniques constrain different features rather than merely providing interchangeable pictures.
In BCS theory, an electron distorts the positively charged lattice, and the retarded response can attract another electron. Within a phonon-energy shell around the Fermi surface, the effective attraction can overcome the screened Coulomb repulsion and destabilize the normal Fermi sea toward Cooper pairs. In conventional elemental superconductors the pairs predominantly join time-reversed states of opposite momentum and spin, forming a spin singlet.
In the weak-coupling approximation,Here is the appropriate single-spin density of states and the effective attractive interaction in a consistent normalization. Both the phonon scale and the exponential coupling matter. A large Fermi-level density of states, often associated with partially filled narrow bands, can raise ; weak coupling or a small density of states can suppress it even in a good conductor. With force constants and coupling fixed, gives the conventional isotope trend. This is not a universal monotonic ranking of elements by atomic mass: phonon stiffness, electron–phonon matrix elements, Coulomb effects and magnetism vary between elements. Magnetic pair breaking helps explain why some elements do not follow a naive density-of-states expectation.
For , its squared projection onto the long axis of every valley is . All six valleys therefore have the same cyclotron effective mass:At the fixed photon energy,Thus the two-peak spectrum is replaced by one peak near . The source does not determine the linewidth or absolute oscillator strength for the new direction; the sketch below shows only a normalized illustrative line at the computed position.
For the electron-doped sample, sketch six closed ellipsoids centred on the --X axes, just inside the six square faces of the face-centred-cubic first Brillouin zone, with long axes pointing radially toward X. In the parabolic approximation,The radial-to-transverse semiaxis ratio is . The readable conduction minimum near X and its crossing of support these electron Fermi surface pockets. The two cyclotron resonance fields arise from the two distinct orientations of the six ellipsoids, rather than two unrelated carrier species. The left panel of the original sketch includes axes, , and the three positive-axis X points; the negative-axis X points are symmetry-equivalent.
The surviving valence maximum lies roughly below the original . Lowering by therefore places it in the upper valence band in the conventional silicon band interpretation. The electron pockets disappear and one sketches a hole pocket centred at , as in the middle panel. Detailed valence-band warping and the number of spin-orbit-resolved sheets cannot be extracted from the damaged figure, and the single drawn surface is schematic rather than a claim that all such sheets coincide.
A discriminating physical property is the Hall coefficient: electron-dominated transport gives a negative value, whereas hole-dominated transport gives a positive value in the ordinary single-dominant-carrier regime. One should not infer a numerical resistivity change without the carrier densities and mobilities.
There is no Landau damping of this branch within the completely degenerate collisionless model. Its phase velocity obeys , while each parallel marginal distribution vanishes outside . There are no particles at the resonant velocity, and . The Landau contour consequently contributes no imaginary part to the dielectric function; a real root is allowed with .
If a small nonzero temperature supplied a tail beyond the Fermi surface, the conclusion would change: the resonant derivative would generally be nonzero. For the convention and a simple weakly damped root, expanding the continued dielectric function would give . This conditional formula is not needed to manufacture damping for the exact cutoff. Neither collisional attenuation nor nonlinear evolution is included in the given dispersion relation.
Past exam of the mathematics course of the University of Cambridge 2008 iii Paper 65 6 Solution Created 2026-10-03 Updated 2026-10-14
A Poisson manifold is a smooth manifold with a smooth antisymmetric bivector whose function bracket satisfies the Jacobi identity. The bracket is automatically a derivation in each argument. A symplectic manifold has a nondegenerate differential two-form satisfying , that is, a closed differential form; nondegeneracy forces its dimension to be even. It determines a nondegenerate Poisson structure. We use matrix convention , so that corresponds to .
Examples of genuinely nonsymplectic Poisson geometries include the zero bracket on and the Lie-Poisson bracket on . Their three-dimensional underlying manifold cannot carry a nondegenerate two-form. In the latter case the Poisson rank is two away from the origin and zero at the origin, with spheres and the origin as symplectic leaves. Even in even dimension a given Poisson structure need not come from a symplectic form: on satisfies Jacobi but vanishes along . The statement concerns this degenerate structure, not a claim that admits no other symplectic structure.
For any candidate bivector, applying the Jacobi identity to coordinate functions gives the necessary conditionIt is sufficient as well: expanding and its cyclic companions cancels all terms with second derivatives by antisymmetry of . What remains is . This is the coordinate Jacobi condition for a Poisson bivector.
For a symplectic form, differentiate to obtain . Substituting this into the cyclic expression givesbecause . Thus the inverse symplectic structure always satisfies the Jacobi identity. Conversely, for a nondegenerate Poisson structure, multiplying by three inverse matrices proves closure of its associated two-form.
In momentum space, choose Hamiltonian and the constant Poisson bivectorIts Poisson bracket is . The Hamiltonian vector field therefore givesexactly the prescribed motion. The sign here uses the signed charge as printed; an electron's physical charge may be negative. Since the magnetic field is uniform, every derivative of vanishes, so every term in is zero. Jacobi holds independently of the dispersion function . This is the momentum-space Poisson structure for a uniform magnetic field.
For this bivector has rank two and is a Casimir function of a Poisson manifold: for every . Its symplectic leaves are the planes . For axes with , the leaf form is in our inverse-sign convention. Also , so trajectories on a Fermi surface lie on its intersections with these planes, typically curves. The energy surface is invariant for this Hamiltonian, but need not be a Poisson submanifold; the bracket has been defined on the whole momentum space. If , the Poisson structure and motion vanish.
Past exam of the mathematics course of the University of Cambridge 2011 ii Paper 3 34E Solution Created 2026-09-24 Updated 2026-10-14
Bloch theorem states that energy eigenfunctions in a Bravais lattice potential may be chosen asThe wavevector is defined modulo a reciprocal lattice vector, so one can restrict it to the first Brillouin zone. This follows because lattice translations commute with the Hamiltonian and have simultaneous eigenvalues .
In one dimension write with and expand a Bloch state as . The Schrödinger equation becomesFor zero potential, the parabolas fold into the Brillouin zone. A weak potential shifts a nondegenerate level by at first order, with second-order correction where the denominators stay away from zero. This expansion fails near crossings, where degenerate perturbation theory is required.
At the first zone boundary, put and . The nearly degenerate waves with momenta and are coupled by . Retaining their two-dimensional subspace givesDiagonalizing producesAt there is a gap : the two standing-wave combinations sample the periodic potential differently. Similar Bragg degeneracies occur at , with gaps controlled to first order by the corresponding Fourier components. If that component vanishes, a gap need not open at first order. Between the gaps the continuous energy eigenvalues form energy bands, periodically represented in the reduced-zone scheme. For the first zone edge, the curvature of the upper and lower branches gives a minimum and a maximum respectively for a sufficiently weak nonzero potential, so the avoided crossing is a genuine local forbidden energy interval.
At zero temperature electrons occupy states up to the Fermi energy. The Fermi surface is the set separating occupied from unoccupied states within partially filled bands (Fermi points in one dimension). A partially filled band supplies arbitrarily nearby empty states, allowing occupations to respond to a weak electric field and conduct. Completely filled bands give no net current from such a redistribution; if the next empty band is separated by a positive band gap, the system is a band insulator. Band overlap can instead yield a metal even at an integer band filling. At finite temperature an insulator can conduct through thermally excited electrons and holes.
Past exam of the mathematics course of the University of Cambridge 2014 iii Paper 81 4 f Solution Created 2026-10-03 Updated 2026-10-07
The spin-independent term cancels in the signed sum. The linearized stationary equation becomesThe even powers vanish because the equation is odd under . Equivalently, the mean-field action has curvatureThus the unpolarized stationary point becomes unstable whenAt low temperature, the derivative of the Fermi distribution samples a narrow window around , so for a smooth density of states. Measuring energy from the Fermi level gives , the Stoner criterion in the spin-summed convention fixed above. This identifies local instability of the paramagnetic state; the detailed transition order also depends on higher terms in the action.
In the isotropic ordered phase of itinerant ferromagnetism, continuous spin-rotation symmetry leaves a degenerate direction of magnetization. Its transverse fluctuations produce one gapless, quadratically dispersing mean-field itinerant ferromagnetic Goldstone mode, . The two broken spin generators form a canonical pair, as for the type-B Goldstone boson of the localized ferromagnet. The system also remains metallic, with exchange-split Fermi surfaces and low-energy spin-conserving particle-hole excitations. Longitudinal-amplitude fluctuations and the spin-flip continuum are distinct from the long-wavelength magnon; their energy and damping scales depend on the band structure. Spin anisotropy, if added, could gap the transverse mode, but it is absent from the stated Hamiltonian.
Past exam of the mathematics course of the University of Cambridge 2025 iii Paper 337 2 a Solution Created 2026-09-24 Updated 2026-09-25
Under Fermi-surface renormalization-group scaling, tangential momentum is fixed whileIn frequency space the quadratic action is invariant whenequivalently, in the time representation and . The free Fermi liquid action is therefore marginal.
The deformation has no factor of frequency or normal momentum, so it is relevant. It shifts the zero of the quasiparticle energy from to and hence deforms the Fermi surface.
A generic quartic interaction is irrelevant because momentum conservation fixes a normal component and leaves an additional positive power of . It can be marginal only when all four momenta remain on the Fermi surface while satisfyingFor a smooth generic Fermi surface, the robust possibilities are forward or exchange scattering and the opposite-momentum BCS channel , .
The nuclear Fermi gas model treats protons and neutrons as two species of spin one-half fermions moving approximately independently in a confining nuclear mean field. At a temperature small compared with their Fermi temperature, the Pauli exclusion principle fills the lowest available momentum states. It does not allow all nucleons to sit at zero momentum.
For species , two spin states occupy each momentum-space cell . Counting a filled sphere giveswhere . The Fermi energy is measured from the mean-field well bottom; it need not equal the energy needed to remove a nucleon into vacuum. Occupied-state averaging givesEven at zero temperature there is kinetic energy and degeneracy pressure. As an explicitly illustrative input, total density and give and . These numbers illustrate the formula; they are not additional data supplied by the paper.
Separate proton and neutron seas explain a kinetic contribution to nuclear symmetry energy. At fixed , put and define at . ThenIncreasing one species' population raises its Fermi surface and costs energy, favoring similar populations before electrostatic and interaction terms are included.
pauli blocking suppresses collisions deep in a filled sea because scattering needs unoccupied final states. An energetic external probe can knock a nucleon into an empty state and reveal its initial Fermi motion, making the model useful for broad inclusive scattering distributions. A finite surface can be approximated using a position-dependent nuclear mean field.
A free gas cannot produce nuclear binding or saturation: those require an attractive interaction and its density dependence. The smooth gas picture also omits discrete nuclear shells, nuclear spin-orbit splitting, nuclear pairing, short-distance correlations and deformation. It cannot assign all ground-state spins from a momentum sphere. Its useful prediction is the scale and occupancy of nucleon motion, with a surrounding mean field supplied separately.
Lattice energy is transported by phonons; long-wavelength acoustic modes usually dominate low-temperature conduction. Their speed is set by elastic wave propagation. In the Debye model their volumetric heat capacity grows as at low temperature and approaches the classical lattice limit at high temperature. With boundary-limited mean free path, this gives a low-temperature conductivity; increasing phonon scattering can instead produce a peak and a declining high-temperature trend.
In metals, electrons near the Fermi surface carry both heat and charge. Their heat capacity is linear in T and their typical transport speed is the Fermi velocity, not a classical gas thermal speed. Degeneracy restricts the active thermal fraction but the large speed and long mean free path can make electronic heat conduction dominant. Insulators have few mobile electrons, so phonon conduction usually dominates. The approximate parallel-channel sum is ; which channel dominates is material- and temperature-dependent. [ref]
Past exam of the physics A course of the University of Cambridge 2011 Paper 1 Section A 5 a Solution 2026-10-20
For a free-electron Fermi circle in a square lattice, include two spin states per wavevector. A square cell of side supplies electrons per unit area; counting the disk of occupied states givesThe first Brillouin zone is . For , , so the circular Fermi surface lies wholly inside this square and encloses half its area. The figure uses the stated free-electron approximation; the lattice symmetry alone does not prescribe an exact circular surface.




