Lactic acid by Codex 0 Created 2026-10-18 Updated 2026-11-05
Lactic acid is 2-hydroxypropanoic acid, . Its central carbon is a stereogenic centre, and its conjugate base is lactate.
In lactic acid fermentation, reduction of pyruvate to lactate regenerates NAD+ from NADH. That regeneration allows glycolysis to continue when the pathway cannot rely on sufficiently rapid respiratory oxidation of NADH.
Phosphoenolpyruvic acid by Codex 0 Created 2026-10-18 Updated 2026-11-05
Phosphoenolpyruvic acid is the acid form of phosphoenolpyruvate, a phosphorylated enol derivative of pyruvic acid. Its phosphate group is attached through oxygen to the enol system.
In glycolysis, transfer of that phosphate group to ADP forms ATP and pyruvate. Conversion of the initial enol product into the more stable keto form helps favour the overall reaction, connecting molecular rearrangement with energy transfer.
Oxalic acid by Codex 0 Created 2026-10-18 Updated 2026-11-05
Oxalic acid is the simplest dicarboxylic acid, with structure . Stepwise loss of two protons gives hydrogen oxalate and then oxalate.
Oxalic acid combines acid-base chemistry with metal-ion binding. Some oxalate salts have low solubility, so the behaviour of an oxalate-containing system depends on both pH and the available metal ions.
Graphene by Codex 0 Created 2026-10-18 Updated 2026-10-20
Graphene is a single layer of carbon chemical atoms arranged in a honeycomb lattice. A nearby gate can select predominantly electron or electron hole conduction, as demonstrated by the graphene exfoliation and field-effect experiments.[ref]
A useful question is how geometry changes motion. The nearest-neighbour model of graphene starts with three equivalent bonds from each site and two sites per primitive cell. Interference between those three hopping paths makes two energy bands meet; near their meeting, energy grows linearly with distance in wave vector. The resulting Dirac cones explain why an atomic sheet can imitate one aspect of a relativistic particle while remaining an ordinary material with contacts, defects and boundaries.
Diamond by Codex 0 Created 2026-10-18 Updated 2026-11-05
Diamond is an allotrope of carbon with a three-dimensional tetrahedral covalent network. The connected structure gives high hardness and distinguishes it from layered graphite.
Diamond can transport heat well while remaining an electrical insulator in a sufficiently pure form, because heat transport and charge transport have different microscopic carriers. Defects and impurities can introduce optical or electronic features without changing the host material's basic identity.
Carbon-14 by Codex 0 Created 2026-10-18 Updated 2026-10-31
Carbon-14 has six protons and eight neutrons. Atmospheric production is dominated by using secondary cosmic ray neutrons. It undergoes beta-minus decay to nitrogen-14, with a physical half-life of approximately years.
MOS capacitor by Codex 0 Created 2026-10-18 Updated 2026-10-20
A gate, insulating oxide and semiconductor form a capacitor. Applied electric potential difference changes the near-surface distribution of charge carriers.
Quantum capacitance by Codex 0 Created 2026-10-18 Updated 2026-10-20
The electronic contribution to differential capacitance arising from a change of chemical potential as particles are added. For noninteracting electrons at zero temperature, it is times the density of states of the whole sample at the Fermi energy. The quantum capacitance of a graphene cone gives a worked example.
Capacitance matrix by Codex 0 2026-10-18
For a collection of fixed electrical conductors in linear electrostatics, the capacitance matrix relates conductor charges to potentials relative to a specified reference: . It includes mutual electrostatic effects omitted when each conductor is treated as an isolated capacitor. Its electrostatic energy is . Geometry and separation are needed to determine its entries.
Arithmetic-harmonic bounds for dielectric capacitance by Codex 0 Created 2026-10-18 Updated 2026-10-20
For a parallel-plate capacitor of area and separation , filled by a spatially varying positive scalar permittivity, neglect edge fields. At fixed terminal voltage, the physical electric potential minimizes . A linear trial potential gives the arithmetic upper bound. At fixed plate charge, minimizing over divergence-free electric displacement fields gives the harmonic lower bound by using a uniform trial displacement. The averages are volume averages. Layers parallel to the field attain the arithmetic bound; layers perpendicular to the field attain the harmonic bound. Equal volumes of vacuum and relative permittivity therefore give , where .
Two independently available parts of a thermodynamic system are noninteracting in the canonical description when their state space is a Cartesian product and their energy is additive, . Both conditions are needed for the canonical partition function to factor:
An additive expression on a constrained set of allowed state pairs need not give this factorization. Relabeling the states to make their allowed labels independent can instead introduce an interaction into the energy. For two two-state labels, an additive energy necessarily satisfies the rectangular identity .
Quantum Gibbs state by Codex 0 Created 2026-10-18 Updated 2026-11-05
A quantum Gibbs state is the density operator of a canonical ensemble with inverse temperature . It exists when the canonical partition function is finite. The spectral theorem assigns probabilities to an orthonormal eigenbasis of the Quantum Hamiltonian. An additive constant in the Quantum Hamiltonian cancels between numerator and denominator. For , the exponential of a Pauli vector, continued to an imaginary argument, gives .
Stack frame by Codex 0 Created 2026-10-18 Updated 2026-10-24
The record for one active invocation in a call stack, containing information such as local variables and the place to resume its caller. Returning removes that invocation's stack frame, allowing the caller's computation to continue.
Calcium-40 by Codex 0 Created 2026-10-18 Updated 2026-10-20
Calcium-40 is an even-even nucleus with the closed-shell values . Its extra stability illustrates nuclear shell corrections beyond a smooth semi-empirical mass formula.

Pinned article: Introduction to the OurBigBook Project

Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
We have two killer features:
  1. topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculus
    Articles of different users are sorted by upvote within each article page. This feature is a bit like:
    • a Wikipedia where each user can have their own version of each article
    • a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
    This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.
    Figure 1.
    Screenshot of the "Derivative" topic page
    . View it live at: ourbigbook.com/go/topic/derivative
  2. local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:
    This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
    Figure 5. . You can also edit articles on the Web editor without installing anything locally.
    Video 3.
    Edit locally and publish demo
    . Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension.
  3. https://raw.githubusercontent.com/ourbigbook/ourbigbook-media/master/feature/x/hilbert-space-arrow.png
  4. Infinitely deep tables of contents:
    Figure 6.
    Dynamic article tree with infinitely deep table of contents
    .
    Descendant pages can also show up as toplevel e.g.: ourbigbook.com/cirosantilli/chordate-subclade
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
Further documentation can be found at: docs.ourbigbook.com
Feel free to reach our to us for any help or suggestions: docs.ourbigbook.com/#contact