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A wavenumber measures how rapidly a wave phase changes with distance. Two conventions coexist: angular wavenumber counts radians per unit length, while ordinary spatial frequency counts cycles per unit length. For a monochromatic wave with wavelength $\lambda >0$,Here $K\ge 0$ is the magnitude of the angular wavenumber. The symbol $k$ can instead denote a signed one-dimensional angular wavenumber: a factor $e^{ikx}$ has wavelength $2\pi /|k|$ for real $k\ne 0$. Both conventions have dimensions of inverse length; writing $\mathrm{rad}{\mathrm{m}}^{-1}$ or “cycles per metre” exposes the convention. A quoted value in ${\mathrm{m}}^{-1}$ alone does not resolve the factor of $2\pi$. Spectroscopic wavenumber usually uses the cycles-per-length convention.^[ref]

For a real monochromatic plane wave, fix the conventionThe wavevector $\mathbf{k}$ supplies both the spatial wave phase slope and the normal to the wavefronts; its dot product with position makes the wave phase constant on parallel planes. The angular frequency is $\omega =2\pi f$, with $f>0$ the ordinary frequency. Moving a distance $\lambda$ along $\mathbf{k}$ changes the wave phase by $2\pi$. Holding a wave crest's wave phase fixed gives its phase velocity $\omega \mathbf{k}/K^2$ and phase speedIn one dimension the signed phase velocity is $\omega /k$. This identifies a moving pattern; it does not identify the motion of the medium's particles or a wave packet's group velocity.

For the synthetic plane wave below, choose $\lambda =0.40\mathrm{m}$ and $f=5\mathrm{Hz}$. Then $K=5\pi \mathrm{rad}{\mathrm{m}}^{-1}$, ${\nu }_x=2.5$ cycles per metre, $\omega =10\pi \mathrm{rad}{\mathrm{s}}^{-1}$, and $v_p=2\mathrm{m}{\mathrm{s}}^{-1}$. The wave crests are $0.40\mathrm{m}$ apart at one instant; after a quarter oscillation period, each has advanced $0.10\mathrm{m}$. The lower panel retains whole turns of wave phase, making its slope visible instead of reducing it modulo $2\pi$.

A wave period is the time for a monochromatic wave to complete one oscillation. For angular frequency $\omega$, it is $2\pi /|\omega |$. In cascade order-of-magnitude estimates the factor $2\pi$ is normally suppressed, giving a linear interaction time of order $|\omega {|}^{-1}$.

Use the leading nonrelativistic magnetic coupling for an electronic level with total angular momentum operator $\mathbf{J}$, and choose the $z$ axis along a uniform external magnetic field $\mathbf{B}=B\hat{\mathbf{z}}$, $B\ge 0$. Write its magnetic quantum number as $m_J$, so $J_z|J,m_J⟩=\hslash m_J|J,m_J⟩$. There are $2J+1$ possibilities from $-J$ to $J$. With Landé g-factor $g_J$, the first-order shift isHere $e>0$ is the magnitude of the electron electric charge, $m_e$ its mass, $h$ the Planck constant, and ${\mu }_B$ the Bohr magneton. Both $g_J$ and $m_J$ are dimensionless; with $B$ measured in tesla and ${\mu }_B$ in joules per tesla, $\Delta E$ is in joules. The photon frequency shift $\Delta {\nu }_{ul}$ is in hertz, not angular frequency; indices $u,l$ denote upper and lower levels. NIST states this weak-field convention and its orbital/spin assumptions explicitly.^[ref]

The sign follows directly from magnetic dipole potential energy. Within this electronic $J$ multiplet, the projected magnetic dipole moment is $\mathbf{\mu }=-g_J{\mu }_B\mathbf{J}/\hslash$. Therefore $H_Z=-\mathbf{\mu }\cdot \mathbf{B}$ has the displayed positive coefficient. Subtracting the shifts of the two levels and using photon energy $h{\nu }_{ul}=E_u-E_l$ gives the transition formula. For the orbital case, ${\mu }_B/h=e/(4\pi m_e)$ gives the same leading frequency spacing as the classical charged oscillator. This explains the historical sensitivity to charge divided by mass; the quantum state derivation here is modern.

“Weak” compares interaction energies: mixing with neighbouring fine structure levels must be small, so $J$ remains a useful quantum number. The formula keeps the term linear in $B$ and neglects quadratic shifts. It also omits hyperfine structure; if that is resolved and controls the coupling, the appropriate total electronic-plus-nuclear angular momentum and splitting factor must replace $J,g_J$. Weak compared with fine structure does not automatically mean weak compared with hyperfine structure.

For the prescribed sine-mode model $\omega =k\sqrt{c_s^2+\alpha k^2}$, positive small stiffness shifts higher harmonics more strongly. Writing $\eta =\alpha k_1^2/c_s^2$ and $k_2=2k_1$ gives ${\omega }_2/{\omega }_1=2+3\eta +O({\eta }^2)$. At the original fundamental quarter-period, the fundamental displacement changes to first order, but the second-mode cosine is at an extremum and changes only to second order. If the quarter-period is redefined with the shifted fundamental frequency, that fundamental displacement is exactly zero. Comparing profiles requires specifying which clock convention is held fixed.

Use the equal-component Wien bridge with upper-left parallel arm and lower-left series arm. Let $A$ be the left arm junction, $C$ the upper input node, and $V_i$ the upper-minus-lower input electric potential difference. With $u=\omega RC$, the unloaded transfer ratio $H=(V_A-V_C)/V_i$ is the displayed expression. Its band-pass filter magnitude is $[9+(u-u^{-1}{)}^2{]}^{-1/2}$, maximal at $u=1$ with $H=-1/3$. One continuous wave phase is $\varphi =-\pi -\arctan [(u-u^{-1})/3]$, tending from $-\pi /2$ at low positive frequency to $-3\pi /2$ at high frequency. Reversing the measured output polarity multiplies $H$ by $-1$ and shifts its phase by $\pi$ without changing its magnitude.

Wien's displacement law says that the wavelength maximizing the Planck function per unit wavelength, $B_{\lambda }(T)$, moves inversely with absolute temperature:Here $b$ is the Wien displacement constant. Heating an ideal blackbody therefore shifts this peak toward shorter wavelengths, while also increasing its emission at every fixed wavelength. The peak identifies where equal narrow wavelength intervals carry the most power; it is not a single emitted wavelength. Planck's law supplies the full curve, and the Stefan–Boltzmann law supplies its integral.

Specify the spectral coordinate before finding a peak. The frequency form of Wien's displacement law maximizes $B_{\nu }$, which is spectral radiance per unit frequency. Its maximum is not $c/{\lambda }_{\max }$. The frequency and wavelength spectral radiance conversion changes the density as well as the horizontal coordinate; the existing frequency and wavelength peaks of Planck's law give a complementary numerical comparison.

In his 11 December 1911 Nobel lecture, Wilhelm Wien explained the displacement principle through a thought experiment: compress black-body radiation between reflecting moving walls. Work against radiation pressure raises the energy density, while reflection changes each frequency by the Doppler effect. The Second law of thermodynamics connects the resulting spectrum to one at a higher temperature. This determines how the spectrum scales between temperatures, without determining its complete shape. The Wien approximation is a separate, restricted spectral formula.^[ref]

A physicist.^[ref]

Wien's displacement law connects a thermal spectrum's peak position to temperature. Specifying whether the spectrum is expressed per unit wavelength or per unit frequency is essential to stating which peak is meant.

X-rays are high-frequency electromagnetic radiation, conventionally with wavelengths of roughly $0.01$ to $10\mathrm{nm}$. The precise wavelength convention varies with context. Hot accreting gas and energetic electronic processes can emit X-rays, whose short wavelengths make them useful probes of compact objects and electron shells.

For a photon, $E=h\nu =hc/\lambda$, where $h$ is the Planck constant and $c$ is the speed of light. As a calculated example, $\lambda =0.10\mathrm{nm}$ gives $E\simeq 12.4\mathrm{keV}$, using $hc\simeq 1.23984\mathrm{keV}\mathrm{nm}$. The same wavelength can describe different production mechanisms: bremsstrahlung produces a continuous frequency spectrum, whereas Characteristic X-rays arise from discrete electronic changes in chemical atoms. Measuring transmitted X-rays gives radiography; measuring their frequency spectrum gives spectroscopy.

In August 1896, Pieter Zeeman observed broadened sodium spectral lines at Leiden, initially without resolved components. His lecture describes a slit and concave diffraction grating, then compares the broadening with the sodium doublet separation: about one thirtieth, roughly $0.2$ ångström. This supplied a spectral reference scale, not an absolute magnetic field calibration. Later cadmium photographs displayed resolved transverse triplets and axial doublets.^[ref]

The fuller report specifies a concave diffraction grating of ten-foot radius with 14,438 lines per inch, an adjustable slit and a micrometer eyepiece with vertical crosswire. Salt in a flame between electromagnet poles supplied the sodium spectral lines. Repeated switching broadened and restored them. To test changes in flame temperature or vapour density, Pieter Zeeman examined photon absorption through a heated porcelain tube with water-cooled glass windows. The arc lamp was displaced from the magnet and its light redirected by a mirror to avoid disturbing the arc. Rotating a narrower tube made the absorption spectral lines equally broad at different heights; the magnetic field still broadened their whole length.^[ref]

For the axial test, pierced electromagnet poles let the light travel along the magnetic field. A quarter-wave plate and polarizer selected one broadened edge; rotating the analyser by $90^{\circ }$ or reversing the magnet current exchanged the visible edge. The crosswire made its displacement detectable. This tested electromagnetic polarization as well as line width. For its rough estimate the report compared each side's widening with the sodium doublet separation, obtaining about one fortieth, and stated an approximate magnetic field intensity in historical units. These passages give no absolute field-calibration procedure; the inferred charge-to-mass ratio was explicitly a first approximation.^[ref]

Hendrik Antoon Lorentz's charged-oscillator theory connected the observed splitting to moving electric charge. In modern language, a line-position measurement needs a wavelength or frequency calibration and an independent magnetic field calibration before it determines a magnetic dipole moment. Resolving the individual components adds the transition information used in the worked example below.

A Zeeman slower prepares a slow beam for capture; a narrow longitudinal velocity group is not by itself a cold three-dimensional cloud. The historical apparatus measured slowed-beam velocities with a separate fluorescence probe scanned in frequency, just after switching off the slowing beam. This avoided simultaneous-beam complications.^[ref]

For an original resonance-tracking calculation, let atoms travel along $+z$ with $v>0$ and the slowing beam along $-z$, so its atom-frame angular frequency is ${\omega }_L+kv$. Approximate the selected cycling transition by ${\omega }_{eg}(B)={\omega }_0+\zeta B$ on one field branch; $\zeta$ is its signed angular frequency shift per unit magnetic field. A multilevel atom may require a nonlinear ${\omega }_{eg}(B)$ outside that branch. Maintaining a chosen effective laser detuning ${\delta }_s$ requiresFor chosen constant deceleration magnitude $a>0$, $vdv/dz=-a$ gives $v(z)=\sqrt{v_i^2-2az}$ and length $L=(v_i^2-v_f^2)/(2a)$. Substitution supplies a square-root magnetic field profile, plus a constant offset. The signs follow from the specified directions; reversing the selected transition's magnetic slope reverses the required field variation.

As a hypothetical design, take $v_i=300\mathrm{m}{\mathrm{s}}^{-1}$, $v_f=30\mathrm{m}{\mathrm{s}}^{-1}$ and $a=5.0\times 10^4\mathrm{m}{\mathrm{s}}^{-2}$. The required length is $0.891\mathrm{m}$ and flight time $(v_i-v_f)/a=5.4\mathrm{ms}$. For chosen $\lambda =589\mathrm{nm}$ and $m=3.82\times 10^{-26}\mathrm{kg}$, photon recoil velocity $\hslash k/m\simeq 0.0294\mathrm{m}{\mathrm{s}}^{-1}$ implies roughly $9.17\times 10^3$ directed absorption events. The mean required scattering rate is about $1.70\times 10^6{\mathrm{s}}^{-1}$. This budget must lie below the available scattering rate, with margin for capture and intensity variation. Optical pumping into unwanted hyperfine structure or magnetic sublevels can interrupt the cycle. Longitudinal slowing, transverse recoil heating and final cloud temperature are separate quantities.

Zeeman splitting is the separation of energy levels or mode frequencies by a background magnetic field. In atomic physics, the magnetic field couples to a magnetic dipole moment, lifting quantum degeneracy. Transitions between the shifted quantum states can turn one spectral line into several. A split level and a split spectral line are different objects: the emitted photon measures the difference between two level energies, and the electric-dipole selection rule determines which differences appear.

The Stern-Gerlach experiment also probes magnetic dipole moments, through beam deflection in a magnetic field gradient. Here the readout is a spectral line.

The pattern makes an invisible magnetic field visible through spectroscopy. It also reveals angular momentum and magnetic dipole moments inside chemical atoms. Zeeman slowers exploit a changing resonance frequency to keep moving chemical atoms absorbing laser photons; a magneto-optical trap combines position-dependent shifts with electromagnetic polarization and laser cooling. Related mode shifts occur in Zeeman splitting of an antiferromagnetic spin wave.

Zeeman splitting is the separation of energy levels or mode frequencies by a background magnetic field. For an antiferromagnetic spin wave, opposite circular spin polarizations receive opposite frequency shifts.

At zero frequency the graded-layer transfer equation integrates to $\exp [L\left(\begin{array}{cc}0& 1\\ 1& 0\end{array}\right)]$, where $L=\frac{1}{2}\log (Z_b/Z_a)$. Eliminating the outgoing wave amplitude at the left endpoint gives the displayed incoming-to-outgoing scattering matrix. It is real orthogonal, so it preserves total incoming and outgoing flux. It coincides with continuity of velocity and traction at a sharp seismic impedance interface; the profile between the endpoints enters at nonzero frequency.