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Consider an original noninteracting model with three orthonormal spatial orbitals $A,B,C$ at energies $0,\Delta ,3\Delta$, where $\Delta >0$. Both spin projections are available at each energy, so there are six spin orbitals. The Quantum Hamiltonian is $H=h\otimes I+I\otimes h$, with no interaction between particles and no dependence on spin. Comparing its allowed ground states isolates the effect of fermionic exchange symmetry.

For two distinguishable spin-one-half particles, the spatial ground state is $A\otimes A$ and any of four independent two-spin states is possible: $E_0=0$ and ground-state degeneracy four. For two identical electrons, both can still occupy $A$, using $A\uparrow$ and $A\downarrow$, but there is just one allowed ground state: the symmetric spatial factor times the spin-one-half singlet state,Exclusion has reduced the ground-state degeneracy without raising the ground state energy.

Now restrict both particles to the same spin projection $\uparrow$. Distinguishable particles can still both occupy $A\uparrow$, so $E_0=0$. Identical electrons must occupy different spatial orbitals; the lowest choice is $A,B$, withThe spin factor is a spin-one-half triplet state, and the spatial factor is antisymmetric. These are ground states within the restricted parallel-spin sector, not the unrestricted two-electron ground state. Both restricted models have ground-state degeneracy one.

The first excited two-electron energy in the unrestricted model is $\Delta$, with four independent quantum states: one occupant in $A$, one in $B$, and two spin choices for each. A basis adapted to particle exchange operators separates these into one spin-one-half singlet state with symmetric spatial factor and three spin-one-half triplet states with antisymmetric spatial factor. All four have equal energy in this model. Singlet versus triplet does not by itself determine an energy gap; an interaction or a spin-dependent term is needed to split them.

As a further count, the full two-electron space has dimension $\left(\genfrac{}{}{0ex}{}{6}{2}\right)=15$. Its energies in units of $\Delta$ and corresponding multiplicities are $(0,1,2,3,4,6)$ and $(1,4,1,4,4,1)$. For distinguishable spin-one-half particles the ordered tensor product instead has dimension $6^2=36$, with multiplicities $(4,8,4,8,8,4)$ at those same energies. These are exact model counts, not atomic measurements. The higher restricted ground state energy follows from removing forbidden quantum states; the Quantum Hamiltonian contains no additional “exclusion force”.

Physical states of identical particles have definite symmetry under every particle exchange operator: symmetric for bosons and antisymmetric for fermions.

For identical particles, the particle exchange operator exchanges both spatial and spin labels. The symmetrization postulate requires a symmetric full state for bosons and an antisymmetric full state for fermions. A product $\Psi =\varphi \chi$ must therefore have spatial and spin exchange eigenvalues whose product is $+1$ or $-1$, respectively; a general state may be a sum of such products.

For orthonormal spatial orbitals $u,v$, the combinations ${\varphi }_{\pm }=[u(1)v(2)\pm v(1)u(2)]/\sqrt{2}$ have opposite exchange parities. Two spin-one-half fermions combine ${\varphi }_{+}$ with the antisymmetric spin-one-half singlet state $(|\uparrow \downarrow ⟩-|\downarrow \uparrow ⟩)/\sqrt{2}$, or ${\varphi }_{-}$ with one of the three symmetric spin-one-half triplet states. Two particles in the same spatial orbital must be a spin singlet. This is the Pauli exclusion principle applied to complete spin orbitals, not a ban on sharing a spatial orbital with opposite spins.

A Slater determinant enforces fermionic antisymmetry for many occupied spin orbitals. Bosonic symmetrization instead uses a permanent; repeated orbital occupations are allowed. These exchange requirements apply even when particles do not interact.

For identical bosons the full wave function is symmetric under the particle exchange operator:In the given position-only model this is the spatial parity under the particle exchange operator. If additional spin variables are present, the symmetry applies to the complete state including them.

The orthogonal coordinate change preserves the kinetic energy and takes the particle exchange operator to $(x_{+},x_{-})\mapsto (x_{+},-x_{-})$. Thus the spatial wave function is even in $x_{-}$ for bosons and odd for fermions.

The total potential energy and Hamiltonian separate asAssume $1+2\kappa >0$ so the relative oscillator is confining. Its spectrum is $E_{n_{+},n_{-}}=\hslash \omega (n_{+}+1/2)+\hslash \Omega (n_{-}+1/2)$, and its parity in the two-particle relative coordinate is $(-1{)}^{n_{-}}$.

The lowest boson state uses $n_{+}=n_{-}=0$, whereas the lowest fermion state uses $n_{+}=0$, $n_{-}=1$. ThereforeFor an oscillator of frequency $\Omega$, $⟨x_{-}^2{⟩}_n=(n+1/2)\hslash /(m\Omega )$. Since $(x_1-x_2{)}^2=2x_{-}^2$,The factor three is the extra relative-coordinate excitation required by antisymmetry. The supplied oscillator wave functions correspond to kinetic energy $P^2/(2m)$; the extra factor $1/2$ printed before that term in the hint is inconsistent with those functions and the stated energies. The calculation uses the conventional kinetic energy dictated by particle mass $m$.

For the real scalar field, the mostly-plus Minkowski metric gives a positive kinetic energy. Its canonical momentum and Hamiltonian operator areThe Euler-Lagrange field equation is $(\square -m^2)\varphi =0$, or $({\partial }_t^2-{\nabla }^2+m^2)\varphi =0$. Canonical quantization of a real scalar field promotes the fields to Hermitian operators and replaces the equal-time Poisson brackets by canonical commutation relations:The Heisenberg equation of motion then gives $\dot{\varphi }=\pi$ and $\dot{\pi }={\nabla }^2\varphi -m^2\varphi$, so the classical field equation remains an operator identity. Products at coincident points need a regulator; equivalently, the field is an operator-valued distribution.

Resolve the free field into positive- and negative-frequency plane waves. With $E_{\mathbf{k}}=\sqrt{|\mathbf{k}{|}^2+m^2}$ and $k\cdot x=-E_{\mathbf{k}}t+\mathbf{k}\cdot \mathbf{x}$,Reality pairs the two terms by Hermitian conjugation. The equal-time canonical commutation relations are equivalent toFor example, the two mixed terms in $[\varphi ,\pi ]$ each supply half the Dirac delta function. Thus the normalization $1/\sqrt{2E_{\mathbf{k}}}$ is fixed, not optional. Each independent mode is a quantum harmonic oscillator, with $a$ and $a^{†}$ its annihilation operator and creation operator.

Choose the Fock vacuum by $a(\mathbf{k})|0⟩=0$. Repeated creation operators construct the bosonic Fock space. Substitution into the Hamiltonian operator yieldswhere a finite volume $V$ can be used as a regulator. Normal ordering sets the flat-space vacuum reference to zero. The spatial momentum operator isIn particular, $[H,a^{†}(\mathbf{k})]=E_{\mathbf{k}}{a}^{†}(\mathbf{k})$ and $[\mathbf{P},a^{†}(\mathbf{k})]=\mathbf{k}{a}^{†}(\mathbf{k})$. A one-particle state therefore has positive energy, momentum $\mathbf{k}$, and invariant mass $m$. A scalar field transforms in the trivial spin representation, so its particles have spin zero. Because the field is real there is only one set of oscillators: the particle is its own antiparticle, with no distinct conserved particle-minus-antiparticle charge. The free theory does conserve its occupation-number sum, though generic scalar interactions need not.

A momentum eigenstate extends throughout space. A localized particle is described by a superposition such asIts wave packet evolves through the phase $e^{-i{E}_{\mathbf{k}}t}$; a narrow packet has group velocity $\mathbf{v}=\mathbf{k}/E_{\mathbf{k}}$, whose magnitude is at most one. Localization and dispersion concern these superpositions, rather than classical trajectories attached to individual field modes.

Relativistic spacetime behavior is encoded by microcausality. Directly from the oscillator commutators,This is a Lorentz-invariant distribution and vanishes at equal time. Any spacelike separation can be transformed to an equal-time separation, so $[\varphi (x),\varphi (y)]=0$ for spacelike $x-y$. Thus local operations at spacelike-separated points commute. The vacuum Wightman function need not vanish outside the light cone, but that correlation does not transmit a controllable signal. The Feynman propagator iswhich propagates positive energy forward and negative energy backward in the time-ordered product. For causal response one uses the retarded Green function, whose support lies in or on the future light cone.

Finally, commuting creation operators implyThe multiparticle state is symmetric under the particle exchange operator, which is Bose statistics. For a normalized single mode, the occupation states are $(a^{†}{)}^n|0⟩/\sqrt{n!}$ with $n=0,1,2,\dots$: any number of identical bosons can occupy it. There is no Pauli exclusion principle for these particles. This construction agrees with the Spin-statistics theorem relating integer spin to bosonic exchange symmetry under relativistic locality and positive-energy assumptions. It demonstrates the required scalar case without assuming that theorem as the quantization prescription.

For distinguishable particles with one-particle Hilbert spaces ${\mathcal{H}}_1,\dots ,{\mathcal{H}}_N$, the multiparticle quantum state belongs toA product of one-particle states gives a product vector, and arbitrary linear combinations give entangled states. A noninteracting Hamiltonian is the sum of one-particle Hamiltonians acting on their respective tensor factors, so product-state energies add.

For two identical particles, the particle exchange operator $P_{12}$ swaps every degree of freedom. Since $P_{12}^2=I$, its eigenvalues are $\pm 1$. Particles whose allowed total states satisfyare bosons, while those satisfyingare fermions. Thus bosonic states are symmetric and fermionic states antisymmetric under interchange. The same condition applies to every transposition in a system of more than two identical particles.

identical particles have the same intrinsic properties. Exchanging their bookkeeping labels cannot distinguish a physical preparation or change a measurable prediction. This is stronger than merely failing to track classical trajectories. For ordinary bosons and fermions, the many-particle wavefunction has respectively bosonic exchange symmetry or fermionic exchange symmetry under every particle exchange operator, acting on spatial and spin coordinates together. The Spin-statistics theorem connects integer spin to bosons and half-integer spin to fermions; this connection uses relativistic quantum-field assumptions, rather than following from the nonrelativistic Schrödinger equation alone.

For one-particle states $u,v$ satisfying orthonormality, the two alternatives form a quantum superposition:Its probability density contains an exchange interference term, absent from an incoherent mixture of labelled alternatives. The antisymmetric expression vanishes when both one-particle states are identical: one complete one-particle state can contain at most one fermion. This Pauli exclusion principle explains electron shell filling, the electronic Fermi sea and degeneracy pressure. Opposite spins are different one-particle states, so two electrons may share an atomic orbital. Spatially separated wave packets with negligible overlap can often be treated as distinguishable for local measurements; the underlying exchange symmetry remains.

In thermal equilibrium, occupation of a level of energy $ϵ$ obeysbosons can accumulate macroscopically in one state, giving Bose-Einstein condensation; fermions instead fill successive states up to the Fermi energy at zero temperature. When occupation is dilute, both expressions reduce to the Maxwell-Boltzmann distribution. The identical-particle classical partition function contains $1/N!$, avoiding spurious entropy from permutations and the Gibbs paradox. Exchange effects become conspicuous when the thermal de Broglie wavelength is comparable to the interparticle spacing.

An operational test is the Hong-Ou-Mandel effect. Down-converted photon pairs enter separate ports of a balanced beam splitter; indistinguishable alternatives for one photon per output cancel. Scanning the relative arrival delay restores coincidences away from overlap. Matching polarization, spectral filtering and spatial alignment controls distinguishability; measuring delayed accidental coincidences controls background. The observed dip tests two-photon interference, and its finite depth must not automatically be interpreted as a failure of bosonic symmetry. The original apparatus varied beam-splitter position and subtracted a separately measured accidental background.^[ref]

Addition of two spin-one-half angular momenta gives total spin $S=0$ or $S=1$. The normalized singlet state and triplet states areThey have $S^2$ eigenvalues $0$ and $2{\hslash }^2$, and $S_z=M\hslash$. The singlet state is antisymmetric under a particle exchange operator, whereas all three triplets have symmetric spin-exchange parity. For two identical electrons the full state must be antisymmetric: a singlet state pairs with a spatial state with symmetric exchange parity, a triplet state with an antisymmetric spatial state. Thus two electrons in the same atomic orbital must form a singlet state.

The identity ${\mathbf{S}}_1\cdot {\mathbf{S}}_2=(S^2-S_1^2-S_2^2)/2$ gives $-3{\hslash }^2/4$ in the singlet state and $+{\hslash }^2/4$ in the triplet state. Hence an exchange interaction distinguishes their energies, with ordering determined by its coupling sign. The singlet state has perfect opposite-spin correlations along any common measurement axis and is entangled. The $M=0$ triplet state is also entangled, while the $M=\pm 1$ triplet states are product states along the chosen axis.

For identical bosons the full wave function is symmetric under the particle exchange operator:In the given position-only model this is the spatial parity under the particle exchange operator. If additional spin variables are present, the symmetry applies to the complete state including them.

The orthogonal coordinate change preserves the kinetic energy and takes the particle exchange operator to $(x_{+},x_{-})\mapsto (x_{+},-x_{-})$. Thus the spatial wave function is even in $x_{-}$ for bosons and odd for fermions.

The total potential energy and Hamiltonian separate asAssume $1+2\kappa >0$ so the relative oscillator is confining. Its spectrum is $E_{n_{+},n_{-}}=\hslash \omega (n_{+}+1/2)+\hslash \Omega (n_{-}+1/2)$, and its parity in the two-particle relative coordinate is $(-1{)}^{n_{-}}$.

The lowest boson state uses $n_{+}=n_{-}=0$, whereas the lowest fermion state uses $n_{+}=0$, $n_{-}=1$. ThereforeFor an oscillator of frequency $\Omega$, $⟨x_{-}^2{⟩}_n=(n+1/2)\hslash /(m\Omega )$. Since $(x_1-x_2{)}^2=2x_{-}^2$,The factor three is the extra relative-coordinate excitation required by antisymmetry. The supplied oscillator wave functions correspond to kinetic energy $P^2/(2m)$; the extra factor $1/2$ printed before that term in the hint is inconsistent with those functions and the stated energies. The calculation uses the conventional kinetic energy dictated by particle mass $m$.

Expanding the total angular momentum and replacing transverse components by ladder operators givesThe particle exchange operator obeys $P_{12}^2=I$ and $P_{12}{s}_{1\alpha }{P}_{12}=s_{2\alpha }$, with the reverse relation for index $2$. These statements also apply to the ladder operators. Exchanging the indices preserves $s_1^2+s_2^2$ and $s_{1z}+s_{2z}$; it interchanges the last two terms in $S^2$. Operators on different tensor factors commute. HenceThe full particle exchange includes the spin coordinates as well as the spatial coordinates.

Spin isomers of hydrogen are two forms of molecular hydrogen, ${}^1{\mathrm{H}}_2$, distinguished by the combined nuclear spin of their two protons. They have the same chemical formula and electronic ground state, but different allowed molecular rotation states. Parahydrogen has total nuclear spin zero and even rotational quantum number $J$; orthohydrogen has total nuclear spin one and odd $J$. The difference makes heat capacity a probe of fermionic exchange symmetry, and makes cooling history matter for a tank of molecular hydrogen.

Assume the electronic ground state $X{}^1{\Sigma }_g^{+}$ and the vibrational ground state of a free molecule. The electronic factor is symmetric under exchanging the two protons, and the vibrational factor depends only on their separation, so it is also symmetric. These assumptions concern the exchange of protons; the electronic wavefunction separately obeys fermionic exchange symmetry under exchange of electrons. Neglect electronic excitation, vibrational excitation, external fields, and small interactions involving nuclear spin when calculating rotational energy eigenvalues.

The two protons are identical particles with spin $1/2$. Their complete wavefunction must change sign under their particle exchange operator. Interchanging the two ends reverses the internuclear direction $\hat{\mathbf{r}}$, and the spherical harmonic rotational factor satisfiesThe antisymmetric spin-one-half singlet state therefore requires symmetric, even-$J$ rotation; the symmetric spin-one-half triplet state requires antisymmetric, odd-$J$ rotation. This is exchange symmetry of two identical spin-one-half fermions applied inside a diatomic molecule, not an extra rotational force. A linear rigid rotor may omit spin-dependent splittings while still requiring this restriction on its allowed quantum states.

The particle exchange operator $P_{12}$ swaps the complete particle slots, including spin. Its antisymmetric projector is $A_{12}=(I-P_{12})/2$. For orthonormal one-particle states $u,v$, the normalized multiparticle quantum state isBut attempting the same construction with $v=u$ gives the zero vector:The zero vector cannot be normalized to a quantum state. This is exclusion as cancellation of probability amplitudes, rather than a repulsive force. More generally, for normalized $u,v$ the squared norm of the numerator divided by $\sqrt{2}$ is $1-|⟨u|v⟩{|}^2$; the expression has unit norm only when $u,v$ are orthogonal. An overall quantum phase difference between $u,v$ describes the same one-particle state and also gives zero. Pauli explicitly connects exclusion with a vanishing antisymmetric wavefunction.^[ref]