At fixed volume, entropy from heat capacity obeys . The Third law of thermodynamics fixes when the ground state is nondegenerate, so below the transition
Above the transition,
For a transition with no latent heat, entropy is continuous, and comparison with gives the directly testable relation
Thus calorimetric measurements of and verify . More generally, if a measurable latent heat is present, , and the formula becomes
For , the preceding density of states has
When , the Bose-Einstein distribution has the classical approximation
Each of the modes therefore contributes to the energy, so the Dulong-Petit law gives
When , the upper integration limit tends to infinity. The Bose integral
then yields
Hence the heat capacity at constant volume is
so . The high-temperature constant is the classical equipartition theorem result, while the low-temperature power law makes as required by the Third law of thermodynamics.