For a classical dilute ideal gas in thermal equilibrium, the probability of a single-particle velocity is proportional to the Boltzmann factor for kinetic energy, $e^{-m{v}^2/(2k_{B}T)}$. Velocities with speed between $v$ and $v+dv$ fill a spherical shell of velocity-space volume $4\pi v^{2}dv$. The normalized Maxwell speed distribution is thereforeThe factor $v^2$ counts states, rather than representing an extra Boltzmann energy factor.

Set $\alpha =m/(2k_{B}T)$ and use $I_j={\int }_0^{\infty }{v}^j{e}^{-\alpha v^2}dv$. Normalization cancels in ratios, so the given recurrence givesConsequentlyThe root mean square speed is larger than the mean speed, consistent with the positive variance of the speed distribution.

A Carnot cycle consists of four reversible stages: isothermal expansion at the hot-reservoir temperature $T_h$, adiabatic expansion to $T_c$, isothermal compression at $T_c$, and adiabatic compression back to the starting state. The adiabatic stages exchange no heat. For one mole of an ideal gas, the two isothermal stages have heats $Q_h=R{T}_h\ln (V_B/V_A)$ and $Q_c=R{T}_c\ln (V_C/V_D)$ in magnitude. The reversible adiabatic relations ensure $V_B/V_A=V_C/V_D$.

More generally, the total entropy change over any reversible cycle is zero. The two heat exchanges therefore satisfyWith work output $W=Q_h-Q_c$, its thermal efficiency isThe temperatures must be absolute. The second law makes this the maximum efficiency for an engine exchanging heat only with those two reservoirs; irreversible entropy production lowers the efficiency.

Following the moving fluid. The Eulerian velocity field $\mathbf{u}(\mathbf{x},t)$ assigns a velocity to each position. A fluid particle satisfies $\dot{\mathbf{x}}=\mathbf{u}$, so the chain rule gives the material derivative, also called the convective derivative,Even in steady flow a particle can accelerate because it moves between regions with different velocity. For example, flow around a curved obstacle changes direction despite ${\partial }_t\mathbf{u}=0$. Mass conservation isFor a constant-density incompressible fluid, $\nabla \cdot \mathbf{u}=0$.

Euler equations for an inviscid fluid and Bernoulli's equation. Neglect viscosity and take the body force per unit mass to be $-\nabla \Phi$. Newton's second law for a fluid element givesFor steady flow, dot with displacement along a streamline. The tangential component of $\mathbf{u}\cdot \nabla \mathbf{u}$ is the derivative of $u^2/2$ along that line. For constant density, integration givesIn uniform gravity, $\Phi =gz$. Thus pressure, kinetic energy per unit mass and gravitational potential energy per unit mass exchange along a streamline. For a barotropic compressible fluid, replace $p/\rho$ by $\int dp/\rho (p)$. Different streamlines need not have the same Bernoulli constant.

Vorticity and potential flow. Vorticity is $\mathbf{\omega }=\nabla \times \mathbf{u}$. A small fluid element rotates locally with angular velocity $\mathbf{\omega }/2$ after its deformational part is separated. The vector identitygives $\nabla B=\mathbf{u}\times \mathbf{\omega }$ for steady constant-density inviscid flow. Thus an irrotational region has one common Bernoulli constant on each connected region. In a simply connected irrotational domain, introduce a velocity potential $\mathbf{u}=\nabla \varphi$. Incompressibility then gives Laplace's equation, ${\nabla }^2\varphi =0$. For unsteady irrotational flow,An impermeable stationary wall fixes ${\partial }_n\varphi =0$, but ideal potential flow does not enforce no slip. In a multiply connected domain, irrotational flow may still have nonzero circulation around an excluded vortex core, so a globally single-valued potential requires care.

For example, uniform two-dimensional flow past a circular cylinder has $\varphi =U(r+a^2/r)\cos \theta$ outside $r=a$. Its normal velocity vanishes at the cylinder, and its surface tangential velocity is $-2U\sin \theta$. Bernoulli's equation predicts a symmetric pressure distribution and zero drag. This is D'Alembert's paradox: the assumptions omit the viscous boundary layers, separation and wake responsible for real drag.

For an incompressible fluid of constant kinematic viscosity $\nu$, the curl of the motion equation givesThe first term stretches and tilts vortex lines; the second diffuses vorticity. In two-dimensional incompressible inviscid flow the stretching term is absent and vorticity is carried with the fluid. In a three-dimensional inviscid flow it can be amplified by stretching. Density gradients not parallel to pressure gradients provide an additional source in a general compressible fluid.

Viscous flow. A Newtonian fluid's shear stress is proportional to rate of strain. For constant viscosity and incompressibility the Navier-Stokes equation iswith dynamic viscosity $\eta$ and kinematic viscosity $\nu =\eta /\rho$. At an ordinary solid wall, the no-slip boundary condition sets fluid velocity equal to the wall velocity. Viscosity transfers momentum between neighbouring layers and converts mechanical energy into heat; unlike the pressure force, its shear contribution depends on velocity gradients.

For plane Couette flow between plates $y=0,h$, with the upper plate moving at $U$, the steady solution is $u_x=Uy/h$, with shear stress $\eta U/h$. For pressure-driven flow through a pipe of radius $a$, a constant pressure gradient gives the parabolic Poiseuille profileThe Reynolds number $\mathrm{Re}=\rho UL/\eta$ compares convective inertia with viscous force. Small Reynolds number often permits the Stokes-flow approximation; large Reynolds number can produce thin boundary layers and, under suitable conditions, turbulence. It does not justify neglecting the wall conditions. Bernoulli's inviscid constant is generally not conserved along a viscous streamline, and pipe flow instead shows a pressure loss corresponding to dissipation.