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Radiometry measures the energy and power carried by electromagnetic radiation, including light. It asks how much radiation a source supplies, where it travels, and how much reaches a receiving surface. The measurements are physical rather than weighted by the sensitivity of the human eye: equal radiant fluxes at different wavelengths need not look equally bright. ^[ref].

The five quantities below answer different questions about the same radiation. The International System of Units makes the distinctions visible: a watt is a joule per second, while a steradian measures solid angle. ^[ref].

Resolving wavelength or frequency adds a further “per unit interval”, as in spectral radiance. The notation is consistent with NIST's table of spectral quantities. In particular, radiant flux is power, whereas the existing astronomical radiative flux is power per area. ^[ref].

This bookkeeping makes an optical camera's collected signal calculable from a source's radiance and the geometry of the receiving aperture. It also lets radiation measurements from different instruments be compared. For example, NIST describes separate calibrations of spectral radiance and spectral irradiance for instruments used to observe Earth. ^[ref].

A radio wave is electromagnetic radiation in the radio portion of the frequency spectrum. In vacuum its frequency and wavelength obey the vacuum frequency-wavelength relation.

Rayleigh scattering is elastic scattering of electromagnetic radiation by particles much smaller than the incident wavelength. In the stationary particle approximation, the scattered electromagnetic radiation keeps the incident frequency: its direction changes, rather than its color. The incident electric field induces an oscillating electric dipole moment, which produces electric dipole radiation. This is a useful example of how a microscopic response can explain a familiar large-scale sight, why the sky is blue. ^[ref].

The smallness condition for Rayleigh scattering by a small sphere of radius $a$ is $ka\ll 1$, where the wavenumber is $k=2\pi /\lambda$ and $\lambda$ is the surrounding medium's wavelength. For ordinary materials with modest refractive index, the incident electric field then varies little across the particle, making the electric-dipole approximation for radiation useful. For very large refractive index, also check the internal size $|m|ka\ll 1$ before applying the simple electric dipole model. Once these conditions fail, use Mie scattering for a sphere instead of extrapolating the Rayleigh scattering wavelength dependence.

Historically, the 1871 paper ^[ref] connected the color and polarization of an electromagnetic wave of scattered skylight with particles smaller than the wavelength. Its dimensional analysis anticipates scattered light intensity proportional to particle volume squared and to ${\lambda }^{-4}$. The original mechanical picture is historical; the modern explanation uses induced electric dipole radiation.

Consider a fixed, homogeneous, nonabsorbing, nonmagnetic sphere of radius $a$ in vacuum. Let $m$ be its relative refractive index, a fixed real number; in vacuum this equals the sphere's refractive index. Treat $m$ as independent of wavelength over the range being compared, neglecting optical dispersion. Air can be approximated by vacuum here because its refractive index is close to one. These assumptions describe a toy particle, rather than a literal model of an individual air molecule.

The Rayleigh scattering cross-section $\sigma$ is an effective area: the total scattered power is $P_{\mathrm{sca}}=I_{\mathrm{inc}}\sigma$, where $I_{\mathrm{inc}}$ is the incident light intensity. For $ka\ll 1$ its leading approximation isThe units are area, since $k^4{a}^6$ has units ${\mathrm{m}}^{-4}{\mathrm{m}}^6={\mathrm{m}}^2$. This Rayleigh scattering cross-section measures scattering, not conversion of the incident electromagnetic radiation into heat. The definition follows ^[ref].

To see the mechanism, the nearly uniform applied electric field produces an electric dipole moment with peak magnitudewhere $E_0$ is the incident electric field peak wave amplitude and ${ϵ}_0$ is vacuum permittivity. This is the sphere's response in electrostatics, with its permittivity divided by vacuum permittivity equal to $m^2$ under the nonmagnetic assumption. ^[ref]. The averaged electric dipole radiation power is $P_{\mathrm{sca}}={\omega }^4{p}_0^2/(12\pi {ϵ}_0{c}^3)$, with angular frequency $\omega =ck$ and speed of light $c$. Dividing by $I_{\mathrm{inc}}={ϵ}_{0}c{E}_0^2/2$ gives the displayed Rayleigh scattering cross-section. Thus doubling radius multiplies the electric dipole moment by eight and the scattered power by $64$, provided the larger sphere still satisfies $ka\ll 1$. ^[ref].

A spectroscopic wavenumber commonly means the reciprocal of the vacuum wavelength ${\lambda }_0$ of electromagnetic radiation, often in $\mathrm{c}{\mathrm{m}}^{-1}$. It is an ordinary spatial frequency, so the vacuum angular wavenumber is $K_0=2\pi \tilde{\nu }$. Specify vacuum or in-medium wavelength: the same frequency can have different wavelengths in different media. IUPAC's “wavenumber in medium” entry defines the in-medium reciprocal $1/\lambda$ and notes that unqualified spectroscopic usage often means the vacuum reciprocal.^[ref]

For example, a vacuum wavelength of $500\mathrm{nm}=5\times 10^{-5}\mathrm{cm}$ corresponds to $\tilde{\nu }=20000\mathrm{c}{\mathrm{m}}^{-1}=2\times 10^6{\mathrm{m}}^{-1}$. Multiplication by $2\pi$ gives $K_0=4\pi \times 10^6\mathrm{rad}{\mathrm{m}}^{-1}$. Converting centimetres to metres and converting cycles to radians are separate operations.

Thermal radiation is electromagnetic radiation emitted by matter because of its temperature. Matter in thermal equilibrium emits a spectrum governed by its absorptivity, approaching the Planck law for a blackbody.

Ultraviolet is electromagnetic radiation with wavelengths shorter than the violet end of ordinarily visible light. The CIE convention uses $100$–$400\mathrm{nm}$, subdivided into UV-A at $315$–$400\mathrm{nm}$, UV-B at $280$–$315\mathrm{nm}$ and UV-C at $100$–$280\mathrm{nm}$. These divisions name intervals; they do not mark universal changes in every material's response. The boundary with visible light is not sharp, and other fields use near-, far-, vacuum- and extreme-ultraviolet divisions. ^[ref]. For example, NASA's Solar Dynamics Observatory observes extreme-ultraviolet bands below $100\mathrm{nm}$; the CIE interval is therefore not the full extent of astronomical ultraviolet usage. ^[ref].

The CIE ultraviolet interval corresponds to frequencies about $7.49\times 10^{14}$–$3.00\times 10^{15}\mathrm{Hz}$ and photon energies $4.97\times 10^{-19}$–$1.99\times 10^{-18}\mathrm{J}$, using vacuum wavelength and $E=hc/\lambda$ with Planck constant $h$ and speed of light $c$. Shorter wavelength means larger energy per photon; larger irradiance means more incident power per area. These are different comparisons. At the same incident power, a $254\mathrm{nm}$ ultraviolet beam has fewer photons per second than a $940\mathrm{nm}$ infrared beam, even though each ultraviolet photon has more energy.

A common ultraviolet mechanism is photon absorption promoting an Electron from a ground state to an excited state of a chemical atom or molecule. By contrast, many infrared absorption bands involve stretching or bending chemical bonds. For either mechanism, both the energy difference and the coupling to the incident electromagnetic field matter. One concrete example is the $217\mathrm{nm}$ absorption discussed for butadiene: an Electron moves between molecular orbitals, and the position of the absorption reveals their energy separation. Ultraviolet absorption can therefore probe molecular orbitals, while infrared spectroscopy probes many molecular motions. ^[ref].

Subsequent chemical reactions depend on the absorbing chemical substance and its environment; the label ultraviolet alone does not predict a reaction rate. At sufficiently short wavelength, a photon can cause photoionization if its energy exceeds the relevant ionization energy. There is no single wavelength that separates all ionizing from all nonionizing behavior for every chemical substance. Likewise, eventual heating after photon absorption is possible in both ultraviolet and infrared. The distinction is useful because different optical spectra expose different processes, not because the two ranges obey different laws of electromagnetism.

Ritter's 1801 observation used a chemical readout rather than a thermometer. In Caltech/IPAC's account, sunlight passed through a glass optical prism and silver chloride was placed in different parts of the optical spectrum. Darkening was weak toward red, stronger toward violet, and pronounced beyond the visible violet edge. The measured evidence was a change in the chemical substance's appearance at a spatial location with no visible color, establishing radiation beyond the eye's ordinary range. It was not a calibrated measurement of a universal ultraviolet optical spectrum. ^[ref].

A controlled modern interpretation of such a chemical test would compare equal exposure durations and matched fresh samples, keep an unexposed sample in darkness, monitor temperature, and distinguish scattered visible light from the intended short-wavelength beam with characterized filtering. These are proposed controls, not an assertion that Ritter performed them. Unequal sample preparation or heating can change a reaction rate. The optical prism, terrestrial atmosphere and sample response restrict which wavelengths the test detects. Darkening is a detector-weighted response, so its spatial maximum is not automatically the maximum of incoming radiant flux or of photon energy.

Thomas Larason and Jeanne Houston's NIST report documents a quantitative ultraviolet detector comparison. An argon source feeds a double-diffraction grating spectrometer; a shutter and mirrors deliver the selected band to a working-standard or test photodiode, successively at the same position. A beam splitter supplies a monitor photodiode. Amplifiers and voltmeters record detector and monitor simultaneously; shutter-closed readings provide dark baselines. The $200$–$500\mathrm{nm}$ scan, typically with $4\mathrm{nm}$ bandpass, measures spectral responsivity. Monitor normalization suppresses source drift; known spectral lines calibrate wavelength. The report assesses temperature effects and unwanted light outside the band, weighted by detector response. The latter need not cancel between different spectral responsivities. ^[ref].

This determines electrical response without visual perception. Bandpass and spatial nonuniformity limit the calibration; aging and changed temperature can affect later use. The scan includes visible light and ultraviolet; no response below $200\mathrm{nm}$ follows from it.

For a narrow beam, the idealized substitution calculation isHere $R$ is spectral responsivity; $I$ and $M$ are dark-subtracted detector and monitor electric currents. This follows by writing $I=RP$ for each detector and using the monitor to track changes in radiant flux. It assumes linear response, unchanged beam splitting and collection geometry, and a sufficiently narrow band. For an illustrative standard with $R_{\mathrm{std}}=0.15\mathrm{A}{\mathrm{W}}^{-1}$, ratios $I_{\mathrm{std}}/M_{\mathrm{std}}=2.0$ and $I_{\mathrm{test}}/M_{\mathrm{test}}=1.6$ give $R_{\mathrm{test}}=0.12\mathrm{A}{\mathrm{W}}^{-1}$. These invented arithmetic inputs illustrate the method; they are not NIST measurements.

An independent photon-counting model connects spectral responsivity to quantum efficiency. If $\eta (\lambda )$ is the number of collected Electrons per incident photon, there is no internal multiplication, and $q$ is the elementary charge, thenAt illustrative constant $\eta =0.60$ and $P=1\mu \mathrm{W}$, this gives about $0.123\mu \mathrm{A}$ at $254\mathrm{nm}$ and $0.455\mu \mathrm{A}$ at $940\mathrm{nm}$. The ultraviolet readout is smaller in this model because there are fewer incident photons, not because their individual energies are smaller. Real quantum efficiency depends on wavelength, windows, absorption and carrier collection; a detector's band gap and construction determine its usable range. Constant $\eta$ across these two wavelengths is an analytical comparison, not a claimed specification of a real photodiode.

The curve is the calculated relation $E=hc/\lambda$, and the shaded ranges use the stated CIE conventions. The lower diagram abstracts the detector comparison rather than reproducing an instrument drawing. Together with the infrared heat-balance illustration, it shows why a calibrated detector response, rather than what looks bright to an observer, is the bridge between invisible radiation and a quantitative measurement.

The wavelength $\lambda$ is the spatial period of a monochromatic wave, measured at a fixed time along the wavevector. For a plane wave with a sinusoid as its profile, it is the distance between consecutive wave crests, or between any consecutive points with the same wave phase modulo $2\pi$:Here $\mathbf{k}$ uses angular wavenumber, $f$ is ordinary frequency, and $v_p$ is phase speed. A distance between arbitrary zero crossings need not be a wavelength: consecutive zeros of a sinusoid are only $\lambda /2$ apart, with opposite slopes. In a standing wave, consecutive nodes of a standing wave are also $\lambda /2$ apart; $\lambda$ refers to the constituent travelling waves, even though the nodes of a standing wave do not travel.

Across a stationary interface between stationary linear media, the incident, reflected and transmitted monochromatic waves have the same frequency. The boundary conditions must hold at every time: terms oscillating with different angular frequencies cannot cancel throughout the entire time record. Each medium's dispersion relation then determines its own angular wavenumber and wavelength, soFor electromagnetic radiation in a transparent medium with refractive index $n$, $v_p=c_0/n$ and $\lambda ={\lambda }_0/n$, where $c_0$ is the vacuum speed of light. A synthetic example with ${\lambda }_0=600\mathrm{nm}$ and $n=1.5$ gives $\lambda =400\mathrm{nm}$ at the same frequency. This conservation argument assumes time-independent linear material response and a stationary interface in the chosen frame. A moving interface can produce a Doppler effect; time-dependent or nonlinear response can change or generate frequencies.^[ref]

A broad frequency spectrum generally supplies many component wavelengths, rather than one wavelength for an entire pulse. Even two tones have both their individual wavelengths and a different overall repetition distance: the $2$- and $8$-cycle-per-metre sum in spatial sampling of a wave repeats after $0.50\mathrm{m}$, but contains the finer $0.125\mathrm{m}$ structure. A narrow wave packet can have an approximate carrier wavelength; the wave envelope propagates approximately at group velocity, determined by the slope of the dispersion relation. Substituting that group velocity into $\lambda =v_p/f$ generally gives the wrong carrier wavelength. Where the medium varies slowly, local wavelength gives a more useful description.

X-rays are high-frequency electromagnetic radiation, conventionally with wavelengths of roughly $0.01$ to $10\mathrm{nm}$. The precise wavelength convention varies with context. Hot accreting gas and energetic electronic processes can emit X-rays, whose short wavelengths make them useful probes of compact objects and atomic structure.