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For emission take integers $n_i>n_f\ge 1$. Applying conservation of energy to the model's internal energy difference, while neglecting the much smaller whole-atom photon recoil, givesThus Johannes Robert Rydberg's Rydberg formula is a difference of two energy levels expressed as a spectroscopic wavenumber. The same constants determine every line; there is no new parameter for each electronic transition. With the chosen inputs, $R_H=1.096775834\times 10^7{\mathrm{m}}^{-1}$. All wavelengths below are calculated in vacuum, not air, and are rounded model predictions rather than historical measurements.

The conventional names commemorate Theodore Lyman and Johann Jakob Balmer. Fixing $n_f=1$ produces the ultraviolet Lyman series, beginning with the Lyman-alpha line; fixing $n_f=2$ produces the Balmer series. As $n_i\to \infty$, the wavelength approaches $n_f^2/R_H$: $91.1763\mathrm{nm}$ at the Lyman limit and $364.705\mathrm{nm}$ for the Balmer series. Crowding follows directly from $E_{n+1}-E_n\sim 2B_H/n^3$. Discreteness therefore coexists with a series limit.

Correct line positions do not give wave intensities, lifetimes or electric-dipole selection rules for hydrogen. Those require a theory of the wavefunctions and their coupling to electromagnetic radiation. The circular model also omits spin, relativistic corrections and the Lamb shift. Its successful gross energy levels do not make its assumed orbits modern atomic orbitals.

An ice floe is a connected floating piece of sea ice. Its diameter relative to wavelength and its thickness affect the reflection, transmission and dissipation of surface gravity waves.

Insert a transverse plane wave $\mathbf{u}={\mathbf{u}}_0{e}^{i(\mathbf{k}\cdot \mathbf{r}-\omega t)}$ into the inertial-wave vorticity equation, with $\mathbf{k}\cdot {\mathbf{u}}_0=0$. It gives $\omega \mathbf{k}\times {\mathbf{u}}_0=2i(\mathbf{\Omega }\cdot \mathbf{k}){\mathbf{u}}_0$. Applying $\mathbf{k}\times$ again and using transversality gives the title dispersion relation. If $\theta$ is the angle to the rotation axis, $|\omega |=2|\Omega \cos \theta |$. At fixed direction the angular frequency does not depend on wavelength. Parallel wavevectors give the maximum $2|\Omega |$; perpendicular ones have zero frequency and belong to the nonoscillating balanced limit.

Infrared is electromagnetic radiation with wavelengths longer than the red end of ordinarily visible light. A useful named convention is the CIE range $780\mathrm{nm}$ to $1\mathrm{mm}$; the approximate visible range $400$–$700\mathrm{nm}$ used in some teaching texts puts the boundary nearer $700\mathrm{nm}$. ^[ref]. Neither number is a sharp physical cutoff of human vision. The CIE divisions IR-A, IR-B and IR-C are respectively $0.78$–$1.4\mu \mathrm{m}$, $1.4$–$3\mu \mathrm{m}$ and $3$–$1000\mu \mathrm{m}$; the boundaries of near-, middle- and far-infrared vary between applications. ^[ref].

Use vacuum wavelength $\lambda$ when comparing these ranges. With frequency $\nu$, speed of light $c$, Planck constant $h$ and photon energy $E$,Thus the CIE infrared interval corresponds approximately to $3.00\times 10^{11}$–$3.84\times 10^{14}\mathrm{Hz}$ and $1.99\times 10^{-22}$–$2.55\times 10^{-19}\mathrm{J}$ per photon, with the smaller energy at the longer wavelength. A $940\mathrm{nm}$ infrared photon has $E\simeq 2.11\times 10^{-19}\mathrm{J}$, whereas a $254\mathrm{nm}$ ultraviolet photon has $E\simeq 7.82\times 10^{-19}\mathrm{J}$. These are calculations from $hc/\lambda$, not measurements of a particular source. A television remote is a familiar approximately $940\mathrm{nm}$ source; its information is carried by variations in the emitted radiant flux. ^[ref].

Detection and visual perception answer different questions. A photodetector can respond to infrared even when an observer perceives no light; a thermometer detects an increase in temperature after photon absorption. Conversely, a small readout can reflect a small spectral responsivity, rather than absence of incident electromagnetic radiation. Images made from infrared readouts use display colors chosen by the imaging system; those colors are not the colors of the incoming infrared.

The important microscopic mechanisms also differ. In infrared spectroscopy, photon absorption often increases the energy of a normal mode in which chemical bonds stretch or bend. The corresponding optical spectrum helps distinguish molecules by their motions. For the usual electric dipole mechanism, the motion must change the electric dipole moment; matching the frequency alone is not sufficient. ^[ref]. Electronic processes can also emit or absorb infrared, so it is not exclusively radiation from molecular motion. ^[ref]; ^[ref].

Infrared is especially useful for observing thermal radiation from objects near everyday temperatures. For an ideal $300\mathrm{K}$ blackbody, Wien's displacement law gives a wavelength peak near $9.66\mu \mathrm{m}$. A thermal camera's readout nevertheless depends on emissivity, reflected surroundings and transmission along the path, as well as temperature. ^[ref]. A source emitting infrared need not be hot: an infrared remote is useful precisely because a photodetector can distinguish its signal from a background. Visible light and ultraviolet can also cause heating when absorbed; “infrared” names a wavelength range, not a unique form of heat.

Herschel's 1800 discovery made the distinction between sight and detection experimentally concrete. His report describes a optical prism spreading sunlight across a white, ruled receiving surface, with three thermometers at different positions near the end of the visible optical spectrum. He observed heating beyond the red edge where no visible color appeared. The result established that sunlight contained invisible radiation less strongly refracted by that optical prism than the visible red; it did not measure a photon energy or establish today's infrared boundaries. ^[ref]; ^[ref].

A documented modern version by Caltech/IPAC uses a glass optical prism, white paper in a shaded box and three blackened liquid-filled thermometers. Initial readings in shade provide each thermometer's baseline; subsequent readings compare blue, yellow and just beyond red after the bulbs have had time to warm. The measured quantity is the rise in temperature, not a “temperature of a color”. The lesson reports the expected largest rise beyond visible red and specifically discusses matching the bulb coatings and thermometer calibration. Clouds and changes in the projected optical spectrum affect the comparison. ^[ref].

For a stronger modern interpretation, an additional shaded thermometer would monitor ambient drift, exchanging bulbs between positions would test differences between thermometers, and blocking the incident beam would distinguish beam-dependent heating from warmed supports or air. These are suggested controls, not claims about Herschel's historical procedure. Thermal conduction through the mounting and convection can change the readout. A broad bulb also samples a range of wavelengths; the optical prism's transmission and optical dispersion, the bulb's absorption and heat loss all affect the position of the largest rise. In particular, the result does not show that an infrared photon carries more energy than a visible photon.

A simple analytical illustration makes those limitations explicit. Let $\theta =T-T_{\mathrm{amb}}$ be the bulb's excess temperature, $C$ its heat capacity, $G$ its effective heat-loss coefficient in $\mathrm{W}{\mathrm{K}}^{-1}$, and $P_{\mathrm{abs}}$ the absorbed power. Assume one uniform bulb temperature, constant ambient temperature, constant $C,G$, and losses linear in $\theta$. Thenfor a beam switched on at $t=0$ with $\theta (0)=0$. After switching the beam off at $t=t_s$, $\theta (t)=\theta (t_s)e^{-(t-t_s)/\tau }$. The exponential function follows by solving this linear differential equation. The steady excess temperature measures $P_{\mathrm{abs}}/G$; it is not a direct measurement of the optical spectrum. With illustrative $C=0.020\mathrm{J}{\mathrm{K}}^{-1}$ and $G=0.0010\mathrm{W}{\mathrm{K}}^{-1}$, $\tau =20\mathrm{s}$. Absorbed powers of $1.0$ and $0.5\mathrm{mW}$ give steady rises of $1.0$ and $0.5\mathrm{K}$, regardless of which wavelengths supplied that absorbed power.

The upper schematic represents the logic of the optical prism experiment; its light ray positions are not a calibrated wavelength scale. The lower curves use the illustrative heat-balance model, with the beam blocked at $60\mathrm{s}$; they are not historical or modern measured data. The beauty of the experiment is that a simple change of detector extends observation beyond what the eye can perceive.

Infrared spectroscopy measures a sample's response to infrared electromagnetic radiation. Absorption associated with stretching or bending motions of chemical bonds helps identify groups and their environments. Peak positions are commonly reported as reciprocal wavelength, in $\mathrm{c}{\mathrm{m}}^{-1}$; a lower value means lower frequency. ^[ref]

With fixed spectral resolving power, wavelength interval, diffraction grating geometry, photodetector sampling and collimator focal ratio, a beam diameter scales as the spaxel width $\theta$, but the optical camera focal length stays fixed. A simple on-axis beam-envelope model therefore gives collimator and disperser volumes proportional to ${\theta }^3$ and optical camera volume proportional to ${\theta }^2$. With a fixed number of spaxels per photodetector, replication multiplies these volumes by $M\propto {\theta }^{-2}$. A fixed photodetector field adds transverse clearances and changes the small-$\theta$ limit; these exponents are not universal mechanical-volume laws.

At a stationary, uniform planar boundary, incident and transmitted plane waves have the same variation of wave phase along the interface and in time. The figure marks places where equal-wave phase wavefronts meet the boundary. Although their perpendicular spacing differs, their intersections must advance along the boundary together. This is the local mechanism behind Snell's law.^[ref]

For a short derivation, let $x$ run along the interface and $z$ increase into the transmitted medium. Write each wave phase as ${\Phi }_j=k_{j,x}x+k_{j,z}z-{\omega }_{j}t+{\varphi }_j$. The electromagnetic boundary conditions must hold at every $x,t$ on $z=0$; their matching requires ${\omega }_i={\omega }_t$ and $k_{i,x}=k_{t,x}$. Constant offsets ${\varphi }_j$ and wave amplitudes are determined separately. Since $k_{j,x}=k_j\sin {\theta }_j$, this givesFor nonzero tangential wavenumber, the spacing of equal-wave phase intersections along the interface is ${\lambda }_i/\sin {\theta }_i={\lambda }_t/\sin {\theta }_t$. It is not the perpendicular wavelength. At normal incidence, the tangential wavenumber vanishes and the interface is uniform in wave phase.^[ref]

Wave interference is the reinforcement or cancellation that occurs when overlapping wave amplitudes add by the superposition principle. For two monochromatic waves of the same frequency, mutual optical coherence means that their relative wave phase is stable during the observation. Equal wave phases give constructive interference; a half-cycle phase difference gives the destructive interference intensity minimum. Wave amplitudes add before their squares determine wave intensity. ^[ref].

Consider two overlapping beams in a homogeneous medium, with the same polarization of an electromagnetic wave and individual local time-averaged light intensities $I_1,I_2$. Their phase difference $\delta$ is measured in radians. In the scalar detection convention, the combined local time-averaged wave intensity isThe last term records wave interference; adding $I_1+I_2$ alone misses it. The formula describes irradiance when both fields propagate along the same direction, or when the same detector geometry factor is included in all three intensities. For crossing beams it describes the squared electric field response, proportional to scalar wave intensity; a specified component of the Poynting vector also requires the propagation geometry. The ideal crossing plane waves below make that distinction explicit.

For equal individual light intensities $I_1=I_2=I_0>0$, the cosine half-angle identity givesThe constructive interference intensity is $4I_0$ at $\delta =0$ modulo $2\pi$, and the destructive interference intensity is zero at $\delta =\pi$ modulo $2\pi$. At phase quadrature, $\delta =\pi /2$, it is $2I_0$. With $I_1=1$ and $I_2=0.25$ in the same arbitrary wave intensity unit, the maximum is $2.25$, the minimum is $0.25$, and the phase quadrature value is $1.25$: unequal wave amplitudes cannot cancel completely.

Both curves use the same wave intensity unit and a horizontal angle in radians. The dashed levels are the averages over a full phase difference cycle. Equal beams have interferometric visibility one; the unequal example has interferometric visibility $0.8$.

A spatially varying phase difference turns the same law into interference fringes. Take two ideal plane electromagnetic waves with common wavelength $\lambda$, equal individual light intensities $I_0$, and propagation directions at angles $+\theta$ and $-\theta$ from the $z$ axis in the $xz$ plane, with $0<\theta <\pi /2$. Both have linear polarization along $y$, perpendicular to both propagation directions. Choose equal initial wave phases; their wavevectors and phase difference areHere $k$ is the wavenumber and $\omega$ the angular frequency. The common $z$ and time terms cancel, so the interference fringes stay at fixed $x$ for every $z$. Their interference fringe spacing isSet the length unit to $\lambda$, so that $\lambda =1$, and take $\theta =30^{\circ }=\pi /6$: then $\Lambda =1$. The constructive interference intensity bands lie at integer $x/\lambda$; the destructive interference intensity bands lie at half-integer $x/\lambda$.

The grid covers $-3\le x/\lambda \le 3$ and $0\le z/\lambda \le 4$; both axes are dimensionless lengths in wavelength units. The colour scale is $I/I_0$ from zero to four, using the same single-beam normalization as the equal-beam curve above. This is an ideal plane wave superposition, with no slits or point sources and no near-field approximation. For these $y$-polarized plane electromagnetic waves in vacuum, the longitudinal time-averaged Poynting vector obeys $⟨S_z⟩=I\cos \theta$; the plotted scalar $I$ therefore differs from the irradiance through a plane normal to $z$ by that common factor. This relation follows by adding the magnetic fields as well as the electric fields.

The bright peaks do not create energy. Averaging over one interference fringe spacing, or equivalently over one full phase difference cycle, givesbecause the integral of the cosine is zero, with sine as its antiderivative. Equal beams thus average to $2I_0$, despite bright bands at $4I_0$. For the crossing-wave geometry, the average longitudinal energy flux is correspondingly $2I_0\cos \theta$. Bright and dark regions redistribute the incoming energy; conservation of energy concerns the full energy flux, rather than the height of one peak.

Wave interference is useful because phase differences convert small changes in optical path length into measurable changes of wave intensity, as in a Mach-Zehnder interferometer. Its beauty is that the same superposition principle produces both complete cancellation and fourfold brightening; adding more coherent contributions also produces the narrow peaks of a diffraction grating. Feynman's treatment connects this many-source pattern directly to addition of complex amplitudes. ^[ref].

A short proof outline uses local real fields $E_j(t)=A_j\cos (\omega t+{\varphi }_j)$ with parallel linear polarizations. Write $I=C⟨(E_1+E_2{)}^2{⟩}_t$ and $I_j=C{A}_j^2/2$ for the same positive conversion factor $C$. Averaging over many wave periods while the phase difference stays fixed uses $⟨{\cos }^2(\omega t+{\varphi }_j){⟩}_t=1/2$ and $⟨\cos (\omega t+{\varphi }_1)\cos (\omega t+{\varphi }_2){⟩}_t=\cos \delta /2$, giving the stated law. Equivalently, add the complex amplitudes and take the squared complex modulus. ^[ref].

For different fixed linear polarizations in a common transverse plane, the cross term acquires the dot product of their real unit vectors, equal to $\cos \alpha$ for relative angle $\alpha$. Orthogonal linear polarizations remove the cross term in polarization-insensitive scalar detection; different orientations generally only reduce it. A common polarizer can select overlapping components and recover wave interference. Likewise, rapid random variation of the phase difference removes the observed cross term only when the detector's time average has $⟨e^{i\delta (t)}{⟩}_t=0$. Slowly varying wave phases can instead move resolved interference fringes, and biased or incompletely sampled wave phases can leave residual contrast. Finite optical coherence therefore depends on the observation time as well as the fields.