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A coverage-preserving detector-width bound from a variance interval transforms uncertainty in a nonnegative response variance without imposing a symmetric width error bar. Let and let a random interval have stated frequentist coverage for . Define the width confidence set byFor the true width ,The events are identical, so their coverage probabilities are identical. The transformation does not create coverage that the original interval lacked. Resolution-limit conditioning in finite-input detector calibration explains why working with the variance difference first is useful near a barely resolved detector response.
For an original explicit measurement model, suppose has a normal distribution with mean and known standard deviation . A reading gives an approximately 95 percent interval . Intersecting with the physical range and taking square roots gives . This is an assumed normal model for measuring , not a claim that any difference of fitted squared widths is automatically normal.
If the entire variance interval is negative, the result is an empty physical confidence set for a detector variance difference. Do not replace its negative upper endpoint by zero and report an apparently exact zero width: that changes the confidence-set construction. An empty realization signals disagreement between that interval and the physical parameter range; it can occur even in a valid procedure on an occasional sample that misses the true value.
NIST distinguishes a standard uncertainty from an interval with a justified confidence level and explains the distributional assumptions behind a coverage factor near two.[ref]
Guidelines for Evaluating and Expressing the Uncertainty of NIST Measurement Results by Barry N. Taylor and Chris E. Kuyatt. §§6.2–6.3, Expanded Uncertainty
The normal interval above needs its stated model; the monotone transformation proof itself does not. Application to a detector additionally requires the nonnegative-profile convolution assumptions of finite-input correction in pulse-detector calibration; a correct statistical transformation cannot repair an invalid physical variance identity.Operating-point transfer of an overlap reference asks whether a state-dependent normalization correction measured under reference conditions remains valid at the specimen's optical and electrical settings. Detector bias, optical power, beat frequency, amplifier range and illumination can all define the operating point. Repeated readings at one setting establish repeatability there, rather than transfer over an untested range.
Let the true optical log-ratio be and the instrumental state offset at power be . A reference measurement estimates . Applying it to a specimen at leavesThis follows directly from reference-state transfer in overlap normalization. The difference between operating points is a measurement-model input, not extra independent readout noise.
An original local model writes . References at two powers support linear interpolation at an intermediate :The weights sum to one. A specimen outside the tested range requires extrapolation, which is more sensitive to model error.
Curvature error in overlap-reference transfer is visible in an exactly solvable example. If the true offset is linear plus , its difference from endpoint interpolation is . For powers 1 and 3 mW, suppose the measured endpoint offsets are 0.02 and 0.06. The interpolated offset at 2 mW is 0.04. A quadratic term , with powers expressed in mW, leaves both endpoints unchanged but makes the actual midpoint offset 0.03. Correcting by 0.04 then leaves a log-ratio error of . These are stipulated response values, not observations.
Reference uncertainty also transfers. At a fixed, known interpolation power,Here are standard uncertainties; uncertainty in requires additional terms. A shared calibration can correlate the endpoints, so their covariance should not be dropped merely because they were measured at different powers.[ref]
A useful proposed experiment brackets specimen acquisitions in time, samples several operating powers and repeats at the intended bias and frequency. Check for optical changes as well as electronic response: NIST's primary heterodyne apparatus controls spatial mode and polarization before electrical calibration.[ref]
Frequency response metrology for high-speed optical receivers by Paul D. Hale and others. PDF p. 1, Heterodyne measurements
The interpolation calculation above diagnoses a transfer assumption; it is not an attributed NIST procedure.The mismatch remaining after common RC gain cancellation is the timing error caused by unequal gains in the amplitude and threshold paths after their common multiplicative part has canceled. It depends on their ratio, so improving a shared gain alone does not remove it.
For the zero-baseline RC threshold-crossing time, let with . If the amplitude is multiplied by and the threshold by , define the residual relative error by . The exact result from ratiometric cancellation of RC timing gain errors isHere is the time constant. As approaches one, the crossing is arbitrarily late; at or above one there is no finite rising crossing. An error budget must check this existence condition as well as a small timing residual.
For a new example, set , and . A one-percent positive mismatch gives ; a one-percent negative mismatch gives . The first-order estimate is , or here. The unequal exact magnitudes are a consequence of the logarithm, not an asymmetric tolerance specification.
If , monotonicity gives the exact worst absolute errorThus a bound in this example requires , about . This is a bound on the gain ratio, not on either gain separately.
For small fractional path errors , andA perfectly shared component has zero contribution to that difference. This is the law of propagation of uncertainty applied to the two gains; it does not cancel a change in , an additive threshold error or a nonzero unscaled baseline.[ref]
A proposed check varies the common gain while holding its ratio fixed, then varies only one path. Recording the two electric potential differences and the crossing on an oscilloscope distinguishes the exact common-gain invariance from the surviving mismatch.
Rare-event discovery versus inverse-moment precision separates seeing an influential thin region from estimating its contribution to inferred density. In a two-point thickness model, let a rare thickness occur with probability , with reciprocal thickness , while common regions have reciprocal thickness . For independent observations, the rare count has a binomial distribution. The chance of at least one rare observation isTo make this at least , choose . For stipulated and , the smallest integer is 29,956. This planning statement assumes the specified rare-event probability; it does not estimate that probability from a sample that missed the event.[ref]
The sampling distribution of the estimated inverse moment answers another question. With the observed rare count,Thus a target relative standard uncertainty for the inverse moment requiresThis is a contribution-weighted precision target for inverse moments: the required count depends on both rarity and the leverage of the rare value.
Use the original model , and . Here and . ConsequentlyAt the 95%-discovery count, this relative standard uncertainty is still about 28.9%. Reaching 10% for the inverse moment needs 249,975 observations in this model, while reaching 10% for the rare fraction itself needs 999,900. The factor of four arises because the rare excess accounts for half the total inverse moment, so its relative fluctuation is diluted in the total.
These are exact variance calculations under a stipulated distribution, not confidence-coverage guarantees or measured material properties. Spatially clustered thin regions reduce the effective independent sample count. A credible physical lower-thickness bound or better resolved imaging can change the model more substantially than merely extending a simulation with an unsupported tail.
Eigenmode alignment in overlap variance correction describes how shared calibration directions change the mean of a variance-corrected overlap, even when the marginal distributions of the reading and estimated variance are fixed. In the quadratic Gaussian overlap correction model, let have the standard multivariate normal distribution, and , with symmetric positive semidefinite matrix and . The corrected estimate is .
Write with orthogonal matrix , and let . Completing the square in the Gaussian density givesThe eigenvalues determine the variance estimator's distribution. Its eigenvectors determine which of those directions also enters . Rotating relative to a fixed preserves those eigenvalues but changes the last sum.
An original rank-one example takes , with unit vector , and . If is the angle between and , direct inversion of givesParallel alignment gives a mean ratio about ; perpendicular alignment gives about . Both estimated variances have mean one and distribution . Unbiased estimation of the logarithmic variance therefore does not itself make the corrected arithmetic overlap unbiased.
A Rayleigh quotient bounds every orientation when :The endpoints occur when lies in the respective extreme eigenspaces. Substituting these bounds into the logarithmic mean formula gives a deterministic range over all alignments with the stated eigenvalues.
There is an instructive dependence trap. Symmetry gives , while the Gaussian fourth moments giveZero linear covariance between the signed residual and the variance estimate therefore does not establish that they are independent random variables. Squaring the residual exposes shared directions.
For an actual calibration, the joint input model must describe which records are reused. JCGM 101 separates assigning input distributions from propagating them and presents the multivariate normal distribution as one possible joint assignment.[ref] The examples and orientation bounds above are derived probability models, not measured heterodyne performance.
An acquisition duration from a power-law tail-energy tolerance extends a measurement until the validated envelope's unrecorded energy is below a chosen tolerance. For the model in power-law tail from a decaying rate envelope, with ,The parent article integrates this envelope and inverts the tolerance. Writing , its positive-duration requirement is when ; otherwise no additional duration is required.
In applying the rule, uncertainty in the exponent can dominate the result. With fixed and , differentiating the active branch givesThe required duration decreases with a larger exponent. For a guaranteed parameter range, a validated lower bound on a power-law tail exponent is therefore more useful than its best-fit value alone. Since decreases with for every , using the smallest allowed exponent bounds the entire tail, not just one selected sample.
For an original design example, let , and . A nominal exponent gives initial allowance , and . If the validated exponent range is instead , its slowest permitted tail has initial allowance and requires . The nominal duration does not guarantee the tolerance over that range. Upper bounds on and can likewise be used conservatively because increasing either raises the envelope pointwise.
If the allowed exponents reach one or below, these envelope assumptions alone no longer supply a finite all-time energy guarantee. This is a limitation of the bound, not proof that the actual pulse has infinite energy. The model must also hold throughout the unobserved interval: later pulses, persistent backgrounds or an electrical detector tail misidentified as optical power can invalidate it. NIST's independent receiver-response measurement illustrates this last experimental distinction.[ref]
Calibration Service for Low-level Pulsed-Laser Radiometers at 1.06 µm: Pulse Energy and Peak Power by Rodney W. Leonhardt. Appendix C.1–C.2, printed pp. 36–37
The power-law examples are original conditional models, not observed decay laws attributed to that apparatus.Tyranni, the suboscines, is a major branch of Passeriformes distinct from Acanthisittidae and from the songbirds of Passeri. It includes the eastern phoebe. The taxonomic distinction makes comparisons of vocal development especially informative: a pattern established in an oscine songbird need not apply to every passerine.[ref]
Earth history and the passerine superradiation. Results, principal passerine branches
A 1991 experiment tested whether the eastern phoebe required hearing its own voice to develop normal song. Four birds were collected as nestlings and hand-reared; before they began singing, they were deafened. Their later songs were compared with those of intact laboratory birds and wild males and were judged normal. In these tested birds, normal song development therefore did not require auditory feedback.[ref]
The experiment separates a developmental requirement from a correlation: hearing song and producing song normally occur together, but removing feedback tests whether it is necessary. The result concerns the tested species and conditions. It should not be generalized into a claim that no member of Tyranni can ever modify a vocalization through learning.
Acanthisittidae is the New Zealand wren family, a major branch of Passeriformes distinct from both Tyranni and the songbirds of Passeri. The rifleman is one representative. The familiar word “wren” is not by itself evidence that these birds belong with every other small bird given that common name.[ref]
Earth history and the passerine superradiation. Results, three principal passerine branches
The rifleman searches trunks and branches for small invertebrates and makes short flights between feeding sites. Such observations describe how a living member uses its environment; they are a different kind of evidence from the DNA comparisons used to establish the family's evolutionary position.[ref]
Rifleman in New Zealand Birds Online. identification and behaviour/ecology
A useful classification test therefore asks two separate questions: does another bird share a similar body shape or feeding habit, and does it share the ancestry indicated by a phylogenetic tree? Similar ecological demands can produce similar appearances in different branches. Broad genomic sampling places Acanthisittidae in the passerine tree without defining the group merely by small size, a short tail or an English common name.
Invariance of noise-whitened spectral angles to the whitening factor means that any two complete whitening transformations for the same positive-definite covariance give the same angles between transformed shapes. Suppose square invertible matrices satisfy . Put . Since ,Thus is orthogonal. It may rotate or reflect the whitened coordinates, but preserves their inner products, norms and angles. The noise-whitened angle between spectral signal and nuisance shapes is consequently a property of the shapes and covariance, not a particular whitening algorithm.
For an original example, chooseDirect multiplication gives . With and , the whitened shapes are and , meeting at . Using instead gives and , again at , although the coordinate components differ.
SciPy describes covariance whitening as transforming variables to unit covariance and illustrates it with a precision-matrix construction.[ref] The matrix proof above establishes the invariance independently of an implementation's chosen factor.
The same principle requires covariance-consistent rescaling of whitened spectral coordinates. If raw measurement units change by an invertible matrix , transform both shapes by and covariance by ; then reproduces the same whitened shapes. Changing a plotted channel's scale without transforming its noise model is not this invariant operation.
The claim assumes a full whitening of a positive-definite covariance. Truncating modes can remove information and change angles, while a singular covariance requires restriction to its supported range. Uncertainty in an estimated covariance is also separate from this exact algebraic invariance.
The threshold-reset margin for a periodic RC pulse train is the separation between the reset threshold of an electronic comparator and the largest baseline that the periodic RC low-pass filter may leave between pulses. A positive margin excludes missing comparator reset in an RC pulse train in the ideal threshold model; its size measures tolerance to additional electric potential difference errors.
Let be the input high level, the high duration, the quiet duration and the time constant. From the periodic solution in missing comparator reset in an RC pulse train, writeThis defines a margin in volts, rather than in units of standard deviation. If a nominal baseline has a known absolute error bound and the reset threshold has bound , a sufficient worst-case condition isThese are simultaneous bounds on the actual baseline and threshold. Adding their standard uncertainties would not by itself provide a deterministic guarantee; a probabilistic statement requires a specified joint probability distribution.[ref]
Guidelines for Evaluating and Expressing the Uncertainty of NIST Measurement Results by Barry N. Taylor and Chris E. Kuyatt. §§6.2–6.3, distributional conditions for interpreting uncertainty intervals
For an original example, let , and . Then , and the peak is . A threshold of gives . Bounds and leave . Raising the baseline bound to would remove this guarantee even though the nominal waveform still crosses the threshold.
A positive minimum separation does not specify the reset dwell time below threshold in an RC pulse train. A real electronic comparator needs enough time to switch, and the peak must separately exceed the acceptance threshold. For a Schmitt trigger, use the lower switching threshold in , while checking the upper one against the peak.
A focused bench test records the pulse generator output, capacitor output and electronic comparator output on an oscilloscope, then varies near the predicted boundary. Compare the measured minimum with the reset threshold and record the low interval as well as the minimum. The underlying exponential decay can be checked by the natural-response experiment in the MIT laboratory; the margin calculation above is an original application of that model.[ref]
Laboratory 11: Sinusoidal Steady State Response of RC and RL Circuits by MIT OpenCourseWare. Printed p. 1, capacitor response after switching and time-constant measurement
Constraint redundancy in baseline-noise minimization occurs when some signal-preservation or baseline-rejection conditions are linear combinations of others. In minimum-noise weights under baseline moment constraints, the estimator weights satisfy . A necessary and sufficient feasibility condition isIndeed, multiplying the constraints by gives necessity. Sufficiency follows because the range of is the orthogonal complement of the kernel of . Redundant conditions are harmless only when their required responses obey the same dependencies.
For an original three-sample example, let the pulse template be and the constant baseline . The columns contain a duplicated baseline condition. The required response is feasible and gives the same minimum-noise weights as the two independent columns alone. With independent sample variance , its variance remains ; writing the constant condition twice adds no information.
By contrast, requiring responses would demand both and . The dependency has , exposing the inconsistency.
With positive-definite error covariance and feasible constraints, put . A redundant-column version of the optimum iswhere is the Moore-Penrose inverse. Feasibility ensures . Without the null-space feasibility test for baseline-estimator constraints, this formula can silently return approximate responses instead of the requested exact cancellations. Variance still uses the full covariance quadratic form.[ref]
NIST's before/after pulse baselines motivate such cancellation constraints experimentally.[ref]
Calibration Service for Low-level Pulsed-Laser Radiometers at 1.06 µm: Pulse Energy and Peak Power by Rodney W. Leonhardt. §3.5, printed p. 8; §7.2, Leakage Effect
A singular value decomposition can diagnose numerical dependence, but a small singular value caused by time units or poor scaling is not automatically permission to discard a physical drift-rejection requirement.Logarithmic tail-duration change at the zero-extension boundary describes a recording requirement whose input ratio crosses the point where no further acquisition is needed. For fixed decay time , put and . The physical extension isHere the logarithm applies to the input ratio, not to a zero output duration. Logarithmic condition numbers of a tail-acquisition requirement applies only where .
At , the left derivative is zero and the right derivative is . The directional derivative of a clipped logarithmic acquisition time along a signed input change isThus no single ordinary derivative describes threshold-crossing perturbations. Nevertheless, the duration is stable in absolute units:This follows because the positive-part map has Lipschitz continuity with constant one.
For an original interval example, take and a justified input-ratio range . The corresponding duration range is . Its lower part is clipped at zero. Linearizing only on the zero-duration side would incorrectly predict no possible extension even though the allowed set crosses the threshold. A relative error divided by a nominal is undefined, while this absolute bound remains meaningful.
If is uncertain too, optimize the full expression over the justified joint parameter set rather than treating this fixed- inequality as a complete uncertainty analysis. The tail model must bound optical power throughout the missed interval. NIST's calibration apparatus measured detector/cable/oscilloscope response separately, illustrating why a recorded electrical decay cannot automatically certify such an optical envelope.[ref]
Calibration Service for Low-level Pulsed-Laser Radiometers at 1.06 µm: Pulse Energy and Peak Power by Rodney W. Leonhardt. Appendix C.1–C.2, printed pp. 36–37
The clipping analysis is an original property of the stated conditional acquisition model.Joint radius-setting and log-ratio bounds retain the allowed relationship between the radius-setting parameter and measured log-ratio when inferring an optical radius ratio. Separate marginal intervals form a rectangle that may contain combinations excluded by shared calibration information. Propagating that rectangle can therefore exaggerate the feasible radius range.
For and , defineFor a stated joint set , the compatible ratios are . This set definition precedes any approximation. A deterministic set is not automatically a statistical confidence region; a probability interpretation needs the corresponding input model.
An original exactly linked calibration example has and . The marginal intervals are and , but their extreme values cannot be chosen independently. Writing and using givesThus the joint model gives approximately . Treating the two marginal intervals as an independent rectangle instead allows approximately . The wider result contains parameter combinations that violate . All values describe a stipulated calibration relation, not observed optical data.
For a positive- rectangle wholly inside the inversion range, monotonicity places the minimum ratio at and maximum at . That shortcut is valid for the rectangle, but those corners may be absent from the actual joint set. With nonlinear dependencies, optimize over the stated joint set or parameterize it by the genuinely independent calibration inputs.
The feasible-set boundary in overlap inversion also matters. If part of a joint set crosses , some allowed observations have no finite positive solution in the assumed model. Report that incompatibility and examine the measurement model; silently discarding those points changes the set or probability distribution. JCGM 101 distinguishes input assignment, propagation and output summaries, and specifies conditions for its Monte Carlo approach.[ref]
Experimentally, retain common calibration records when deriving both and . A shared scale or fitted parameter should be varied consistently through both calculations. Independent draws from their marginals erase that information. Conversely, imposing a convenient correlation without physical calibration evidence can create an unjustifiably narrow range. Interval propagation for bounded overlap data is a numerical step conditional on this joint experimental model.
Wall-clock slack in saturation-limited Raman frame allocation is time that remains unused when a fixed number of detector frames has already reached its permitted exposure caps. With pump-on/off pairs, per-frame cap and readout time per frame,assuming . The integer frame-count choice under a Raman saturation limit compares these possibilities over different pair counts. Slack at fixed does not imply that the continuous exposure allocation was optimized incorrectly.
If , both states can use their full live totals , and the shot-noise relative variance is . Increasing only the wall-clock allowance cannot improve it: the marginal value of unused time below a Raman frame cap is zero in this capped regime. Another frame pair changes both the overhead and the allowable division of live time.
For an original example, set , , and . The live time is , readout uses , and slack is . With and , equal capped totals give .
Three pairs increase readout time to , leaving only live time. Yet the larger per-state cap permits the preferred ratio two to one: and . Their variance is , lower despite less total live time. Relieving the weak state's cap outweighs the extra readout cost in this chosen model.
The primary Raman apparatus limited exposures to avoid detector saturation and alternated pump state during shuttered readout.[ref]
Femtosecond Broadband Stimulated Raman: A New Approach for High-Performance Vibrational Spectroscopy by David W. McCamant and others. Data Collection, exposure limit, 10 ms readout and shutter sequence preceding equation 4
The timings above are separate illustrative choices. Read noise, sample drift and switching constraints can change the comparison; unused time and useful precision are different optimization quantities.Capacitance uncertainty in heterodyne current recovery is the contribution of uncertain shunt capacitance to the inferred generated beat electric current. In the capacitive current division in heterodyne receivers model, a measured load-current amplitude is corrected towith load electrical resistance , angular frequency and shunt capacitance . These amplitudes must refer to the stated current-plane convention in heterodyne calibration and use the same peak or root mean square convention.
Differentiation gives the logarithmic sensitivity coefficientThus capacitance contributes little when , contributes half its fractional change at , and contributes nearly its full fractional change when . High-frequency correction increases the required amplitude estimate; it does not make uncertainty in the correction disappear.
Let have covariance matrix . First-order uncertainty propagation givesThis form retains correlations rather than silently assigning four independent inputs. It is the GUM's sensitivity-and-covariance law applied to this particular measurement model.[ref]
For an original small-error example, set , neglect frequency uncertainty, and assign fractional standard uncertainties of to , to and to . With independent inputs,If only the errors have correlation coefficient , the result becomes about ; correlation instead gives about . The same marginal uncertainties can therefore produce different output uncertainty.
Nonlinearity also shifts the mean. Holding fixed and writing with centered small error, a second-order Taylor series givesAt and , this is about , distinct from the first-order spread. Broad or asymmetric inputs require a fuller distribution model.
A proposed diagnostic characterizes the load and shunt response at the actual bias and relevant beat frequencies, then propagates the joint calibration record. NIST's primary apparatus separately calibrates electrical networks and mismatches as well as controlling optical beating.[ref]
Frequency response metrology for high-speed optical receivers by Paul D. Hale and others. PDF pp.1–2, Heterodyne measurements and equations 1–4
A fitted capacitance is only one part of that response: a single-pole model should not absorb untested cable, transit-time or amplifier effects.The European wildcat, Felis silvestris, is a wild species of Felis associated with European and neighboring forest populations. In the Cat Specialist Group's classification it is distinct from the Afro-Asiatic wildcat and the domestic cat. The common word wildcat in older literature can refer to a broader collection of regional lineages, so the scientific name must be read in context.[ref]
Hybridization with domestic cats complicates identification. Nuclear genetic markers and DNA inherited through mitochondria need not tell exactly the same ancestry story. The 2007 wildcat comparison explicitly marked individuals whose nuclear clustering and mitochondrial lineage differed. That makes a single coat pattern or one inherited marker an incomplete account of ancestry.[ref]
The Near Eastern origin of cat domestication by Carlos A. Driscoll and others. Figures1–2: regional clades and cytonuclear-discordant individuals
For an illustrative comparison, two striped cats could have similar appearance while differing in their inherited marker combinations. Appearance remains useful for observing animals, but testing population ancestry requires a stated set of markers, reference samples and classification criteria. Geographic location alone is also insufficient to turn every free-living domestic cat into a European wildcat.
The Afro-Asiatic wildcat, Felis lybica, is a wild species of Felis distributed across much of Africa and parts of Asia. The Cat Specialist Group distinguishes it from the European wildcat, Felis silvestris, and the domestic cat, Felis catus. Some older work treated these regional wildcats as subspecies of a more broadly defined Felis silvestris.[ref]
Afro-Asiatic wildcat species account by the IUCN SSC Cat Specialist Group. Description and distribution; provisional species classification
Its relationship to domestication has been investigated genetically. The 2007 comparison of domestic and wild cats found close clustering of domestic samples with sampled Near Eastern wildcats, rather than with every wildcat population equally. In that paper, the relevant lineage was named within the older subspecies scheme.[ref]
The Near Eastern origin of cat domestication by Carlos A. Driscoll and others. Abstract; Figures1–2: regional samples and genetic clustering
This supports a particular ancestry relationship in the sample; it does not make a present-day Afro-Asiatic wildcat simply a lost pet. A feral cat is a domestic-lineage animal living independently of direct care. Current behavior and genetic ancestry should therefore be recorded separately when studying encounters or hybridization between the populations.
A power-law tail from a decaying rate envelope arises when a positive instantaneous decay rate weakens with time. The time-dependent decay-rate envelope with givesfor , and . The parent article obtains this envelope by integrating the rate. Its use for recording design additionally requires integrating over the entire unrecorded tail.
For , integration after an extension givesHence the acquisition duration from a power-law tail-energy tolerance is zero when ; otherwise it is sufficient to choose
In an original example, , and give an initial energy allowance . Reducing the remaining allowance to requires . An exponential envelope with the same initial allowance and a decay time would require only . Equal initial tail-energy allowances therefore do not imply equal acquisition durations.
For , the envelope tends to zero but its integral after every finite extension diverges. These assumptions then supply no finite missed-energy guarantee. They do not imply that every signal lying below the envelope has infinite energy.
This is an original comparison model, not a measured decay law attributed to a particular detector. In optical pulse metrology, NIST's response measurement separates receiver dynamics from the incident pulse before applying bandwidth corrections.[ref]
Calibration Service for Low-level Pulsed-Laser Radiometers at 1.06 µm: Pulse Energy and Peak Power by Rodney W. Leonhardt. Appendix C.1–C.2, printed pp. 36–37
The same physical distinction is necessary before interpreting any measured slow tail as a global bound on optical power.Tie-line endpoint covariance records how the measurement errors of the two measured liquid-liquid tie line endpoints vary together. Using independent mole fraction coordinates, represent the two endpoint estimates by column vectors . Their cross-covariance matrix isAn individual off-diagonal block need not be symmetric; the full joint covariance matrix must be a symmetric positive semidefinite matrix. The uncertainties of the two endpoint vectors alone do not determine their cross-covariance matrix.
Near an exactly balanced, interior tie-line phase-fraction fit, let be the row-vector sensitivity coefficient defined in tie-line phase-fraction sensitivity. If the overall composition measurement is independent of both endpoints, first-order uncertainty propagation givesThe cross term has a positive coefficient because the two endpoint perturbations enter the phase fraction with the same sign. Correlated endpoints can therefore increase the result. The general rule is to propagate the full joint covariance matrix, rather than assume that correlation always increases or always reduces uncertainty.[ref]
Guide to the expression of uncertainty in measurement by JCGM. §5.2.2, equations13–16, correlated inputs
For a stipulated binary mixture example, use , , , so . Treat as exact and give each endpoint standard uncertainty with correlation coefficient . The lever rule yieldsThis gives for , about for , and for . These are first-order standard uncertainties under the stipulated joint error model, not bounds on all possible errors.
A shared calibration error affecting the overall composition as well changes the calculation. Suppose the same additive error affects identically. ThenThe shared offset cancels exactly. More generally, a common affine map with also cancels in this binary ratio. This common affine calibration cancellation in the lever rule concerns only a truly common contribution; separate sample errors remain. If the shared offset has standard uncertainty , incorrectly treating its three appearances as independent would assign a spurious contribution instead of zero.
In general, stack the inputs as with joint covariance matrix . Let be the corresponding Jacobian matrix row from tie-line phase-fraction sensitivity, including its residual correction when needed. Then automatically includes correlations with the overall composition. The measurement guide specifically identifies common instruments, measurement standards and reference data as sources of such correlations.[ref]
An instructive measurement design analyzes the two equilibrium phases and the overall mixture using one instrument calibration, then repeats the entire procedure with independent instrument calibrations. The within-run contrasts and between-run changes probe different error contributions. Repeated readings under one unchanged instrument calibration cannot by themselves establish the uncertainty of its shared offset. The measurement model must identify which influences are common before the joint covariance matrix can represent them.
Pinned article: Introduction to the OurBigBook Project
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Intro to OurBigBook
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