Prepare size-characterized gold-particle ensembles, heat them on a calibrated in-situ electron diffraction stage, and follow the loss of sharp fcc diffraction features and appearance of liquid-like diffuse scattering. Measure the particle size distribution rather than treating a polydisperse ensemble as one diameter. Temperature-dependent weakening of a diffraction peak alone is insufficient: thermal vibrations, particle motion, coalescence, evaporation and beam damage can also reduce intensity. Low-dose repeats, heating/cooling runs, size checks before and after heating, a bulk-like reference and support-dependent controls help distinguish melting from those effects. Electron diffraction measurements on gold particles down to about 2 nm are a classic demonstration.[ref]
Size effect on the melting temperature of gold particles by Ph. Buffat and J-P. Borel. Physical Review A 13 (1976), pp. 2287–2298, abstract: scanning diffraction and size-distribution analysis
The physical origin is the large interface contribution to free energy at small radius. A curved solid–liquid interface raises the solid's thermodynamic equilibrium chemical potential relative to the flat-interface case, so coexistence occurs below the bulk melting temperature. Reduced coordination and surface disorder provide a microscopic interpretation, but the quantitative continuum relation is a free energy balance, not simply a claim that every surface atom has a universal lower melting point.
In a polyol process, a hot polyol such as ethylene glycol acts as solvent and reductant for a silver precursor. Nucleation creates seeds; controlled reduction supplies atoms for their subsequent growth, while polyvinylpyrrolidone adsorption and seed crystal twinning favour anisotropic growth. For the common silver nanowire route, a fivefold-twinned seed can develop into a pentagonal wire with predominantly side faces and growth at less-passivated ends. Cross-sectional microscopy and diffraction of microtomed wires provide evidence for that twinned structure rather than an inference from a long outline alone.[ref]
Polyol Synthesis of Uniform Silver Nanowires: A Plausible Growth Mechanism and the Supporting Evidence by Yugang Sun and others. Nano Letters 3 (2003), pp. 955–960, pentagonal cross sections and fivefold twinning
The aspect ratio depends on seed population and twin survival, relative end/side growth rates, precursor feed and reduction rate, PVP coverage, temperature, trace halides, dissolved oxygen and growth time. High aspect ratio requires a suitable population of twinned seeds, suppression of competing particle nucleation and continued atom supply while sidewall thickening is restrained. These variables must be controlled together; adding more capping polymer alone is not a universal recipe. Advantages are solution processing, substantial yield and tunable dimensions without an etched hard template. Disadvantages include sensitive batch reproducibility, particle by-products, residual insulating ligand, purification, oxidation/tarnish and nanowire junction resistance in later films. Compare seed/capping/halide controls using microscopy and size distributions, not only solution colour.
An on-axis point illuminator increases spatial coherence. It is not a point object, and it does not remove diffraction. For an ideal aberration-free pupil, coherent imaging is linear in field amplitude and has cutoffFor a real amplitude grating , with and all three field orders inside this pupil, the intensity contrast is . Flat coherent field transfer preserves this contrast; weak input modulation does not itself meet a high resist contrast threshold. Assume a sufficiently high-contrast amplitude mask: for example, gives , exceeding both resist thresholds. Under this assumption, both resists have the same limiting equal-line/space widthThis is an approach to the cutoff from below; finite dose latitude, aberrations and a real binary mask can make usable resolution worse. A general coherent intensity image cannot be obtained by applying an incoherent intensity MTF unchanged: , rather than .[ref]
Advanced Optical Imaging: Incoherent imaging by Delft University of Technology. coherent/incoherent comparison: field cutoff versus the twice-as-wide incoherent intensity cutoff
With , this coherent cutoff is : the low-contrast resist improves from roughly to , while the high-contrast resist worsens from roughly to . Coherence improves contrast within its passband but reduces the ultimate bandwidth relative to incoherent illumination.
With the literal Rayleigh-spacing normalization , the same physical cutoff is instead , not . The corresponding widths from the preceding part would improve from roughly and toward . The cutoff in physical units is unambiguous under the stated ideal on-axis model; the claimed direction and size of a change inferred from the plotted normalized axis depend on its definition. Off-axis illumination, partial coherence and arbitrary phase objects require a fuller imaging model.
A parent initially at rest emits an alpha particle and a recoiling heavy daughter. momentum conservation gives equal and opposite momenta, so their nonrelativistic kinetic energies satisfyHere is the kinetic energy available to this branch; excitation of the daughter reduces it and may be followed by photon emission. For an illustrative MeV, and , the energies are MeV in the alpha particle and keV in the daughter. The heavy daughter receives much less energy, but that does not imply much less atomic damage.
The fast alpha particle loses most of its energy through electronic stopping: ionization and electronic excitation along a relatively long path. It also undergoes nuclear collisions, particularly towards the end of its range, and can produce displacement damage. The slower, heavy, highly charged recoil couples strongly to surrounding nuclei and generates a compact displacement cascade. Successive knock-on atoms create vacancies, interstitial defects and clusters. Some Frenkel pairs recombine as the cascade relaxes; the initial collision count is therefore not the number of defects that remain.
A quantitative illustration comes from brannerite rather than an assumed universal ceramic. Simulations in the primary natural-mineral study used a MeV alpha particle and an keV daughter recoil. The corresponding ranges were about micrometres and nanometres. At the study's assumed eV threshold displacement energy, its tabulated results give roughly – recoil atomic displacements and – alpha particle atomic displacements per radioactive decay. The numbers depend strongly on the displacement threshold and material, but the shorter recoil path contains the dominant and much denser ballistic radiation damage.[ref]
Chemistry, microstructure, and alpha decay damage of natural brannerite by G. R. Lumpkin and others. Chemical Geology 291, section 2.3 and Table 5; simulated ranges and threshold-dependent displacement counts
In a susceptible ceramic, cascade cores can accumulate into an amorphous fraction; defects and associated relaxation can also change volume, thermal conductivity and mechanical response. molecular dynamics simulations of zirconolite found a strongly disordered core surrounded by more isolated point defects, supporting this distinction between local cascade damage and an entirely transformed specimen.[ref]
Molecular dynamics simulation of the α-recoil nucleus displacement cascade in zirconolite by L. Veiller and others. Journal of Nuclear Materials 306, 61–72, abstract and cascade-core/point-defect results
The alpha particle eventually becomes a helium atom after slowing and charge exchange. helium accumulation can have later microstructural effects distinct from the initial knock-on cascade. Material-dependent recombination and annealing limit surviving disorder; a change in diffraction or radiation-induced swelling is not automatically radiation-induced amorphization, and radiation-induced amorphization is not automatically dissolution or release of the contained radionuclide.
An optical soliton maintains a localized profile because nonlinear refraction compensates linear spreading. A temporal optical soliton balances group velocity dispersion against self-phase modulation; a spatial optical soliton balances diffraction against self-focusing. The relevant coordinate and sign of nonlinearity must be specified.
For anomalous group velocity dispersion and positive , a fundamental temporal bright soliton isThe identity verifies both the width relation and propagation phase. Its dispersion length equals its nonlinear length . Bright pulses decay to zero background. dark solitons are intensity depressions on a nonzero background with a phase change across the dip; black dips reach zero intensity, while grey dips do not. For positive the corresponding temporal defocusing regime has normal group velocity dispersion.
A higher-order temporal soliton has soliton order equal to an integer greater than one for the special initial profile in normalized units. It breathes through compression and splitting/recombination, rather than keeping one fixed shape. Separated fundamental solitons can interact and acquire collision shifts. An arbitrary pulse with noninteger is not automatically a pure higher-order soliton; dispersive radiation can carry part of its energy.
In ideal one-dimensional cubic propagation, dispersion and nonlinearity support stable fundamental bright pulses. Loss, higher-order dispersion, delayed nonlinear response and finite bandwidth change real-fibre propagation. A one-dimensional spatial bright solution also does not guarantee stability against two-dimensional collapse. Profile preservation, finite-energy background conditions and robustness should be checked rather than inferred from any solitary-looking peak.
A finite beam has an intensity gradient across its wavefront. In an instantaneous optical Kerr model, . A bright centre therefore sees a larger index for , accumulating more phase than the wings and producing self-focusing. Negative gives self-defocusing. For a short medium and Gaussian , expand the nonlinear phase near the axis:Compare with the in-medium thin-lens phase , where . The Kerr lens has . This local quadratic fit describes the central lens, not the whole Gaussian phase or a guaranteed aberration-free focus.
Propagation combines diffraction with the nonlinear phase. Choose and a scalar paraxial envelope, givingThe diffraction length is of order , while the nonlinear length is . Their competition depends on total beam power as well as spot size. In two transverse dimensions, balancing them gives a critical power scale for positive ; the numerical constant requires a specified transverse profile and critical solution. In the ideal unsaturated cubic model, sufficiently strong focusing can collapse rather than form a stable beam. Real saturation, absorption, ionization or nonparaxial propagation can stop that ideal singularity; the appropriate mechanism depends on the material and pulse regime.
A broad focusing beam can also break into filaments. Perturb the uniform solution by real amplitude and phase components with transverse wave number . Linearization gives the transverse modulational instability rateFor positive , modes with grow. diffraction suppresses very fine perturbations. A finite beam's boundaries and available propagation length limit which filaments develop. The defocusing sign has no growing band in this simple instantaneous local model.
A spatial optical soliton instead has a profile whose nonlinear focusing balances diffraction. A one-transverse-dimensional cubic focusing model supports a stationary bright solution; the existence of that solution does not establish robust two-dimensional cubic self-trapping. A beam can also act on another finite beam through cross-phase modulation, producing an induced lens or steering it towards a high-index region. Unequal polarization response can rotate or reshape the profile. Temporal self-phase modulation is a related consequence of a time-dependent intensity, but should be distinguished from these transverse effects.
For an experimental check, vary power at fixed input waist and compare near- and far-field profiles with a low-power diffraction reference. Repeat with a second beam blocked to separate cross-phase modulation from self-action. Vary pulse duration or repetition rate to test thermal lensing against a prompt electronic response, and monitor transmission to distinguish nonlinear refraction from preferential absorption. A smaller output spot alone does not establish a soliton or a pure Kerr response.
The optical Kerr effect gives an intensity-dependent refractive index, , in the simplest instantaneous isotropic model. A beam whose intensity varies transversely therefore writes a transverse index profile into the medium. Over length its nonlinear phase is approximately , with .
For a bright-centered beam, positive raises the index at the center and produces self-focusing; negative produces self-defocusing. The medium acts as an intensity-dependent lens. This is a transverse effect, distinct from temporal self-phase modulation broadening a pulse's spectrum, though both originate in the same nonlinear index. Kerr lenses can provide intensity-dependent mode selection in a laser, and a beam's index profile can guide or deflect a second beam through cross-phase modulation.
The competition with diffraction appears in a paraxial model,In one transverse dimension, focusing can balance diffraction to support a bright spatial optical soliton under suitable boundary conditions. Transverse perturbations can also grow through modulational instability, breaking a broad beam into localized structures. In an ideal two-transverse-dimensional cubic model, sufficiently strong focusing permits collapse; the critical-power scale is proportional to , with its numerical coefficient depending on the convention and profile used.
A real medium does not develop an actual infinite intensity. Saturation, multiphoton absorption, ionization, nonparaxial propagation and damage can arrest or invalidate the simple model. Filament formation therefore requires more physics than inserting a real constant into a lens formula. The useful applications exploit a controllable index profile; the same positive feedback can be a serious limitation on transporting high-power beams.
Synchrotron radiation is emitted by relativistic charges accelerated along curved paths. A magnetic field can supply the transverse acceleration while doing no work on the charge; the radiated energy must ultimately be replenished if the orbit energy is to remain constant. Relativistic beaming confines much of the radiation to angles of order about the instantaneous velocity.
For circular motion of curvature radius and ,The exact classical circular-orbit power contains an additional factor . A distant observer sees short pulses as the beamed direction sweeps past, producing a broad high-frequency spectrum. Radiation is predominantly linearly polarized in the orbital plane and becomes elliptically polarized off it. The critical frequency is a spectral scale, not a monochromatic emission frequency or a hard cutoff.
Original geometric synchrotron-beaming schematic: radiation near the velocity tangent, cone angle of order inverse Lorentz factor and curved electron trajectory
. Details. Storage rings provide intense radiation for spectroscopy and diffraction, while relativistic electrons in astrophysical magnetic fields also produce synchrotron emission. The classical theory relates total power, angular beaming and spectrum to the particle's trajectory; sufficiently strong quantum recoil requires corrections.[ref]
On the Classical Radiation of Accelerated Electrons by Julian Schwinger. Physical Review 75, 1912 (1949), primary abstract: total radiation, angular preference and high-frequency spectrum of accelerated energetic electrons
Past exam of the optics and electrodynamics course of the University of Cambridge 2017 1 b Solution 2026-10-18
Let be the intensity from either fibre alone at the observation point, assuming equal output intensities, matching polarizations and negligible drift. The screen samples the relative phase between the two outputs. For an ideal monochromatic laser, first-order optical coherence is complete andThe interference fringes are approximately equally spaced in the small-angle far field, with a slowly varying diffraction envelope. If the output separation is and the screen distance is , the interference fringe spacing is approximately . Equal phases at the two input ends do not ensure a central bright fringe: the extra fibre contributes carrier phase in addition to the free-space optical path difference.
For a finite linewidth, the time-averaged interference signal becomesHere may be defined for the slowly varying field envelope, with the carrier phase already included in . A realistic laser therefore gives reduced interferometric visibility; for , its extrema are and .
Ideal and finite-linewidth interference for equal output intensities
. Details. For a Lorentzian line shape of frequency full width at half maximum , temporal optical coherence givesThe relevant index is the group index. Using the intended nondispersive approximation ,This delayed-fibre linewidth measurement assumes the loss of contrast comes from linewidth. Unequal output intensities, polarization mismatch or mechanical phase fluctuations also lower interferometric visibility. If dispersion matters, the stated phase index alone does not specify the necessary group index.
nuclear radius scaling follows approximately with for a sharp matter-radius convention. Consequently the interior nucleon density is nearly independent of mass number: nuclear forces are short range and exhibit nuclear matter saturation. A diffuse nuclear charge distribution has a charge-weighted root mean square radius, not a hard surface. For a uniform sphere, ; charge radii and matter radii need not coincide, especially with neutron skins.
Elastic electron scattering measures the nuclear charge form factor. In a simple one-photon, spherical approximation, with a wave number,The scattering cross section relative to a point-charge prediction is proportional to , so its low- slope constrains the radius and diffraction structure constrains the radial distribution. Finite momentum coverage and Coulomb distortion in electron scattering limit reconstruction. In Robert Hofstadter's experiment a magnetic spectrometer separated elastic and inelastic electron peaks; beam-charge normalization and closed-slit background checks prevented raw count structure from being mistaken for a nuclear charge form factor.[ref]
Electron Scattering and Nuclear Structure by Robert Hofstadter. §III(b)(1), pp. 222–223; §IV(a), pp. 227–231
A useful intrinsic-shape description is . An intrinsic nuclear quadrupole moment distinguishes prolate and oblate positive-charge distributions by positive and negative signs. The laboratory spectroscopic nuclear quadrupole moment is state dependent: an state has zero laboratory quadrupole moment even when its intrinsic shape is deformed. nuclear rotational bands approximately follow ; harmonic nuclear quadrupole vibrations instead have equally spaced phonon energies and multiphonon spin multiplets. Measured electric quadrupole transitions test the collective interpretation in addition to level energies. Radius probes spatial extent; quadrupole observables and collective spectra probe shape.
High-energy elastic electron scattering probes nuclear charge through the electromagnetic interaction. Resolve the elastic peak with a spectrometer, measure its angular dependence and normalize by beam charge, target thickness and detector acceptance. In a plane-wave, approximately static treatment,Here is physical momentum transfer divided by , not the momentum itself. The low- slope, , determines the charge r.m.s. radius. A sharp uniform sphere hasIts first diffraction minimum is at , illustrating how angular structure determines size. Radii approximately follow , but a sharp radius, a surface half-density radius and an r.m.s. radius are different definitions.
A motivating experimental implementation is Hofstadter's magnetic-spectrometer measurement: selecting outgoing electron momentum separates elastic scattering from nuclear excitation, rather than treating every scattered electron as an elastic event. Beam-energy and angle calibration, empty-target or blocked-acceptance backgrounds, and target-thickness checks matter. Finite resolution mixes nearby excitations; multiple scattering and Coulomb distortion require correction before a precision density is inferred.[ref]
Electron Scattering and Nuclear Structure by Robert Hofstadter. §III(b), pp.222–223; §IV(a), pp.227–231, spectrometer scans and elastic/inelastic separation
Shape information comes from quadrupole moments, Coulomb-excitation transition strengths and rotational spectra. An intrinsic axial moment is positive for a prolate charge distribution and negative for an oblate one. A laboratory quadrupole moment is not identical to : a rotationally averaged spin-zero state can have zero laboratory moment despite intrinsic deformation. Collective rotational levels approximately follow , while measured strengths test the associated charge collectivity. Muonic-atom X-rays and isotope shifts supply complementary charge-radius constraints; hadronic probes provide additional, more interaction-dependent matter and neutron information. Neither a charge radius alone nor a finite-range form-factor measurement uniquely fixes the entire nuclear shape.
Original model charge form factors at equal r.m.s. radius; the diffraction structure carries information beyond the radius
. Details. Past exam of the particle and nuclear physics course of the University of Cambridge 2017 2 a Solution Created 2026-10-18 Updated 2026-10-20
What is measured. A monoenergetic electron beam is directed at a thin target. A movable magnetic spectrometer selects the scattering angle and outgoing momentum, separating elastic scattering from nuclear excitation and other backgrounds. Incident beam current and target thickness supply the normalization of the differential scattering cross-section. The Hofstadter nuclear electron scattering experiment is a classic implementation of this electromagnetic probe.
For a heavy, approximately spin-zero atomic nucleus, neglecting recoil and treating the electron in the Born approximation, the point-charge result is multiplied by the nuclear charge form factor:Here is the magnitude of the spatial momentum transfer in natural units. The cosine factor includes the electron spin. Dividing the elastic data by the point-charge factor isolates within these approximations. Recoil, magnetic terms for targets with spin, radiative corrections and particularly Coulomb distortion in electron scattering must be included when significant.
From scattering to size and shape. For a spherical nuclear charge distribution,Thus the nuclear charge form factor is a normalized Fourier transform. Its low- expansion,measures the nuclear charge radius . Larger momentum transfers resolve the density profile through diffraction maxima and minima. For a uniform sphere of sharp radius , the uniform-sphere nuclear charge form factor is ; its first zero is at , while .
A practical extraction fits a family of densities to all measured cross sections, rather than treating a few measured values of as a complete density reconstruction. Finite angular coverage, resolution and the missing sign information make this an inverse problem.
Observed pattern. Apart from the lightest nuclei, the central density is approximately constant; the size grows approximately as and there is a diffuse surface. The coefficient describes an equivalent sharp nuclear radius, rather than the root-mean-square radius itself. Heavy nuclear charge distributions are often described by the two-parameter Fermi nuclear charge distribution, , with half-density radius scaling roughly as and diffuseness around . The surface thickness is then about . Shell effects, deformation and the lightest systems give departures from this smooth pattern. These qualitative features are established by the electron scattering density measurements.[ref]
Original sharp-edge and diffuse nuclear charge models, showing how a surface profile changes the nuclear charge form factor
. Details. Complementary probes. Transition energies in a muonic atom are especially sensitive to nuclear size because the heavy negative muon orbits close to the charge. Electronic isotope shifts, after separating nuclear-mass and finite-size contributions, measure changes in . Both require atomic-structure calculations. Electromagnetic excitation and transition strengths constrain deformation and charge multipoles. Hadronic scattering can also constrain nuclear dimensions, but carries uncertainties from the strong interaction and probes matter rather than purely electric charge.
Let be the intensity that either narrow slit would produce alone, and let measure screen displacement from the perpendicular bisector. The optical path difference is approximately . Equal coherent field amplitudes then giveThe maxima are at ; the minima are halfway between them. HereThe expression uses the paraxial approximation and neglects the slowly varying single-slit diffraction envelope because the slit widths are unspecified.
In wave optics, a finite lens aperture produces diffraction. Contributions interfere constructively near the geometric focus but form a finite point spread function, rather than a point of infinite intensity. For a uniformly illuminated circular aperture of diameter , the paraxial focal pattern is an Airy disk, with first dark-ring radius approximately . Aberrations can broaden or distort it further; even an ideal lens retains the finite diffraction scale.
With the Sun behind the observer and raindrops ahead, the one-reflection branch sends many light rays toward directions close to the minimum deviation angle. Nearby values of the angle of incidence produce nearly the same outgoing direction there, forming a wave caustic. For water the resulting cone is approximately from the antisolar direction. The observer sees the intersecting drops as a circular rainbow, or the part of that circle visible above the ground.
Normal dispersion makes the refractive index larger for violet than for red light. At the minimum, increasing the refractive index increases the deviation angle, and therefore decreases the viewing angle . Red is on the outer edge of the primary rainbow, violet on the inner edge. The internal specular reflection is partial: with , the relevant is below the critical angle . Diffraction and the finite angular size of the Sun smooth the geometrical concentration; the physical intensity does not actually become infinite.
In Fraunhofer diffraction, the source and observation geometry make the incident and outgoing wavefronts effectively planar across the aperture. For direct propagation over distance , the quadratic variation in propagation phase across a slit of width must be negligible, approximately . The far-field angular amplitude is then the Fourier transform of the aperture's complex illumination. A converging lens also produces this angular distribution in its rear focal plane for collimated illumination, without requiring a physically enormous observation distance. The approximation concerns the aperture-dependent phase, not the absence of diffraction.
Let the slit run over and let its coherent illumination have constant complex amplitude . In a direction making angle to the normal, the relative propagation phase from position is , with . Summing the secondary amplitudes givesThe intensity is proportional to the squared modulus, hence within the usual scalar Fraunhofer diffraction approximationThe central value is defined by the continuous limit . The nonzero minima satisfy for integer . This expression neglects the slowly varying obliquity factor and uses a uniform slit; it describes the narrow-angle diffraction pattern for .
A mercury-vapor lamp is an extended, spontaneously emitting source, so practical interference requires spatial filtering and spectral selection. A narrow illuminated source slit gives sufficient spatial coherence; selecting one strong spectral line improves temporal coherence and avoids overlapping differently spaced interference fringes.
In the classical double-slit experiment, both apertures are illuminated by the same narrow source. The arrangement is symmetric, permits direct measurement and adjustment of slit separation, and has equal optical materials in the two paths. Its main drawbacks are low transmitted intensity through narrow apertures, the need for a well-made closely spaced slit pair and alignment, and the finite single-slit diffraction envelope. A broad source washes out interference fringes.
Lloyd's mirror uses the direct wave from a narrow source and the reflected wave, which appears to come from its virtual image behind a plane mirror. It requires only one physical source slit; the mirror can be adjusted to make a small effective source separation without manufacturing a double aperture. Only the direct-reflected overlap region shows interference fringes. Finite mirror size, alignment, surface quality, unequal intensities and the polarization-dependent reflection coefficient can reduce visibility. For the usual grazing reflection from glass, the reflected electric wave acquires approximately a phase shift, so the zero path-difference position is dark rather than the bright central fringe of the symmetric classical double-slit experiment. Both arrangements still require adequate spatial coherence and temporal coherence.
Illuminate a narrow entrance slit with the mercury-vapor lamp, use a collimating lens to illuminate two parallel narrow slits coherently, and insert a bandpass filter selecting the green line. Place a screen or scanning detector a measured distance beyond the double slit. The source slit and the two apertures should be parallel. The aperture widths should be appreciably smaller than their separation to provide an extended diffraction envelope; the green filter should reject the other strong mercury lines. The layout is drawn below.
For slit separation and observation angle , the optical path difference in air is . At a bright interference fringe, . For a distant screen and small angles, , givingMeasuring several interference fringe spacings and dividing by their number reduces relative position error. The derivation assumes the slits have equal phase on illumination and that the screen region lies within their common diffraction envelope.
The two wavelengths have independent interference patterns. Their interference fringe spacings areDifferent optical frequencies do not maintain a fixed mutual phase over the detector's integration time, so their intensities add. For narrow equal slits, suppressing the slowly varying diffraction envelopes, one may writeThe relative line strengths are not supplied; the figure illustrates equal peak intensities rather than inferring a quantitative brightness ratio. At both colours are bright, producing a blue-green mixture. Away from the centre the green and blue interference fringes progressively separate, creating alternating colour and brightness variations; places where one line is dark can still be bright in the other. Neither two-line mixing nor its central maximum is generally white.
Across , the green maxima occur at for , and the blue maxima at for . Near , the fourth green and fifth blue maxima nearly coincide: and . The mismatch shows that these are near coincidences, not exact ones for the given wavelengths. The plotted central interval includes all these maxima.





