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A chirped Gaussian wave packet adds a quadratic quantum phase to the zero-mean Gaussian wave packet already evaluated above. Here $\sigma >0$ and $\kappa$ is a real dimensionless parameter. Its probability density function $|{\psi }_{\sigma ,\kappa }(x){|}^2$ is unchanged for every $\kappa$, so $⟨x⟩=0$ and $(\Delta x{)}^2={\sigma }^2$. Nevertheless, applying the momentum operator givesThe sign of the quantum covariance follows directly, without assigning a classical trajectory to the wavefunction:Here $r$ is a normalized symmetrized quantum covariance, analogous to a correlation coefficient. Positive $\kappa$ gives positive $C_{xp}$, and reversing $\kappa$ reverses $C_{xp}$ while leaving both variances unchanged. In the negative-exponent Fourier transform convention used above, the momentum density isConsequently the quantum uncertainty product and the covariance matrix determinant tell different stories:Every member of this pure state family saturates the Robertson-Schrödinger uncertainty relation. Only $\kappa =0$ saturates the Heisenberg uncertainty relation for this fixed pair of position and momentum axes. Thus being a Gaussian wave packet alone does not imply a minimum $\Delta x\Delta p$.

For a concrete comparison, choose a reference length $L$, put $X=x/L$, $P=pL/\hslash$, and set $\sigma =L$. The choices $\kappa =0,+2,-2$ all have $(\Delta X{)}^2=1$, but give $(\Delta P{)}^2=1/4,5/4,5/4$ and $C_{XP}=0,+1,-1$, respectively. The two nonzero cases have $r=\pm 2/\sqrt{5}$ and product $\sqrt{5}/2$; all three covariance matrices have determinant $1/4$.

The phase space curves in the figure satisfy $z^T{\Sigma }^{-1}z=1$ in the dimensionless coordinates, where $z=(X,P{)}^T$. They display second moments, not observed simultaneous position and momentum pairs. Their common area is $\pi \sqrt{\det \Sigma }=\pi /2$, although their coordinate projections differ.

This distinction is useful for predicting focusing. Under free particle evolution with mass $m$, $x(t)=x(0)+tp(0)/m$, soA negative chirp initially narrows the position distribution; positive chirp initially broadens it. For $\kappa <0$, the minimum occurs at $t_{\ast }=-2m{\sigma }^2\kappa /[\hslash (1+{\kappa }^2)]>0$ and has variance ${\sigma }^2/(1+{\kappa }^2)$. At that time the quantum covariance vanishes, and the unchanged momentum spread gives $\Delta x(t_{\ast })\Delta p=\hslash /2$. The extra initial product was a usable position-momentum correlation, not extra measurement backaction.

An energy eigenvalue is an eigenvalue of the Hamiltonian operator $H$: there is a nonzero vector $\psi$ in its operator domain $D(H)$ withFor a self-adjoint operator, $E$ is real. Normalizing $\psi$ produces an energy eigenstate; an ideal energy measurement then returns $E$ with probability one. The associated energy eigenspace includes all vectors with this same energy eigenvalue, including the zero vector, which represents no quantum state. Different energy eigenvalues have orthogonal energy eigenspaces. ^[ref].

The energy eigenvalues form the point spectrum, which can be only part of the spectrum. The term discrete spectrum more specifically means isolated eigenvalues of finite multiplicity. The usual fixed-nucleus hydrogen atom model has discrete negative bound state energy eigenvalues together with a continuum at nonnegative energy. ^[ref]. A quantum system need not have a ladder of discrete energy eigenvalues: a whole-line free particle has continuous spectrum. A plane wave used for a free particle is a generalized eigenfunction of the Hamiltonian operator, rather than a normalized vector in the physical Hilbert space. ^[ref].

For the infinite square well $0<x<L$, the Dirichlet boundary conditions giveSubstitution into $H{\varphi }_n=E_n{\varphi }_n$ and wavefunction normalization verify these statements directly. Here $E_1$ is the ground-state energy, even though its index is one; the labeling convention does not determine which quantum state is lowest. Equal populations of ${\varphi }_1$ and ${\varphi }_2$ have energy expectation value $(E_1+E_2)/2=5E_1/2$, but an energy measurement returns $E_1$ or $4E_1$, each with probability $1/2$. An average of allowed energy eigenvalues need not itself be an energy eigenvalue.

In the stationary-state terminology used here, an excited state is a normalized energy eigenstate with energy eigenvalue $E>E_0$, where $E_0$ is an attained ground-state energy. Its excitation cost above the ground state is $\Delta E=E-E_0>0$. Several energy eigenstates can share one excited energy eigenvalue through degenerate energy levels. An arbitrary quantum superposition with energy expectation value above $E_0$ need not be a single stationary excited state; its energy content is described by its Born rule probabilities or, for a continuum, its scalar spectral measure.

An excited state can be a stationary state: the second infinite square well mode is an immediate example. Spontaneous photon emission is a transition caused by coupling matter to the electromagnetic field; it is absent from an isolated matter-only Hamiltonian operator. The relevant energy eigenstate of that isolated model is therefore not automatically an energy eigenstate of the full interacting system. This distinction explains how an ideal stationary excited state can approximate a state with a finite experimental lifetime. See electric-dipole interaction for the coupling used in the simplest optical model.

For a one-photon transition between stationary internal states, neglecting recoil, conservation of energy requiresHere $h$ is the Planck constant and $\nu$ is the photon frequency. Energy matching alone does not guarantee a transition: in the electric-dipole interaction approximation its strength also involves the matrix element $⟨f|\mathbf{d}\cdot \mathbf{ϵ}|i⟩$, where $\mathbf{d}$ is the electric dipole moment operator and $\mathbf{ϵ}$ specifies photon polarization. A zero matrix element gives an electric-dipole selection rule. Thus an absent optical line does not prove the corresponding energy eigenvalue is absent; a different interaction can couple different states. ^[ref]. The Franck-Hertz experiment gives a particularly instructive comparison between collision excitation and photon emission.

The first excited state terminology assumes a least energy eigenvalue above $E_0$. Such a next level is not guaranteed by quantum mechanics: a continuous spectrum can start immediately above the spectral bottom, or energy eigenvalues can accumulate there. For example, a Hamiltonian operator with energy eigenvalues $0,\epsilon ,\epsilon /2,\epsilon /3,\dots$, where $\epsilon >0$, has a ground-state energy zero but no least positive energy eigenvalue: every candidate $\epsilon /n$ is exceeded downward by $\epsilon /(n+1)$. A free particle on the whole line has neither a ground state nor a first stationary excited state. Each use of a discrete excitation ladder therefore needs a specified Hamiltonian operator and its boundary conditions.

For a free particle of mass $m>0$ in nonrelativistic quantum mechanics, choose the potential energy zero and writeApplying the momentum operator $-i\hslash \nabla$ returns $\mathbf{p}\psi$; this fixes the sign convention. The angular frequency is measured relative to this chosen energy zero. Adding a constant energy changes only a time-dependent global phase, leaving the spatial de Broglie wavelength unchanged. No rest-energy term is included in this nonrelativistic quantum mechanics convention.

The plane wave has $|\psi {|}^2=|A{|}^2$ and probability current $\mathbf{j}=(\mathbf{p}/m)|A{|}^2$. Its real part can be drawn as a sine or cosine, but that graph is a component of a probability amplitude, not a transverse displacement. On infinite space this is a generalized momentum eigenstate, not a state satisfying wavefunction normalization. A narrow wave packet instead moves with group velocity ${\nabla }_{\mathbf{k}}\omega =\mathbf{p}/m$; the phase velocity $\omega /|\mathbf{k}|=|\mathbf{p}|/(2m)$ is not its transport speed.

The equality of canonical momentum and kinetic momentum here assumes a field-free region with the magnetic vector potential chosen zero. For a charged particle in a magnetic field, the kinetic momentum is $\mathbf{\Pi }=\mathbf{p}-q\mathbf{A}$. An arbitrary canonical phase gradient must not then be substituted into $m\mathbf{v}$; the free particle formula needs its stated assumptions.

A ground state is a normalized energy eigenstate that attains the lowest possible energy of a quantum system. Precisely, let the Hamiltonian operator $H$ be a self-adjoint operator bounded below on a Hilbert space, and write $E_{\ast }=\inf \sigma (H)$ for the infimum of its spectrum. A ground state is a unit vector ${\psi }_0$ in the operator domain $D(H)$ satisfyingThus a ground state exists exactly when the spectral bottom $E_{\ast }$ is an energy eigenvalue. The lowest energy eigenvalue among some listed bound states is insufficient if other parts of the spectrum lie below it. The ground-state subspace collects all minimizing energy eigenstates; it can have ground-state degeneracy. The quantum variational principle characterizes $E_{\ast }$ as the infimum of normalized energy expectation values. ^[ref].

For the one-dimensional quantum harmonic oscillator, the ground state has energy $\hslash \omega /2$ above the minimum of the potential energy. This zero-point energy is compatible with being the lowest allowed energy: a localized wavefunction cannot simultaneously have zero kinetic energy. For a free particle on the whole line, the spectral bottom is zero but is unattained by any normalizable wavefunction; see ground-state energy. A lower bound therefore need not describe a physically preparable energy eigenstate.

The ground state supplies a reference for excitation costs and for the quantum variational principle. A ground state is also a stationary state under a time-independent Hamiltonian operator: its quantum phase changes, while its position probability density stays fixed. A nonzero ground-state energy does not imply motion along a classical trajectory, and ground-state degeneracy means there need not be a unique lowest quantum state.

When a ground state exists, its ground-state degeneracy is the dimension of the ground-state subspace:Here $I$ is the identity operator, and the kernel of a linear map is taken within the operator domain of the Hamiltonian operator $H$. The count concerns linearly independent energy eigenstates, rather than every normalized quantum superposition or every choice of global phase. Even a single energy eigenspace contains infinitely many representing vectors; its dimension measures independent freedom. Ground-state degeneracy is the lowest-energy instance of degenerate energy levels.

For an exact finite model with energy unit $\epsilon >0$, let the Hamiltonian operator be the diagonal matrixIts ground-state energy is zero and $g_0=2$: the first two coordinate unit vectors $e_1,e_2$ span the ground-state subspace. Every normalized $a{e}_1+b{e}_2$, with $|a{|}^2+|b{|}^2=1$, is a ground state, including $(e_1+e_2)/\sqrt{2}$. Its energy measurement is certain to return zero, even though a measurement distinguishing $e_1$ from $e_2$ need not have a definite outcome. Under the unchanged Hamiltonian operator, this quantum superposition is a stationary state because both components acquire the same global phase.

Ground-state degeneracy matters when an interaction selects or splits previously equal energy eigenvalues. In the finite model, adding $\epsilon \mathrm{diag}(\delta ,-\delta ,0,0)$ with $0<\delta <2$ gives the formerly lowest pair the distinct energies $\pm \epsilon \delta$, leaving a unique ground state. This direct calculation illustrates why degenerate perturbation theory first examines the perturbation inside the whole ground-state subspace.

A classical continuous-symmetry model can instead have a manifold of minimizing configurations, such as the sphere of orientations of a Néel state in an isotropic Heisenberg antiferromagnet. That geometric description does not by itself count the dimension of a finite quantum ground-state subspace.

The ground-state energy $E_0$ is the energy eigenvalue attained by a ground state. For a self-adjoint operator $H$ bounded below, distinguish this attained value from the always-defined spectral bottom $E_{\ast }=\inf \sigma (H)$. When a ground state exists, $E_0=E_{\ast }$. Some usage calls $E_{\ast }$ the ground-state energy even when it is unattained; here an unattained bottom is explicitly identified as an infimum. The quantum variational principle statesApproaching this infimum with trial wavefunctions does not ensure that a minimizing wavefunction exists. ^[ref].

For the whole-line free particle with mass $m>0$,Its spectrum is continuous and contains no energy eigenvalues represented by normalizable wavefunctions. The Fourier transform makes $H$ multiplication by ${\hslash }^2{k}^2/(2m)$; a fixed energy restricts $k$ to a set of zero length, on which a nonzero square-integrable function cannot be supported. ^[ref]. An explicit family of normalized Gaussian wave packets demonstrates how the bottom is approached:The formula follows from ${\psi }_s^{\prime }=-x{\psi }_s/(2s^2)$, integration by parts, and $⟨x^2{⟩}_s=s^2$. Every finite width gives positive kinetic energy. At zero energy, $H\psi =0$ would require an affine function on the whole line, which is never a nonzero normalizable wavefunction. Spreading a Gaussian wave packet indefinitely produces an unattained infimum, rather than a zero-energy ground state.

An additive choice of energy origin changes the numerical ground-state energy without changing the ground-state subspace. For $H^{\prime }=H+CI$, every energy eigenvalue becomes $E^{\prime }=E+C$, while all differences $E_j-E_i$ stay fixed. Time evolution gains only the global phase $e^{-iCt/\hslash }$. This makes excitation costs and spectroscopic differences more intrinsic than the isolated number $E_0$.

A confined ground state requires $k>0$; take $\alpha >0$ so the trial wavefunction is normalizable. Its normalized form isThe Gaussian moment recurrence gives $⟨x^2⟩=1/(2\alpha )$ and $⟨x^4⟩=3/(4{\alpha }^2)$. Also, integration by parts gives $⟨p^2⟩={\hslash }^2\int |f_{\alpha }^{\prime }{|}^{2}dx={\hslash }^2\alpha /2$. The Rayleigh quotient for the quartic oscillator is consequentlyDifferentiation yields ${\mathcal{E}}^{\prime }(\alpha )={\hslash }^2/(4m)-3k/(2{\alpha }^3)$, so the unique minimum is at ${\alpha }_{\ast }=(6mk/{\hslash }^2{)}^{1/3}$. Since the quotient diverges at both endpoints $0$ and $\infty$, this is the global minimum in the trial family. The Rayleigh-Ritz variational principle givesFor the first excited energy eigenstate, choose the odd trial familyThe even confining potential has an even, nodeless ground state, by the nodeless theorem for a one-dimensional ground state. By the Sturm oscillation theorem, its first excited state is odd with one node. The proposed family has the same parity operator eigenvalue and one node, and is orthogonal to the exact ground state, not merely to its Gaussian trial approximation. Minimization in the odd linear subspace therefore bounds the first excited energy from above. For completeness, its Rayleigh quotient is $3{\hslash }^2\beta /(4m)+15k/(4{\beta }^2)$, minimized at ${\beta }^3=10mk/{\hslash }^2$, giving $E_1\le (9{\hslash }^2/8m)(10mk/{\hslash }^2{)}^{1/3}$. These are Gaussian variational bounds for a quartic oscillator.

If $k=0$, there is no normalizable free particle ground state on the whole line, though the spectral infimum is zero. If $k<0$, the Hamiltonian operator is not bounded below, so a ground-energy bound of the requested kind does not exist.

For a free particle, vary the Euclidean action with a variation $h$ obeying $h(0)=h(T_E)=0$. Integration by parts givesThe Euler-Lagrange equation is therefore ${\ddot{x}}_0=0$. The fixed boundary conditions determine its unique solution:This classical path is also the unique minimum among paths with finite Euclidean action: the second variation is $m{\int }_0^{T_E}{\dot{h}}^{2}d\tau >0$ for every nonzero admissible variation. Its Euclidean action is

The Brownian motion displacement has a normal distribution with variance $\Gamma t$. Its transition probability density function is thereforeComparison with the free particle heat kernel obtained in part (c) gives the required matching:This matches whole path distributions after a linear reparametrization, not merely endpoint variances. To see this, divide the Brownian duration $t$ into $M$ slices of size $\delta t$. The independent increments have normal distributions with variance $\Gamma \delta t$, so their joint density contributesFor the Euclidean path integral, the corresponding expression isThe matching condition makes $\Gamma \delta t=\hslash \delta \tau /m$, so both the exponents and all normalization factors coincide. In particular, identifying Brownian time with imaginary time, $t=\beta \hslash$, requires $\Gamma =\hslash /m$, or diffusion coefficient $D=\hslash /(2m)$.

With both endpoints fixed, the normalized path law is a Brownian bridge. The Euclidean path integral itself is the endpoint density times that conditional path law. In the normalized time coordinate $s=\tau /(\beta \hslash )$, its expected value and covariance areThe classical path is therefore the bridge's expected value, while individual Brownian bridge paths fluctuate about it. Typical Brownian motion paths are continuous but nowhere differentiable: the kinetic Euclidean action is interpreted through the time-sliced diffusion path integral, rather than by assuming that a typical path has an ordinary velocity.

Use position eigenstates normalized by $⟨q|q^{\prime }⟩=\delta (q-q^{\prime })$, and the free Hamiltonian operator $\hat{H}={\hat{p}}^2/(2m)$. The time-sliced path integral is the matrix element of the time-evolution operator:Insert momentum eigenstates, with $⟨q|p⟩=(2\pi \hslash {)}^{-1/2}{e}^{ipq/\hslash }$. The free-particle propagator becomesComplete the square in the exponent:The Fresnel integral, defined by the damping prescription $T\to T-i0$, gives, for $T>0$,The square-root branch is $i^{-1/2}=e^{-i\pi /4}$; it is fixed by the regulated Gaussian integral and the short-time Dirac delta distribution limit, rather than an arbitrary phase.

The Euler-Lagrange equation for the free particle is $m\ddot{q}=0$. Its unique classical path satisfying the endpoint boundary conditions is $q_{\mathrm{cl}}(t)=q^{(i)}+\Delta qt/T$. Therefore its classical action isSubstituting into the operator result yields $\mathcal{I}=C(T)e^{i{S}_{\mathrm{cl}}/\hslash }$, with $C(T)=(m/(2\pi i\hslash T){)}^{1/2}$ independent of the endpoint positions.

The same independence is transparent directly in the path integral. Write $q=q_{\mathrm{cl}}+\eta$, with $\eta (0)=\eta (T)=0$. The cross term in the action is $m{\dot{q}}_{\mathrm{cl}}{\int }_0^T\dot{\eta }dt=0$, so $S[q]=S_{\mathrm{cl}}+(m/2){\int }_0^T{\dot{\eta }}^{2}dt$. The fluctuation integral depends only on $m,T,\hslash$. Because the action is quadratic, the factorization is exact; the semiclassical propagator already equals the full answer.

For a normalized trial state $\psi$, expand it in an orthonormal basis of energy eigenstates, $\psi ={\sum }_n{c}_n{\psi }_n$. The Rayleigh quotient is thenThis is the quantum variational principle: minimizing the expectation of the Hamiltonian operator over any trial family gives an upper bound on the ground-state energy.

Let $\psi$ be the normalized ground-state wavefunction and form the normalized dilation ${\psi }_{\lambda }(x)={\lambda }^{1/2}\psi (\lambda x)$. Its kinetic and potential expectations areThe true ground state makes the energy stationary at $\lambda =1$, soThus the power-law quantum virial theorem gives

If $n\le -3$ and $A>0$, the two sides have opposite signs, because $T>0$ and $V>0$. If $A<0$, the scaled energy ${\lambda }^{2}T+{\lambda }^{-n}V$ tends to $-\infty$ as $\lambda \to \infty$, since $-n>2$, so the Hamiltonian is not bounded below. If $A=0$, the free particle has no normalizable ground state. Hence there is no normalizable ground state for $n\le -3$.

For $n=1$ take the normalized Gaussian functionThe Gaussian integral givesand thereforeIts unique minimum satisfiesAt this point $⟨V⟩=2⟨T⟩$, consistently with the virial theorem, and the resulting variational estimate is

For longitudinal motion in transverse subband $i$,For a completely free particle take $E_i=0$ and use the full wave vector. In a semiconductor the parabolic-band mass is the appropriate effective mass rather than necessarily the bare electron mass.

Put $s=1+it$. Logarithmic differentiation givesThereforeso the appropriate potential energy is $\boxed{V(x)=0}$. The wavefunction never vanishes, so no other time-independent potential gives the same equation for this precise phase choice.

The squared modulus isIt changes width and height with time, so this is not a stationary state. Its integral is the constant $\sqrt{\pi \hslash /m}$; multiplying the wavefunction by $(m/(\pi \hslash ){)}^{1/4}$ normalizes it. The normalized Gaussian wave packet stays centred at zero but spreads, with position variance $\hslash (1+t^2)/(2m)$. It represents a localized free particle with a spread of momenta, rather than an energy eigenstate. Free Gaussian wave packet evolution broadens the packet even with zero mean momentum.

Put $s=1+it$. Logarithmic differentiation givesThereforeso the appropriate potential energy is $\boxed{V(x)=0}$. The wavefunction never vanishes, so no other time-independent potential gives the same equation for this precise phase choice.

The squared modulus isIt changes width and height with time, so this is not a stationary state. Its integral is the constant $\sqrt{\pi \hslash /m}$; multiplying the wavefunction by $(m/(\pi \hslash ){)}^{1/4}$ normalizes it. The normalized Gaussian wave packet stays centred at zero but spreads, with position variance $\hslash (1+t^2)/(2m)$. It represents a localized free particle with a spread of momenta, rather than an energy eigenstate. Free Gaussian wave packet evolution broadens the packet even with zero mean momentum.

The free particle dispersion relation is $\hslash \omega ={\hslash }^2{k}^2/(2m)$. HenceThe phase velocity follows constant-phase surfaces of a plane wave. The group velocity follows the envelope of a narrow-band wave packet and equals its classical velocity $p/m$. Dispersion can spread the packet; the phase speed is not the particle's transport velocity. In three dimensions ${\mathbf{v}}_g=\hslash \mathbf{k}/m$ and the phase speed quoted is along $\mathbf{k}$.

A localized quantum particle is described by a wave packet: a coherent quantum superposition of momentum components, rather than a single delocalized plane wave. The Born rule assigns the position probability density $|\psi (x,t){|}^2$. A useful normalized initial Gaussian wave packet isIts mean position and momentum are $x_0$ and $p_0$, and its standard deviations satisfy ${\sigma }_x(0)={\sigma }_0$, ${\sigma }_p=\hslash /(2{\sigma }_0)$. This unchirped initial state saturates the Heisenberg uncertainty relation.

For a free particle, the momentum-space Schrödinger equation multiplies each amplitude by $e^{-i{p}^{2}t/(2m\hslash )}$. The inverse Fourier transform is a Gaussian integral, giving the free Gaussian wave packet evolutionOne way to obtain this expression explicitly is to write the initial momentum amplitude as proportional to $\exp [-{\sigma }_0^2(p-p_0{)}^2/{\hslash }^2-ip{x}_0/\hslash ]$, multiply by the free evolution phase and complete the square in $p$. Taking the modulus squared removes the position-dependent phase and leavesThe expectation value follows uniform classical motion while the density spreads. A narrower initial packet needs a wider momentum distribution and therefore spreads more rapidly. At long times its width grows linearly with $|t|$; its variance grows quadratically, unlike the linear variance growth of ordinary diffusion. The probability continuity equation preserves total probability despite the decreasing peak height. The mean momentum and the mean energy $(p_0^2+{\sigma }_p^2)/(2m)$ remain constant, since the momentum populations do not change.

The same result has a wave interpretation. For a free nonrelativistic particle $\omega (k)=\hslash k^2/(2m)$, so the group velocity is $d\omega /dk=\hslash k/m$, equal to $p_0/m$ at the packet center. The curvature $d^2\omega /d{k}^2=\hslash /m$ makes different momentum components travel with different group velocities, producing dispersion. The phase velocity is $\omega /k=\hslash k/(2m)$ for this energy convention and does not describe the motion of the envelope. The evolving quadratic spatial phase is essential to the spreading; a density snapshot alone does not specify the full quantum state.

A freely spreading Gaussian wave packet remains a pure Gaussian state but develops position-momentum correlations. Its symmetrized covariance is $C_{xp}=⟨\{x-⟨x⟩,p-⟨p⟩\}⟩/2=t{\sigma }_p^2/m$. ConsequentlyEquality in the Robertson-Schrödinger uncertainty relation survives at every time, whereas the simpler product ${\sigma }_x{\sigma }_p$ equals $\hslash /2$ only initially. A chirped Gaussian wave packet can already have $C_{xp}(0)\ne 0$. More generally, $x(t)=x(0)+p(0)t/m$ gives ${\sigma }_x(t{)}^2={\sigma }_x(0{)}^2+2t{C}_{xp}(0)/m+t^2{\sigma }_p(0{)}^2/m^2$. A sufficiently negative initial covariance permits initial contraction before subsequent spreading.

A potential energy changes this behavior. A quadratic potential preserves the Gaussian form because the evolution of position and momentum is linear. For a quantum harmonic oscillator, the Gaussian covariance in a harmonic potential isA coherent state has ${\sigma }_x^2=\hslash /(2m\omega )$, ${\sigma }_p^2=m\hslash \omega /2$ and zero centered covariance. Its width is constant, and its center follows $x_c(t)=x_0\cos \omega t+p_0\sin \omega t/(m\omega )$. In oscillator notation its coherent state label rotates as $\alpha (t)=\alpha (0)e^{-i\omega t}$, apart from the common ground-energy phase of the state vector. A squeezed coherent state generally has a width that breathes at $2\omega$. Thus being Gaussian does not imply either free spreading or constant width; the Hamiltonian operator and initial covariance determine the result.

For a general nonquadratic potential, different parts of the packet experience different nonlinear forces, and an initially Gaussian profile need not remain Gaussian. Ehrenfest theorem gives the exact relations $d⟨x⟩/dt=⟨p⟩/m$ and $d⟨p⟩/dt=-⟨V^{\prime }(x)⟩$. Replacing the last mean by $-V^{\prime }(⟨x⟩)$ is exact for a quadratic potential and approximate for a packet narrow compared with the scale on which the force varies. This connects packet motion to the correspondence principle without treating a quantum state as a definite classical path. Scattering can split a packet into reflected and transmitted components, while confinement can produce oscillations and interference between discrete energy eigenstates. Their relative phases evolve even when their populations remain constant. Localization, spreading and coherent motion all follow from the same linear unitary time evolution.

For a free particle, the Hamiltonian operator is $H=P^2/(2m)$, where $P=-i\hslash d/dx$ is the momentum operator. The time-independent Schrödinger equation is thereforeThe full stationary state is $\Psi (x,t)=e^{-iEt/\hslash }\psi (x)$. The periodic boundary condition identifies $x$ and $x+2\pi$, giving a particle on a circle with wavefunction normalization over one period.

The free particle has Hamiltonian operator $H=P^2/(2m)$, with momentum operator $P=-i\hslash {\partial }_x$. Its time-dependent Schrödinger equation isHere $x$ measures arc length for the particle on a circle, so the wavefunction normalization uses $dx$, rather than $d(x/R)$.

Split the time-evolution operator into $N$ factors with $ϵ=T/N$, and insert $N-1$ position completeness relations between them. Each factor is evaluated by inserting momentum states normalized by $⟨x|p⟩=(2\pi \hslash {)}^{-1/2}{e}^{ipx/\hslash }$:Multiplying the $N$ kernels and integrating the intermediate positions produces the stated time-sliced path integral, including its $N/2$ normalization power. For a free particle this Gaussian short-time kernel is exact, so the convolution identity already holds at finite $N$. Oscillatory integrals are defined with a vanishing convergence regulator, consistently fixing the square-root phase.