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For a homogeneous harmonic polynomial $H_l$ of degree $l$ in three dimensions, the Euler theorem for homogeneous functions gives $D{H}_l=l{H}_l$, where $D=\mathbf{x}\cdot \nabla$. The orbital angular momentum identity ${\hat{L}}^2=-{\hslash }^2(r^2\Delta -D^2-D)$ therefore gives ${\hat{L}}^2{H}_l=l(l+1){\hslash }^2{H}_l$. This constructs angular momentum eigenstates directly from polynomials.

The Bohr model assumes circular electron orbits with quantized orbital angular momentum $N\hslash$. It reproduces the hydrogen energy levels, but wavefunctions in quantum mechanics describe spatial probability distributions rather than definite trajectories. In particular, spherically symmetric Coulomb bound states have zero orbital angular momentum.

A Coulomb bound state is a physical normalizable eigenfunction for an attractive potential $V(r)=-\gamma /r$, $\gamma >0$. For the usual regular boundary condition at the origin its energies are the displayed values, $N=1,2,\dots$. The spherically symmetric states have orbital angular momentum zero; series-termination quantization of the Coulomb radial equation constructs them as a polynomial times a decaying exponential. Square integrability on the punctured radial interval alone does not replace the physical condition at the origin.

The parity of a two-particle centre-of-mass state with intrinsic parities ${\eta }_1,{\eta }_2$ and relative orbital angular momentum $\ell$ is

An orbital angular momentum eigenstate with quantum number $\ell$ changes by the factor $(-1{)}^{\ell }$ under spatial reflection. Equivalently,

A partial wave is a component of a scattering state with definite orbital angular momentum. A central potential preserves each angular-momentum channel, so the scattering problem decomposes into independent partial waves.