Take the two-dimensional electron gas in the plane, the Hall bar along , and with perpendicular to it. An electron has charge . The confining electron potential energy is approximately flat inside a wide strip and rises at either boundary; smooth quenched disorder adds hills and valleys. For a slowly varying edge, each spin-resolved Landau level approximately follows
Here , and is the guiding centre. For , and the edge group velocity is
Thus electrons move along at the upper edge and at the lower edge. The Lorentz force gives counterclockwise bulk cyclotron motion in this convention. At a hard boundary its interrupted circles become directed skipping orbits; a smooth boundary gives the corresponding guiding-centre drift. Smooth bulk quenched disorder generally gives closed drift contours around localized hills or valleys, with extended trajectories appearing near a broadened level's critical energy. Realistic electrostatic screening can produce alternating compressible quantum Hall edge strips and incompressible quantum Hall edge strips, so the unscreened bending curves are an effective sketch rather than an exact self-consistent edge profile.
In the original diagram, contacts are ordered around the electron propagation direction: upper-left , then lower-right . Let , and the other leads be ideal equilibrating voltage probes. Define and . These choices fix the voltage sign; reversing the field reverses chirality and the Hall polarity. For spin-resolved plateau index ,
At fixed sheet carrier density and increasing field, decreases, giving successively higher Hall plateaus; longitudinal peaks occur between them. Unresolved spin branches can suppress odd plateaus. The sketch uses resistance magnitudes, and every integer step is not promised in an arbitrary sample.
Figure 1.
Hall states and resistance
. Details.
For Fermi-energy oscillations in a two-dimensional electron gas, first distinguish fixed density from fixed reservoir chemical potential. At negligible temperature the former is determined by state counting. Each resolved Landau level contains states per unit area, so
Ignoring spin and broadening for the counting illustration, if then levels are full and level is partly full: . At fixed , increasing increases both level energy and degeneracy. The partly filled level rises in energy until the lower levels can contain all electrons; then drops to the next lower level. The resulting sawtooth is periodic in , with per resolved branch. At an exactly integer filling in an ideal gap, any chemical potential within the gap gives the same zero-temperature particle number; the plotted discontinuity denotes its limiting values.
At fixed while increases, the ideal chemical potential stays at a partly occupied level and steps upward after each additional density . It therefore has a staircase superposed on the rising zero-field trend, not a repeated downward sawtooth. Landau-level broadening and finite temperature smooth both ideal graphs. With an externally pinned chemical potential, density changes instead; the fixed-density sawtooth cannot simultaneously be imposed. In a realistic disordered sample, the Fermi energy sweeps localized states between transport-carrying level centres. The following schematic omits spin for clarity and does not attempt an interaction-corrected density of states.
For transmitted spin-resolved quantum Hall edge states, the Landauer-Büttiker formula reduces, in that contact order, to
Zero probe currents imply and . Hence and the boxed resistance results follow. The spin-resolved conductance quantum arises because the one-dimensional density of states times velocity is per unit energy; a reservoir imbalance supplies per channel. Its value does not depend on edge slope or sample width.
On a plateau, opposite-moving edge channels are separated by a wide bulk with a mobility gap. Ordinary elastic scattering on one edge has no counterpropagating channel into which to reflect; closed bulk orbits do not connect the contacts. Changing or can alter the occupancy of localized states without changing the number of transmitting edge channels. This accounts for the finite plateau width, which an entirely clean set of sharp levels would not explain. Accuracy requires negligible backscattering between opposite edges, low enough current to avoid breakdown, equilibrating contacts and negligible probe loading. The finite-width plateau and the precision of its quantized value are related but distinct observations.
An antidot is a depleted potential hill, not a potential well. Its closed edge circulates oppositely to the outer boundary. In a constriction, tunnelling through an antidot orbit can transfer an electron from a forward edge into the returning edge: resonant antidot backscattering produces conductance dips. For otherwise open spin-resolved channels and one active resonance,
At symmetric coupling a single resonance can remove ; asymmetry or thermal averaging reduces its depth. If the background constriction is closed and the resonant route instead supplies forward transmission, peaks occur. The lead connectivity must therefore accompany the conductance sketch. In the fixed-area single-particle limit, successive alignments change enclosed flux by , giving the Aharonov-Bohm antidot period
The effective orbit area, not merely the etched island area, enters. Charging, screening and spin can modify this simple sequence; two coupled spin branches can yield a near- pattern without changing the elementary flux quantum.[ref]
Figure 3.
Antidot resonant backscattering
. Details.
Use , along , and for the electron's confinement potential energy. The spin-resolved Landau level branches in the smooth-edge approximation are
The spin labels denote upper and lower energies; the sign of a material's effective factor is not inferred from the stated positive splitting. In units of , the four occupied bulk energies are . A chemical potential in therefore gives filling factor four. The branches rise at both confining edges and cross the common Fermi energy once at each edge. Each crossing is one spin-resolved quantum Hall edge state; there are four on either side. The two spin branches within an orbital level are separated by , while the intervening gap to the next orbital pair is .
Figure 1.
Original normalized edge spectrum with four occupied spin-resolved bulk branches
. Details.
In Landau gauge for a uniform magnetic field , the guiding centre is . The group velocity is
Thus the upper edge in the original trajectory diagram carries electrons to the right and the lower edge to the left. Reversing the magnetic field reverses both arrows. Semiclassically these are skipping trajectories; quantum mechanically the guiding centres label propagating quantum Hall edge states. The larger orbital-plus-spin energy crosses the Fermi energy farther toward the interior, because less confinement energy is needed. Opposite spins in one orbital branch are therefore spatially separated.
In a clean bulk with the Fermi energy between Landau levels, there are no extended bulk states at that energy. Occupied bulk cyclotron orbits lie below it; one must not draw them as extra conducting Fermi-level channels. Smooth disorder can instead produce localized bulk contours without adding a direct source-to-drain channel.
Figure 1.
Original guiding-centre trajectories for the four Fermi-level channels on each boundary
. Details.
For the spin separation at a smooth quantum Hall edge, linearize the confinement energy at a crossing. Compensating a spin energy difference by a potential-energy change gives
Here is interpreted as the specified slope of electron potential energy. If it denotes electrostatic voltage per length instead, the denominator is . The two edges of a neck and the two sides of an antidot have oppositely directed slopes; the formula is a positive local separation on any one edge. For local filling two, only the spin pair is occupied at the neck minimum: . Raising both branches with the confinement produces two crossings on each side, as shown in the original neck sketch. This fixed-slope estimate precedes self-consistent electrostatic screening.
An antidot is a depleted potential hill. guiding centres circulate around its closed equipotentials, with chirality opposite to the outer sample edge. A phase-coherent round trip contributes magnetic phase , with . A localized orbit resonant with the incident energy can transfer an electron between extended channels. If the outgoing channel returns toward the injecting reservoir, the process is resonant reflection and reduces electrical conductance. If coupling instead connects an otherwise blocked incident channel to the far reservoir, it is resonant transmission and adds electrical conductance. Transmission peaks require that forward connectivity; a closed orbit by itself does not guarantee them. Interchannel scattering can change which orbit participates.[ref]
For the antidot resonance conductance bounds with one active spin-resolved resonance, write
Here are energy broadenings; the corresponding escape rates are . In a reflection-dominated configuration with two otherwise transmitted channels, : a background can dip to . In a transmission-dominated configuration with one spectator channel and the second otherwise blocked, : peaks rise from toward . These are the two ideal channel-count examples plotted below. More generally, or ; a different spectator count changes the integer offset. The constriction filling alone does not specify every tunnel coupling or resonance height. Equal couplings permit unit resonant transfer in the isolated-level model; asymmetry, temperature and dephasing reduce the contrast. Holding the effective orbit area approximately fixed gives for one branch, not a universal charging-corrected period.
Figure 1.
Original neck spectrum, alternative channel connectivities and illustrative antidot conductance dips and peaks
. Details.
In quantum-dot versus antidot resonance topology, a quantum dot is a potential well holding a finite electron island. Its closed guiding-centre circulation is reversed relative to an antidot at the same field. With two barriers in series, current follows source dot drain; off resonance there need not be a direct conducting path. A gate shifts a level or an addition electrochemical potential into alignment with the reservoirs and produces a electrical conductance peak. For an isolated coherent spin-resolved level, the zero-temperature peak is at most and reaches it only for equal couplings; unresolved noninteracting spin degeneracy doubles this bound. In weak sequential tunnelling, peak height depends on rates and temperature rather than being quantized. Charging produces Coulomb blockade peaks with spacing set by addition energy and gate lever arm. An antidot also supports discrete orbit/charging resonances, but can be side-coupled to already open channels and produce dips. Gate voltage changes both orbit area and confinement, whereas a magnetic sweep directly changes enclosed flux.
Figure 2.
Original series-dot paths and gate resonances compared with a side-coupled antidot
. Details.
Coulomb interactions require a self-consistent confinement potential. A gradual decrease in electron density cannot leave arbitrary uncompensated donor charge at no cost. Partly occupied Landau levels have a large charge response: electrostatic screening flattens their effective energy near the Fermi energy over compressible quantum Hall edge strips. Between them, integer-filled incompressible quantum Hall edge strips have a gap, weak density response and most of the potential variation. In an idealized cross-section the effective branch thus alternates between flat, partially occupied portions and rising portions crossing a gap; its carrier density varies oppositely. The bare levels still have Landau level and spin splittings locally, but the common electrostatic potential is no longer an imposed straight slope. exchange interaction can additionally renormalize spin gaps. Widths must follow electrostatics and the density gradient, so the unscreened separation is not a quantitative screened-strip width.[ref]
graphene is a two-dimensional honeycomb lattice with two sublattices. Nearest-neighbour hopping gives two bands . They touch at two inequivalent valleys. Expanding near valley gives
The two-component spinor describes sublattice amplitudes, not real spin. This is a massless two-dimensional Dirac Hamiltonian with material velocity in place of . The emergent band quasiparticles are relativistic in this mathematical sense; the electron's vacuum rest mass is not set to zero. Real spin and valley each contribute a degeneracy of two in the ideal low-energy model.
A single-walled carbon nanotube is a rolled graphene sheet with carbon nanotube chiral vector . Periodicity requires , selecting lines through graphene momentum space and producing one-dimensional transverse electronic modes. Near a valley,
A quantization line through one of the Dirac valleys in graphene gives a metallic branch; ideal nanotube zone folding gives the criterion . Otherwise the nearest line misses the valley and opens . The transverse momentum gives a carbon-nanotube Dirac mass, with . For a large-radius ideal semiconducting tube, and , showing the inverse-diameter gap. Curvature, strain, spin-orbit coupling and interactions can change the simple classification; nominally metallic non-armchair tubes can acquire small gaps. One-dimensional transverse electronic mode thresholds give Van Hove singularities, unlike graphene's low-energy density of states proportional to .
A gate changes occupation and the Fermi level in both systems. Ideal monolayer graphene can be tuned through charge neutrality from holes to electrons, but an ordinary scalar gate does not open a bulk band gap. Including spin and valley,
The gate relation includes geometric and quantum capacitances, so one should not equate gate voltage to Fermi energy without the capacitance model. A semiconducting carbon nanotube can instead be depleted when its Fermi level lies in a gap and turned on in electron or hole bands. Contact Schottky barriers can strongly influence the observed nanotube field effect. A truly gapless ideal metallic tube cannot be switched off simply by moving the Fermi level through its band crossing. These gate responses reflect band structure and contacts, not a change of wrapping indices.
Figure 1.
Original low-energy graphene cut and metallic or gapped nanotube subbands
. Details.
Integer Hall transport and filling. A clean two-dimensional electron gas at low temperature in a strong perpendicular magnetic field forms Landau levels with orbital spacing , where . Examples include semiconductor heterojunctions and inversion layers. On integer plateaus,
with integer plateau index . The density of states in one resolved Landau branch is per unit area, so the actual filling factor is
It varies continuously with density and field. Within a disorder-broadened plateau, localized states can change occupation without changing the integer number of transporting edge branches; the filling need not equal the plateau integer at every point in that interval.
At a boundary, the confining potential bends the Landau energies through the Fermi energy, giving chiral edge states, interpreted semiclassically as skipping orbits. Opposite edges carry opposite propagation directions. An ideal spin-resolved transmitted edge channel contributes ; such channels give . Chirality and suppressed backscattering between well-separated edges explain vanishing longitudinal voltage. Ideal reservoirs and appropriate probe equilibration are part of this edge-state transport model.
A gated antidot. A local repulsive gate potential depletes an island inside the Hall bar. Edge states circulate around its boundary as closed antidot orbits. When a localized orbit is weakly coupled to extended channels on opposite sides, resonance at the reservoir electrochemical potential permits backscattering and produces conductance dips on an otherwise quantized transmitting plateau. If the path instead adds a transmission route between otherwise disconnected channels, resonant peaks can occur: the sign depends on the device's tunnel connectivity and what conductance is measured. An isolated antidot too far from every conducting edge has negligible transport signature.
For the simplest opposite-edge backscattering picture with one active branch,
where branches would otherwise transmit. A gate moves the resonance through the Fermi energy by changing both confinement and orbit area. Stronger depletion of the constrictions also changes , producing broad conductance plateaus or pinch-off, with narrow resonances superposed where coupling is finite. Low temperature resolves individual resonances; thermal and tunnel broadening can merge them.
For a fixed-area single-electron orbit, a phase change of corresponds to
Sweeping gate voltage at fixed field shifts enclosed area and level energy, giving oscillatory resonance tracks. This period is not automatically set by the lithographic gate area. Charging energy, self-consistent screening and spin branches modify spacings; in particular coupled spin branches in a charging model can generate two resonances per cycle without changing the electron flux quantum.[ref]
Figure 1.
Original schematic antidot resonances on transmitting plateaus: varied coupling and gate-controlled channel opening; illustrative coordinates rather than experimental data
. Details.
No antidot dimensions, capacitances, lever arms or measured spectrum are supplied, so absolute periods and resonance voltages cannot be extracted. The sketch illustrates the mechanisms and regimes requested, rather than inventing a numerical device data set.
Improving the bare edge potential. A picture of noninteracting Landau levels simply intersecting a prescribed smooth confinement ignores the redistribution and screening of electron charge. A self-consistent electrostatic calculation combines gate and donor potentials, electron density and Coulomb interactions. Where a partially occupied Landau level has a large density response, electrons screen strongly and create a compressible strip with nearly pinned level energy. Regions with the chemical potential in a gap are incompressible and support much of the potential change. Consequently the screened edge alternates between compressible and incompressible strips, rather than preserving an arbitrary externally drawn slope. Finite temperature, disorder, exchange and edge reconstruction can require refinements beyond the simplest electrostatic model.[ref]
Fractional states and composite fermions. Very clean two-dimensional systems show plateaus at selected fractional fillings, with small longitudinal resistance and a many-electron excitation gap. Electron-electron correlations are essential; partial filling of a noninteracting Landau level is not enough. The simplest composite fermion binds two statistical flux quanta to each electron. This is a representation of correlated electron motion, not a physical solenoid attached to a particle. With , , and density , the mean effective field is
Define a signed effective filling . Then
For , filled composite-fermion levels produce . For reversed effective field write , giving ; the nontrivial fractional upper sequence starts with . If effective filling is defined as nonnegative using , retain these as separate field-direction branches instead of using the signed expression blindly. At the mean vanishes and the effective filling diverges, so it is not an integer composite-fermion Hall plateau in this simplest construction. Attaching two flux quanta preserves fermionic statistics; the emergent integer-like gaps organize a prominent sequence of fractional electronic states.[ref]
Transverse confinement in a short clean channel gives subband dispersions
A gate varies the subband thresholds and channel width. If elastic backscattering is negligible and spin is degenerate, the two-terminal linear conductance is
A fully open subband has , producing conductance steps in units . Magnetic spin splitting can resolve steps. A finite two-terminal resistance remains in a perfect ballistic channel because reservoirs supply and absorb a finite number of transport modes; it does not prove momentum-randomizing scattering inside the constriction.
At finite source-drain bias the two reservoir distributions differ over an energy window rather than at one Fermi energy. Choose and take positive current from source to drain. For spin-degenerate channels,
At zero temperature with a rigid transmission spectrum, . For symmetric bias and neglecting an explicit bias response of ,
If the two window edges lie above different numbers of subbands, the differential conductance can lie at half-integer values in units . For example, two open subbands at one edge and one at the other give . This is a bias-window effect, not fractional charge or a fractional Hall state.
Figure 1.
Original ideal one-dimensional subbands sampled by a symmetric bias window, with integer and half-integer differential-conductance plateaus
. Details.
Mapping transconductance versus gate voltage and source-drain bias reveals boundaries where a reservoir chemical potential crosses a subband bottom, enabling energy-spacing spectroscopy under a specified lever arm and bias division. Finite temperature rounds thresholds over ; reflection, disorder, series resistance and a saddle-shaped barrier reduce or smooth plateaus. Large bias can alter the electrostatic potential, heat carriers or produce inelastic scattering, so the rigid-transmission differential formula is not generally valid without its assumptions. One-dimensional interaction effects can add anomalies beyond this independent-channel model.
A straight line in against means . Reading its intercept and slope gives approximately and ; the graphical precision is only a few percent. Hence the molar heat capacity is approximately
The linear electronic heat capacity comes from conduction electrons within energy of order of the Fermi energy; the Pauli exclusion principle prevents deeply occupied states from contributing freely. The cubic lattice term is the low-temperature Debye heat capacity of three-dimensional acoustic phonons, whose low-frequency density of states is proportional to frequency squared. These are molar coefficients, so the temperature powers carry the extra kelvin factors indicated.
Only states within an energy window of order around the Fermi energy can change occupation in a degenerate metal. A Sommerfeld expansion gives electronic energy above its zero-temperature value proportional to , hence . Three-dimensional linear-dispersion acoustic phonons have density of states proportional to ; integrating their Bose occupations gives thermal energy proportional to and the Debye heat capacity . Thus at sufficiently low temperature in the normal state.
Reading the straight low-temperature fit gives approximately and . These estimates agree with the reported fit to this material in the original experiment.[ref] Treating the graph values as approximate, the molar density of states is
The stipulated two electrons per formula unit give . For a single spin-degenerate parabolic band, the molar density of states is . Hence
These are model-dependent effective parameters inferred from the measured heat capacity and assumed carrier count, rather than an independent determination of a unique band structure.
Using the Debye prefactor stated in the question gives
This prefactor counts three effective modes per formula unit. Consistently choosing the same count for the Debye wavevector gives . The corresponding average sound speed is
There is a normalization choice here: a formula unit has 31 atoms. With the conventional full atomic-mode count, the molar Debye coefficient contains an additional factor 31, and both and increase by . That convention gives and , while leaving the inferred sound speed unchanged. The mode count in the Debye model must be used consistently; mixing the printed temperature with an atomic-count wavevector gives an erroneous sound speed.
The upward curvature above about indicates low-energy vibrations missing from a pure acoustic model. In this cage compound, the original analysis fits an additional localized mode with , assigned to a rattling mode of a barium guest atom.[ref] At temperatures high compared with all relevant phonon energies, the full lattice approaches the Dulong-Petit law, . The reduced three-mode model alone approaches and omits the other branches. An approximately linear electronic term can still be added while the carriers remain degenerate, but cannot be extrapolated beyond their Fermi temperature.
A charge density wave is a spatial modulation of the electron charge density, often accompanied by a periodic lattice distortion. Write a weak modulation as . In a one-dimensional metal, the Peierls distortion couples states near opposite Fermi points most strongly for . Opening a gap near the Fermi energy lowers occupied electronic energies, while the lattice deformation has a positive elastic energy cost. Their competition can make a periodic state favorable below a transition temperature.
The modulation can be commensurate or incommensurate with the underlying Bravais lattice. Diffraction detects additional satellite peaks, while transport can show reduced low-energy carrier density. Impurities can pin its phase; above a depinning field a collectively sliding modulation can contribute nonlinear current. These effects distinguish collective density modulation from simply assigning independent static charges to isolated lattice sites.
Electrons contribute magnetic response through both spin and orbital motion. In an ordinary weakly interacting metal, a field splits the two spin energies. Only states near the Fermi energy can change occupancy because of the Pauli exclusion principle, producing Pauli paramagnetism. For a total two-spin density of states , the simple result is . Orbital cyclotron motion gives Landau diamagnetism; for an isotropic parabolic free-electron band it contributes . Filled shells can also supply a diamagnetic background.
Interactions can favor parallel spin occupancy. In an itinerant description, the exchange-energy gain competes with the kinetic-energy cost of redistributing electrons between spin bands. The Stoner criterion describes when an unpolarized state becomes unstable, with the precise factor in depending on whether the density of states counts one spin or both. This mechanism can yield spontaneous ferromagnetism and magnetic domains. Alternatively, sufficiently localized moments in a metal can interact through conduction electrons. A high density of states alone is therefore not a complete microscopic explanation of a material's magnetism; band structure, electron interactions and temperature matter.
The de Haas-van Alphen effect is an oscillation of equilibrium magnetization, and hence magnetic susceptibility, as Landau levels pass through the Fermi energy when the field changes. For a fixed slice perpendicular to the field, Onsager quantization gives
At , successive crossings change by one, so
Here is the oscillation frequency in inverse field. In three dimensions, integrating the oscillatory response over the momentum parallel to the field causes most sections to cancel by phase averaging. The leading surviving contributions come from stationary, hence extremal, cross-sectional areas. Low temperature and sufficiently weak scattering are needed to resolve the levels. Measuring several field directions therefore probes the shape of the Fermi surface rather than only a single scalar electron density.
For the cylindrical sheet, . The measured frequency gives
There are electrons per site in this band, with two spin states per wavevector. Thus the occupied disk takes fraction of the square Brillouin zone:
This uses the paper's circular, electron-occupied disk approximation and equal band populations.
In the tight-binding approximation, hopping to the two neighbors at adds phase factors and . Their sum is ; absorb twice the hopping matrix element into . With no or hopping this yields . For , occupancy is centered on . The filling fraction of an independent cosine band is , requiring the occupied strip , so sheet consists of the two planes ; sheet similarly has . Each extends along , with no dispersion in that direction. The sheet is a cylinder along , of radius .
Numerically the planar offsets are , the zone boundary is , and the cylinder radius is in dimensionless coordinates. If instead, the band minimum is at the zone edge; occupying its lowest two-thirds puts the planes at or , with the central third unoccupied. The sign of the hopping must therefore accompany an absolute placement of these open sheets. The following sketch uses and the stipulated independent-band model, before any avoided crossings caused by additional interorbital hybridization.
Figure 1.
Independent-band Fermi-surface cross-sections for negative cosine hopping and equal populations of the three bands
. Details.
In a conductor, mobile electrons redistribute in response to an electric potential, producing an induced charge density that opposes its source. Finite electronic compressibility means a finite density change requires a change of local kinetic Fermi energy. Screening is therefore not perfect at every microscopic distance. On scales comparable to atomic structure or the Fermi wavelength, a continuum local-density model itself fails.
Thomas-Fermi screening treats electrons as a locally uniform degenerate free electron gas, replaces the ionic background by a smooth neutralizing charge, and neglects nonlocal response, exchange and correlation corrections. The electrochemical chemical potential is uniform in equilibrium. Because an electron has charge , its electrostatic energy is , giving
At zero potential . Linearizing at fixed , with , gives
Insert this in Poisson's equation to obtain , where the Thomas-Fermi screening length is
Away from a point source, direct radial differentiation shows . The decaying solution is therefore . Integrating Poisson's equation over a small sphere containing charge fixes . For a sufficiently large source, the linearized formula is only a far-field approximation, not a justified description of its singular core.
For monovalent sodium, the electron number density is its atomic number density,
This gives and
Room temperature is far below the corresponding Fermi temperature, so degeneracy is well justified, and sodium's simple conduction band makes a free-electron estimate useful. However and the mean atomic spacing is . The potential varies on a scale shorter than and the atomic spacing, so the slowly varying local-density and continuum assumptions are not quantitatively controlled at the screening length itself. A nonlocal treatment includes Friedel oscillations, absent from the pure exponential.
Nearly unchanged interlayer force constants in two-layer and twenty-layer films are consistent with very local screening and bonding forces: reducing the distant bulk need not strongly change the force between adjacent layers. They also indicate that metallic electronic response can survive in the thin film. The observation does not by itself validate the numerical Thomas-Fermi approximation, establish an identical full phonon spectrum, or rule out surface-induced electronic changes; it directly constrains the measured local force constant.
In a weak applied field, magnetic susceptibility relates magnetization to magnetic field intensity, . Its sign, temperature dependence and nonlinear field dependence distinguish several mechanisms.
Diamagnetism is the orbital response opposing an applied magnetic field, with . Closed-shell atoms and filled bands generally give a weak, nearly temperature-independent response. In a simple free electron metal, Landau diamagnetism contributes ; the factor is specific to the isotropic parabolic-band model and is not universal in crystals.
Paramagnetism gives . Localized magnetic moments align statistically with the field against thermal disorder. For independent moments of angular momentum ,
which is the Curie law. Exchange interactions often lead approximately to the Curie–Weiss law, , sufficiently far above any ordering temperature. The sign of suggests predominantly parallel or antiparallel exchange, though it is not a complete classification. Conduction electrons instead exhibit Pauli paramagnetism:
for and a spin-summed density of states per unit volume. Only states close to the Fermi energy change occupation, making this response nearly temperature independent when .
Ferromagnetism has spontaneous parallel magnetic order below a Curie temperature. Exchange interaction, not simply classical dipole attraction, provides the dominant alignment mechanism. In the convention , positive favours alignment. Magnetic domains can make a ferromagnet's total magnetization vanish before an external field aligns its domains. Domain motion and anisotropy produce saturation, hysteresis, remanent magnetization and a reverse field measured by magnetic coercivity.
Figure 1.
Qualitative linear magnetic responses and a ferromagnetic hysteresis loop
. Details.
Antiferromagnetism has oppositely ordered sublattices below a Néel temperature; equal opposing moments give zero net magnetization while retaining a nonzero staggered order parameter. A susceptibility anomaly and magnetic neutron diffraction reveal this order even when bulk magnetization vanishes. Ferrimagnetism also has opposing sublattices but unequal contributions, giving a nonzero spontaneous net moment. Above their ordering temperatures both can become paramagnetic. Measurements with a magnetometer as a function of field and temperature, supplemented by magnetic diffraction, therefore distinguishes a compensated ordered material from an ordinary paramagnet.
A solid stores thermal energy in lattice vibrations and, when available, electronic and other excitations. For a nonmagnetic insulating crystal at sufficiently low temperature, the gap suppresses mobile electronic excitations and the leading bulk contribution normally comes from acoustic phonons. The three-dimensional Debye heat capacity is
The vibrational density of states scales as , so only a fraction proportional to of the modes is thermally active at low temperature. The two limiting forms are
The high-temperature value is the Dulong-Petit law, or per mole of atoms. Optical phonons add thermally activated contributions as their characteristic energies become accessible. A multiatom cell has more branches, but still three vibrational degrees of freedom per atom.
A normal metal has an additional low-temperature electronic heat capacity. The Pauli exclusion principle restricts excitations to a shell of width about around the Fermi energy. The number of thermally active electrons is therefore proportional to , rather than the total electron number contributing a classical heat capacity. With spin-summed electronic density of states for the whole specimen,
For a three-dimensional free-electron gas, and . Only a small fraction of the classical electronic value is accessible when , even though the electronic term dominates the phonon term as in a normal gapless metal.
Figure 1.
Debye lattice heat capacity and the low-temperature electronic intercept in a normal metal
. Details.
Plotting against gives a straight line with intercept and slope in the appropriate low-temperature range. This separates the electronic density-of-states information from the acoustic-phonon scale. In a Fermi liquid, the interacting quasiparticle density of states replaces the free value, so an enhanced effective mass enhances .
The qualifications matter experimentally. Superconductivity can gap electronic excitations, magnetic order adds magnetic excitations, defects can generate additional low-temperature terms, and low-dimensional or very small specimens need not obey the bulk cubic law. The Debye expression is for constant-volume heat capacity; constant-pressure heat capacity differs through thermal expansion, although the difference is often small at low temperature. Thus the normal-metal and ordinary insulating limits are useful leading behaviors, not universal formulas for every solid in every phase.
The energy favoring spin polarization must compete with the increase in Fermi kinetic energy. Assume the usual three-dimensional zero-temperature parabolic conduction band at fixed and . Write the spin polarization as , so . The unpolarized Fermi energy is
The two spin populations have Fermi energies . Summing their individual mean kinetic energies gives
The specified interaction is an energy per electron, . Thus the energy change per electron near the unpolarized state is
The quadratic coefficient changes sign at the Stoner threshold for an interaction normalized per electron,
The positive quartic term gives a continuous onset in this model. More globally, . Convexity of makes this nonnegative for , so no lower polarized minimum appears before that threshold.
At fixed number density , the critical is independent of the total sample size. A comparison restricted to a fully polarized state gives a different numerical coefficient, , but the same requested density scaling; it misses the partially polarized onset. One must also distinguish this , with units of energy, from a contact coupling multiplying an interaction-energy density : here . Importing a differently normalized Stoner criterion would introduce an erroneous extra density factor.
Diagonalization and conventions. The spin-dependent part is . For a Hermitian Hamiltonian is real; the supplied lower-band spinor uses the convention , which will be adopted below. The squared spin matrix is . Hence the two ordered energies are
In the plane, let and . Then
If , use to retain the energy ordering, and interchange the spin directions assigned below. This is an isotropic Rashba effect; has units of inverse length, whereas has units of energy times length.
Band minima. Define and . Completing the square gives
Along , the radial coordinate is , so the lower branch has two minima:
In the full plane these are points on a circle of minima . Both branches meet at , . Their ordered energy curves contain : the lower curve descends from the crossing on either side, while the upper rises. Treating them as globally labeled smooth spin branches without switching labels across would obscure the lower-band minima.
Occupied regions and Fermi contours. At zero temperature each spin-split eigenstate with energy below is occupied. Put
For , . The lower-band roots are and , while the upper band is entirely empty. Thus the central disk is unoccupied, the annulus is singly occupied, and the exterior is unoccupied. Both Fermi circles belong to the lower band; there is no doubly occupied region.
At , the lower band is occupied for , giving a singly occupied disk with outer Fermi circle at . The two bands also meet the Fermi energy at the origin. That isolated degenerate point is not a finite doubly occupied disk, and occupation exactly at the Fermi energy is a boundary convention of zero area. Outside the outer circle the states are empty.
For , . The lower branch has outer radius , while the upper branch has inner radius . The disk is doubly occupied, with one state in each band at every momentum. The annulus is singly occupied, in the lower band only, and the exterior is unoccupied. These are the Fermi contours of an isotropic Rashba band; double occupancy here refers to two orthogonal spinor states at the same momentum, not two electrons occupying one identical quantum state.
Figure 1.
Rashba dispersion and occupied momentum regions below, at and above the band crossing
. Details.
Inferring the splitting. Above the crossing, the two positive radii differ by :
The minimum radius is therefore . It is the difference of the measured radii that is required for ; below the crossing the two lower-band radii instead add to .
Spinors and spin direction. Write , which has for . An orthogonal normalized partner to the supplied lower-band state is
Indeed . Direct multiplication by the spin matrix gives eigenvalues and for and , respectively, so orthogonality has selected the other band rather than merely another arbitrary spin basis.
For a normalized spinor , the Pauli expectation values are . Consequently the Rashba spin texture is
The spin lies in the plane and is perpendicular to momentum. On the outer circle , which belongs to , it points clockwise as viewed from ; at it points along . On the inner circle , belonging to , it points counterclockwise; at it points along . Opposite momenta have opposite spins, consistent with time-reversal symmetry. At the origin the eigenstates are degenerate and no unique spin orientation is defined.
Figure 2.
Opposite tangential spin textures on the outer lower-band and inner upper-band Fermi circles
. Details.
A magnetic field quantizes a charged carrier's cyclotron motion into Landau levels. For an isotropic parabolic band, neglecting spin splitting,
The degeneracy of each orbital level per unit perpendicular area is per spin. Increasing the field changes both the level spacing and the number of states in each level. Successive levels cross the Fermi energy, producing an oscillatory density of states and hence quantum oscillations in thermodynamic and transport quantities.
For a general closed semiclassical orbit, Onsager quantization relates its wavevector-space area to field:
Setting this area to an extremal Fermi-surface cross-section gives successive inverse-field crossings separated by
A typical oscillatory contribution is proportional to . The oscillations are periodic in , not in . In three dimensions, extremal cross-sections dominate because contributions from other longitudinal momenta cancel by phase averaging. Rotating the field therefore maps the shape of the Fermi surface.
Figure 1.
Quantized orbital crossings and their periodicity in inverse magnetic field
. Details.
Oscillations in magnetization are the de Haas-van Alphen effect; oscillations in longitudinal electrical resistivity are the Shubnikov-de Haas effect. They are most readily observed in clean samples at low temperature. The thermal damping factor is
and a common first-harmonic disorder factor is . Thus the Landau spacing must be sufficiently large compared with thermal broadening and disorder broadening, approximately and , with the displayed factors giving the quantitative suppression.
The temperature dependence measures the cyclotron effective mass, and the field-dependent damping probes the quantum lifetime . That lifetime need not equal the momentum relaxation time controlling electrical conductivity: small-angle scattering can broaden Landau levels while relaxing electric current inefficiently. Spin splitting can generate further modulation or resolved spin structure. Oscillations are not the same as the ordinary smooth magnetoresistance or cyclotron resonance; they probe quantized orbital state counting near the Fermi energy.
Dielectric screening is the rearrangement of a medium's charges in response to an applied charge. In a metal, mobile electrons accumulate near a positive perturbation and reduce its long-range potential. Thomas-Fermi screening treats the electron gas locally as an equilibrium gas whose density responds to the local electrostatic potential, ignoring gradients of the density on the microscopic wavelength scale.
Take , background permittivity , and electrostatic potential . An electron's potential energy is , so the local kinetic Fermi energy becomes . For a three-dimensional spin-degenerate parabolic band at zero temperature,
where is the spin-summed density of states per volume per energy. The induced charge is . Combining it with Poisson equation gives
For a point external charge , spherical symmetry and decay at infinity select
Thus the bare potential is cut off exponentially. Fourier transformation makes the same result transparent: , so the static longitudinal dielectric factor is relative to the background. For a free electron band, and .
Figure 1.
Local Thomas-Fermi screening and optical/acoustic modes of an illustrative diatomic chain
. Details.
The local linear approximation requires a weak perturbation and slowly varying fields on the relevant microscopic scale. It omits nonlocal Friedel oscillations and atom-scale structure; a nonlinear local-density treatment is needed near a sufficiently strong charge. Finite temperature replaces by the appropriate compressibility derivative . The nondegenerate limit gives classical screening rather than the degenerate Thomas-Fermi length. A larger density of states means that a smaller potential can move more carriers, hence stronger screening.
Noninteracting spectral line. Treat as a wavevector, so physical crystal momentum is . Write ; an energy zero at the chemical potential can be chosen throughout. The temporal factor of a noninteracting state is . With the Fourier transform convention ,
Thus its normalized frequency spectral function is
One should not square the delta distribution as if it were an ordinary finite-time transition amplitude. More precisely, the fermionic retarded Green function is . Its Fourier transform is , whose negative imaginary part divided by is the same delta peak.
Interactions and lifetime. Interactions change the dispersion through the real part of the self-energy and permit decay into other excitations through its imaginary part. In the simplest quasiparticle-pole model, exponential decay of the retarded amplitude gives
Performing the causal integral,
The corresponding Lorentzian quasiparticle spectral peak is
Its total frequency integral is one. The exponential amplitude lifetime is ; the probability lifetime is . Describing as a scattering rate therefore requires the lifetime convention to be specified. The energy half-width is .
A general interacting electron is more accurately described by near the pole. The coherent peak then integrates to the quasiparticle residue and an incoherent continuum carries the remaining weight. In an energy-unit self-energy convention,
Linearizing the real denominator gives and at the pole. The requested unit-weight Lorentzian is the normalized quasiparticle model, not the most general exact interacting spectrum.
Peak position and width. At fixed , put and . Differentiation gives
It is positive for and negative for , so the only maximum is at , with height . Setting to half this height gives . Therefore
In energy units the maximum is and the half-width is . Frequency dependence of the self-energy would require reconsidering both the shape and peak position.
Fermi gas and Fermi liquid. A noninteracting Fermi gas has a delta-function spectral line at its bare dispersion for every momentum. A normal three-dimensional Fermi liquid has a shifted coherent peak plus incoherent spectral weight; close to the Fermi surface its width scales as . At zero temperature the peak becomes arbitrarily sharp at the Fermi surface, while it broadens farther away. Spectral functions include addition and removal weight; occupied-only photoemission contains an extra Fermi factor.
Figure 1.
A free spectral line and broadened quasiparticle peaks, with a separate incoherent background
. Details.
Photoemission measurement. A photon of known energy ejects an electron. Measure its kinetic energy and emission direction. For binding energy below the Fermi level and the appropriate calibrated work function , conservation of energy gives
Conservation of momentum parallel to a periodic surface gives
where is a surface reciprocal-lattice vector. At suitable photon energies the photon momentum can be neglected; at higher energies it must be retained. The surface breaks perpendicular translation symmetry, so the perpendicular crystal momentum generally needs a final-state model. A two-dimensional band can be reconstructed directly from the parallel components.
Within the sudden approximation and electric-dipole approximation, photoemission intensity and spectral function are related by
Here is measured relative to the chemical potential. Instrumental resolution convolves the product and inelastic scattering adds background. Thus ARPES maps the occupied electron removal spectral function, weighted by a matrix element; it does not measure the full unoccupied spectrum or an unweighted spectral function automatically. Bright ridges give dispersions, and intrinsic widths give decay information after instrumental effects are removed.
Reading the supplied image. Its bright ridges form a graphene-like cone. The crossing near is the Dirac point, not in general the Fermi level. In the paper's plotted energy coordinates its energy is roughly –. A velocity follows from a branch slope independently of the energy zero:
For example, the lower branch moves by about between and . This gives and
Reading other points changes the estimate by tens of percent. The original exam image has unequal energy increments on nearly equally spaced labelled ticks, so it does not justify a precise fitted velocity. The value is an estimate of the cone slope extrapolated to the Fermi crossing, rather than a measured derivative exactly at a visibly identified Fermi cutoff.
To determine a Fermi energy, first calibrate the Fermi edge, then subtract the chosen reference energy. Neither a Fermi-level marker nor an explicit energy-zero convention is supplied in this crop. If its upper termination near is intended to represent the Fermi cutoff, the conditional graph answer is on that axis, or relative to the Dirac crossing. Identifying the crossing itself as the Fermi energy would incorrectly assume undoped graphene.
The research article cited by the exam identifies this as linearly polarized graphene ARPES and independently states for the substrate-doped sample. That resolves the relative energy when this external calibration is admitted.[ref] The crop alone does not uniquely fix an absolute Fermi energy; the source-supported relative value and the conditional axis reading should be distinguished.