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Write the real displacement as $U_n(t)=\mathrm{Re}[u{e}^{i\omega t-iqna}]$, choosing real positive peak amplitude $u$. Nearest-neighbour harmonic springs store energy in their extension $U_n-U_{n+1}$, each spring counted once. Therefore the instantaneous physical energy isThe printed complex displacement is a calculation device: squaring the complex phasor itself would not produce physical energy. The chain sketch in the accompanying figure shows masses at equilibrium spacing $a$, with longitudinal displacements along the chain.

The two spring forces on site $n$ giveSubstituting the normal-mode phasor and cancelling its nonzero amplitude givesThe long-wavelength limit is acoustic, $\omega \simeq a\sqrt{\alpha /M}|q|$, and the first Brillouin zone ends at $|q|=\pi /a$. The maximum angular frequency is ${\omega }_m=2\sqrt{\alpha /M}$.

Time averaging uses $⟨[\mathrm{Re}(z{e}^{i\omega t}){]}^2⟩=|z{|}^2/2$. ConsequentlyThe dispersion relation makes these two contributions equal, givingThis is equality of time-averaged kinetic and potential energies in a harmonic normal mode; the instantaneous energy partition need not be equal.

Use periodic boundary conditions on length $L=Na$ to count modes: $q_j=2\pi j/L$. The density on the signed $q$ axis is $L/(2\pi )$. Using folded wave-number counting for a monatomic chain combines $q$ and $-q$ at positive magnitude and counts both directions, so the convention used by the requested expression isThis is a large-$N$ continuum density, not a second independent branch. It gives $N$ modes after integrating over that half-zone; endpoint counting changes only finite-size corrections.

For positive $q$, $\omega ={\omega }_m\sin (qa/2)$ andThe density of states of a monatomic harmonic chain vanishes outside the band, is constant to leading order near zero, and has an integrable Van Hove singularity at the upper band edge where group velocity vanishes. Normalization checks the directional counting:

Use periodic boundary conditions temporarily to count the allowed wavevectors. Each state occupies $(2\pi {)}^3/V$ in reciprocal space. For one acoustic polarization, the spherical shell between $k$ and $k+dk$ containsBoth positive and negative wavevector directions are already included in that sphere; no further factor of two is needed. With the linear dispersion relation $k=\omega /v_s$,A three-dimensional monatomic crystal has three acoustic branches. Under the stated common-speed approximation,This is a phonon density of states per unit angular frequency, not per unit ordinary frequency. If longitudinal and transverse speeds differ, the isotropic expression becomes $g=V{\omega }^2(v_L^{-3}+2v_T^{-3})/(2{\pi }^2)$. In the Debye model, imposing ${\int }_0^{{\omega }_D}g(\omega )d\omega =3N$ sets the cutoff; the linear approximation is not continued to arbitrarily high frequency in a finite lattice.

For a uniform taut sheet in the small-displacement approximation, the two-dimensional wave equation isSeek a harmonic solution $Y(y)e^{i\omega t-i{k}_{x}x}$. The clamped edges impose Dirichlet boundary conditions $Y(0)=Y(b)=0$. Hence $Y^{\prime \prime }+k_y^{2}Y=0$ has nontrivial solutions only forTaking the real part gives the stated sinusoidal transverse profile. There is no nonzero $n=0$ mode satisfying both clamped boundaries.

Substitution gives the dispersion relationThe three branches have cutoffs ${\omega }_{c,n}=n\pi v/b$ at $k_x=0$ and approach $\omega =v|k_x|$ at large $|k_x|$. Only frequencies above a branch's cutoff give traveling waves along an infinitely long guide; below it, the axial dependence is evanescent. For a forward propagating mode,The phase velocity exceeds $v$, while the group velocity is smaller: the carrier phase speed is not the signal speed.

Here the first two cutoff frequencies are $50$ and $100\mathrm{Hz}$, so both modes propagate at $200\mathrm{Hz}$. With $\omega =400\pi {\mathrm{s}}^{-1}$,Each transverse mode independently acquires its axial phase. The second mode first changes sign relative to the first when $(k_1-k_2)x_1=\pi$, givingAt that distance a common temporal phase is $\varphi =-k_1{x}_1$ modulo $2\pi$; the second term is negative relative to the first for every $y$ and every time, not just at one selected instant.

In an optical fibre, different guided modes have different group velocities, so an input pulse becomes a sum of differently delayed pulses. This intermodal dispersion broadens pulses and can make adjacent digital symbols overlap. A single-mode optical fiber removes this particular mode-delay mechanism; a graded-index optical fiber can reduce it in a multimode design. Single-mode propagation still permits wavelength-dependent group delay, so it does not remove every kind of optical dispersion.

Taking $L=1.00\mathrm{cm}$ as the distance travelled in the medium, the narrowband group delay isIf $1\mathrm{cm}$ denotes a slab thickness measured normal to the interface instead, the central ray travels $L/\cos 17.80^{\circ }$, giving about $92.1\mathrm{ps}$. The coordinate-mixed velocity above would give $89.3\mathrm{ps}$ for a $1\mathrm{cm}$ path; it should not replace the consistent calculation silently.

The pulse envelope travels at the local group velocity, while individual carrier crests move at the phase velocity. In general, variation of group velocity across the pulse spectrum produces different delays, temporal broadening and chirp. Absorption can reshape the spectrum and envelope as well. The refraction data also show wavelength-dependent angles, so a finite-width incident beam acquires spatial separation of its spectral components. The supplied first derivative determines the central delay but does not specify a pulse duration, absorption spectrum or reliable second derivative of the dispersion relation; it therefore does not determine a numerical broadening, or its sign. If propagation phase is effectively linear across a sufficiently narrow spectrum, the leading approximation is a delayed pulse with unchanged shape.

Superpose two nearby harmonic waves. The identityseparates a rapid carrier from a slow beat envelope. A constant point of the envelope moves at $\Delta \omega /\Delta k$, which tends toas the components approach one another. Equivalently, expand a narrow wave packet spectrum around $k_0$: $\omega (k)={\omega }_0+v_g(k-k_0)+\cdots$. Factoring the carrier out of its Fourier transform representation leaves an envelope depending on $x-v_{g}t$. This interpretation requires a narrow spectrum and little attenuation or distortion; higher derivatives of the dispersion relation can change the envelope shape. The carrier phase velocity is $v_p=\omega /k$ and need not equal $v_g$.

The Debye model treats a solid's low-frequency lattice vibrations as acoustic phonons in an elastic continuum. There are three polarizations per wavevector, one longitudinal and two transverse, with approximately linear dispersion relations. A cutoff is chosen to preserve the total $3N$ vibrational modes of $N$ atoms. The phonon number itself is not fixed; mode occupations follow the Bose-Einstein distribution with zero chemical potential.

For one polarization of speed $v_s$, counting wavevector states in a spherical shell gives $g_s(\omega )=V{\omega }^2/(2{\pi }^2{v}_s^3)$. Define an average Debye speed by $3/v_D^3=1/v_L^3+2/v_T^3$. The total density of states can then be writtenThe Debye wavevector is $k_D=(6{\pi }^{2}N/V{)}^{1/3}$, the Debye frequency is ${\omega }_D=v_D{k}_D$, and the Debye temperature is ${\Theta }_D=\hslash {\omega }_D/k_B$.

Omitting the temperature-independent zero-point energy, the vibrational energy and resulting Debye heat capacity areAt low temperature the upper limit can be extended to infinity. The integral is $4{\pi }^4/15$, givingOnly the long-wavelength acoustic modes are appreciably populated, explaining the Debye T-cubed test. At high temperature every mode contributes $k_B$ by equipartition theorem, so $\boxed{C_V\to 3N{k}_B}$, the Dulong-Petit law.

The model succeeds especially at low temperature, where long-wavelength elasticity is reliable. It replaces real anisotropic branches by a simple continuum and cannot reproduce detailed optical phonon branches or every intermediate-temperature feature. Metals also have an electronic heat capacity approximately proportional to $T$; defects, magnetic excitations or a phase transition can add other terms. Experiments often measure heat capacity at constant pressure, which need not equal the harmonic model's $C_V$ exactly.

Use the quantum free electron model: conduction electrons move as independent particles in a three-dimensional box of volume $V$, with a uniform positive background replacing the ionic lattice potential. Neglect the detailed periodic potential and explicit electron-electron interactions; the interior one-electron dispersion relation is $ϵ={\hslash }^2{k}^2/(2m_e)$. The boundary confines the particles, and its detailed shape does not affect the bulk state count in a sufficiently large sample.

The electrons are spin-$1/2$ fermions: each spatial quantum state accommodates two opposite spin states, with occupations given by the Fermi-Dirac distribution and the Pauli exclusion principle. A fixed number $N$ of conduction electrons and thermal equilibrium are assumed. Collisions can be represented by a phenomenological momentum relaxation time for transport, but are unnecessary for the equilibrium state counting here. These assumptions distinguish the quantum model from a classical Maxwell-Boltzmann electron gas.

A Bloch state in a crystal experiences a periodic lattice potential. Its band dispersion relation $ϵ(k)$ encodes the lattice response, so an effective mass allows a wavepacket's acceleration under a weak applied force to be described without explicitly following the microscopic periodic forces.

In one dimension the wavepacket group velocity and semiclassical equation for crystal momentum areDifferentiating the first equation with respect to time givesDefining $F=m^{\ast }a$ yieldsThis band effective mass is controlled by band curvature, not the slope. A band minimum has positive $m^{\ast }$; a band maximum has negative electron $m^{\ast }$ and is often more conveniently described with positive-mass electron holes. In three dimensions the inverse effective mass is generally a tensor, $(m^{\ast -1}{)}_{ij}={\hslash }^{-2}{\partial }_{k_i}{\partial }_{k_j}ϵ$. The scalar formula assumes motion along a specified direction in an isolated band, weak fields and negligible interband transitions; the bare electron mass has not physically changed.

A dispersion relation specifies the allowed angular frequency $\omega (k)$ of a wavevector $k$. A single harmonic wave $A\cos (kx-\omega t)$ has constant-phase surfaces moving at the phase velocity,For two nearby components, use the identityThe slowly varying envelope moves at $\Delta \omega /\Delta k$. Taking a narrowband limit gives the group velocity,More generally, expand $\omega (k)$ around the central wavevector of a wavepacket. The linear term translates its envelope at $v_g$; the quadratic and higher terms produce group velocity dispersion and packet distortion. This interpretation needs a sufficiently narrow spectrum and weak enough absorption and distortion for an identifiable envelope to persist.

For light in a transparent material, $k=n(\omega )\omega /c$, soThe derivative is evaluated at the wavepacket's central frequency and ${\lambda }_0$ is the vacuum wavelength. In a nondispersive medium with constant $n$, the two velocities coincide and a packet can propagate without dispersion. In normal optical dispersion $dn/d{\lambda }_0<0$, the displayed model gives $v_g<v_p$.

The two velocities can differ even without material dispersion: a waveguide mode with ${\omega }^2={\omega }_c^2+c^2{k}^2$ has $v_p=\omega /k>c$ and $v_g=c^{2}k/\omega <c$, with $v_p{v}_g=c^2$. The phase velocity is not a signal speed. Near strongly absorbing resonances an anomalous derivative can also make the group velocity exceed $c$ or become negative; reshaping then prevents its simple identification with information transport. Relativistic causality constrains the signal front, not the speed of an arbitrary moving phase or distorted intensity maximum.

Build a narrow-band wave packet from plane waves with wavenumbers close to $k_0$:The Taylor expansion of the dispersion relation is $\omega (k)\simeq {\omega }_0+{\omega }_0^{\prime }(k-k_0)$, where ${\omega }_0^{\prime }=(d\omega /dk{)}_{k_0}$. Put $\kappa =k-k_0$ to obtainThe carrier's wave phase travels at the phase velocity ${\omega }_0/k_0$, while the envelope has constant shape at constant $x-{\omega }_0^{\prime }t$. Its group velocity is thereforeThe approximation neglects higher derivatives of the dispersion relation. Those derivatives cause the wave packet to spread or distort over sufficiently long propagation times; the result describes the local envelope speed of a sufficiently narrow band.

For the $n$th transverse mode, substitute $q_n=n\pi /a$ into the membrane waveguide dispersion relation:Longitudinal propagation requires real nonzero $k$, henceBelow the cutoff frequency of a membrane waveguide, $k=i\kappa$, with $\kappa =\sqrt{(n\pi /a{)}^2-\sigma {\omega }^2/T}$, and a bounded excitation decays as $e^{-\kappa x}$ rather than carrying a travelling wave along an infinite guide. At equality $k=0$, the displacement has no longitudinal phase advance and the group velocity is zero; it is a cutoff oscillation, not a propagating mode carrying finite longitudinal power.

The quantum free electron model treats conduction electrons as independent particles moving in an approximately constant potential, with parabolic dispersion relation $E={\hslash }^2{k}^2/(2m)$. Fermi-Dirac statistics successfully explains important features such as a Fermi energy and a small electronic heat capacity, but a constant potential gives no band gaps and cannot by itself explain why different band fillings produce metals, semiconductors and band insulators. It also misses lattice-dependent effective masses, detailed directional responses and the topology of real Fermi surfaces. Scattering and finite electrical resistivity require additional physics.

The nearly-free electron model introduces a weak periodic lattice potential. Bloch's theorem replaces individual free plane waves by Bloch states, and Fourier components of the potential mix plane waves whose wavevectors differ by a reciprocal lattice vector. Near degeneracy at a Brillouin zone boundary, this coupling opens a band gap; for a two-wave crossing its size is $2|V_G|$. Away from the crossing, energies remain close to free-particle values. Band curvature produces band effective masses, and band filling determines whether the Fermi energy lies inside an allowed band or a gap.

The improvement is the inclusion of lattice periodicity, rather than a switch from classical to quantum statistics: the quantum free electron model already uses Fermi-Dirac statistics. The strong delta barriers in the later numerical example are treated exactly by the Kronig-Penney model, rather than by assuming that their strength is perturbatively small.

A wave propagates an organized disturbance through space. What oscillates depends on the medium: displacement in a string or solid, pressure and density in a fluid, electric fields and magnetic fields in an electromagnetic wave, or a quantum wavefunction. The propagation law follows from the restoring mechanism, inertia and relevant boundary conditions. A common linear equation is $u_{tt}=c^2{\nabla }^{2}u$, whose plane waves obey $\omega =c|\mathbf{k}|$. The resulting phase velocity and group velocity coincide, so a narrow wave packet can travel without dispersive spreading. More generally the material supplies a dispersion relation $\omega (\mathbf{k})$; the envelope velocity is ${\nabla }_{\mathbf{k}}\omega$, while constant phase surfaces move at the corresponding phase velocity.

Mechanical waves make the balance of restoring force and inertia particularly visible. A flexible stretched string has $c=\sqrt{T/\mu }$: greater tension stiffens the string, whereas greater linear mass density slows its transverse motion. Small-amplitude acoustic waves in a uniform fluid are longitudinal, with $c_s=\sqrt{K_s/\rho }$, where $K_s$ is the adiabatic bulk modulus. For an ideal gas, $c_s=\sqrt{\gamma p/\rho }$. Pressure changes in rapid sound oscillations are approximately adiabatic because little heat crosses a wavelength in one period. Fluids do not support ordinary bulk shear waves, whereas an elastic solid supports both longitudinal and transverse waves. In an isotropic solid their speeds are $c_L=\sqrt{(K+4G/3)/\rho }$ and $c_T=\sqrt{G/\rho }$, where $G$ is the shear modulus.

A material can be dispersive even when its equilibrium properties are uniform. In a liquid with a free surface, gravity and surface tension act as restoring mechanisms. A simple inviscid capillary-gravity wave haswhere $h$ is depth and ${\gamma }_s$ is surface tension. Long shallow gravity waves have approximately constant speed $\sqrt{gh}$; deep-water gravity waves have $\omega =\sqrt{gk}$ and group velocity half their phase velocity. Short capillary waves have a different dispersion dominated by surface tension. Bending stiffness similarly changes short-wavelength propagation in a string or plate, giving a contribution proportional to $k^4$ in ${\omega }^2$. Different restoring mechanisms can therefore control different wavelength ranges of the same medium.

Electromagnetic waves propagate in vacuum without material displacement, because Maxwell equations couple changing electric and magnetic fields. They are transverse and travel at $c=1/\sqrt{{ϵ}_0{\mu }_0}$. In a simple transparent isotropic material, the phase speed is $1/\sqrt{ϵ\mu }=c/n$, where $n$ is the refractive index. Real material polarization depends on frequency. A Lorentz oscillator model for bound charges explains why permittivity and refractive index become strongly frequency dependent near material resonances, accompanied by absorption. In a birefringent medium, different field polarizations have different propagation constants, permitting wave plates and mode-dependent delays. A electrical conductor additionally supports dissipative currents; its complex wavenumber gives attenuation and, for a good conductor, a skin depth approximately $\sqrt{2/(\mu \sigma \omega )}$. Energy removed from the wave becomes heat rather than disappearing.

At an interface, frequency is conserved for stationary media, and tangential wave phase must match. These conditions give Snell's law for refraction and constrain reflected and transmitted directions. Amplitudes follow from continuity of the appropriate fields or mechanical forces. On strings the relevant mechanical impedance is $\sqrt{T\mu }$; for sound it is related to $\rho c_s$, and for electromagnetic waves to $\sqrt{\mu /ϵ}$. A mismatch gives wave reflection, and a lossless boundary conserves the total incident, reflected and transmitted power. Multiple reflections can reinforce or cancel, as in a Fabry–Pérot etalon. Total internal reflection and other boundary conditions confine waves in waveguides. Transverse modes then become discrete, and even an otherwise nondispersive material develops longitudinal cutoffs and wave dispersion. A membrane strip, for example, obeys ${\omega }_n^2=c_m^2[k^2+(n\pi /a{)}^2]$.

Propagation also involves transport and loss. The Poynting vector gives electromagnetic energy flux; mechanical energy transport is force or pressure times velocity, averaged over a cycle. Wave absorption, viscosity, electrical resistance and imperfect boundaries dissipate energy. Scattering redistributes energy into other directions and modes, while geometric spreading reduces local intensity without necessarily dissipating anything. These mechanisms should be distinguished when interpreting a decreasing measured amplitude. In strongly absorbing or rapidly varying dispersive regimes, the derivative called group velocity is not automatically the speed of a sharp signal front; pulse reshaping and the medium's causal response must be considered.

Finally, quantum matter waves illustrate how the same propagation mathematics can describe a different physical quantity. For a free nonrelativistic particle, $\omega =\hslash k^2/(2m)$, so the group velocity $\hslash k/m$ equals its particle velocity and differs from the phase speed $\hslash k/(2m)$. In a periodic crystal, Bloch's theorem replaces the free dispersion by energy bands. Their slope controls wave-packet velocity, $v_g={\hslash }^{-1}dE/dk$, and their curvature gives band effective mass. Thus mechanical confinement, material response and microscopic periodicity all reshape propagation through their allowed modes and dispersion, while the physical interpretation of the wave and its transported quantities remains essential.

For the deep-water gravity wave, the phase velocity and group velocity follow from its dispersion relation:The wave packet travels at $v_g$, while the individual crests travel at $v_p$. Let its effective length be $D\simeq 5\lambda$, where $\lambda =2\pi /k$ is the carrier wavelength. A fixed observer is inside the wave packet for $\Delta t=D/v_g$, and crests arrive with wave period $\lambda /v_p$. ThusCrests enter the rear of the moving wave packet and disappear at its front, so the five visible at one instant are not five permanently identifiable crests. The count uses the intended narrow-band, approximately unchanged wave packet and neglects the precise visibility of its end crests.

The Debye model approximates a three-dimensional crystal as an elastic continuum supporting quantized normal modes, or phonons. At long wavelengths, the acoustic phonon branches have approximately linear dispersion relations ${\omega }_s(k)=v_{s}k$: one longitudinal branch and two transverse branches. Replace their complicated actual spectra by these linear forms, then introduce a cutoff chosen to preserve the total $3N$ vibrational degrees of freedom for $N$ atoms. This is an approximation to the spectrum, not a claim that a real crystal has no non-acoustic branches.

For periodic boundary conditions in volume $V$, each allowed wavevector occupies $(2\pi {)}^3/V$ in the space of wavevectors. Counting a spherical shell for each branch gives the density of states per unit angular frequencyAn effective speed of sound $v_D$ can be defined by $3/v_D^3=1/v_l^3+2/v_t^3$. In the single-speed Debye model, choose ${\omega }_D=v_D{k}_D$ so thatThus the Debye wavevector, Debye frequency and Debye temperature satisfyHere $g$ has units of seconds when angular frequency is measured in ${\mathrm{s}}^{-1}$; its integral is the dimensionless number of normal modes. The spherical cutoff replaces the real Brillouin zone by an equal-count continuum construction.

Each phonon mode is a quantum harmonic oscillator. Since phonon number is not conserved at thermal equilibrium, the chemical potential is zero and its Bose-Einstein distribution gives mean thermal energy $\hslash \omega /[e^{\hslash \omega /(k_{B}T)}-1]$. The zero-point energy is independent of temperature in the harmonic, fixed-volume approximation and does not contribute to the heat capacity at constant volume. Excluding that constant term,Differentiating the first integral at fixed volume avoids losing the temperature-dependent upper limit in the second one. The resulting Debye heat capacity isFor $T\ll {\Theta }_D$, extend the upper limit to infinity. Expanding $1/(e^x-1)={\sum }_{r\ge 1}{e}^{-rx}$ and integrating term by term gives ${\int }_0^{\infty }{x}^3/(e^x-1)dx=6\zeta (4)={\pi }^4/15$. ThereforeThis $T^3$ law follows from the three-dimensional ${\omega }^2$ density of states and the availability only of low-frequency modes at low temperature. It is a central success of the Debye model.

For $T\gg {\Theta }_D$, the Bose-Einstein distribution reduces to the classical equipartition theorem: every mode contributes thermal energy $k_{B}T$. Consequentlythe Dulong-Petit law, or $3R$ per mole of atoms. The simple model omits detailed phonon dispersion relation, distinct optical phonon branches, and anharmonic effects such as thermal expansion. In a metal, the low-temperature total heat capacity additionally contains a term approximately proportional to $T$ from electrons, so the lattice $T^3$ term should not be mistaken for the whole measurement.

A nondispersive wave has a linear dispersion relation $\omega =vk$ over the relevant range, so every Fourier transform component has the same phase velocity $v_p=\omega /k=v$ and group velocity $v_g=d\omega /dk=v$. A wave packet then translates without spreading in an ideal homogeneous lossless medium.

For wave dispersion, $v_p$ depends on frequency or wavenumber. Different components accumulate different phases, and in general the group velocity differs from the phase velocity; variation of group velocity across the spectrum produces spreading of a wave packet. The membrane material can be nondispersive while confinement in a membrane waveguide introduces wave dispersion along its length.

Let $d=1,2,3$ and take a specimen of length, area or volume $L^d$. One monovalent atom per unit cell supplieselectrons. At zero temperature, the Pauli exclusion principle fills the lowest energy states, with two spin states per spatial wavevector. The occupied region is an interval, disk or ball of radius $k_F$. Using the $k$-space density of states gives, in one dimension,In two dimensions,In three dimensions,Each Fermi energy follows from the free electron model dispersion relation $E_F={\hslash }^2{k}_F^2/(2m)$. The Fermi wavevectors have units ${\mathrm{m}}^{-1}$ and the Fermi energies have units joules for $a$ in metres and $m$ in kilograms. No numerical lattice spacing is supplied, so numerical energies in electronvolts cannot be uniquely calculated. The spin factor of two is necessary here for actual monovalent crystals; the spinless auxiliary count of part (a) was not an instruction to remove electron spin from these crystals.

Keep the electron number fixed, soand $\mu (0)=E_F$. Heating smooths the Fermi-Dirac distribution across the Fermi energy, creating holes below $\mu$ and particles above it. The sign of the low-temperature adjustment of chemical potential follows from the local slope of the density of states.

In one dimension, $g\propto {ϵ}^{-1/2}$ decreases with energy. At fixed $\mu$, smoothing removes more electrons below it than it adds above it, so $\mu$ initially rises. In three dimensions, $g\propto {ϵ}^{1/2}$ increases, so $\mu$ falls. In two dimensions the constant density of states makes the leading changes cancel, so $\mu$ stays extremely close to $E_F$ in the degenerate regime.

For quantitative checks, a Sommerfeld expansion gives, for $k_{B}T\ll E_F$,For a constant two-dimensional density of states above an unbounded parabolic band bottom, the number integral can be done exactly:soIt actually decreases, but its low-temperature correction is exponentially small rather than quadratic. “Constant in two dimensions” is therefore a low-temperature approximation, not an exact statement for every $T$.

The one-dimensional rise is also only an initial trend. In the high-temperature Maxwell-Boltzmann distribution limit, the ideal $d$-dimensional electron gas has $\mu \simeq k_{B}T\ln [n_d{\lambda }_T^d/2]$, where $n_d=N_e/L^d$ and ${\lambda }_T=\sqrt{2\pi {\hslash }^2/(m{k}_{B}T)}$ is the thermal de Broglie wavelength. It eventually becomes negative and decreases in every dimension. The one-dimensional chemical potential thus passes through a maximum. This high-temperature statement refers to the stipulated unbounded free-electron dispersion relation, not a claim that a real finite-width crystal band remains parabolic indefinitely.

State a time convention before using complex response: take fields proportional to $e^{i(kz-\omega t)}$, with $k=k_r+i\kappa$ and $\kappa \ge 0$ for a passive wave entering the material. In a homogeneous Ohmic medium, Maxwell equations with $\mathbf{J}=\sigma \mathbf{E}$ giveThe ohmic-conductor complex wavenumber describes both phase advance and amplitude decay. Real constant conductivity is only a low-frequency approximation. In the Drude model, $m\dot{\mathbf{v}}+m\gamma \mathbf{v}=-e\mathbf{E}$ giveswith a fixed positive ionic background and no additional bound-electron contribution in this simple model. The plasma frequency marks the inertial electron-response scale. More elaborate band structure, interband transitions and nonlocal transport limit this scalar treatment.^[ref]

In the collisionless nonmagnetic limit, the dispersion relation is ${\omega }^2={\omega }_p^2+c^2{k}^2$. For $\omega >{\omega }_p$,A crest can move faster than $c$ without carrying a new signal faster than light. Below cutoff the ideal wave is evanescent, with penetration length $c/\sqrt{{\omega }_p^2-{\omega }^2}$; it does not propagate as an ordinary real-$k$ bulk wave. Evanescence in the lossless limit is not Joule dissipation. Nonzero collision rate gives a dissipative conductivity and smooths this ideal cutoff picture.

For a good conductor with approximately real $\sigma \gg \omega ϵ$, the spatial branch becomesA field amplitude falls as $e^{-z/\delta }$, while intensity falls as $e^{-2z/\delta }$. The phase velocity is $\omega \delta$ in this limit. Magnetic and electric amplitudes are not related by the vacuum ratio: $Z_s=E/H=(1-i)\sqrt{\mu \omega /(2\sigma )}$ with the chosen time convention. Its positive real part is the surface resistance. The local mean heating is $\frac{1}{2}\mathrm{Re}\sigma |E{|}^2$, consistent with electromagnetic energy flowing into the metal. skin depth is an amplitude length; interpreting it as an intensity length gives a factor-of-two error.

A transmission-line mode propagates chiefly through the dielectric between conductors, even though finite metal conductivity causes loss at its boundaries. With per-length parameters $R^{\prime },L^{\prime },G^{\prime },C^{\prime }$, the telegrapher's equations give, for the same $e^{-i\omega t}$ convention,Writing a forward wave as $e^{-\Gamma z}$, $\Gamma =\alpha -i\beta$, gives ${\Gamma }^2=(R^{\prime }-i\omega L^{\prime })(G^{\prime }-i\omega C^{\prime })$. In the low-loss regime $R^{\prime }\ll \omega L^{\prime }$ and $G^{\prime }\ll \omega C^{\prime }$, set $Z_0\simeq \sqrt{L^{\prime }/C^{\prime }}$ to obtainThis low-loss transmission-line attenuation separates series conductor loss from dielectric leakage loss. Average forward power falls as $e^{-2\alpha z}$. In the normal skin-effect regime, reduced conducting area makes the AC conductor resistance increase roughly as $\sqrt{\omega }$; dielectric loss can supply a separate frequency dependence. Reflection from a mismatched termination changes delivered power without being, by itself, dissipation in the line.^[ref]

To test loss, compare several lengths of otherwise identical line with matched terminations, calibrate connectors and incident/reflected power, and monitor temperature. Separate amplitude attenuation from phase delay and from standing-wave minima. Bulk penetration, line attenuation and dielectric propagation speed are related electromagnetic quantities but describe different experimental geometries.

Displacement current makes Ampère's law compatible with charge conservation. The macroscopic Maxwell equations areTaking the divergence of the last equation and using Gauss's law gives $\nabla \cdot {\mathbf{J}}_f+{\partial }_t{\rho }_f=0$. Omitting ${\partial }_t\mathbf{D}$ would wrongly require the conduction current to be divergence free during charging. The displacement-current density ${\partial }_t\mathbf{D}$ has current-density units, but need not represent free charges crossing a region.

The surface independence of Ampère circulation during capacitor charging illustrates the need directly. A surface spanning the circuit can cut the wire or pass between the plates. For ideal parallel plates, $Q={ϵ}_{0}AE$ andThe corrected circulation of $\mathbf{H}$ is independent of that surface choice. Free conduction current stops at a plate; displacement current supplies the gap contribution.

In vacuum the two time-dependent curl equations support waves. Taking a curl of Faraday's law in a source-free region yieldsThe corresponding magnetic equation is identical. For a plane wave, $\mathbf{k}\cdot \mathbf{E}=\mathbf{k}\cdot \mathbf{B}=0$ and $\mathbf{B}=\mathbf{k}\times \mathbf{E}/\omega$. The fields carry energy through the Poynting flux. Dropping displacement current everywhere would remove these freely propagating solutions.^[ref]

In a metal, conduction and displacement compete. For a uniform ohmic material with ${\mathbf{J}}_f=\sigma \mathbf{E}$, constant $ϵ,\mu$, and transverse waves,Use $e^{i\mathbf{k}\cdot \mathbf{r}-i\omega t}$. The dispersion relation and conduction-to-displacement current ratio areWhen $\sigma \gg \omega ϵ$, $k\simeq (1+i)/\delta$ with $\delta =\sqrt{2/(\mu \sigma \omega )}$: fields are screened within a skin depth and energy is dissipated by Joule heating. This quasistatic limit neglects displacement current locally compared with conduction; it does not invalidate the full Maxwell law. At sufficiently high frequency, conductivity and permittivity are frequency dependent, so a constant-$\sigma$ approximation must be replaced by a material model.

In an unmagnetized cold plasma, electron inertia gives a cutoff. With immobile ions and negligible collisions, $m_e\dot{\mathbf{v}}=-e\mathbf{E}$ and $\mathbf{J}=-n_{e}e\mathbf{v}$ give $\sigma (\omega )=i{n}_e{e}^2/(m_e\omega )$. For the transverse wave cutoff in a cold unmagnetized plasma, combining this carrier current with vacuum displacement current givesTransverse waves propagate above ${\omega }_p$ and are evanescent below it. The group velocity is $c\sqrt{1-{\omega }_p^2/{\omega }^2}<c$ even though the phase velocity exceeds $c$. The cold model also has longitudinal charge-density oscillations at ${\omega }_p$, distinct from transverse light waves. Collisions add damping, and pressure or magnetic fields modify these simple dispersions. To avoid carrier-current double counting in effective permittivity, once the carrier response is included in ${ϵ}_{\mathrm{eff}}$ it must not be counted a second time as a separate conductivity. Displacement current therefore connects circuit continuity, vacuum radiation, conductor screening and plasma propagation within one consistent field theory.^[ref]