To preserve the convention of part (a), first count one spin species. Define as the number of spatial states in the whole specimen in that energy interval. Put
In one dimension there are intervals near both and , so the one-dimensional free-electron density of states is
Thus . The factor of two here comes from opposite momenta, not spin. For physical electrons with two spin states, the spin-summed density of states is . These expressions are continuum approximations away from individual discrete levels.
Let and take a specimen of length, area or volume . One monovalent atom per unit cell supplies
electrons. At zero temperature, the Pauli exclusion principle fills the lowest energy states, with two spin states per spatial wavevector. The occupied region is an interval, disk or ball of radius . Using the -space density of states gives, in one dimension,
In two dimensions,
In three dimensions,
Each Fermi energy follows from the free electron model dispersion relation . The Fermi wavevectors have units and the Fermi energies have units joules for in metres and in kilograms. No numerical lattice spacing is supplied, so numerical energies in electronvolts cannot be uniquely calculated. The spin factor of two is necessary here for actual monovalent crystals; the spinless auxiliary count of part (a) was not an instruction to remove electron spin from these crystals.
The length, area and volume of a first Brillouin zone are . The corresponding occupied -space measures are
Hence
This is state counting, independent of the interval/disk/ball geometry. One Brillouin zone contains one spatial state per unit cell in a single energy band, and that band can hold two electrons per cell because of spin. One electron per cell therefore occupies half of it. The “volume enclosed” is the occupied Fermi sea, not the lower-dimensional area of the Fermi surface itself. Its half-volume does not mean half the distance to the zone boundary in two or three dimensions.
Keep the electron number fixed, so
and . Heating smooths the Fermi-Dirac distribution across the Fermi energy, creating holes below and particles above it. The sign of the low-temperature adjustment of chemical potential follows from the local slope of the density of states.
In one dimension, decreases with energy. At fixed , smoothing removes more electrons below it than it adds above it, so initially rises. In three dimensions, increases, so falls. In two dimensions the constant density of states makes the leading changes cancel, so stays extremely close to in the degenerate regime.
For quantitative checks, a Sommerfeld expansion gives, for ,
For a constant two-dimensional density of states above an unbounded parabolic band bottom, the number integral can be done exactly:
so
It actually decreases, but its low-temperature correction is exponentially small rather than quadratic. “Constant in two dimensions” is therefore a low-temperature approximation, not an exact statement for every .
The one-dimensional rise is also only an initial trend. In the high-temperature Maxwell-Boltzmann distribution limit, the ideal -dimensional electron gas has , where and is the thermal de Broglie wavelength. It eventually becomes negative and decreases in every dimension. The one-dimensional chemical potential thus passes through a maximum. This high-temperature statement refers to the stipulated unbounded free-electron dispersion relation, not a claim that a real finite-width crystal band remains parabolic indefinitely.
Use a cold, unmagnetized, collisionless electron plasma with immobile ions. For an oscillating field proportional to , the electron displacement follows . Hence and
The induced polarization opposes the field because electron inertia changes the phase of its displacement. Maxwell's equations give transverse electromagnetic dispersion
Thus transverse waves propagate above the plasma frequency, while below it the wavenumber is imaginary and a semi-infinite lossless plasma reflects an incident wave with an evanescent interior field. In the cold electrostatic model, a longitudinal density oscillation instead has frequency .
Collisions at rate give for this time convention, introducing absorption. A background magnetic field makes the response anisotropic, and thermal motion supplies additional dispersion and static screening. The divergent zero-frequency cold collisionless formula should not be mistaken for a complete description of static Debye screening. The simple dielectric function is a dynamical electron-inertia response under stated assumptions.
Use peak phasors with time dependence , real positive electrical conductivity , and absolute permeability . Ampère-Maxwell equation and Faraday equations give
so . The sign of the imaginary term follows from the stated time convention. For a transverse plane wave in a homogeneous conductor,
In the good-conductor limit, choose the root that decays into :
The electric phasor and physical field are consequently and , as required. Tangential boundary matching sets ; it need not equal the incident amplitude.
Faraday's law fixes the magnetic field, including its phase:
For real and , this means , with other components zero. The time-averaged Poynting vector is
The energy entering a thin slab exceeds that leaving it by per unit volume, giving
Directly, and at each time. Therefore is exactly this loss. The factors one half use peak rather than root mean square phasors; amplitude decays over , while intensity decays over .
For a cold collisionless unmagnetized plasma, electron inertia gives and real . Above the plasma frequency the wave propagates without this resistive attenuation. Below it, a semi-infinite plasma supports an evanescent field with electric and magnetic components in quadrature and zero mean inward energy flux: the incident energy is reflected, not absorbed as Joule heating. electron kinetic energy is reversibly stored, so the nondispersive dielectric field-energy formula alone is incomplete. Collisions introduce a real dissipative electrical conductivity and can produce absorption.[ref]
For a cold, unmagnetized, collisionless plasma, take an equilibrium electron density , electrons of mass and charge , and approximately stationary ions. Use fields proportional to . The electron displacement satisfies
Its electric polarization is , hence the cold collisionless plasma dielectric response
The negative susceptibility arises from the inertial electron response, rather than a restoring force binding an electron to a particular atom.
A transverse electromagnetic wave then obeys
For , the plasma supports propagation, with refractive index . The phase velocity is greater than , while the group velocity is ; their product is , and no superluminal signal is implied. Below the plasma frequency, the bulk wavenumber is imaginary and the field is evanescent. A sufficiently thick plasma largely reflects such radiation in the lossless model.
Including an electron momentum-relaxation rate replaces the denominator by :
Its imaginary part describes absorption with the stated time convention. Finite electron temperature also produces plasma screening of slowly varying electrostatic fields, with . That spatial, longitudinal screening problem is distinct from simply taking in the cold transverse-wave formula. Magnetic bias, ion motion and kinetic resonances require more general dielectric responses.
For weak fields in a linear isotropic material, magnetization is , with magnetic susceptibility . Paramagnetism has , while diamagnetism has . In either case, . These weak responses generally disappear when the applied field is removed, unlike hysteretic ferromagnetism.
A paramagnet can contain permanent magnetic moments from unpaired electrons or atomic angular momentum. Alignment lowers the energy , while thermal disorder opposes it. For independent classical moments of magnitude , their weak-field average projection is , so
This is Curie's law; it assumes weak magnetization and no important interactions between moments. With quantum angular momentum , replace by . Strong-field magnetization saturates instead of growing linearly without limit. Conduction electrons also exhibit Pauli paramagnetism: only occupations near the Fermi surface readily redistribute between spin states, giving a nearly temperature-independent susceptibility when .
Diamagnetism is an induced orbital response opposing the applied magnetic field. For bound electrons, a weak field changes orbital motion and induces an opposing magnetic moment. For an isotropic collection of atoms, the elementary orbital estimate is
where the sum runs over the electrons of one atom. It is usually small and weakly temperature dependent. Delocalized electrons also have orbital Landau diamagnetism; for an ideal three-dimensional free electron gas with a quadratic isotropic dispersion and electron spin with , . Both spin and orbital contributions must be included to determine the total response. Diamagnetism is not a consequence of permanent dipoles choosing to align against the field; that orientation would increase their energy.
The appropriate quantity to minimize is the energy including exchange of particles with the electron reservoir, . The occupation of an interacting localized electron level follows from
For repulsion , the first electron costs and the second costs . Comparing all three grand energies gives
For attraction , the singly occupied state never minimizes the grand energy. At the crossing of the empty and doubly occupied states, , its grand energy is , while both competing states have zero grand energy. Hence
For the two thresholds coincide at , giving a direct step. At a threshold, distinct occupations are degenerate; zero-temperature minimization alone does not select a unique occupation. A grand canonical ensemble at small positive temperature smooths the steps, with
In particular, the equal-weight empty/pair limit for gives mean occupation one exactly at its crossing; this is not a finite-width singly occupied plateau.
Figure 1.
Zero-temperature occupation of a localized impurity level in a crystal with repulsive, zero and attractive interaction
. Original plots of the minimizing occupation away from degeneracy points. Dashed vertical lines mark the chemical potentials at which different occupations have equal grand energy. Their vertical segments indicate jumps, not intermediate stable states. Details.
A dielectric responds to an electric field mainly by displacing or orienting bound charges, rather than by sustaining a steady conduction current. The polarization density is electric dipole moment per unit volume. It creates bound charge
Separating these charges from free charge motivates
For an isotropic linear dielectric, , so
The electric susceptibility describes material polarization and is not the magnetic susceptibility. More generally it is a tensor and can depend on frequency, field strength and temperature.
Electronic polarization displaces an electron cloud relative to its nucleus; ionic polarization displaces positive and negative ions; orientational polarization partially aligns permanent molecular dipoles against thermal disorder. For independent permanent moments of magnitude , weak-field orientational response gives when local-field corrections and interactions are negligible. This explains a common inverse-temperature contribution without asserting that every dielectric follows that law.
At a static interface, and the tangential electric field is continuous. Bound surface charge is already included through . For a homogeneous filled capacitor, , and a reversible linear dielectric stores energy density . At fixed voltage, insertion raises the stored field energy but the voltage source also supplies energy; force arguments must include that source. At fixed charge the capacitor energy instead decreases on insertion.
At frequencies too high for a polarization mechanism to follow the field, its contribution weakens. A complex permittivity represents dissipative dielectric loss as well as phase lag; the sign of its imaginary part depends on the time convention. Strong fields can cause nonlinear response or dielectric breakdown, beyond the reversible linear model.
Magnetization and field response. A magnetic material contains microscopic magnetic moments associated with electron spin and orbital motion. The magnetization is magnetic dipole moment per unit volume. In SI the macroscopic fields satisfy
Here separates free-current excitation from the material response. A uniform isotropic linear material has , giving
This constant scalar magnetic permeability model is useful only within its linear range. Crystals can have a susceptibility tensor; strongly magnetic materials depend on field and magnetic history. For a finite specimen the internal also includes its demagnetizing field. In a uniformly magnetized ellipsoid, along a principal axis, so sample shape affects the apparent susceptibility.
Diamagnetic and paramagnetic response. Diamagnetism is a weak negative susceptibility caused by induced orbital response opposing the applied field. It occurs in all matter but can be masked by larger positive contributions. Closed-shell materials such as bismuth or many organic compounds show it clearly. Ordinary diamagnetism is often only weakly temperature dependent; superconducting flux exclusion is a separate collective phenomenon and is not described by an arbitrarily small negative susceptibility.
Paramagnetism arises when available magnetic moments partially align with a field. Thermal disorder prevents complete alignment at weak fields. For independent localized moments of magnitude , the classical weak-field result is
where the second expression uses in a weakly magnetic sample. Thus localized moments obey a Curie law in this regime. Quantum angular momentum changes the coefficient to the appropriate expression and gives saturation at strong field. Conduction electrons instead exhibit Pauli paramagnetism: only states near the Fermi surface can change spin populations, so a degenerate gas has a nearly temperature-independent response. Its orbital diamagnetism must also be included for a full metallic susceptibility.
Collective magnetic order. Exchange interactions can favor parallel alignment, producing ferromagnetism below the Curie temperature. Iron, cobalt and nickel are familiar examples. A material may contain regions of spontaneous magnetization, or magnetic domains, while having little net external moment because the domains point in different directions. Applied fields move domain walls and rotate moments; at large fields the magnetization approaches saturation. Pinning and energy barriers make this process hysteretic. Remanence is the magnetization left after removing the driving field, and coercivity measures the reverse field needed to bring the chosen response back to zero.
The area of a closed – loop is the energy dissipated per unit volume per quasistatic cycle, , with positive dissipated magnitude. Consequently the magnetic permeability is neither one universal constant nor enough information to describe a ferromagnet: differential magnetic permeability , saturation and hysteresis all matter. Above the ordering temperature the spontaneous moment disappears, and a Curie–Weiss law is often an appropriate approximate paramagnetic description away from the critical region.
In antiferromagnetism, ordered opposing sublattices have equal moments and cancel macroscopically in the ideal compensated case. The order disappears above the Néel temperature. In ferrimagnetism, opposing sublattices have unequal moments and leave a net magnetization. Ferrites combine ferrimagnetic response with relatively high electrical resistivity, making them valuable when eddy-current losses would be substantial in a metallic core.
Electromagnets and engineering choice. A coil supplies free-current magnetomotive force . For a simple uniform magnetic path, Ampère's law gives and flux . A high-magnetic permeability soft magnetic core concentrates flux and reduces the current required for a given field. With an air gap ,
Even a short gap can dominate the magnetic reluctance. The approximate attractive force across one uniform gap is , obtained from the field energy, with fringing neglected.
Soft magnetic materials have small coercivity and narrow hysteresis loops; they suit relays, electrical transformer cores and controllable electromagnets. Hard magnetic materials retain their magnetization and suit permanent magnets. Laminating metallic cores breaks large eddy-current loops; ferrites are useful at higher frequencies because of their resistivity. Increasing current cannot increase indefinitely through the linear formula: core saturation, coil heating and leakage limit performance. A good design selects material for the field amplitude, switching frequency and acceptable loss, rather than simply choosing the largest quoted magnetic permeability.
Electromagnetic waves drive mobile charges in a conducting medium. Their current changes both the phase and attenuation of the wave. A description in terms of a real, frequency-independent refractive index is therefore generally insufficient: the material response and the propagation constant are complex and frequency dependent.
Use phasors proportional to , with and for a passive medium. In a homogeneous, isotropic, linear material, let represent the permittivity associated with bound-charge electric polarization, the magnetic permeability and the mobile-charge conductivity. The macroscopic Maxwell equations give
For a transverse plane wave, taking another curl yields
This division of the response avoids counting mobile electrons both in and in . Define the complex refractive index . For a nonmagnetic medium, . Its real part determines the phase variation, while the positive optical extinction coefficient gives amplitude attenuation and intensity attenuation . The amplitude penetration length is
A simple microscopic explanation comes from the Drude model. Let electrons of charge , mass and number density move against an effectively stationary positive background. Collisions relax their mean velocity at rate :
Consequently
With a vacuum-like bound-charge background, this gives
Its imaginary part is positive for positive , consistent with dissipation under the chosen phasor convention. Real materials can require an effective electron mass, a nontrivial bound-charge response, or additional absorption associated with the electronic band structure.
A plasma is a conducting ionized medium with mobile electrons and ions, approximately neutral on large scales because of plasma screening. For the electron-frequency transverse waves considered here, the heavy ions can often be treated as stationary. In a dilute weakly collisional plasma, , so
For , is real in this collisionless model and the wave propagates. Its phase velocity is , while its group velocity is ; their product is . A phase crest exceeding does not imply superluminal information transport. For , the refractive-index square is negative and
The transmitted field is evanescent rather than a traveling bulk wave. A sufficiently thick collisionless plasma reflects such radiation without Ohmic absorption. Collisions make the response complex and permit absorption. This accounts for a plasma cutoff and, qualitatively, the reflection of some radio frequencies by ionized atmospheric layers. The simple model describes transverse waves; plasmas also support longitudinal collective modes.
In a metal, positive ions usually form a crystal lattice. Mobile conduction electrons occupy states described by the electronic band structure and normally form a degenerate Fermi gas. The conduction-electron density is usually much higher than in a dilute gas plasma. Thus its plasma frequency is commonly in the optical or ultraviolet range, rather than the lower radio-frequency values possible in dilute plasmas. Electron scattering from the lattice, defects and other excitations gives a finite relaxation rate. The distinction is not that every plasma is collisionless and every metal collisional: the controlling ratio for either material is , together with its carrier density and bound-charge response.
At sufficiently low frequency, , the metal's conductivity is approximately real, . In a good conductor the conduction current dominates the displacement current, . The wave equation then gives
For example, a tangential electric field varies as
The current is therefore concentrated within a few skin depths of the surface: this is the skin effect. As frequency increases within this regime, . In a wire whose radius greatly exceeds , only a thin outer region carries appreciable alternating current, increasing the effective resistance. In a conducting shield, the same penetration suppresses the field transmitted through a sufficiently thick wall.
The Poynting theorem identifies the loss as Joule heating. The cycle-averaged heating density for a complex conductivity is
The wave impedance is . For incidence from vacuum at normal incidence, the electric reflection amplitude is , where . A good conductor has small and therefore strong reflection, while the part of the incident power entering it is dissipated over the skin depth.
At high enough frequency that , a metal's free-electron response also approaches the collisionless plasma form. The low-frequency formula must not simply be extrapolated into that regime. Real optical behavior additionally depends on the electronic band structure and transitions between bands. Both plasmas and metals are therefore described by the same electromagnetic response framework, but their relevant densities, scattering rates and frequency regimes differ.
An electron has electric charge , so its gain of kinetic energy through an accelerating electric potential difference of magnitude is . Starting from rest, conservation of energy gives
With , electron mass , and ,
This is a speed; the velocity points along the accelerating path, opposite the electric field. Here , where is the speed of light, so the classical kinetic energy approximation is accurate. As a check, special relativity gives and , agreeing to the quoted precision.
By symmetry, the two grounded plates take equal induced surface charge and the electric field has magnitude between either plate and the sheet. The grounded-plate potential of a central charged sheet is therefore
An electron released at zero potential gains kinetic energy . Thus
The planar infinite-sheet approximation neglects edge effects. Here denotes charge magnitude; the electron's negative charge makes it accelerate toward the positive sheet. Relativistic corrections are below0.1%. Numerical constants use rounded CODATA values, not a claim about the historical handbook: , and . [ref]
For , and , with . Thus
A photon obeys ; and agree because in vacuum.
Take the incident photon along , and write for the boost. In the boosted frame the initial momenta are
Their sum vanishes when , giving and . The initial photon energy there is , and total energy is .
For right-angle Compton scattering in the centre-of-momentum frame, choose the outgoing ZM photon along . The electron has the opposite momentum . Conservation of energy determines its magnitude:
Thus . Inverting the velocity transformation gives
Consequently
The electron recoils below the incident direction for our choice of photon scattering above it; the reflected configuration reverses both transverse signs. Finally,
As a check, , so the final energies sum to the initial . The outgoing laboratory photon makes with .
For steady currents in vacuum, Ampère's law is . A rectangular loop with one long side inside an ideal long solenoid and the other outside gives , because the exterior field is negligible and the perpendicular sides contribute zero. Thus , approximately uniform away from the ends.
Write the electron electric charge as , with . The Lorentz force is ; it does no work. For perpendicular motion, gives
Here is the positive angular speed; the rotation sense is determined by the negative electron electric charge.
The parallel velocity is unaffected, while the perpendicular component rotates. Hence the path is a helix with and . For on-axis entry into a solenoidal tube, the transverse circle passes through that axis: its guiding centre is displaced by , and its maximum distance from the tube axis is , not .
Figure 1.
End-on electron orbit: the circle passes through the tube axis and reaches twice its Larmor radius from it
. Details.
Using the nonrelativistic approximation appropriate to ,
The cyclotron period is , so the flight lasts revolutions. The electron therefore crosses the axis again four times before leaving. At , . Wall clearance requires , giving
The transit is longer than a full orbit, so the maximum transverse excursion really is sampled before exit.
For the solenoidal time-of-flight energy window, the prescribed time fixes , while . Therefore
These are total kinetic energies. The upper value is the ideal grazing limit; if touching the wall counts as rejection, it is a supremum approached from below.
The de Broglie wavelength fixes the same momentum , but the nonrelativistic electron has :
Here , consistent with the stated nonrelativistic approximation. The photon energy and electron kinetic energy are not interchangeable.
Here is potential energy, is the stationary state's total energy, and is its spatial probability amplitude. The wave function has time factor ; is a position probability density for a normalized state. Stationary plane-wave scattering solutions are idealizations described by probability-current ratios, or components of a normalizable wave packet.
Above an upward step, a classical particle is fully transmitted with reduced speed. Quantum mechanically the abrupt wavelength change generally produces both reflected and transmitted amplitudes even though both regions are classically allowed. With unit incident amplitude and no wave arriving from the right,
The reflected component has signed wavevector and the same wavenumber magnitude as the incident component. A finite potential jump with constant mass and no delta interaction requires continuity of and :
The probability current gives probability reflection and transmission and , with . The amplitude may exceed one without violating conservation of total probability, because the transmitted group speed is smaller.
For , let . The bounded right-hand solution is , an evanescent wave tail with amplitude penetration scale . It carries no outgoing probability current in an infinitely long forbidden half-space, so reflection is total. This differs from transmission through a finite potential barrier, where a second boundary can support quantum tunnelling.
For a downward step, replace by . The same boundary conditions give a nonzero negative , corresponding to a reflected amplitude with phase reversal. If reflection were forbidden, would require both and , impossible for a nonzero step. Reflection therefore does not require a classical potential barrier; the discontinuity of wavenumber mismatch is enough.
For the specified electron energies, , so the requested amplitude coefficients are
The corresponding probability coefficients are approximately and . electron mass cancels from these ratios; there is no need to invent an additional material effective mass.
The threshold must conserve both energy and momentum. For head-on photons, the total energy is , while the total momentum has magnitude . Their combined invariant mass satisfies
At the threshold for photon-photon pair production, the electron and Positron have no relative momentum in their centre-of-momentum frame, so . Therefore
Simply equating the laboratory energy to would miss the very large laboratory momentum: the newly produced pair must carry it away.
For a photon, the photon energy formula and the vacuum relation give . For an electron, the de Broglie wavelength gives the same momentum magnitude , but the nonrelativistic kinetic energy is . Using , and ,
Thus, to the precision of the wavelength,
The electron answer is its kinetic energy, as required for the diffraction experiment; its relativistic energy would additionally include the approximately rest energy. Since , the nonrelativistic approximation is well justified. Equal wavelengths imply equal momenta, not equal energies for particles with different energy–momentum relations.