Past exam of the quantum condensed matter course of the University of Cambridge 2014 2 c Solution Created 2026-10-18 Updated 2026-10-20
Both models respect Bloch's theorem and describe electrons in a periodic lattice, but they start from different useful limits.
In the nearly-free electron model, start with extended plane waves and free-electron energies . A weak periodic potential has Fourier coefficients at reciprocal lattice vectors and couples to . Away from degeneracies its corrections are small. Near a Bragg scattering, retain the two resonant plane waves and diagonalizeThe resulting eigenvalues areAt the crossing the gap is . The two standing-wave combinations place electronic density differently relative to the periodic potential and therefore acquire different energies. Folding the many free parabolas into the first Brillouin zone produces the repeated band labels; the nonzero potential opens avoided crossings between coupled states. A Fourier component forbidden by symmetry need not open its corresponding first-order gap.
In the tight-binding model, instead start with localized orbitals on well-separated atoms or sites, with discrete on-site energies. Their overlap permits tunneling represented by hopping integrals. Bloch sums of these orbitals diagonalize the lattice translation symmetry. For one orthonormal orbital per site in a one-dimensional nearest-neighbor chain,The many initially degenerate copies of one atomic orbital broaden into a band. Other atomic orbitals or multiple sites per primitive cell produce additional bands; their hybridization creates bonding and antibonding combinations and may open gaps. For two orbitals per cell, one illustrative Hamiltonian iswith eigenvalues . This shows explicitly how two bands arise from the two cell degrees of freedom, even when the isolated sites have equal on-site energies.
For each orbital degree of freedom per primitive cell there is one band per spin; band filling and the presence of a gap at the Fermi level determine metallic or insulating behavior. The nearly-free limit emphasizes weak Bragg scattering of extended states, while tight binding emphasizes hopping between localized states. They are complementary approximations to electronic band structure, rather than two incompatible explanations of why periodic solids have bands.
Past exam of the quantum condensed matter course of the University of Cambridge 2014 3 Solution Created 2026-10-18 Updated 2026-10-20
Diagonalization and conventions. The spin-dependent part is . For a Hermitian Hamiltonian is real; the supplied lower-band spinor uses the convention , which will be adopted below. The squared spin matrix is . Hence the two ordered energies areIn the plane, let and . ThenIf , use to retain the energy ordering, and interchange the spin directions assigned below. This is an isotropic Rashba effect; has units of inverse length, whereas has units of energy times length.
Band minima. Define and . Completing the square givesAlong , the radial coordinate is , so the lower branch has two minima:In the full plane these are points on a circle of minima . Both branches meet at , . Their ordered energy curves contain : the lower curve descends from the crossing on either side, while the upper rises. Treating them as globally labeled smooth spin branches without switching labels across would obscure the lower-band minima.
Occupied regions and Fermi contours. At zero temperature each spin-split eigenstate with energy below is occupied. PutFor , . The lower-band roots are and , while the upper band is entirely empty. Thus the central disk is unoccupied, the annulus is singly occupied, and the exterior is unoccupied. Both Fermi circles belong to the lower band; there is no doubly occupied region.
At , the lower band is occupied for , giving a singly occupied disk with outer Fermi circle at . The two bands also meet the Fermi energy at the origin. That isolated degenerate point is not a finite doubly occupied disk, and occupation exactly at the Fermi energy is a boundary convention of zero area. Outside the outer circle the states are empty.
For , . The lower branch has outer radius , while the upper branch has inner radius . The disk is doubly occupied, with one state in each band at every momentum. The annulus is singly occupied, in the lower band only, and the exterior is unoccupied. These are the Fermi contours of an isotropic Rashba band; double occupancy here refers to two orthogonal spinor states at the same momentum, not two electrons occupying one identical quantum state.
Rashba dispersion and occupied momentum regions below, at and above the band crossing
. Details. Inferring the splitting. Above the crossing, the two positive radii differ by :The minimum radius is therefore . It is the difference of the measured radii that is required for ; below the crossing the two lower-band radii instead add to .
Spinors and spin direction. Write , which has for . An orthogonal normalized partner to the supplied lower-band state isIndeed . Direct multiplication by the spin matrix gives eigenvalues and for and , respectively, so orthogonality has selected the other band rather than merely another arbitrary spin basis.
For a normalized spinor , the Pauli expectation values are . Consequently the Rashba spin texture isThe spin lies in the plane and is perpendicular to momentum. On the outer circle , which belongs to , it points clockwise as viewed from ; at it points along . On the inner circle , belonging to , it points counterclockwise; at it points along . Opposite momenta have opposite spins, consistent with time-reversal symmetry. At the origin the eigenstates are degenerate and no unique spin orientation is defined.
Opposite tangential spin textures on the outer lower-band and inner upper-band Fermi circles
. Details. Past exam of the quantum condensed matter course of the University of Cambridge 2014 4 Solution Created 2026-10-18 Updated 2026-10-20
Nondegenerate carrier product. Assume three-dimensional parabolic energy bands near their extrema, spin degeneracy two, and no additional uncounted valley multiplicity. Near the conduction edge, a Boltzmann approximation to the Fermi-Dirac distribution givesAngular integration and the Gaussian radial integral yieldFor valence electron holes, the empty-state probability is . Measuring electron hole kinetic energy downwards from similarly givesThe factors two count spin once in each band. Multiplying cancels the chemical potential and proves the semiconductor mass-action law:In an intrinsic neutral semiconductor, . In a doped equilibrium semiconductor the same product holds under the stated nondegenerate assumptions, even when . Extra valleys or several valence branches must be included in the effective density-of-states factors rather than counted inconsistently.
Equilibrium junction. Put the p region on the left and the n region on the right. Before contact their majority carriers are electron holes and electrons, respectively. Diffusion initially sends electrons from n to p and electron holes from p to n. This leaves negative ionized acceptors on the p side and positive ionized donors on the n side, creating a depletion region and an electric field directed from n to p. At equilibrium this field balances diffusion, so the net electric current vanishes.
For a homojunction the gap remains constant while the conduction band and valence band edges bend downwards from p to n by . The equilibrium chemical potential is flat. Since , the electrostatic potential rises from p to n. The carrier profiles satisfyWith fully ionized nondegenerate dopants, the neutral p side has , , while the neutral n side has , . Thus the electron concentration rises across the junction and the electron hole concentration falls, with both small relative to the far-side majority densities in much of the depleted region. The ideal depletion approximation neglects these mobile populations when calculating the fixed space electric charge, but the actual equilibrium profiles are smooth.
Equilibrium band bending, a flat chemical potential and complementary electron/hole profiles across a homojunction
. Details. The built-in potential follows from these Boltzmann factors:There is no applied terminal bias; the internal electrostatic potential variation does not contradict a constant electrochemical potential.
Opposing carrier fluxes under reverse bias. Use for the magnitude of reverse bias and for reverse electric current, as in the PDF. The junction barrier increases by . The Shockley diode equation in that orientation can be writtenThe reverse-directed contribution is supplied by minority electrons on the p side and minority electron holes on the n side. They reach the depletion edge by diffusion and are swept across by the built-in field. The opposing contribution is associated with majority carriers thermally crossing the barrier in the forward direction; reverse bias suppresses it by the Boltzmann factor. At zero bias detailed balance makes the two equal, while at large enough reverse bias the opposing flux becomes negligible.
In the ideal neutral-region diffusion model,Here are minority-carrier diffusion coefficients, their diffusion lengths, and is junction area. The two terms inside this positive prefactor are the electron and electron hole contributions; both flow in the same reverse-current direction. This separates the two carrier-species contributions from the two opposing fluxes in the Shockley diode equation. Calling the saturation term a drift current refers to its passage across the depleted region, and does not eliminate the minority-carrier diffusion needed to supply it.
Reading the measured curves. At , the ideal equation gives , initially proportional to reverse electric potential difference. At , it approaches a plateau . The thermal electric potential differences at the three temperatures are about –, consistent with a rise at small reverse biases and near saturation at larger ones. Higher temperature produces a much larger plateau because thermal electron-hole excitation raises exponentially.
The lower-temperature curve has a noticeable residual electric potential difference dependence rather than a perfectly flat plateau. Depletion-region generation, surface leakage or other departures from the ideal diffusion model can contribute. The sharp upturn at the largest reverse electric potential differences is reverse breakdown, outside the unextended Shockley diode equation; the plot alone does not identify a unique microscopic breakdown mechanism. The original horizontal axis duplicates the final decade label, so a precise breakdown electric potential difference cannot be read reliably. Neither issue prevents estimating the gap from the intermediate-bias saturation region.
Band-gap estimate. Use plateau electric currents at a common intermediate reverse bias, away from both the small-bias rise and the breakdown upturn. Approximate readings are , –, and . Kelvin temperatures are required in the activation law.
For fixed effective masses, . If the remaining transport prefactor is approximately constant, extracting a semiconductor band gap from diode saturation current therefore usesUsing the widest temperature separation and the rounded readings givesNeglecting all algebraic prefactors and fitting instead gives about . These differ by roughly , a material correction on the graph's precision scale. Thus an honest graph-based conclusion isThe nonflat low-temperature plateau, rough electric current readings, unprovided temperature dependence of , and possible gap variation prevent a more precise extraction. If depletion-region generation dominated rather than the specified mechanism, its activation slope could involve a different energy scale; the displayed estimate explicitly uses the diffusion-dominated saturation model requested here.
Past exam of the quantum condensed matter course of the University of Cambridge 2016 1 c Solution Created 2026-10-18 Updated 2026-10-20
For nondegenerate electrons in a parabolic conduction band,when the density-of-states effective mass and valley multiplicity are fixed. The intrinsic carrier extrapolation across a crossover must therefore specify how the activation energy changes with temperature.
The usual intended estimate treats the quoted as a constant intrinsic activation energy between the two temperatures, and identifies the crossover by . ThenFor , and , the exponent is and the prefactor is . HenceEquivalently, a fixed-gap intrinsic model with gives this result. A crossover is gradual: if denotes the net ionized donor density and , charge neutrality gives the actual electron population , rather than exactly .
There are two limits to interpreting the numerical estimate literally. First, the printed data specify only at , without specifying or the valence density of states. They do not mathematically determine : without the intended activation assumption the answer remainsSecond, using the original PDF's and density implies , extraordinarily large for a conventional semiconductor. This confirms that the numerical data should not be treated as a realistic material determination. No unprinted decimal-point correction has been assumed.
Past exam of the quantum condensed matter course of the University of Cambridge 2016 2 a Solution 2026-10-18
A junction field-effect transistor has a conducting channel between source and drain, with gate regions forming reverse-biased p-n junctions to that channel. In an n-channel device, a more negative gate-source electric potential difference increases the reverse bias and widens the depletion region. The conducting cross-section shrinks, reducing the drain electric current. The gate ideally draws only a small leakage electric current, giving a high input resistance; the source-drain supply provides the controlled output power. Carrier motion in a p-channel device reverses the relevant polarities.
At small positive , the channel conducts approximately as a resistor. As the potential rises from source to drain, the local gate-channel reverse bias increases toward the drain. The depletion layers are therefore thicker there. For a symmetric n channel of half-thickness , uniformly doped at density , the one-sided depletion approximation giveswhere is the depletion width from each side and the built-in junction potential. The neutral channel closes locally when . Define the positive geometrical depletion electric potential difference . The approximate drain-end pinch-off condition isMore negative gate bias makes this saturation occur at a smaller drain electric potential difference.
Gate depletion, drain-end pinch-off and approximate current saturation in an n-channel JFET
. Details. Pinch-off in a junction field-effect transistor does not mean that the drain electric current vanishes. Electrons arriving through the remaining neutral channel are swept across the high-field depleted region into the drain. Further increases in mostly fall across that region, so the electric current changes only weakly: this is the saturation regime used for amplification. Channel shortening gives a finite output slope in real devices. Excessive reverse electric potential difference eventually causes breakdown, beyond the normal saturation model.
A sufficiently negative gate electric potential difference can instead deplete the entire channel from the source end and produce cutoff. In the simplified geometry its threshold is . A commonly used approximate transfer law in saturation isHere is the saturated drain electric current at zero gate-source bias. The square law is a useful device approximation, not an exact result for arbitrary channel profiles. It connects field control of depletion to a measurable transfer characteristic while keeping drain-end pinch-off distinct from complete gate cutoff.
Past exam of the quantum condensed matter course of the University of Cambridge 2016 2 b Solution Created 2026-10-18 Updated 2026-10-20
Direct exchange is a quantum-mechanical spin-dependent energy arising from the Coulomb interaction and the required antisymmetry of a two-electron state. It requires spatial overlap of the relevant orbitals. It is not the classical magnetic dipole force between two small magnets, and it can be much stronger than that force.
For an explicit fixed-orbital illustration, take orthonormal spatial orbitals . Orthonormality means ; it does not require their spatial densities to occupy disjoint regions. The normalized spatial states areThe symmetric spatial state combines with the antisymmetric spin-one-half singlet state, and the antisymmetric spatial state combines with a symmetric spin-one-half triplet state, so that the complete fermionic state is antisymmetric.
For Coulomb potential , distinguish the direct electrostatic integral and exchange integral:The Coulomb exchange splitting of two orbitals givesThe repulsive Coulomb potential makes in this model. Thus the triplet is favored when the orbitals have nonzero exchange overlap. Its antisymmetric spatial wavefunction suppresses close electron encounters and reduces their repulsion. Since the Coulomb interaction contains no explicit spin operator, the spin dependence enters through the allowed spatial symmetry.
For dimensionless spin operators , whose pair eigenvalues are in the triplet and in the singlet, the same splitting is represented byThis explicitly states the sign convention: positive here favors parallel spins. A convention would instead have .
In a crystal, direct exchange therefore depends sensitively on orbital extent, overlap and interatomic spacing. It often decreases rapidly as localized orbitals separate. The fixed-orbital example does not prove that every material must be ferromagnetic: orbital rearrangement and competing kinetic or virtual-hopping processes alter the singlet-triplet balance. In particular, antiferromagnetic superexchange through an intermediate ligand is a different mechanism and should not be confused with direct overlap exchange.
Past exam of the quantum condensed matter course of the University of Cambridge 2016 3 Solution Created 2026-10-18 Updated 2026-10-20
mass as band curvature. In a periodic potential, a weakly forced electron is usefully described by a wave packet confined to one energy band. Its group velocity isDifferentiating the velocity givesThis effective-mass tensor describes the band response, not a change of the electron's bare rest mass. Along a principal direction, a steep upward curvature gives a small positive mass and a flatter curvature a larger one. Near a band maximum the electron curvature and effective mass are negative; the corresponding missing-electron description uses positive electron hole masses. Anisotropy produces distinct principal masses, and strong nonparabolicity makes them momentum dependent. The single-band semiclassical description assumes fields weak and slowly varying enough to avoid substantial interband transitions.
Lattice symmetry and Bloch's theorem. Use the active spatial translation operator . A lattice-periodic scalar potential satisfies , while the kinetic term is translation invariant. Therefore . The lattice translations also commute with one another, so they can be diagonalized simultaneously with , including within a degenerate energy subspace.
For a common eigenstate, write . Unitarity gives , and the group law gives . On primitive Bravais vectors , choose . Every lattice vector is an integer combination of these generators, henceThe vector is defined modulo a reciprocal lattice vector. The band index labels the different energy eigenstates with the same translation character. Define . The phase factors cancel under a lattice translation, proving Bloch's theorem in its usual form:This is the Translation-character proof of Bloch theorem; the commutator guarantees a basis of such states, even when an arbitrary superposition of different translation characters is not itself a translation eigenstate.
Periodic Hamiltonian. Acting once with momentum gives . Applying it again and cancelling the common plane-wave factor yieldsThe Bloch Hamiltonian acts on lattice-periodic functions in a unit cell. Expanding its square separates a zero-momentum Hamiltonian, a term linear in and an identity term quadratic in .
Expansion about the zone centre. Let , , and normalize all these states using a unit-cell inner product. For the real scalar Hamiltonian in the question, a nondegenerate zone-centre eigenfunction can be chosen real. Thenbecause opposite unit-cell faces cancel. Equivalently, time-reversal symmetry forbids a nonzero electric current in this nondegenerate spinless state. This explains why no linear energy term appears; it should not simply be omitted without a symmetry or extremum argument.
The first-order energy shift is therefore . In the second-order sum the quadratic term is proportional to the identity and has no off-diagonal matrix elements. Only the linear momentum vertex contributes. Second-order nondegenerate perturbation theory gives the momentum matrix-element expansion of band energyHermitian operator makes the two reciprocal matrix elements complex conjugates. All other periodic eigenstates at enter the sum. The remainder is even because time-reversal symmetry gives near this isolated state. At a degeneracy the denominators signal the need for degenerate perturbation theory instead.
mass ratio and the printed formula. Write . Differentiating the quadratic energy yieldsFor a specified unit direction , the resulting scalar mass ratio isIn an isotropic three-dimensional band, averaging equivalent directions givesCoupling to lower bands contributes positively to inverse mass; coupling to higher bands contributes negatively. Their signs and matrix elements determine the actual curvature.
The original PDF prints . Taken literally as a three-dimensional Laplacian, this misses a factor of three for an isotropic scalar mass. The correct identities areThe printed expression would return even for the free dispersion . It is correct in one dimension, or if its second derivative is interpreted directionally. For completeness, its literal three-dimensional trace ratio would instead be ; that is the trace of the dimensionless inverse-mass tensor, not the usual scalar .
Past exam of the quantum condensed matter course of the University of Cambridge 2016 4 Solution Created 2026-10-18 Updated 2026-10-20
Relaxation-time model. The Drude model treats mobile charge carriers as independent particles accelerated by the Lorentz force between scattering events. Collisions randomize the drift momentum toward local equilibrium and are represented by a uniform, field-independent momentum relaxation time. For the present calculation the carrier density, isotropic mass and relaxation time are fixed, the fields are uniform and stationary, and quantum orbital quantization and intercarrier correlations are neglected. The steady drift velocity obeysHere is the number of carriers of that species per unit volume, their signed charge, their inertial or isotropic band mass, the momentum relaxation time, and their single-species electrical conductivity at zero field.
One-carrier tensor. With and , solving for the electric field givesSince and ,Thus the resistivity tensor, defined by , isIts off-diagonal signs follow from the stated axes and signed . For zero transverse electric current, is the Hall electrical resistivity; reversing charge reverses it. The single-species longitudinal electrical resistivity is independent of in this ideal isotropic model.
Adding electrons and electron holes. Let both species have density and charges , with . The stipulated equal zero-field electrical conductivity means equal positive charge carrier mobility , even if their masses and momentum relaxation times separately differ. Put and . Inverting each electrical resistivity matrix givesBoth species experience the same electric field, so their electric current densities add. Therefore it is their conductivity tensors, rather than their resistivity tensors, that must be summed. The Hall parts cancel andThis is compensated two-carrier magnetoresistance. Although the net Hall field vanishes, each carrier species is bent in its own direction; maintaining the total longitudinal electric current requires an increasing longitudinal field. Equal carrier numbers alone do not ensure zero Hall response if charge carrier mobilities differ; both equalities given here are used.
Large-field limit and quantum oscillations. Expanding the exact diagonal entry,For ,Here the last equality applies to either species with its own mass and transport time; the stipulated charge carrier mobilities give the same threshold. This is the classical strong-field condition : carriers turn substantially before their drift momentum relaxes.
Observable quantum oscillations additionally require sufficiently sharp Landau levels and a sufficiently cold Fermi-Dirac distribution, approximatelyWhen , the disorder field scale is comparable to the onset scale for large classical magnetoresistance. The thermal condition can demand a much larger field, and when even the disorder criterion is stronger. The quantitative damping factors in Q2(c) show that these are crossover scales rather than sharp visibility boundaries. A large smooth magnetoresistance therefore does not itself demonstrate Landau level; it can exist while thermal smearing suppresses oscillations. Conversely, the asymptotic condition is stronger than merely reaching unity, so there is no universal ordering of the two experimental onset fields without temperatures and lifetime information.
Scaling function. The material's actual zero-field longitudinal electrical resistivity is . Dividing the exact answer by this value givesThe assumption that stays constant is essential to eliminating further temperature-dependent parameters. is a dimensionful scaling variable; is its dimensionless version. The corresponding fractional increase is .
What the supplied data test. In the original PDF's left panel, the field dependence is strongly temperature dependent. In the right panel, plotting the fractional magnetoresistance against the squared rescaled field makes the displayed 125, 150, 175, 200 and 225 K curves collapse approximately onto one straight line, over the field intervals where they overlap. This supports the proposed one-parameter scaling and, on that range, the quadratic field law. The 100 K curve does not collapse: it bends away and has a different slope in the rescaled plot. The indicated scaling is therefore supported for the displayed 125–225 K data, not for the entire displayed temperature range. The graph alone does not locate a sharp transition between 100 and 125 K or establish behavior above 225 K.
This empirical collapse is Kohler's rule. It is consistent with a common temperature-dependent charge carrier mobility or relaxation scale and a fixed carrier population; it is not a unique proof of exact compensation or of one microscopic scattering mechanism. A change in relative scattering times, carrier population or Fermi-surface structure could spoil the collapse, and this figure alone does not select the cause of the 100 K departure.
There is a factor-of-two normalization convention in the printed text. The introduced for each species gives , whereas the final paragraph calls “.” If denotes the experimentally measured zero-field electrical resistivity, the consistent slope isIf one instead keeps the literal single-species definition , the same model has . The choice rescales and offsets the axes by temperature-independent constants, so it does not change which temperature curves collapse, but it must be resolved before inferring a carrier density from the slope.
Past exam of the quantum condensed matter course of the University of Cambridge 2017 1 a Solution Created 2026-10-18 Updated 2026-10-20
Choose the convention. The steady displacement in the Lorentz oscillator model has complex amplitudeThe induced electric dipole moment is , so the microscopic electric polarizability is . For identical oscillators per unit volume, . ConsequentlyHere the dimensionless quantity called polarizability in the paper is the electric susceptibility; the single-electron polarizability has different units. The sign of the electron charge disappears because both the driving force and dipole moment contain .
Multiplying by the complex conjugate of the denominator givesFor positive damping and positive frequency, , as required for passive wave absorption in this Fourier convention. At zero frequency, and . Near a weakly damped resonance the imaginary part has a narrow positive peak, while the real part rises on the low-frequency side and then falls steeply through at . It can become negative above resonance for sufficiently strong oscillator strength and weak damping. At large frequency, and : both approach the vacuum values. The absorption maximum is close to, but need not be exactly at, for finite damping.
Past exam of the quantum condensed matter course of the University of Cambridge 2017 1 b Solution Created 2026-10-18 Updated 2026-10-20
A self-assembled InAs quantum-dot single-photon source uses small indium arsenide islands inside a larger-gap gallium arsenide host. Strain during epitaxial growth favors islands after a thin wetting layer has formed. Their characteristic diameter is of order – and their height a few nanometres, for example –. Growth conditions determine the areal density: low-density samples suitable for isolating dots can be around –, while ordinary dense layers can be much denser. The particular electrically driven device underlying the supplied image had about . These are characteristic scales, not dimensions deducible from the emission image.[ref]
Quantum confinement in the dot traps both electrons and electron holes in three directions, giving discrete energy levels. In a junction device, injected carriers relax into these levels. Electron-hole recombination then emits a photon, and the dot must be repopulated before emitting again on that same transition. Spatial selection of one dot, spectral selection of one line, and well-separated injection pulses make this a single-photon source. Photon antibunching, rather than low average brightness alone, establishes suppression of simultaneous photons. In particular, collecting both photons of a cascade without selecting a line would not produce exactly one collected photon per excitation.
The lower-current feature is the transition from one confined exciton to the empty dot. The higher-current feature is the first step of the biexciton cascade : it becomes strong when the dot can contain two electron-hole pairs. In the weak-pumping limit the probabilities of one and two pairs scale approximately as and , respectively. Coulomb and confinement energies shift the two transitions relative to one another; is not a photon of twice the energy. In this particular image the photon is about – higher in energy. With , this is a negative biexciton binding energy, since .
For the mass estimate, the original plot places the line at approximately , with graph-reading precision of order . Under the prescribed identification of photon energy with the full lowest exciton excitation energy,The three-dimensional screened Wannier-Mott exciton has the hydrogenic exciton binding energyThereforeReading the line as instead gives ; about – is an appropriate precision. This inference uses the supplied pair-creation energy and a three-dimensional screened hydrogenic model. In a real dot, strain and confinement also alter transition energies, so it is an effective model estimate and does not independently determine either individual carrier mass.
Past exam of the quantum condensed matter course of the University of Cambridge 2017 1 c Solution Created 2026-10-18 Updated 2026-10-20
Specify the spin counting first. Let denote the unpolarized single-spin density of states per atom per energy, and put . At fixed total occupation , the two Hubbard model mean-field energies can be writtenThe common shift can be absorbed into the chemical potential. Lowering the up-spin band by adds carriers, while raising the down-spin band removes the same number. ThusIf is the atom number density, the magnetization is . The Stoner-enhanced magnetic susceptibility in SI volume units is thereforeHere is the noninteracting Pauli paramagnetism result. If the paper's counts both spins, and the same result isA susceptibility per atom omits . Stating the spin and volume conventions avoids an otherwise spurious factor of two or a dimensional mismatch.
The Stoner criterion is , equivalently with spin-summed . To see the instability, transfer electrons per atom from one spin band to the other. The band-filling cost is , whereas the interaction energy changes by . Their sum becomes negative at the threshold. The unpolarized state then ceases to be a local minimum, and nonlinear band filling determines the spontaneous ferromagnetism. The negative continuation of the displayed linear susceptibility beyond the threshold is not a stable paramagnetic response.
Past exam of the quantum condensed matter course of the University of Cambridge 2017 2 a Solution Created 2026-10-18 Updated 2026-10-20
Dielectric screening is the rearrangement of a medium's charges in response to an applied charge. In a metal, mobile electrons accumulate near a positive perturbation and reduce its long-range potential. Thomas-Fermi screening treats the electron gas locally as an equilibrium gas whose density responds to the local electrostatic potential, ignoring gradients of the density on the microscopic wavelength scale.
Take , background permittivity , and electrostatic potential . An electron's potential energy is , so the local kinetic Fermi energy becomes . For a three-dimensional spin-degenerate parabolic band at zero temperature,where is the spin-summed density of states per volume per energy. The induced charge is . Combining it with Poisson equation givesFor a point external charge , spherical symmetry and decay at infinity selectThus the bare potential is cut off exponentially. Fourier transformation makes the same result transparent: , so the static longitudinal dielectric factor is relative to the background. For a free electron band, and .
Local Thomas-Fermi screening and optical/acoustic modes of an illustrative diatomic chain
. Details. The local linear approximation requires a weak perturbation and slowly varying fields on the relevant microscopic scale. It omits nonlocal Friedel oscillations and atom-scale structure; a nonlinear local-density treatment is needed near a sufficiently strong charge. Finite temperature replaces by the appropriate compressibility derivative . The nondegenerate limit gives classical screening rather than the degenerate Thomas-Fermi length. A larger density of states means that a smaller potential can move more carriers, hence stronger screening.
Past exam of the quantum condensed matter course of the University of Cambridge 2017 2 c Solution Created 2026-10-18 Updated 2026-10-20
A normal Fermi liquid has interacting fermions whose low-energy excitations can be followed continuously from those of a Fermi gas, provided no phase transition destroys that correspondence. A Landau quasiparticle is a particle together with the surrounding many-body response. It has the appropriate charge and spin, a renormalized dispersion and a long lifetime close to the Fermi surface. Interactions remain in both the quasiparticle parameters and the interactions between quasiparticles; they have not been discarded.
Near an isotropic Fermi surface,The last relation defines the local isotropic Fermi-liquid effective mass. The Landau quasiparticle energy functional expresses how changing occupations shifts other quasiparticle energies:with normalization of the sum absorbed into . Its angular components give Landau parameters describing collective density and spin response.
The Pauli exclusion principle severely restricts the available final states for low-energy collisions. In an ordinary three-dimensional Fermi liquid with regular interactions,At zero temperature the decay width decreases faster than , making quasiparticles increasingly sharp near the Fermi surface. Their coherent spectral weight is the quasiparticle residue , and the true electron momentum distribution has a discontinuity of height at zero temperature. The rest of the spectral weight is incoherent. The quasiparticle occupation itself still follows a Fermi-Dirac distribution.
The low-temperature electronic heat capacity is linear, , where is the spin-summed quasiparticle density of states. In an isotropic spin-one-half model, the uniform spin susceptibility and compressibility take the formsThus enhanced effective mass and residual interactions can separately change observable responses. The familiar electrical resistivity requires a mechanism relaxing electrical current, such as allowed Umklapp processes; collisions in a perfectly clean Galilean-invariant continuum conserve total momentum and do not alone produce a finite dc resistivity.
Zero sound is a collisionless collective density oscillation sustained by the quasiparticle interaction; ordinary first sound occurs when collisions establish local equilibrium during a cycle. Metals and normal liquid helium-3 supply important examples. The description fails in phases with no sufficiently sharp low-energy quasiparticles, such as generic interacting one-dimensional systems, and must be modified after pairing or another ordering transition.
Past exam of the quantum condensed matter course of the University of Cambridge 2017 3 Solution Created 2026-10-18 Updated 2026-10-20
Band edges and optical transitions. A direct band gap has the conduction minimum and valence maximum at the same crystal momentum. A near-edge photon then connects the two almost vertically on an energy-versus-wavevector plot, because its momentum is small on the Brillouin zone scale. An indirect band gap has the extrema at different momenta, so an additional momentum transfer, commonly supplied by phonon absorption or emission, is required for a near-edge radiative transition. This reduces its probability relative to an allowed direct transition.
Near the zone centre, an isotropic direct-gap model has and downward valence dispersions . The heavy-hole and light-hole bands are the upper branches with large and small positive hole masses: the heavy branch is flatter. In common cubic semiconductors these arise from the manifold, while spin-orbit coupling places the split-off valence band lower by . Its thermally generated hole population is suppressed by approximately relative to upper-valence holes, apart from density-of-states factors. Neglect is justified when ; it is not a universal exclusion of this band at arbitrary temperature.
Original schematic direct and indirect band edges, including heavy, light and split-off hole branches
. Details. For an indirect material such as Si, the conduction minimum need not be at . In applying the carrier-density formulae, must mean the actual minimum of the included conduction valley. The supplied scalar effective masses and densities of states constitute a simplified band-edge model; they do not specify Si's full valley anisotropy or multiplicity.
Carrier populations. Let be the Fermi-Dirac distribution. In the nondegenerate conduction tail, . Set and integrate the given density of states:The integral is . Defining the effective density of states givesThe factor two is already included in the supplied density of states; it must not be added a second time.
A hole is an unoccupied valence state. For sufficiently below , . Substitution of gives in exactly the same wayTheir product eliminates the chemical potential:This is the semiconductor mass-action law at thermal equilibrium. In an intrinsic semiconductor, charge neutrality additionally givesIn a doped semiconductor the product still applies in this nondegenerate equilibrium model, but the two populations need not be equal.
Intrinsic chemical potential. Taking logarithms of yields the intrinsic-semiconductor chemical potentialFor unequal band degeneracies, use the first form with the full . For the supplied mass ratio , the shift from midgap at is approximately , toward the valence edge.
Three temperature regimes. The original plot runs from high temperature on the left to low temperature on the right. At high temperature, thermal excitation across the gap dominates and rises rapidly with temperature. In the middle, donors and acceptors are effectively ionized, the material is extrinsic, and makes the plateau. At low temperature, dopant freeze-out binds increasing numbers of electrons to donor levels, reducing the mobile-electron population as the sample cools. Its activation scale is a donor binding energy, not the full band gap. Compensation and incomplete ionization affect that regime.
Gap estimate from the original figure. On the dashed intrinsic branch, . Hence band-gap extraction from intrinsic carrier activation uses the slope of versus . With and expressed in eV/K, two points giveThe very compressed intrinsic branch is only approximately readable: near and near . These give , rather than a precision determination. Neglecting the thermal prefactor gives about from those same rough points. Thus a gap of order – is justified by this schematic plot; its resolution does not support distinguishing a few hundredths of an electronvolt. The declining freeze-out branch must not be used to infer the full gap.
Room-temperature densities. At , the supplied masses giveIn the fully ionized extrinsic plateau, put . Charge neutrality and the mass-action law implySince , is insensitive to the imprecise gap. The minority density is much more sensitive:Using gives and . Using instead gives and . These are explicitly conditional estimates within the stated mass model. The plot alone cannot fix a precise minority density because the uncertain gap occurs inside an exponential.
Past exam of the quantum condensed matter course of the University of Cambridge 2017 4 Solution Created 2026-10-18 Updated 2026-10-20
Noninteracting spectral line. Treat as a wavevector, so physical crystal momentum is . Write ; an energy zero at the chemical potential can be chosen throughout. The temporal factor of a noninteracting state is . With the Fourier transform convention ,Thus its normalized frequency spectral function isOne should not square the delta distribution as if it were an ordinary finite-time transition amplitude. More precisely, the fermionic retarded Green function is . Its Fourier transform is , whose negative imaginary part divided by is the same delta peak.
Interactions and lifetime. Interactions change the dispersion through the real part of the self-energy and permit decay into other excitations through its imaginary part. In the simplest quasiparticle-pole model, exponential decay of the retarded amplitude givesPerforming the causal integral,The corresponding Lorentzian quasiparticle spectral peak isIts total frequency integral is one. The exponential amplitude lifetime is ; the probability lifetime is . Describing as a scattering rate therefore requires the lifetime convention to be specified. The energy half-width is .
A general interacting electron is more accurately described by near the pole. The coherent peak then integrates to the quasiparticle residue and an incoherent continuum carries the remaining weight. In an energy-unit self-energy convention,Linearizing the real denominator gives and at the pole. The requested unit-weight Lorentzian is the normalized quasiparticle model, not the most general exact interacting spectrum.
Peak position and width. At fixed , put and . Differentiation givesIt is positive for and negative for , so the only maximum is at , with height . Setting to half this height gives . ThereforeIn energy units the maximum is and the half-width is . Frequency dependence of the self-energy would require reconsidering both the shape and peak position.
Fermi gas and Fermi liquid. A noninteracting Fermi gas has a delta-function spectral line at its bare dispersion for every momentum. A normal three-dimensional Fermi liquid has a shifted coherent peak plus incoherent spectral weight; close to the Fermi surface its width scales as . At zero temperature the peak becomes arbitrarily sharp at the Fermi surface, while it broadens farther away. Spectral functions include addition and removal weight; occupied-only photoemission contains an extra Fermi factor.
Photoemission measurement. A photon of known energy ejects an electron. Measure its kinetic energy and emission direction. For binding energy below the Fermi level and the appropriate calibrated work function , conservation of energy givesConservation of momentum parallel to a periodic surface giveswhere is a surface reciprocal-lattice vector. At suitable photon energies the photon momentum can be neglected; at higher energies it must be retained. The surface breaks perpendicular translation symmetry, so the perpendicular crystal momentum generally needs a final-state model. A two-dimensional band can be reconstructed directly from the parallel components.
Within the sudden approximation and electric-dipole approximation, photoemission intensity and spectral function are related byHere is measured relative to the chemical potential. Instrumental resolution convolves the product and inelastic scattering adds background. Thus ARPES maps the occupied electron removal spectral function, weighted by a matrix element; it does not measure the full unoccupied spectrum or an unweighted spectral function automatically. Bright ridges give dispersions, and intrinsic widths give decay information after instrumental effects are removed.
Reading the supplied image. Its bright ridges form a graphene-like cone. The crossing near is the Dirac point, not in general the Fermi level. In the paper's plotted energy coordinates its energy is roughly –. A velocity follows from a branch slope independently of the energy zero:For example, the lower branch moves by about between and . This gives andReading other points changes the estimate by tens of percent. The original exam image has unequal energy increments on nearly equally spaced labelled ticks, so it does not justify a precise fitted velocity. The value is an estimate of the cone slope extrapolated to the Fermi crossing, rather than a measured derivative exactly at a visibly identified Fermi cutoff.
To determine a Fermi energy, first calibrate the Fermi edge, then subtract the chosen reference energy. Neither a Fermi-level marker nor an explicit energy-zero convention is supplied in this crop. If its upper termination near is intended to represent the Fermi cutoff, the conditional graph answer is on that axis, or relative to the Dirac crossing. Identifying the crossing itself as the Fermi energy would incorrectly assume undoped graphene.
The research article cited by the exam identifies this as linearly polarized graphene ARPES and independently states for the substrate-doped sample. That resolves the relative energy when this external calibration is admitted.[ref]
https://hrg.pusan.ac.kr/articles/JPCM_0953-8984_26_33_335501.pdf. Section 3, printed p.2 and figure 1(b): Dirac point below the Fermi energy
The crop alone does not uniquely fix an absolute Fermi energy; the source-supported relative value and the conditional axis reading should be distinguished. Past exam of the quantum condensed matter course of the University of Cambridge 2018 Section A 1 b Solution Created 2026-10-18 Updated 2026-10-20
A positive gate voltage attracts electrons towards the oxide interface of the p-type semiconductor and repels mobile electron holes. The uncovered ionized acceptors form a negatively charged depletion region. Increasing the voltage further creates a thin electron-rich semiconductor inversion layer at the surface. The conduction band and valence band both bend downwards towards the positively biased gate, because an electron's electrostatic energy is .
In an ideal nondegenerate substrate with acceptor density , write and surface potential relative to the neutral bulk. The electron and hole surface densities areThe first change of majority-carrier type occurs at , where . The conventional MOS inversion threshold for appreciable strong inversion isAt threshold the inversion sheet is just developing, while a much thicker depletion region lies between it and the neutral p-type bulk. Inversion does not require the conduction band to cross the Fermi level: the surface can remain nondegenerate.
The metal and semiconductor Fermi levels need not be equal. The ideal oxide blocks particle exchange, so the gate and substrate can maintain different electrochemical potentials. In a biased MOSFET, the gate-to-substrate Fermi-level difference is , when the applied voltage is defined in the electron-reservoir convention. Each region can separately be in internal equilibrium. If an external zero-voltage connection instead equilibrates the reservoirs, their Fermi levels coincide, but different work functions can still cause band bending. Here the chemical potential shown in a band diagram is the electron electrochemical potential; the purely chemical contribution alone is not the equilibrium criterion for charged particles.
Past exam of the quantum condensed matter course of the University of Cambridge 2018 Section B B2 Solution Created 2026-10-18 Updated 2026-10-20
Equilibrium junction. Put the p-type side on the left and n-type side on the right. When they are joined, electrons diffuse from n to p and electron holes diffuse from p to n. This leaves negative ionized acceptors on the p-side and positive ionized donors on the n-side of the depletion region. The resulting built-in electric field points from n to p, opposing further diffusion. At equilibrium there is one constant Fermi level, and drift and diffusion currents cancel for each carrier species.
In the nondegenerate, fully ionized limit, the neutral-region carrier densities areThe conduction band and valence band lie higher on the p-side and bend down towards the n-side. The gap between them stays fixed for a homojunction. If increases towards the n-side, both edges shift by , whileThus rises and falls continuously across the junction; neither mobile population is an exact step function. Their depletion exposes fixed dopant charge density, rather than an absence of every kind of charge. The built-in voltage is
Light emission. Forward bias lowers the barrier and injects minority carriers across the p-n junction. In a light-emitting diode, electron-hole recombination converts some of their energy into photons. A direct band gap permits efficient radiative transitions with nearly conserved crystal momentum; nonradiative channels compete. Near-edge emission has and . Material composition and confinement select the emission colour. Reverse-bias saturation is not the ordinary LED operating mode.
Reverse current. Take and to mean reverse voltage and reverse current magnitudes. The Shockley diode equation in this convention isThe bias-independent term is the supply of thermally excited minority carriers from the neutral regions, swept across the junction by its electric field. The opposing injection current is reduced by the extra barrier energy and is . Their equality gives zero net current at zero bias; for , the reverse current approaches until leakage or breakdown invalidates this ideal law. The collecting field need not create the minority carriers; their thermal supply limits the diffusion-dominated current.
For an ideal long junction of area , steady diffusion with recombination gives the diode minority-carrier diffusion currentIt depends on doping, geometry, carrier diffusion coefficients and lifetimes, and especially the intrinsic carrier concentration. Depletion-region generation current and surface leakage can add nonideal contributions to the measured reverse current.
Band-gap estimate from the data. Read a nearly flat region well above the small-bias knee and below the high-bias upturn, rather than estimating in the breakdown region. For a diffusion-dominated junction with nearly temperature-independent gap and effective masses,so , where includes transport and doping factors. Extracting a semiconductor band gap from diode saturation current amounts to measuring the slope of against : it is . If the prefactor is taken approximately constant over a short interval,Approximate readings from the original PDF plateaus areUsing the two warmer curves and givesKeeping the factor but taking the residual transport factor constant changes this estimate to approximately . The justified graphical estimate is thereforeThe colder curve is a genuine limitation of the supplied data: the to pair gives only about with a constant prefactor, and the endpoint pair gives about . Thus all three cannot support one precise diffusion-only activation slope. A depletion-region generation current, approximately proportional to rather than , can have a roughly half-gap activation energy; other leakage and temperature-dependent transport can also alter the slope. The PDF alone does not identify their relative contributions. A reliable precision gap measurement would use more temperatures and verify the transport regime instead of forcing one fit through these three readings.
Past exam of the quantum condensed matter course of the University of Cambridge 2019 Section A 2 Solution Created 2026-10-18 Updated 2026-10-20
Use Thomas-Fermi screening, treating a homogeneous three-dimensional conductor in static linear response. For a positive test charge the screened electric potential and bare Coulomb potential areHere is the background permittivity before the mobile carriers screen; it is in the simplest free-electron model. Both curves have the same leading divergence near the origin, while the screened curve lies below the bare one and decays much faster.
A positive potential attracts electrons. If is their total spin-summed density of states per volume and energy, and . Inserting this charge into Poisson equation gives the Thomas-Fermi screening lengthA larger density of states lets the conductor rearrange more charge for the same potential change and shortens the screening length. For a parabolic free electron model, , hence .
The exponential form is the intended local screening model. A microscopic zero-temperature metal also has Friedel oscillations, so the exponential alone is not an exact description at every length scale.
Past exam of the quantum condensed matter course of the University of Cambridge 2021 Section A 1 Solution Created 2026-10-18 Updated 2026-10-20
For state counting in a Bloch band, take a primitive cubic lattice of spacing and impose periodic boundary conditions on lengths . The allowed wavevectors are . The first Brillouin zone has side , so it contains distinct values in each direction and hence wavevectors. Each orbital-derived energy band has one state per wavevector per spin orientation. ThereforeThe phrase “per atom” attached to in the PDF is a counting error: is the total, not the per-atom count.
By the Pauli exclusion principle, a monovalent crystal supplies valence electrons and half-fills a spin-degenerate band; its Fermi level lies within allowed states, giving a metal in the independent-electron picture. Two electrons per atom can fill one band. If a band gap separates it from all empty bands, the crystal is a band insulator. An even valence count only permits insulation: overlapping bands can still produce a metal. Conversely, electron interactions can produce a Mott insulator, and symmetry breaking can permit insulation outside this simple spin-degenerate electronic band structure criterion. The relevant count in a crystal with a basis is per primitive unit cell.
Past exam of the quantum condensed matter course of the University of Cambridge 2021 Section A 2 Solution Created 2026-10-18 Updated 2026-10-20
In a simple metal, conduction electrons can move collectively in response to an incident electromagnetic wave. The Drude model gives, with time dependence ,In the low-loss range , the relative permittivity is approximately . The wavevector inside is predominantly imaginary, so the field is evanescent and penetrates only a short distance. Surface currents reradiate the field; little energy enters a good conductor. The normal-incidence Fresnel equations giveMany ordinary metals have their plasma frequency in the ultraviolet, placing visible light below this reflection edge. For the free-carrier contribution permits propagation; at , and . The electrons' inertial response becomes too small to screen the rapidly oscillating field.
Ultraviolet transparency is a simple-metal model prediction, not a universal property of real metals. Electronic transitions between bands and bound-electron absorption can remain strong, shift the plasma edge and prevent transparency; transmission also depends on thickness and attenuation. The robust explanation is the change from a reflective negative-permittivity range to a possible propagating range above the plasma edge.












