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A superposition of two distinct energy eigenstates gives the expectation value of a time-independent observable an interference term proportional to $e^{-i(E_2-E_1)t/\hslash }$. The displayed beat period applies when that term has nonzero amplitude. A vanishing off-diagonal matrix element, zero state coefficient or equal energies instead gives a constant expectation value.

Let $H,V$ be orthogonal linear polarizations, and prepare the Bell state $|{\Phi }^{+}⟩=(|HH⟩+|VV⟩)/\sqrt{2}$. The $+1$ analyzer vector is $|a⟩=\cos a|H⟩+\sin a|V⟩$; its orthogonal companion has outcome $-1$. Direct inner products with the Bell state give $P_{++}=P_{--}={\cos }^2(a-b)/2$ and $P_{+-}=P_{-+}={\sin }^2(a-b)/2$. Thus the expectation value of the outcome product is $E(a,b)=\cos 2(a-b)$. These are physical polarizer angles; their corresponding Bloch sphere angles are doubled.

For a stipulated isotropic admixture, use the density matrixThe maximally mixed state contributes zero correlation, so $P_{st}(a,b)=[1+stv\cos 2(a-b)]/4$ for $s,t\in \{-1,1\}$. Each local marginal is $1/2$, independently of the other setting, illustrating quantum no-signalling. In this model $v$ is the interferometric visibility of the coincidence fringe; other noise models need not have one common visibility for every basis.

Choose $a_0=0^{\circ }$, $a_1=45^{\circ }$, $b_0=22.5^{\circ }$ and $b_1=-22.5^{\circ }$. The four correlations in the displayed CHSH inequality are $v/\sqrt{2},v/\sqrt{2},v/\sqrt{2},-v/\sqrt{2}$. Consequently $S=2\sqrt{2}v$, exceeding the local bound exactly when $v>1/\sqrt{2}$. Perfect correlation at a single common setting would not yield this comparison between incompatible quantum measurements.

To connect probabilities with expected counts, stipulate $M$ emitted pairs per setting pair and independent detection efficiencies ${\eta }_A,{\eta }_B$, independent also of settings, outcomes and hidden variables. The expected joint counts are $n_{st}=M{\eta }_A{\eta }_B{P}_{st}$. Their normalized correlation isFor original teaching inputs $M=1000$, ${\eta }_A=0.8$, ${\eta }_B=0.75$ and $v=0.8$, the $(a_0,b_0)$ expected counts are $n_{++}=n_{--}\simeq 234.85$ and $n_{+-}=n_{-+}\simeq 65.15$. They total $600$ and give $E_{\det }\simeq 0.56569$, hence $S\simeq 2.26274$. Fractional expected counts are not measured data. Efficiency cancels here because the loss model was specified to be independent; this algebra supplies no justification for discarding failures in an arbitrary Bell test with a detection loophole.

For a positive self-adjoint Hamiltonian operator, finite energy means that a normalized state lies in $D(H^{1/2})$, its form domain, and has expectation value $q_H(\psi )$. This domain can be larger than $D(H)$. With a complete orthonormal basis of energy eigenstates, $\psi ={\sum }_n{c}_n{e}_n$ and $H{e}_n=E_n{e}_n$ give $q_H(\psi )={\sum }_n{E}_n|c_n{|}^2$ by applying $H^{1/2}$ and taking its squared norm. Membership in $D(H)$ instead requires ${\sum }_n{E}_n^2|c_n{|}^2<\infty$. For a Dirichlet free-particle Hamiltonian operator on an interval, the energy form is ${\hslash }^2\int |{\psi }^{\prime }{|}^2/(2m)$ on functions with square-integrable weak derivative and zero endpoint values.

For an admissible quantum state with zero position and momentum means, positivity of the squared norm $\Vert (p-isx)\psi {\Vert }^2$ for every real $s$ givesThe discriminant is nonpositive, hence $\Delta x\Delta p\ge \hslash /2$. Subtracting the expectation values from the position operator and momentum operator extends this outline to nonzero means.

Quantum state tomography estimates a density operator from measurement frequencies on many independently and identically prepared systems. One fixed projective measurement reveals only its basis populations, so further measurement settings are generally needed. For a qubit, writeThe three Pauli matrices thus turn measured expectation values into the Bloch vector. This reconstruction uses the Bloch ball representation of arbitrary qubit density operators. ^[ref].

Divide the prepared ensemble into groups measured in the $X$, $Y$ and $Z$ bases. For example, positive-outcome frequencies $0.8,0.5,0.9$ give the estimate $\mathbf{r}=(0.6,0,0.8)$ andHere $|\mathbf{r}|=1$, so the reconstructed state is the pure state $(3|0⟩+|1⟩)/\sqrt{10}$. Its $Z$ frequencies alone also fit the diagonal mixed state with populations $0.9,0.1$; the $X$ data distinguish them. For the angular pure state in measurement in quantum mechanics, $r_x=\sin \theta \cos \varphi$, $r_y=\sin \theta \sin \varphi$ and $r_z=\cos \theta$, so $Y$ resolves the sign of the phase that $X$ alone cannot.

Finite samples introduce statistical uncertainty: with $N$ independent binary trials in one basis, the frequency has variance $p(1-p)/N$. At $p=1/2$ and $N=100$, its standard deviation is $0.05$. Fluctuations can place a naive Bloch vector estimate outside the Bloch ball; a physical reconstruction must enforce positivity of the density operator. Repeated measurements on one unprepared specimen sample its changing conditional state, rather than independent copies of its original state. Multiple bases are needed in this projective protocol; a single fixed informationally complete POVM, such as the tetrahedral qubit POVM, is an alternative. It still requires an ensemble of trials.

The quantum variational principle estimates the lowest energy by choosing a trial wavefunction and computing its expectation value, without solving the Schrödinger equation exactly. Minimizing over a manageable family of trial wavefunctions gives an upper bound; enlarging that family can improve the estimate.

Let $H$ be a self-adjoint operator bounded below, and put $E_{\ast }=\inf \sigma (H)$. For $\Vert \psi \Vert =1$ in its operator domain $D(H)$,Trial states may also lie in the form domain $Q(H)=D((H-bI{)}^{1/2})$, where $b\le E_{\ast }$. Then use the quadratic form of a positive quantum Hamiltonian shifted by $b$:This extends the expectation value beyond $D(H)$ without requiring $H\psi$ to exist. Equality for a normalized state holds exactly in the energy eigenspace at $E_{\ast }$, if that eigenvalue exists. ^[ref].

A short proof makes the direction of the bound memorable. If $H$ has a complete orthonormal basis of energy eigenstates ${\varphi }_n$, writeThe expectation value is a weighted average of allowed energies:Equality requires every occupied energy eigenstate to have energy $E_{\ast }$. ^[ref]. With continuous spectrum, the spectral theorem replaces the sum by an integral against the scalar spectral measure; the same nonnegative-difference argument works.

For an unnormalized trial wavefunction, divide by its squared norm: $R_H[\psi ]=q_H[\psi ]/\Vert \psi {\Vert }^2$ is the form version of the Rayleigh quotient. The quantum variational principle supplies an upper bound on $E_{\ast }$; it supplies neither a lower bound on $E_{\ast }$ nor, by itself, a guarantee that a bound state exists.

To see the method at work, choose the real Gaussian wave packetThe Gaussian integral gives wavefunction normalization and the two useful position averages:Thus its position probability density is a normal distribution with standard deviation $1/\sqrt{2a}$: large $a$ means narrow confinement. In units $\hslash =m=1$, integration by parts and ${\psi }_a^{\prime }=-ax{\psi }_a$ give the kinetic energyThese smooth, rapidly decaying trial wavefunctions belong to the operator domains of both polynomial Quantum Hamiltonians below. Narrowing the Gaussian wave packet increases its kinetic energy; widening it increases the potential energy in either confining potential.

For the quantum harmonic oscillator, take $\hslash =m=\omega =1$:The trial values at $a=1/2,1,2$ are respectively $0.625,0.5,0.625$. The derivative $E_{\mathrm{ho}}^{\prime }(a)=(1-a^{-2})/4$ changes sign at $a=1$, where kinetic energy and potential energy are both $1/4$. Here the trial family contains an exact ground state:The zero-point energy remains positive even at the best width. For comparison, removing the potential leaves $E(a)=a/4\to 0$ as $a\to 0$: the free Quantum Hamiltonian on the line has spectral bottom zero but no normalizable zero-energy energy eigenstate. A sequence of ever broader trial wavefunctions need not approach an actual bound state.

For a pure quartic oscillator, keep $\hslash =m=1$ and set the quartic coefficient to one:The trial values at $a=1,2,3$ are respectively $1,0.6875,0.833333\dots$. Setting the derivative to zero givesThe sign of this derivative changes from negative to positive at the optimum, giving the smallest energy within this Gaussian wave packet family:At this width, $⟨T⟩\approx 0.454280$ and $⟨V⟩\approx 0.227140$, so $2⟨T⟩=4⟨V⟩$, as expected from the power-law quantum virial theorem for a scale-optimized trial wavefunction. The number $0.681420$ is an upper estimate of the ground-state energy, not an asserted exact energy eigenvalue. Indeed,depends on $x$ for every $a>0$, so no member of this trial family is an energy eigenstate. Nevertheless, a single width parameter already turns a difficult Schrödinger equation into a useful, explicit energy estimate.

At the self-dual circle, left and right dimension-one currents generate $SU(2{)}_L\times SU(2{)}_R$. The compact-coordinate vertex $\partial Y_L\bar{\partial }{Y}_R$ is a Cartan–Cartan component of a scalar field in the $(3,3)$ representation. Its expectation value changes the circle radius and leaves $U(1{)}_L\times U(1{)}_R$ unbroken. The four extra charged vectors acquire the displayed mass, and four scalar field polarizations become their longitudinal modes. This realizes the Higgs mechanism geometrically. In a bosonic string the ever-present tachyon and additional scalar field instabilities prevent interpreting the whole family as a stable vacuum.

The Robertson uncertainty principle bounds the product of the standard deviations of two observables in the same quantum state. For a normalized pure state $|\psi ⟩$ and self-adjoint operators $A,B$, write their expectation values and variances asand similarly for $B$, where $I$ is the identity operator. The quantum uncertainties $\Delta A,\Delta B$ then obeyHere $[A,B]$ is the commutator, and every expectation value is taken in the same $|\psi ⟩$. These standard deviations describe the outcome spreads when $A$ and $B$ are measured on separate ensembles prepared in that same quantum state. They are not instrument errors or the change caused by a preceding measurement in quantum mechanics. The definition and bound are developed in Barton Zwiebach, Uncertainty Principle and Compatible Observables, 2013, §§1–2.

For unbounded self-adjoint operators, the operator domains matter. Assume $\psi \in D(A)\cap D(B)$, so that both second moments are finite; $⟨A^2⟩$ here means the second moment of the measured probability distribution, equal to $\Vert A\psi {\Vert }^2$, even if $A^2\psi$ is undefined. To use the displayed operator commutator, also assume $\psi \in D(AB)\cap D(BA)$. Without these product-domain assumptions, the always meaningful version on $D(A)\cap D(B)$ uses $|\mathrm{Im}⟨A\psi |B\psi ⟩|$ as its right-hand side. These qualifications prevent a formal commutator identity from being applied to an inadmissible quantum state.

The brief proof is Cauchy-Schwarz inequality applied to $u=(A-⟨A⟩I)\psi$ and $v=(B-⟨B⟩I)\psi$:The final equality uses self-adjointness and the product-domain assumptions. Thus a geometric statement about inner products becomes a constraint on experimental spreads. For nonzero $\Delta A,\Delta B$, equality requires $u,v$ to be proportional with a purely imaginary proportionality factor; the equality case of the Heisenberg uncertainty relation turns this condition into a Gaussian wave packet.

The bound is useful because computing a single commutator and its expectation value can constrain two entire outcome distributions. Its right-hand side depends on the quantum state: the spin uncertainty state dependence example gives both a positive saturated bound and a zero bound for the same noncommuting observables. Robertson's paper, titled "The Uncertainty Principle", appeared on 1 July 1929 in Physical Review, volume 34, starting at page 163. ^[ref].

The laboratory expectation value of the axial electric quadrupole moment in the stretched nuclear quantum state $|I,M=I⟩$; $M\hslash$ is the laboratory $z$ component of total angular momentum. It differs from the intrinsic nuclear quadrupole moment $Q_0$. In an axial nuclear rotational band with $K=0$, projection onto definite angular momentum givesHere $K\hslash$ denotes the component of total angular momentum along the intrinsic symmetry axis. Consequently a positive $Q_0$ for a prolate spheroid corresponds to a negative $Q_s(2)$ in this model. The sign of the laboratory moment alone must be interpreted together with the band assignment.

The $I=0$ result has a short symmetry explanation. A spin-zero state has no preferred spatial direction. Its second charge moments satisfy $⟨x^2⟩=⟨y^2⟩=⟨z^2⟩$, so $⟨2z^2-x^2-y^2⟩=0$. Equivalently, averaging an intrinsic axis uniformly over directions gives $⟨P_2(\cos \theta )⟩=0$, where $P_2(u)=(3u^2-1)/2$ is a Legendre polynomial. This is a statement about a quantum expectation value, not a classical picture of a spinning object sweeping through orientations.

For an independent check of the $I=2$ sign, the $K=0$, $M=2$ rotor orientation probability is proportional to $|Y_2^2{|}^2\propto {\sin }^4\theta$, using a spherical harmonic. With $u=\cos \theta$,A zero static laboratory moment does not make every quadrupole observable zero. With electric multipole operator ${\mathcal{M}}_{2\mu }=\int {\rho }_{\mathrm{ch}}{r}^2{Y}_2^{\mu }{d}^{3}r$, define the reduced transition strength using a reduced matrix element:In the axial $K=0$ rotor, angular projection gives $B(E2;0^{+}\to 2^{+})=5Q_0^2/(16\pi )$ and $B(E2;2^{+}\to 0^{+})=Q_0^2/(16\pi )$. The factor of five is the ratio of the numbers of magnetic substates. Thus an electric quadrupole transition can reveal collective deformation even when $Q_s(0)=0$. These strengths determine $|Q_0|$ within the model; their squares alone cannot distinguish its sign.

For spin one-half, choose the normalized spin eigenstates $|+z⟩,|-z⟩$ with $S_z|\pm z⟩=\pm (\hslash /2)|\pm z⟩$. The spin one-half along an axis pure state in the $xz$ plane isIts norm is one because the two eigenstates are orthogonal and ${\cos }^2(\theta /2)+{\sin }^2(\theta /2)=1$. Applying the Born rule to a $z$ projective measurement givesConsequently the expectation value, second moment, and variance areAt $\theta =\pi /3$, the outcome probabilities are $3/4$ and $1/4$, the mean is $\hslash /4$, and the variance is $3{\hslash }^2/16$. Every individual outcome remains $\pm \hslash /2$. At $\theta =\pi /2$, the mean is zero and the variance is maximal, ${\hslash }^2/4$. At either pole, one outcome has probability one and the variance vanishes.

The diagonal mixed state ${\rho }_{\mathrm{diag}}=p_{+}|+z⟩⟨+z|+p_{-}|-z⟩⟨-z|$ has the same $S_z$ probabilities, expectation value, and variance as $|{\psi }_{\theta }⟩$. It is nevertheless a different quantum state for $0<\theta <\pi$: the displayed pure state has $⟨S_x⟩=\hslash \sin \theta /2$, while ${\rho }_{\mathrm{diag}}$ has $⟨S_x⟩=0$. A single component's mean does not reveal all relative quantum phases or establish purity of a density operator.

For a central-potential Hamiltonian operator with the spin-orbit interaction $H_{\mathrm{so}}=[r^{-1}{V}^{\prime }(r)/(2m^2{c}^2)]\mathbf{L}\cdot \mathbf{S}$, use $\mathbf{J}=\mathbf{L}+\mathbf{S}$ andA coupled angular momentum eigenstate makes this angular factor a number. The radial operator commutes with all angular factors, giving the energy shift in the title. It is independent of the magnetic projection $m_j$, so a fixed-$j$ multiplet retains its $2j+1$ degeneracy.

For spin one-half, the angular bracket is $l$ when $j=l+1/2$ and $-(l+1)$ when $j=l-1/2$. Only the former exists at $l=0$, where it is zero. For the Coulomb potential energy, $r^{-1}{V}^{\prime }(r)=e^2/(4\pi {ϵ}_0{r}^3)$; the radial normalization convention must be respected when computing its expectation value.

For a qubit, use the dimensionless Pauli matrices as observables $A={\sigma }_x$, $B={\sigma }_z$. Their Pauli matrix multiplication law givesThese observables have eigenvalues $\pm 1$; the physical spin components are $S_j=(\hslash /2){\sigma }_j$, where $\hslash$ is the reduced Planck constant, so their standard deviations acquire a factor $\hslash /2$.

In the computational basis, prepare $|+y⟩=(|0⟩+i|1⟩)/\sqrt{2}$, an eigenstate of ${\sigma }_y$ with eigenvalue $+1$. Direct multiplication givesBoth Pauli measurements return $+1$ and $-1$ with equal probabilities, and the Robertson uncertainty principle is saturated: $1\cdot 1=1$.

Instead prepare $|+z⟩=|0⟩$. Now the expectation values are $⟨{\sigma }_x⟩=⟨{\sigma }_y⟩=0$, $⟨{\sigma }_z⟩=1$, so $\Delta {\sigma }_x=1$, $\Delta {\sigma }_z=0$. The Pauli measurement of ${\sigma }_z$ is certain, and both sides of the bound vanish. The commutator is still nonzero as an operator: noncommuting observables do not guarantee a positive lower bound independent of the quantum state. This example is useful for distinguishing the algebra of the observables from the expectation values in a particular preparation.

A Stern-Gerlach experiment separates atomic beams according to a component of their magnetic moment in a nonuniform magnetic field. For an appropriate two-state spin system, calibrated outputs distinguish the two spin eigenvalues; Stern-Gerlach expectation estimation explains how repeated fresh preparations turn channel counts into an expectation value.

The decisive contrast is between two separated components of an atomic beam and the continuous spread predicted for randomly oriented classical magnetic moments. Neither component need be an infinitely narrow spot: velocity spread and the resolving power of the scientific instrument affect the spatial image. The apparatus converts an internal magnetic moment into a displacement large enough to inspect, connecting angular momentum eigenstates to macroscopic evidence.

The canonical ensemble assigns the density matrix $e^{-\beta H}/Z$, with $Z=\mathrm{Tr}{e}^{-\beta H}$. Its expectation value of an observable is the displayed normalized trace. In imaginary time, cyclicity of this trace gives periodic bosonic correlation functions; it does not make the imaginary-time Heisenberg operator itself periodic.

For a two-species uniform boson number state, set $S_i^{+}=a_i^{†}{b}_i$. A single spin ladder operator changes the species occupation numbers, so its expectation value vanishes. At distinct sites, $⟨S_i^{+}{S}_j^{-}⟩=n_A{n}_B/L^2$, proving the displayed transverse two-point correlation function. For $n_A/L,n_B/L$ tending to nonzero constants, this correlation function has a nonzero large-distance limit despite the global U(1) symmetry. This diagnoses long-range order in the auxiliary state; its interpretation as a state of fixed physical spins still requires the Schwinger boson constraint.

For normalized pure states $|u⟩,|v⟩$, a two-member quantum state ensemble gives the maximally mixed state of a qubit exactly when its members are orthogonal and equally probable. To prove necessity, take expectation values of its density matrix in the two members: $1/2=p+(1-p)|⟨u|v⟩{|}^2\ge p$ and $1/2=1-p+p|⟨u|v⟩{|}^2\ge 1-p$. Hence $p=1/2$ and the overlap vanishes. Sufficiency is the resolution of the identity in an orthonormal basis.

rounding an unclipped voltage to equally spaced levels of separation $\Delta$ leaves error in $[-\Delta /2,\Delta /2]$. If the fractional position within a conversion interval is uniformly distributed, direct integration gives zero mean and expectation value $⟨{ϵ}^2⟩={\Delta }^2/12$. This is a statistical model for the error, not a claim that the converter adds independent white noise for every possible input.

The variational method estimates the lowest energy of a Quantum Hamiltonian by choosing a trial wavefunction, evaluating its energy, and optimizing the trial parameters. It uses the quantum variational principle, the Rayleigh-Ritz variational principle expressed for quantum states. Let $H$ be a self-adjoint operator bounded below, and define $E_0=\inf \sigma (H)$, the bottom of its spectrum. Every normalized admissible trial quantum state satisfiesWhen $E_0$ is an energy eigenvalue, it is the ground-state energy; equality holds precisely for a quantum state in the ground-state subspace. Otherwise the bottom of the spectrum need not be attained by any normalizable wavefunction.

Admissible means finite form energy. Choose a real $b\le E_0$ and use the shifted quadratic form of a positive quantum Hamiltonian:The form domain $Q(H)$ is independent of this choice of $b$ and can be larger than the operator domain $D(H)$. For $\psi \in D(H)$, $E_{\psi }=⟨\psi ,H\psi ⟩$ is the usual expectation value; for nonzero unnormalized trials, divide $q_H[\psi ]$ by $\Vert \psi {\Vert }^2$ to get the form version of the Rayleigh quotient. See the quantum variational principle for the general domain justification.

Thus each trial energy is an upper bound on $E_0$, and minimizing within a trial family improves that upper bound. It is not a lower bound on $E_0$. The Gaussian variational energy for the harmonic oscillator reaches $E_0=1/2$ because its family contains an exact ground state. The exact variational solution in a two-level system makes the equality condition visible as vanishing excited-state probability amplitude.

The method is useful when solving the Schrödinger equation exactly is difficult but integrals of a trial wavefunction are tractable. Enlarging a trial family cannot increase its optimal energy, although an optimum need not be attained. The beauty is that even an imperfect trial gives a rigorous bound, provided its form energy is computed exactly: numerical integration errors require separate control. The Gaussian variational estimate for a solvable sextic potential provides an existing example beyond a quantum harmonic oscillator.

A short proof explains the direction. With a complete orthonormal eigenbasis of energy eigenstates, write $\psi ={\sum }_n{c}_n{\varphi }_n$, where $H{\varphi }_n=E_n{\varphi }_n$ and ${\sum }_n|c_n{|}^2=1$. ThenThis is a weighted mean of nonnegative energy differences; equality requires every occupied energy eigenstate to have energy $E_0$. ^[ref]. For continuous spectrum, the spectral theorem replaces the sum by an integral against the scalar spectral measure of $\psi$, with the same nonnegative integrand. This proves the bound without assuming an orthonormal eigenbasis exists.

The historical setting predates quantum mechanics: Rayleigh's The Theory of Sound, volume I, appeared in 1877, and Ritz's paper on solving variational problems of mathematical physics appeared in volume 135 of Crelle's journal, catalogued by its publisher as 1909, pp. 1–61. These are original works associated with the Rayleigh-Ritz method; the dates here identify the publications rather than assert priority. ^[ref]; ^[ref].