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A lowered Maxwellian velocity distribution subtracts the value of a Maxwell-Boltzmann velocity distribution at the escape velocity and sets the result to zero beyond escape. This gives a nonnegative phase-space distribution function vanishing continuously at the boundary. If $A=n_0/(2\pi {\sigma }^2{)}^{3/2}$ and $x_e=v_e/(\sqrt{2}\sigma )$, its actual number density is $n=n_0[\mathrm{erf}{x}_e-2x_e{e}^{-x_e^2}/\sqrt{\pi }-4x_e^3{e}^{-x_e^2}/(3\sqrt{\pi })]$. Thus $n_0$ is a normalization parameter, not generally the integrated density. Integrating only speeds below $V<v_e$ gives the same bracket with the first two terms at $X=V/(\sqrt{2}\sigma )$ and the last term $-4X^3{e}^{-x_e^2}/(3\sqrt{\pi })$.

The Lyman-alpha forest is the multitude of foreground Lyman-alpha absorption features in a distant quasar's spectrum, at wavelengths shorter than its own redshifted Lyman-alpha emission. The quasar supplies a bright background; intervening neutral hydrogen atoms remove photons near their local Lyman-alpha line resonance. Many dips can therefore come from one atomic transition encountered at different redshifts, rather than from many different chemical elements. Some features are instead transitions of other ions, so a dip alone does not identify Lyman-alpha absorption. This makes faint foreground gas detectable through the light it removes, even when its own emission would be difficult to see. ^[ref].

Ignoring peculiar velocity for the moment, an absorber at cosmological redshift $z_a$ puts its Lyman-alpha line atThe rest wavelength is in the ultraviolet; at $z_a=2$ it appears at $3647.01\text{A˚}$ in the optical spectrum. In a toy sightline to a quasar at $z_Q=3$, absorbers at $z_a=2,2.35,2.7$ appear at $3647.01,4072.4945,4497.979\text{A˚}$, all shortward of the quasar's Lyman-alpha emission position $4862.68\text{A˚}$. The absorbing atoms see the selected photons at their own resonance; the observed dip's redshift belongs to the foreground gas. Peculiar velocity adds a Doppler shift, so the inferred $z_a$ is not a pure distance coordinate. The rest wavelength and resonance interpretation are given in Rauch (1998), section 1.

The diagram uses invented optical depths and 26 Doppler cores; three selected foreground regions are marked. Their drawn positions and sizes are schematic. The dashed comparison imposes a uniform optical depth $\tau =2$, giving transmission $e^{-2}\simeq 0.135$ throughout the chosen foreground band. It is an idealized smooth-absorption model, not a measured spectrum or a prediction of the actual intergalactic medium.

The smooth comparison explains the Gunn-Peterson effect: neutral hydrogen distributed throughout an expanding intergalactic medium can absorb continuously over a wavelength interval, because different parts of the path resonate with different observed wavelengths. The resolved Lyman-alpha forest instead has strong transmission fluctuations and distinguishable absorption lines. These need not represent isolated compact clouds: diffuse sheets and filaments in the cosmic web can generate peaks in optical depth along one line of sight. A continuously varying gas distribution can look like a collection of lines. ^[ref]. ^[ref].

An early observation makes the identification concrete. Lynds's 1971 paper analyzed six spectrograms of the quasar 4C 05.34, with emission redshift $2.877$, taken in spring 1970 using an image-tube spectrograph on Kitt Peak's 84-inch telescope. Five covered $3200$–$7500\text{A˚}$ with approximately $10\text{A˚}$ resolution; the most informative covered about $3500$–$6000\text{A˚}$ at $5\text{A˚}$ resolution. Its reproduced spectrogram shows the strong Lyman-alpha emission flanked mostly on the short-wavelength side by numerous absorption lines. Lynds tabulated their wavelengths and estimated strengths, identified five absorption redshift systems, and proposed that many remaining unidentified lines were the same Lyman-alpha line at additional redshifts. He explicitly warned about blending, an incomplete census of weak lines, and wavelength errors around $0.5$–$1\text{A˚}$. The result established a striking spectral pattern; the paper's proposed interpretation did not measure a separate physical cloud for every dip. ^[ref].

A contrasting observation demonstrates smooth, very strong absorption. Becker and collaborators (2001) used the Echelle Spectrograph and Imager on Keck II to observe the quasar SDSSp J103027.10+052455.0 at $z_Q=6.28$. Sky lines gave an instrumental full width at half maximum of about $1.8\text{A˚}$ near $8500\text{A˚}$, or spectral resolving power $R\simeq 4700$. After sky subtraction and flux calibration, the mean continuum-normalized transmission over $8450$–$8710\text{A˚}$ was $0.0038\pm 0.0026$, consistent with zero; this corresponds to absorption redshifts approximately $5.95$–$6.16$. They identified a Gunn-Peterson trough. Crucially, resonant Lyman-alpha absorption is so sensitive that even a small neutral fraction can make transmission undetectable: the trough alone does not establish a mostly neutral intergalactic medium or uniquely date reionization. ^[ref].

What a spectrum constrains is a radiative transfer problem. For an ideal foreground screen with negligible emission into the observed beam, the intrinsic continuum-normalized transmission isHere $F$ is spectral radiative flux, $F_{\mathrm{cont}}$ is its unabsorbed continuum, $\tau$ is optical depth, $n_{\mathrm{HI}}$ is neutral hydrogen number density, and $N_{\mathrm{HI}}$ is neutral hydrogen column density along proper path length $\ell$. A Voigt profile model constrains redshift, column density and a velocity width together. A nearly black line has lost much of its sensitivity to further increases in optical depth; blending and an uncertain continuum can also admit different fitted components. Finite spectral resolving power and noise limit which widths and weak features can be measured. ^[ref]. ^[ref].

For a purely thermal Doppler core, use the velocity convention $\tau (v)\propto \exp [-(v-v_0{)}^2/b^2]$. The Maxwell-Boltzmann velocity distribution then giveswhere $k_B$ is the Boltzmann constant, $T$ is temperature and $m_{\mathrm{H}}$ is a hydrogen atom's mass. This $b$ is $\sqrt{2}$ times the Gaussian distribution's standard deviation. Higher temperature spreads the same column density over more velocities. An instrument also broadens a line: locally, for a nearly flat continuum, the recorded transmission is approximately the convolution of $\mathcal{T}$ with the normalized instrumental response, not the exponential of a convolved optical depth. A Gaussian response with full width at half maximum $c/R$ has standard deviation $c/[R\sqrt{8\log 2}]$, where $c$ is the speed of light and $R$ the spectral resolving power.

The upper model fixes the integral $\int \tau (v)dv$, hence the neutral hydrogen column density for this transition, while changing temperature. A cooler line blurred by an instrument resembles a warmer intrinsic line. The lower model has two equal Doppler cores separated by $24\mathrm{km}{\mathrm{s}}^{-1}$: reducing spectral resolving power merges them into one apparent feature. Both panels use invented profiles, Gaussian instrumental responses, and no noise or damping wings. They illustrate an inverse problem, rather than measurements of temperature or a universal relation between a dip and a cloud.

Better observations provide the inputs to that inverse problem. Kim, Cristiani and D'Odorico (2001) analyzed three quasars with the VLT's UVES spectrograph. For HE2217–2818, Table 1 records $z_Q=2.413$ and $16200\mathrm{s}$ of exposure in the $3050$–$3860\text{A˚}$ setup in October 1999. Isolated thorium-argon lamp lines measured $R\simeq 45000$; the data were resampled into $0.05\text{A˚}$ bins, with signal-to-noise ratios about $45$–$50$ per pixel over $3550$–$4050\text{A˚}$. They fitted a local polynomial continuum, fitted Voigt profiles, and compared statistics of the transmitted flux. Their analysis excluded the region near the quasar to avoid the quasar proximity effect and used the interval between its Lyman-beta and Lyman-alpha emission to reduce confusion with other Lyman-series absorption. Features below $N_{\mathrm{HI}}=10^{12.5}\mathrm{c}{\mathrm{m}}^{-2}$ became confused with noise, setting their adopted lower column density limit. Figure 1 shows the measured spectrum, fitted profiles and residuals. This was a calibrated absorption measurement, with explicit selection limits. ^[ref].

Even after instrumental correction, a width need not be purely thermal Doppler broadening. Hubble flow across extended gas, peculiar velocity structure and unresolved blends can contribute. If an isolated line's intrinsic width obeys $b^2=b_{\mathrm{th}}^2+b_{\mathrm{nt}}^2$ with an independent Gaussian nonthermal contribution $b_{\mathrm{nt}}^2\ge 0$, then $T\le m_{\mathrm{H}}{b}^2/(2k_B)$; $b=25\mathrm{km}{\mathrm{s}}^{-1}$ gives a computed upper bound about $3.79\times 10^4\mathrm{K}$. A complex blend need not satisfy this single-component model. Noise can also bias the fitted widths of weak lines. This is why the thermal cutoff of Lyman-alpha line widths, calibrated against gas models, is more informative than assigning a temperature to every dip. ^[ref].

Finally, neutral hydrogen column density is not total gas mass density. In a pure hydrogen approximation, with gas optically thin to ionizing radiation and nearly fully ionized in photoionization equilibrium, the Lyman-alpha forest photoionization scaling giveswhere $n_{\mathrm{H}}$ counts all hydrogen nuclei, $\Gamma$ is the photoionization rate, $\alpha (T)$ is the radiative recombination coefficient and $x_{\mathrm{HI}}=n_{\mathrm{HI}}/n_{\mathrm{H}}$ is the neutral fraction. At fixed temperature and $\Gamma$, doubling $n_{\mathrm{H}}$ quadruples $n_{\mathrm{HI}}$; doubling $\Gamma$ halves it. These computed examples explain both the sensitivity to density contrast and the ambiguity: stronger absorption can mean denser gas, weaker ionizing radiation, a different temperature, or more path length. The Jeans-length ionization correction for the Lyman-alpha forest adds a size model rather than an independently measured depth. Optically thick Lyman limit systems and damped Lyman-alpha systems require different treatment. ^[ref]. ^[ref].

The beauty of the Lyman-alpha forest is that a spectrum converts otherwise faint foreground gas into a sequence of markers through cosmic time. With a model of radiative transfer, velocities, ionizing radiation and the temperature-density relation of photoionized intergalactic gas, its transmission statistics probe the cosmic web and gas thermal history. A single line of sight remains one narrow sample, not a unique three-dimensional density map. ^[ref].

The Maxwell-Boltzmann distribution describes the random velocities and speeds of particles in a classical ideal gas at thermal equilibrium. Individual particles keep changing velocity through collisions, while the equilibrium probability distribution stays fixed. For one species of particle mass $m$ at positive temperature $T$, the characteristic scale iswhere $k_B$ is the Boltzmann constant. A signed velocity component follows a normal distribution; the nonnegative magnitude follows the Maxwell speed distribution. Their peaks differ because a speed measurement groups together all directions of motion.

Use the gas rest frame, three spatial dimensions, and nonrelativistic particles, with $k_{B}T\ll m{c}^2$ where $c$ is the speed of light. Assume a dilute gas whose interactions between encounters can be neglected in the ideal gas approximation and whose translational motion is classical. A sufficient condition for negligible quantum exchange effects is $n{\lambda }^3\ll 1$, where $n$ is the number density and $\lambda$ the thermal de Broglie wavelength. Diluteness alone does not guarantee thermal equilibrium; the gas must have equilibrated. These are the assumptions behind the classical Maxwell-Boltzmann velocity distribution. ^{[ref] [ref]}

The connection to Maxwell–Boltzmann statistics is the Boltzmann factor for translational kinetic energy, $E_{\mathrm{kin}}=m|\mathbf{v}{|}^2/2$. Normalizing $e^{-E_{\mathrm{kin}}/(k_{B}T)}$ over velocity gives a probability density; an occupation factor $e^{(\mu -E)/(k_{B}T)}$ instead specifies a mean occupation, with chemical potential $\mu$. Their normalizations serve different purposes. ^[ref]

This connects microscopic motion to measurements: a gas thermometer uses the ideal gas law, collisions and the mean free path govern transport, and measurements of spectral lines use thermal Doppler broadening to infer temperature. Each probes a different aspect of the same thermal motion.

In 1860, James Clerk Maxwell presented the component and speed laws in Part I, Proposition IV of Illustrations of the Dynamical Theory of Gases, pp. 22–23. His argument combined independence of the three velocity components with isotropy, and he explicitly compared the component law with the normal distribution of observational errors. Independence is an assumption of that argument; perpendicular coordinate axes alone do not establish it. ^[ref]

The Mayer f-function measures how a pair potential changes a pair's Boltzmann factor relative to the noninteracting value one:It vanishes where $u=0$, lies between $-1$ and $0$ for repulsion, and is positive for attraction. Even an infinite hard-core potential energy produces the finite value $f=-1$. This is why expanding in Mayer f-functions handles a hard-sphere gas more naturally than a Taylor series in $u$. ^[ref]

For pairwise-additive potential energy $U={\sum }_{i<j}u(r_{ij})$, the exact identityturns the configurational part of the canonical partition function into a sum of products associated with pairs. Drawing one edge for each chosen factor $f(r_{ij})$ gives the graphs used in the cluster expansion. The second virial coefficient uses just one pair's relative-position integral, $B_2=-\frac{1}{2}\int f{d}^3\mathbf{r}$.

For the square-well toy pair potential in second virial coefficient, $f=-1$ in the core, $f=e^{1/T^{\ast }}-1$ in the attractive shell, and $f=0$ beyond it. Its positive plateau need not be small: low number density, rather than small $f$ at every separation, controls the dilute-gas approximation. The integral weights each plateau by spherical-shell volume; equal-looking unweighted areas on a plot of $f$ versus $r$ need not cancel in $B_2$.

The mean free path is the average distance travelled between collisions. For dilute targets with number density $n$ and effective collision cross-section ${\sigma }_c$, $\ell \sim 1/(n{\sigma }_c)$; identical-particle conventions introduce factors such as $\sqrt{2}$.

Let $f_X={\partial }^2\mathcal{N}/(\partial N\partial X)$ count neutral hydrogen absorbers per column density and absorption distance. The summed column per unit proper light-path length is the mean neutral number density. Since $d\ell =cdz/[(1+z)H(z)]$ and $dX/dz=H_0(1+z{)}^2/H(z)$, that density is $(H_0/c)(1+z{)}^3\int N{f}_{X}dN$. Dividing the proper mass density by $(1+z{)}^3$ gives the comoving density in the displayed formula. The denominator is today's critical density; including neutral helium requires a stated mass correction. For a distribution per redshift, replace $H_0{f}_X$ by $H(z)f_z/(1+z{)}^2$.

For a dilute nonrelativistic gas with $x=m/T\gg 1$ and zero chemical potential, the Bose-Einstein distribution approaches the Maxwell-Boltzmann distribution. Expanding $E=m+p^2/(2m)+\cdots$ in the number density integral gives $n\sim g(mT/(2\pi ){)}^{3/2}{e}^{-x}$. Since $\rho =mn+3nT/2+\cdots$ and $P=nT$, the entropy density at zero chemical potential gives $s=n(x+5/2+\cdots )$ and hence the displayed leading expression. This includes the internal multiplicity $g$; a single real scalar field has $g=1$.

The number current is $J^a=n{u}^a$, where $n$ is the rest-frame number density and $u^a$ the unit four-velocity. Its covariant continuity equation is ${\nabla }_a{J}^a=0$, equivalently $u^a{\nabla }_{a}n+n{\nabla }_a{u}^a=0$. Integration over a spacetime volume and the divergence theorem equate the particle numbers crossing its boundary. This conservation law is separate from stress-energy conservation.

For the spherical Abel deprojection, put $A_r=r^2+b^2$ and $s=(R^2+b^2)/A_r$. Then $d{R}^2=A_{r}ds$ and $\sqrt{R^2-r^2}=A_r^{1/2}\sqrt{s-1}$. Consequently the integral appearing in the reconstruction of $n$ isDifferentiate before substituting the numerical value of $I_{5/2}$:For the projected second stellar velocity moment, $N{\sigma }^2=N_0{\sigma }_0^2{b}^6(R^2+b^2{)}^{-3}$. The identical substitution in isotropic stellar pressure deprojection givesFor completeness, setting $t=1/s$ yields $I_{\alpha }=B(1/2,\alpha -1/2)$, where $B$ is the Euler beta function. The Gamma function recurrence gives $I_{5/2}=4/3$ and $I_3=3\pi /8$. This also checks the normalization of the power-law spherical projection kernel.

The radial Jeans equation is $p^{\prime }=n{\psi }^{\prime }$. Since $p^{\prime }=-105N_0{\sigma }_0^2{b}^{6}r/(16A_r^{9/2})$, division by the tracer number density givesWriting $A=315\pi {\sigma }_0^{2}b/128$, the total gravitational acceleration is thereforeTo find all gravitating mass density, apply the Poisson equation for Newtonian gravity, with the same sign convention:Equivalently, the enclosed mass is $M(r)=A{r}^3/[G(r^2+b^2{)}^{3/2}]$, and ${\rho }_{\mathrm{tot}}=M^{\prime }/(4\pi r^2)$. The inferred total mass is $A/G$ and its relative potential is $A/\sqrt{r^2+b^2}$, a Plummer model. The tracer number density has a different radial exponent from this total mass density. One must not multiply $n$ by an arbitrary stellar mass and identify it with all matter: the inferred field can include unobserved stars, gas, and dark matter.

Use the same conserved-source interpretation, comoving number density $n_0$ and normalization $a_0=1$ as in the preceding part. DefineThe open matter-dominated Friedmann solution then has $a=C(\cosh u-1)$, $t=(C/\kappa )(\sinh u-u)$ and $dt=(C/\kappa )(\cosh u-1)du$. The present parameter satisfiesThe cosmological bolometric background from conserved sources is thereforeSince ${\cosh }^{2}u=(1+\cosh 2u)/2$, the open dust bolometric background integral isThis leaves the answer in the requested parameter form and makes no use of a radial-distance approximation. For arbitrary proper number density instead, the same calculation gives

For the conserved population, compare models with the same present $n_0,L,H_0$. As ${\Omega }_0\to 0$, $u_0\to \infty$ and $\cosh u_0\sim 2/{\Omega }_0$. The leading term in the square bracket is $\sinh (2u_0)/4\sim 2/{\Omega }_0^2$; the terms linear in $\sinh u_0$ and $u_0$ vanish after multiplication by ${\Omega }_0^2$. HenceThis is also immediate in the Milne model, for which $a=t/t_0$ and $t_0=H_0^{-1}$. If one compares at fixed cosmic age instead, the results are $L{n}_0{t}_0/2$ and $3L{n}_0{t}_0/5$, so the empty open model gives $5/6$ of the flat-model flux. Specifying what is held fixed is necessary because the two expansion histories have different ages at the same Hubble constant.

An isotropic source's bolometric luminosity is distributed over a wavefront of physical area $4\pi a_0^2{r}^2$. Each photon loses an energy factor $(1+z{)}^{-1}$ through cosmological redshift, and successive photons arrive with a further rate factor $(1+z{)}^{-1}$ through cosmological time dilation. Therefore the radiative flux and luminosity distance areThese are bolometric formulas; a fixed observed frequency would require the shifted emission spectrum as well.

Normalize the scale factor by $a_0=1$. Summing the radiative flux over the source counts on an FLRW past light cone makes the transverse shell-area factors cancel:Thus ${\mathcal{F}}_0$ is power per effective detector area, summed over the whole sky; an all-sky detector of effective area $A_{\det }$ receives $A_{\det }{\mathcal{F}}_0$. The corresponding intensity per solid angle is ${\mathcal{F}}_0/(4\pi )$. Restoring the speed of light multiplies these flux integrals by $c$.

Spatially uniform $n(t)$ by itself does not specify its time evolution. For a persistent population comoving with the expansion, with neither creation nor destruction, the cosmological continuity equation for source number is $\dot{n}+3Hn=0$. Its conserved comoving number density is $n_0=a^{3}n$, so the cosmological bolometric background from conserved sources becomes $L{n}_0\int adt$. For the Einstein-de Sitter universe,The last equality uses $H_0=2/(3t_0)$. The early-time improper integral converges despite the diverging physical source density. If instead the proper number density were maintained at a constant value $n_0$ by continuous source creation, the same geometry would give $3L{n}_0{t}_0/11$. For a completely unspecified source history the general integral above is the determined answer; constancy of individual luminosity alone does not imply number conservation.

Use units $c=1$, and let $r$ be the areal radial coordinate of the FRW metric, rather than the radial comoving distance when $k\ne 0$. On a constant-cosmic time slice the spatial metric tensor isThe determinant of the spatial metric tensor supplies the factor $(1-k{r}^2{)}^{-1/2}$. Integrating over the solid angle gives $d{V}_{\mathrm{shell}}=4\pi a^3{r}^2|dr|/\sqrt{1-k{r}^2}$. An incoming radial null geodesic obeysConsequently the proper shell volume sampled by an emission-time interval of positive width $dt$ is $4\pi a^2{r}^{2}dt$. Multiplying by the proper number density proves the source counts on an FLRW past light cone:Here $r(t)$ is evaluated on the observer's past light cone, not along a fixed source worldline. The curvature factor cancels between the spatial volume and the radial light speed; it has not been set to one.

Cosmic inflation addresses the horizon problem by extending the causal past of the observed region, the flatness problem by damping the curvature contribution, and the cosmological monopole problem by diluting unwanted relics. A canonical inflaton can drive this expansion when its potential energy density exceeds twice its kinetic energy density.

Use the unreduced Planck mass $m_P=G^{-1/2}$, consistent with the coefficient in the Friedmann equation, and take $V_0>0$, $c\ne 0$. Seek the exponential-potential power-law inflation solution $\varphi =A\log (\beta t)$ and $a=a_{\ast }(t/t_{\ast }{)}^p$. The kinetic energy density is proportional to $t^{-2}$. The inflaton potential must have the same scaling, soSubstitution into the inflaton equation of motion givesThe Friedmann equation now reduces toConsequently the nontrivial positive-potential solution isA positive $V_0$ requires $p>1/3$. Accelerating expansion occurs exactly for $p>1$, givingThis is an exact solution, not a use of the slow-roll approximation. The first Hubble slow-roll parameter and equation-of-state parameter are constant:If the reduced Planck mass $M=m_P/\sqrt{8\pi }$ is used instead, the dimensionless exponential slope is $\lambda =c/\sqrt{8\pi }$ and the exponent becomes $p=2/{\lambda }^2$; these are the same solution.

For $p>1$, the comoving Hubble radius decreases as $(aH{)}^{-1}\propto t^{1-p}$. A region initially in causal contact can grow beyond that radius before the hot radiation-dominated universe begins. In the ideal power law extrapolated all the way to $t=0$, the particle horizon integral ${\int }_0^{t}d{t}^{\prime }/a(t^{\prime })$ diverges, so the solution has no finite past particle horizon. A finite, physically trustworthy inflationary interval instead requires a sufficiently large number of e-folds to enlarge an initially causal patch.

For a small curvature contribution, the Friedmann equation gives $|\Omega -1|=|k|/(a^2{H}^2)\propto t^{2-2p}\to 0$, solving the flatness problem. Conserved nonrelativistic magnetic monopoles have number density proportional to $a^{-3}$, while the inflaton energy density is proportional to $t^{-2}$; their energy-density ratio therefore falls as $t^{2-3p}$. This gives the required dilution, provided later reheating does not recreate them. Inflationary shear damping similarly suppresses anisotropic expansion.

The main failure is no automatic graceful exit or reheating. The first Hubble slow-roll parameter never reaches one, and the exponential inflaton potential has no finite minimum about which the field can oscillate. Additional dynamics are needed for a graceful exit from inflation and transfer to a hot radiation-dominated universe. The ideal solution also retains a curvature singularity at $t=0$; solving the horizon problem does not itself explain the beginning of the universe. For $c=0$, the constant inflaton potential instead permits constant-field de Sitter spacetime expansion; the logarithmic field solution is inapplicable.

The event rate counts unordered pairs of reacting nuclei. For unlike species there are $n_i{n}_j$ pairs per unit-volume normalization; for identical species there are approximately $n_i^2/2$ pairs, since counting ordered pairs counts each collision twice. The Kronecker delta therefore supplies exactly the required divisor $1+{\delta }_{ij}$. It is the event rate, not the destruction rate of identical nuclei: one identical-pair reaction destroys two nuclei.

The temperature dependence combines the high-energy tail of the Maxwell-Boltzmann distribution with quantum tunnelling through the Coulomb barrier. The principal exponential factor in the energy integral is $\exp [-E/(k_{B}T)-b/\sqrt{E}]$. Its stationary point, the Gamow peak, has $E_0\propto T^{2/3}$ and exponent $\eta =3E_0/(k_{B}T)\propto T^{-1/3}$. Integrating around this peak gives a prefactor proportional to $T^{-2/3}$, or ${\eta }^2$, when the nuclear factor varies slowly. Thus the supplied thermonuclear reaction rate is locally proportional to ${\eta }^2{e}^{-\eta }$. The slow weak interaction in the proton-proton reaction also makes its overall coefficient very small; its local thermal slope follows the supplied formula.

At fixed number densities, define the local temperature exponent of a thermonuclear reaction by a logarithmic derivative. Since $d\eta /d\log T=-\eta /3$,For proton-proton reactions, $A=1/2$ and $Z_1=1$. At $T_6=15$, ${\eta }_{11}=13.67$ and $\alpha =3.89$. For two helium-3 nuclei, $A=3/2$ and $Z_3^2{Z}_3^2=16$, giving ${\eta }_{33}=49.68$ and $\beta =15.89$. For helium-3 with helium-4, $A=12/7$ and the same charge product gives ${\eta }_{34}=51.95$ and $\gamma =16.65$. HenceThese are local powers near the specified temperature, not constant exponents over an arbitrarily large range. The greater reduced nuclear mass in the $34$ reaction increases its tunnelling exponent and its thermal sensitivity.

For the effective proton-proton reaction network, denote the event rates byThe short-lived beryllium intermediate can be eliminated, so production through $R_{34}$ feeds $n_7$, representing predominantly lithium-7. This rapid conversion is electron capture. Count the nuclei consumed and produced in each reaction: $11$ consumes two protons and makes one deuterium; $21$ consumes a proton and a deuterium and makes one helium-3; $33$ consumes two helium-3 and makes one helium-4 and two protons; $34$ consumes one of each helium isotope; $17$ consumes a proton and lithium-7 and makes two helium-4. It follows thatFor closure, ${\dot{n}}_7={\lambda }_{34}{n}_3{n}_4-{\lambda }_{17}{n}_1{n}_7$. These nuclear terms conserve $n_1+2n_2+3n_3+4n_4+7n_7$, providing an independent stoichiometric check. They describe a fixed local volume; compression or mixing would add transport terms.

The roughly one-second destruction time of deuterium is negligible compared with the proton-burning and helium-3 evolution times. Its abundance rapidly adjusts to the slowly evolving production rate. Set ${\dot{n}}_2\simeq 0$, giving the deuterium quasi-equilibrium in proton-proton burningSubstitution, without setting ${\dot{n}}_1=0$, givesThe helium-3 relaxation time of about $6\times 10^5$ years is likewise short compared with the central proton-burning time and the age of the Sun. On this relaxation time the proton and helium-4 abundances, and the background temperature, can be treated as fixed. Put $A={\lambda }_{33}$, $B={\lambda }_{34}{n}_4$, $C={\lambda }_{11}{n}_1^2/2$. Then ${\dot{n}}_3=C-A{n}_3^2-B{n}_3$, and its nonnegative equilibrium isThe other root is negative and unphysical. Write $n_3=n_{3e}+x$ and subtract the equilibrium equation. Exactly, for a fixed background,Dropping the quadratic displacement givesThus small displacements decay exponentially. A slowly moving equilibrium introduces an additional $-{\dot{n}}_{3e}$ term, negligible to leading order when $\tau$ is short compared with background evolution.

To estimate the temperature for helium-3 freeze-out, use the cooler pp-I-dominated region and neglect $B$ compared with $2A{n}_{3e}$. Then $n_{3e}\simeq n_1\sqrt{{\lambda }_{11}/(2{\lambda }_{33})}$ and ${\tau }^{-1}\simeq n_1\sqrt{2{\lambda }_{11}{\lambda }_{33}}$. With the local powers just obtained and fixed proton number density, $n_{3e}\propto T^{-6}$ and $\tau \propto T^{-10}$. Adopting $t_{\odot }\simeq 4.6\times 10^9\mathrm{yr}$ givesThis is an order-of-magnitude extrapolation of local exponents. Keeping the supplied exponential factors gives the helium-3 freeze-out estimate with Gamow factorswhich yields about $6.8\times 10^6\mathrm{K}$ with the same normalization and fixed-density approximation. Thus the robust estimate is several million kelvin. The supplied data do not fix the local density, composition or pp-II fraction away from the centre, so they cannot determine an exact transition temperature or radius. In particular, using $\tau \propto T^{-16}$ alone would omit the temperature dependence of the equilibrium helium-3 abundance.

The solar hydrogen and helium-3 abundance profiles follow from burning, finite equilibration time and convection. Central hydrogen has been consumed, so $X_1$ is lowest in the centre and increases toward its much less processed outer value. In the hot centre, rapid destruction keeps helium-3 small. Moving outward initially raises its equilibrium abundance because ${\lambda }_{11}/{\lambda }_{33}$ rises strongly as temperature falls. Further out, equilibration is no longer reached within the solar age, and still farther out even production is slow. Hence $X_3$ has an off-centre maximum and then declines toward its small outer abundance. The outer convective envelope mixes each abundance toward a constant value.

The sketch shows these qualitative shapes; the helium-3 ordinate is scaled to its own maximum. The illustrated amplitudes, peak radius and envelope boundary are schematic, not a numerical solar-model solution.

The factor called $N$ in the formula must be the stellar number density $n$, not a dimensionless count. Indeed ${\sigma }^3/(G^2{m}^2)$ has dimensions time per volume, so a density in the denominator is essential. If $N_{\ast }$ is the population in a representative volume $V$, then $n=N_{\ast }/V$.

For a weak encounter between equal-mass stars, let $u$ be the asymptotic relative speed and $b$ the impact parameter. In the straight-line impulse approximation, one star's transverse kick isThe other receives the opposite kick, so the relative-velocity change is $\Delta u_{\perp }=4Gm/(bu)$. Encounters in $(b,b+db)$ occur at rate $2\pi bdbnu$. Independent random kicks add in squared magnitude, givingThis is the random-walk derivation of stellar relaxation. The Coulomb logarithm in stellar dynamics is $\ln \Lambda =\ln (b_{\max }/b_{\min })$. The upper cutoff is the size or inhomogeneity scale beyond which independent local encounters are inappropriate. The lower cutoff is of order the strong-deflection scale $G(2m)/u^2$, or a larger stellar-size/softening scale if applicable. A self-gravitating system commonly has $\Lambda$ of order its total number of stars; that population count is distinct from $n$ in the diffusion rate.

To state the numerical convention explicitly, use representative encounter speed $u=\sqrt{2}\sigma$ and define the relaxation estimate from the relative-velocity diffusion rate with reference squared velocity $3{\sigma }^2$. This givesThis recovers the printed coefficient under a specified convention. There is no convention-independent exact numerical prefactor determined by a representative one-dimensional velocity alone. Using the single-star diffusion rate with the same $3{\sigma }^2$ reference instead gives four times this time; averaging over a full velocity distribution also changes the prefactor. The relaxation time conventions in stellar dynamics must therefore distinguish single-star and relative kicks. The physical scaling is $T_R\propto {\sigma }^3/(n{G}^2{m}^2\ln \Lambda )$, and the printed $N$ must be interpreted as number density.

There is a genuine flux typo in the original PDF. A received bolometric radiative flux must have inverse-square luminosity distance, so the physically consistent thermal bremsstrahlung expression is $S_X\propto d_L^{-2}\int n_e^2{T}_e^{1/2}dV$. The printed single power of $d_L$ cannot imply the requested Hubble constant scaling.

For an approximately uniform, spherical galaxy cluster let its depth be $\ell =q\theta d_A$, where $q$ is a fixed geometrical factor. With fixed profile coefficients $A,B$, the Rayleigh-Jeans law limit of the thermal Sunyaev-Zeldovich effect and the bolometric X-ray radiative flux giveEliminate the electron number density and use $d_L=(1+z{)}^2{d}_A$:The cluster distance from Sunyaev-Zeldovich and X-ray signals is consequentlyAt low cosmological redshift, $d_A\simeq cz/H_0$, sowhen the other observables and profile parameters are held fixed. With the PDF's literal $d_L^{-1}$ instead, $S_X/D^2\propto \ell /(T_e^{3/2}{d}_L)=q\theta /[T_e^{3/2}(1+z{)}^2]$, independent of distance: this explicitly shows why the correction is necessary.

Real galaxy clusters are neither uniform nor generally spherical. The inferred depth depends on the ratio of line of sight depth to transverse extent; elongation and orientation selection therefore bias the distance. density clumps enhance X-ray emission, which weights $n_e^2$, more than the thermal Sunyaev-Zeldovich effect, which weights $n_e$. An unmodelled gas clumping factor greater than one makes the inferred distance too small and the inferred Hubble constant too large in this simple model. Temperature gradients and multiple thermal components bias the X-ray spectral temperature relative to the pressure-weighted Compton y parameter. Metals alter the cooling spectrum, and finite X-ray bands require a spectral and redshift correction to the bolometric approximation. Relativistic thermal corrections, the kinetic Sunyaev-Zeldovich effect, radio sources and primary Cosmic microwave background anisotropy contaminate the signal. Finally, calibration, angular-profile fitting and low-redshift peculiar velocities affect the observables and the relation between measured redshift and expansion distance.

Define neutral-hydrogen column density along a ray by $N=\int n_{\mathrm{HI}}d\ell$, in atoms per unit area. The neutral-hydrogen column-density distribution per redshift isso $f_{z}dNdz$ is the expected number of absorbers in those intervals along one sightline. A logarithmic column bin instead has distribution $N\ln (10)f_z$; the bin convention must be specified.

Let $n_c$ be a constant comoving number density and ${\sigma }_p$ a constant physical interception area. The corresponding physical number density is $n_p=n_c(1+z{)}^3$. Proper light-path length satisfies $d\ell =c|dt|=cdz/[(1+z)H(z)]$. The expected intersection count, or first-order probability in infinitesimal $dz$, is thereforeThe Friedmann equation, the constant-equation-of-state density scaling for pressureless matter, and the present cosmological density parameters giveCombining them yields the absorber incidence and comoving number density relationHere the constant cross-section is physical, as required for this result; a fixed comoving cross-section would instead decrease in physical area as $(1+z{)}^{-2}$. It is convenient to define absorption distance by $dX/dz=(H_0/H(z))(1+z{)}^2$ and $f_X=f_z/(dX/dz)$, so a population with these non-evolution assumptions has constant incidence per $X$.