Chemical kinetics 2026-10-13
Chemical kinetics studies how quickly chemical reactions proceed and how their reaction rates depend on composition and conditions. It connects a measured change in concentration to a rate law, then uses a rate equation to predict future concentrations. This makes it useful for choosing how long to wait for conversion and for testing a proposed reaction mechanism. Changing temperature, reactant concentrations, or the presence of a catalyst can change reaction rates; see Flowers et al., Chemistry 2e, §12.2: factors affecting reaction rates.
Chemical equilibrium specifies the eventual balance under given constraints; chemical kinetics determines how rapidly it is approached. At fixed temperature and pressure, a decrease in Gibbs free energy favours conversion but does not guarantee a fast chemical reaction: reaching a transition state can require crossing a substantial barrier. Thus a mixture can change imperceptibly over an observation period without being at chemical equilibrium. The distinction separates which direction is favoured from how long conversion takes. See 12.5 Collision Theory (§12.5: collision theory and reaction barriers) and Chemistry 2e, §16.1: spontaneity and speed.
Rate law 2026-10-14
A rate law specifies how a reaction rate depends on concentrations under stated conditions. A common form is
where is a rate constant and the exponents are partial orders of reaction. Determine them experimentally, or derive them from a justified reaction mechanism. Do not infer and from the net chemical equation: its coefficients describe consumption ratios, whereas the exponents describe sensitivity to concentration. See IUPAC Gold Book: rate law and Flowers et al., Chemistry 2e, §12.3: rate laws.
A rate law becomes a prediction of time evolution when combined with stoichiometry in a rate equation, for example . Agreement with a measured rate law is useful evidence for a reaction mechanism, but several routes can give the same dependence.